• Title/Summary/Keyword: 황의만

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동아시아 장거리 오염물질 이동에 대한 한.중.일 모델링 결과 비교분석

  • Son, Hye-Yeong;Kim, Cheol-Hui;Lee, Tae-Yeong;Jo, Nam-San
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2008.11a
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    • pp.79-81
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    • 2008
  • 동아시아 지역의 대기오염물질의 장거리 이동에 대한 한중일 3국의 모델링의 결과를 비교 분석한 결과, 일본의 경우 한국에서 사용한 모델링의 결과보다 SO$_2$와 SO$_4$ 농도장 모두 과소평가되어 나타남을 볼 수 있었다. 이는 각 나라마다 모델에 적용한 기상장이 다르고, 서로 다른 모델을 사용하였기 때문에 차이가 나는 것으로 판단된다. 추후 중국의 모델링 결과도 함께 분석하여 보다 정확한 모델의 검정을 할 것이며, 황의 침적량에 대한 영향도 분석할 예정이다.

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Influence of Sulfur in Melting and Solidification of Stainless Steel Weld Pool (스테인레스강의 용접 풀(Pool)에서 용융 및 응고시의 황의 영향)

  • 김원훈;나석주
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 1998.04a
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    • pp.33-33
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    • 1998
  • 용접 공정은 우주 항공 산업 분야에서 금속 구조물의 확실한 기밀 보장을 위해 필수적인 매우 중요한 공정 중의 하나로서 특히 새로이 개발되는 비강도가 높은 신소재의 경우일수록 그 재료에 대한 용접성이 주요 해결 과제이다. 용접 공정에서 모재는 국부적으로 용융 온도 이상으로 가열되었다가 급히 냉각되기 때문에 열 사이클은 용접부의 크기, 형상 및 용접 공정에 따라 큰 차이를 보이며, 제품 품질에 큰 영향을 끼치고 있다는 것은 널리 알려진 사실이다.

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Bio-dissolution of waste of lithium battery industries using mixed acidophilic microorganisms isolated from Dalsung mine (달성 광산(鑛山)에서 채취(採取)한 혼합(混合) 호산성 균주를 이용(利用)한 폐리튬 밧데리의 바이오 침출(浸出))

  • Mishra, Debaraj;Kim, Dong-Jin;Ahn, Jong-Gwan;Ralph, David E.
    • Resources Recycling
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    • v.17 no.2
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    • pp.30-35
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    • 2008
  • Mixed acidophilic bacteria were approached for leaching of cobalt and lithium from wastes of lithium ion battery industries. The growth substrates for the mixed mesophilic bacteria are elemental sulfur and ferrous ion. Bioleaching of the metal was due to the protonic action of sulfate ion on the metals present in the waste. It was investigated that bioleaching of cobalt was faster than lithium. Bacterial action could leach out about 80 % of cobalt and 20 % of lithium from the solid wastes within 12 days of the experimental period. Higher solid/liquid ratio was found to be detrimental for bacterial growth due to the toxic nature of the metals. At high elemental sulfur concentration, the sulfur powder was observed to be in undissolved form and hence the leaching rate also decreased with increase of sulfur amount.

A Study of the Single Crystal Growth of $Ag_2S$ Mixed Conductor and it$s Characteristics (혼합 반도체 $Ag_2S$의 단결정 성장 및 특성에 관한 연구)

  • 김병국;신명균;윤종규
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.2 no.1
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    • pp.76-85
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    • 1992
  • ${\beta}-$Ag_2S$(high temperature phase) was grown by solid/vapour reaction growth based on solid -state electrochemisty. In S/V growth, one of the reactants, silver ion, is supplied to the growth surface through the solid $Ag_2S$ from one side and the other reactants, surfur, is transported in the phase of vapour from the other side. With the sufficient supply of S vapour, the growth rate increased as increasing $T_d$(decomposition temperature of $Ag_2S$) and ${\Delta}T$ between $T_d$ and $T_g$(temperature of growth surface). At low S vapour pressure, growth rate decreased with decreased vapour pressure and ${\beta}-$Ag_2S$ was grown in the form of whisker, when Ag+ion is sufficiently supplied. The measured values of electronic conductivity of ${\beta}-$Ag_2S$ showed that electronic conductivity of the poly crystal was larger than that of single crystal.

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An Analysis and Improvement of the Experiments for Comparing Properties of a Mixture with a Compound of Iron and Sulfur in the Middle School Science Textbooks (중학교 과학 교과서에 제시된 철과 황의 혼합물과 화합물 성질 비교 실험의 분석 및 개선)

  • Park, Kyong-Hee;Kang, Seong-Joo
    • Journal of the Korean Chemical Society
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    • v.51 no.1
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    • pp.93-100
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    • 2007
  • The purposes of this study were to analyze problems in the experiments for comparing properties of a mixture with a compound of iron and sulfur and then to suggest the improved experiments. For this study, the experimental methods in 9th science textbooks described were analyzed and middle school science teachers were asked to conduct the experiment according to the process of the textbook and to point problems of the experiment. Two alternative experiments, which improves the problems of the toxic and provocative experiment and of distinction between a mixture and a compound by magnetic properties, were proposed. The two experiments were applied to the 10 science teachers and 60 students from a “S” middle school. They responded that the experiments were suitable for comparing properties of a mixture and a compound and helpful to understand the concept.

The Effects of Sulfur on the Catalytic Reaction between Carbon Monoxide and Nitric Oxide on Polycrystalline Platinum Surface (다결정 백금표면에서의 일산화탄소와 일산화질소의 촉매반응에 미치는 황의 영향)

  • Park, Youn-Seok;Kim, Young-Ho;Lee, Ho-In
    • Applied Chemistry for Engineering
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    • v.1 no.2
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    • pp.215-223
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    • 1990
  • The effects of sulfur on the catalytic reaction between CO and NO on polycrystalline Pt surface, which is very important in the development of catalyst for automobile exhaust gas control, have been studied using thermal desorption spectrometry(TDS) under ultra-high vacuum(UHV) conditions. Sulfur weakened both the adsorptions of CO and NO by direct site blocking and indirect electronic effect. S(a) desorbing below 800 K gave little effect on reaction activity whereas S(a) desorbing above 800 K, which adsorbs as an atomic state, gave much effect on it. The adsorbed sulfur existed on the surface of platinum in the form of islands, and also reduced the adsorption energies of adsorbates by the long-ranged electronic effect. The platinum catalyst in the reaction between CO and NO was poisoned selectively by S(a), poisoning firstly the active sites of this reaction.

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Energy Recovery via Pyrolysis of Waste Tire Rubber : Desulfurization Effect of Pyrolysis Oil by Adding Waste Polypropylene (폐타이어의 열분해를 통한 에너지화 : 폐폴리프로필렌 첨가 시 열분해 오일의 탈황 효과)

  • Jeong, Jaeyong;Lee, Uendo;Chang, Wonseok;Oh, Munsei;Jeong, Soohwa
    • Journal of Energy Engineering
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    • v.26 no.3
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    • pp.97-104
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    • 2017
  • In this study, waste tire rubbers were pyrolyzed in a lab-scale pyrolysis plant equipped with a fluidized bed reactor in a temperature ranges of $450-650^{\circ}C$. The main object of this work is to investigate the properties of pyrolysis oil with reaction temperatures and the behavior of sulfur in the products when waste polypropylene was added for co-pyrolysis. The maximum yield of oil was about 52wt.% at the reaction temperature of $456^{\circ}C$. From GC-MS analysis, the pyrolysis oils consisted mainly of limonene, toluene, xylene, styrene, trimethylbenzene, methylnaphthalenes and some heteroatom(sulfur and nitrogen)-containing compounds. The addition of waste polypropylene resulted in decrease in sulfur contents of the pyrolysis oils.

A Study on the Antigastritic Effects of Rheum Species Extracts and Their Active Components (대황 추출물의 항위염 작용과 유효성분에 관한 연구)

  • Hwang, In Young;Jeong, Choon Sik
    • Journal of Food Hygiene and Safety
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    • v.28 no.4
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    • pp.330-336
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    • 2013
  • Rheum tanguticum has long been used in oriental medicine as antipyretics, analgesics, anti-inflammation, aperient, hypertension medicine and medicine for skin disease. This study has investigated the effectiveness of defense for gastritis making use of Rheum tanguticum and its similar plants, Rumex cripus, Rheum officinale, Rhem palmatum and Rheum undulatum. Chysophanol, chrysophanol-8-O-glc, Desoxyrhaponticin desoxyrhaponti-genin, emodin, isorhaponticin, 2-methoxy-4-hydroxyanthraquinone-5-O-glc, physcion, pirace-tannol-3'-O-glc, resveratrol, rhaponticin and rhapontigenin are used as the components of Rheum tanguticum. In HCl ethanol-induced gastritis in rat, the most effective extract was 70 percent ethanol which is of Rheum tanguticum, showing the inhibition of 91.8 percent to the gastric lesions. 70% ethanol extract of Rhem palmatum and Rumex cripus shown inhibition of 75.6 percent and 73.2 percent, respectively. This effectiveness is considered as acid-neutralizing capacity, anti-H.pylori and anti-oxidant activity. 70% ethanol extract of Rheum tanguticum and its component, piracetannol-3'-O-glc exhibited higher free radical scavenging activity than others. These results suggest that Rheum species extracts and their active components could be utilized for the treatment of gastritis. Furthermore, these results are expected to contribute the standardization with objectivity and reliability for Rheum species, medicinal herbs. In addition, it can contribute to the prevention of indiscriminate distribution of imitation, and the rising rate of dependence on imports of medicinal herbs, and mixing prevention of low-quality goods.

Nucleophilic Displacement at Sulfur Center (ⅩⅡ). Solvolysis of Dimethylsulfamoyl Chloride in Aqueous Binaries (황의 친핵성 치환반응 (제12보). 이성분 수용액에서의 염화디메틸술파모일의 가용매 분해반응)

  • Byong Choon Lee;Ikchoon Lee
    • Journal of the Korean Chemical Society
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    • v.24 no.5
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    • pp.342-346
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    • 1980
  • Rates and activation parameters have been determined for the solvolysis of N, N-dimethylsulfamoyl chloride in aqueous binaries of MeOH, EtOH, $(Me)_2CO$ and MeCN. Various solvent effect correlation showed that the solvolysis proceeded via the dissociative $S_n2$ mechanism.

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