• Korean Journal of Materials Research
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• v.7 no.10
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• pp.898-907
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• 1997

Fe-22Cr-5AI-X(X=Zr, Y)합금을 1143K, 고온 황화(P$s_{2}$=1.11x$10^{-7}$atm, P$O_{s}$ =3.11x$10^{-20atm}$) 및 황화/산화 (P$s_{2}$=8.31x$10^{-8}$atm, P$O_{s}$ =3.31x$10^{-18atm}$) 환경의 복합가스 분위기에서 1-30시간동안 노출하여 합금표면에 형성된 부식층을 관찰하여 SEM/EDS로 분석하였다. Fe-22Cr-5AI합금은 고온 부식환경에서 부식 생성물의 성장은 포물선법칙을 따르고 주요 성분은 결함이 많고 다공질인 철과 크롬의 황화물[(Fe, Cr)Sx]이므로 고온 내식성이 감소하였다. Zr을 1wt%첨가한 Fe-22Cr-5AI합금의 고온 부식거동은 Y을 1wt%첨가한 합금과 비슷한 거동을 나타내었다. 황화환경에서는 Cr의 선택 황화에 의한 크롬 황화물(CrS)이 생성되고 노출시간의 경과에 따라 (Fe, Cr)Sx나 (Cr, Fe)Sx 등의 황화물의 성장으로 고온 내식성이 감소하였다. 그러나 황화/산화환경에서는 초기에는 알루미늄산화물(A $I_{2}$ $O_{3}$)및 지르코늄산화물(Zr $O_{2}$)등이 생성되어 보호적이었으나 15시간이후 부터 (Fe, Cr)Sx나 (Cr, Fe)Sx 의 황화물의 성장으로 고온 내식성이 감소하였다.

• Journal of Environmental Health Sciences
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• v.17 no.1
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• pp.39-49
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• 1991

고온에서 황화수소(H$_{2}$S)를 제거하기 위한 흡착제를 개발할 목적으로 ZnO에 $Fe_{2}O_{3}$를 5~50 atomic %까지 첨가시켜 제조한 다공성 흡착제와 황화수소와의 반응(sulfidation)을 thermogravimetric analyzer (Shimadzu DT-30)로 수행하였으며, 고정층세서 zinc ferrite 흡착제의 흡착능을 측정하였다. 반응온도는723$^{\circ}$K~973$^{\circ}$K범위이며, 반응기체는 황화수소(2vol.%)와 질소와 혼합기체로서 total gas flow rate는 200ml/min으로 고정시켰다. Grain Model을 사용하여 실험데이터를 분석한 결과 전화율이 낮을 때 zinc ferrite와 황화수소 반응의 율속단계는 화학반응이었고 황화수소 농도에 대해 1차 반응이었다. 실험한 흡착제 중 10 atomic %의 $Fe_{2}O_{3}$를 첨가하여 제조한 zinc ferrite형 흡착제가 반응속도, 흡착능, 그리고 재생성면에서 우수한 흡착제로 밝혀졌다.

• Journal of the Korean Vacuum Society
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• v.4 no.2
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• pp.150-155
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• 1995

Mo 단결정 표면에 황을 흡착시켜 형성된 상층구조를 AES와 LEED로써 연구하였다. 황의 피복률은 sulfur gun으로부터 생성되는 S2 flux로써 조절하였으며, 여러 가지 흡착된 황의 상층구조를 LEED로써 관찰하였다. 황화된 Mo 표면에서 탈산소반응(HDO)의 모델 분자로서, Furan의 흡착과 반응을 승온반응분광법(TPRS)으로 조사하였다. 낮은 온도에서 Furan 분자의 헤테로 원자는 직접 이탈하여 안정한 기체상의 반응 생성물인 일산화탄소를 형성하였으며, 이 반응은 Mo의 (100) 및 (110)면에서 각각 깨끗한 표면 및 황화된 표면에 관계없이 일어났다. 이를 바탕으로 Mo 표면에서 Furan의 분해반응에 대한 메카니즘을 제안하였다.

• Journal of Soil and Groundwater Environment
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• v.13 no.1
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• pp.24-31
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• 2008

Sulfate reducing bacteria (SRB) is universally distributed in the sediment, especially in marine environment. SRB reduce sulfate as electron acceptor to hydrogen sulfide in anaerobic condition. Hydrogen sulfide is reducing agent enhancing the reduction of the organic and inorganic compounds. With SRB, therefore, the degradability of organic contaminants is expected to be enhanced. Ferrous iron reduced from the ferric iron which is mainly present in sediment also renders chlorinated organic compounds to be reduced state. The objectives of this study are: 1) to investigate the reduction of TCE by hydrogen sulfide generated by tht growth of SRB, 2) to estimate the reduction of TCE by ferrous iron generated due to oxidation of hydrogen sulfide, and 3) to illuminate the interaction between SRB and ferrous iron. Mixed bacteria was cultivated from the sludge of the sewage treatment plant. Increasing hydrogen sulfide and decreasing sulfate confirmed the existence of SRB in mixed culture. Although hydrogen sulfide lonely could reduce TCE, the concentration of hydrogen sulfide produced by SRB was not sufficient to reduce TCE directly. With hematite as ferric iron, hydrogen sulfide produced by SRB was consumed to reduce ferric ion to ferrous ion and ferrous iron produced by hydrogen sulfide oxidation decreased the concentration of TCE. Tests with seawater confirmed that the activity of SRB was dependent on the carbon source concentration.

• Journal of the Mineralogical Society of Korea
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• v.19 no.3 s.49
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• pp.139-151
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• 2006

Base metal sulfides occur in the Huronian sedimentary rocks that cover the Archean volcanic rocks in the Cobalt area, Ontario, Canada. They are mostly concentrated in the basal conglomerate which was formed in the pre-Huronian basin structure. Sulfide occurrence can be grouped as massive sulfide clasts in the basal and Coleman conglomerate, disseminated sulfides throughout the sediments, and disseminated sulfides near Ag-Co-Ni-As carbonate veins. Detrital mechanism can explain features such as angularity of sulfide fragments and graded bedding of dissemnated sulfides. Sulfides concentrated near carbonate veins are probably of hydrothermal origin. Nearby strata-bound type massive sulfide ore deposits and mineralized interflow units are the most probable sources for syngenetic sulfides. This is supported by the angularity of sulfide fragments, presence of massive sulfide boulders which are identical in mineralogy and texture to the strata-bound type sulfide deposits in the Archean basement, and a similar composition of sphalerite in the Archean volcanic rocks and Huronian sedimentary rocks. Some sulfide grains, especially in sandstones and argillites, were undergone recrystallization during the intrusion of the Nipissing diabase.

• 한국해양학회지
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• v.28 no.3
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• pp.229-240
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• 1993

This study investigated the behaviour of sulfur species after the early diegenetic reduction of sulfate from pore solution in an anoxic intertidal flat deposit in the Banweol area of Kyeong-gi Bay, west coast of Korea. A total of seven sediment cores were collected during 1990∼1992 and were analyzed for their solid-phase sulfur species (acid-volatile sulfur, element sulfur, pyrite sulfur) as well as for chemical components in the pore solution, such as sulfate, ammonium, hydrogen sulfide, phosphate and Fe ion. The pore water sulfate oncentration was found to decrease rapidly downward from the sediment surface, while that of hydrogen sulfide, ammonium and phosphate showed and increase. The dissolved iron concentration in pore water, on the other hand, was found high in the surface layer of sediment, but fell sharply below this layer. these characteristic profiles of pore water sulfide and iron concentrations suggest that some reaction occurs between dissolved iron and sulfide ions, leading to the formation of various sulfide minerals in the sedimentary phase. The amount of inorganic sulfur species in the sediment increased downward, and showed a maximum of up to 7.9 mg/g. among the three species analyzed, acid-volatile sulfur (AVS) was dominant comprising more than 50% of the total. The amount of pyrite sulfur was greater than that of element sulfur. This implies that the formation of pyrite was restricted in this environment. the limited amount of element sulfur in this deposit may have discouraged the active formation of pyrite.

• Textile Coloration and Finishing
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• v.2 no.1
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• pp.44-67
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• 1990

오늘날 셀룰로오스 염색은 단지 5가지의 염료들이 사용되고 있다. Table 1에서와 같이 황화염료 및 직접염료가 세계적으로 가장 보편적으로 사용되고 있다. 그러나 선진국에서는 지난 수년간에 걸쳐 황화염료 및 디아조 염료의 사장점유율의 현저한 감소와(Table 2,3) 반응성 염료의 사장점유율의 증가가 있었다. 오늘날 사용되는 염료 분류는 3가지의 상이한 염색원리로 섬유에 적용된다.(중략)

• Journal of Environmental Health Sciences
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• v.14 no.1
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• pp.1-9
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• 1988

석탄유도가스에 포함된 황화수소를 제거시킬 흡착제를 개발하기 위하여 알칼리 토금속, 천이원소 및 아연의 이온반경보다 이온반경이 작은 금속산화물을 산화아연에 첨가시켜 다공성 흡착제를 제조하였다. 600$\circ$C에서 이들 첨가시료를 2.09vol.% 황화수소와 질소가스 혼합기체로 반응시켜 초기속도를 측정하고, 같은 온도에서 사용된 흡착제를 공기로 재생시켰다. 사용된 금속산화물 첨가 흡착제중에서 CaO, TiO$_2$, $Fe_2O_3$, CuO, $Ga_2O_3$ 및 Si$_2$O가 ZnO 흡착제의 초기속도를 증가시켜 첨가제로 사용할 수 있음을 보였다.

• Korean Journal of Microbiology
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• v.40 no.2
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• pp.127-132
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• 2004

We isolated 50 strains from sludge of wastewater treatment aeration tank using selective medium for Thio-bacillus sp. by membrane filtration method. They were identified as Thiobacillus neapolitanus (7), T. tepidarius (4), T. dientrificans (5), T. versutus (23), T. intermedius (2) and T. perometabolis (9). We selected Thiobacillus versutus strain KT51, which had the highest removal efficiency (100％) of hydrogen sulfide and the highest removal efficiency (85％) of dimethyl sulfide for 30 min in screen test. Also Thiobacillus versutus strain KT81 had the highest removal efficiency (26％) of dimethyl disulfide for 30 min in screen test. In applification of lab-scale reactor (closed-biological treatment) using Thiobacillus versutus strain KT51, results were 99.8％ (＜0.02 ppm) removal efficiency of hydrogen sulfide for 15 min.

• Clean Technology
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• v.20 no.4
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• pp.367-374
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• 2014

Several experiments have been done to investigate the removal of hydrogen sulfide ($H_2S$) synthetic gas from biogas streams by means of chemical absorption and chemical reaction with 0.1-1 M Fe/EDTA solution. The roles of Fe/EDTA were studied to enhance the removal efficiency of hydrogen sulfide because of oxidizing by chelate. The motivation of this investigation is first to explore the feasibility of enhancing the toxic gas treatment in the biogas facility. The biogas purification strategy affords many advantages. For instance, the process can be performed under mild environmental conditions and at low temperature, and it removes hydrogen sulfide selectively. The end product of separation is elemental sulfur, which is a stable material that can be easily disposed with minor potential for further pollution. As the Fe-EDTA concentration increased, the conversion rate of hydrogen sulfide increased because of the high stability of Fe-EDTA complex. pH as an important environmental factor was 9.0 for the stability of chemical complex in the oxidation of hydrogen sulfide.