• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.545-548
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• 2008

In this study aluminium sulfate, Ca(OH)$_2$, K-R Slag and $Na_2SO_4$ were used as active admixtures and their concentration 1, 3, 5, 7 weight percent in cement. The physical properties of active admixtures cement mortar were investigated by flow test and compressive strength. It was found that the resulting active admixtures exhibited the higher compressive strength than OPC mortar up. From the test results, cement mortars added active admixture have a good fundamental property.

• Journal of the Korea Institute of Building Construction
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• v.14 no.1
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• pp.37-44
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• 2014

Recently, many efforts related to the utilization of industrial by-products have been made to reduce carbon dioxide emissions in the construction industry. Of these various efforts, concrete incorporating ground granulated blast furnace slag (BFS) provides many advantages compared to conventional concrete, such as high long-term compressive strength, improved durability and economic benefits because of its latent hydraulic property, and low compressive strength at early curing age. This paper investigates the compressive strength of high-activated ground granulated blast furnace slag blended mortar with slag by-product S type(SBP-S). The results of the experiment revealed that incorporating high-activated ground granulated blast furnace slag would affect the compressive strength of mortar. It was found that increasing the Blaine fineness and replacement ratio of slag by-product S type shows high compressive strength of mortar at early curing age because of its high $SiO_2$ and CaO contents in the slag. It is confirmed that an increase of curing age does not affect the compressive strength of mortar made with slag by-product S type at a high curing temperature. Moreover, it is possible to develop and design concrete manufactured with high-activated ground granulated blast furnace slag as binder considering the acceleration curing conditions and mix proportions.

• Journal of Korean Society of Environmental Engineers
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• v.39 no.5
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• pp.303-309
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• 2017

This study investigated the potential use of steel slag (SS) (0.5~2.0 g/200 mL) for the removal of phosphate from wastewater compared with activated carbon (AC) (3.0~6.0 g/200 mL). The adsorption equilibrium data were best represented by Langmuir isotherm and its calculated maximum adsorption capacity was 91 mg/g for SS, 27 mg/g for AC. The adsorption kinetics was found to follow the pseudo-second order kinetics model and its rate constant was $0.0232{\sim}0.1357g/mg{\cdot}min$ for SS, $0.0247{\sim}0.1221g/mg{\cdot}min$ for AC. The overall uptake for the SS and AC was maximum at pH 2. Therefore, it can be concluded that steel slag could play an effective role in reducing phosphate concentration compared with activated carbon.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.7
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• pp.810-819
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• 2007

Investigation of alkali activation of fly ash and blast furnace slag was carried out using waterglass and sodium hydroxide. XRD, FTIR, $^{29}Si$ and $^{27}Al$ NMR, TGA and SEM were used to observed the reaction products and microstructure of the fly ash/slag cement (FSC) pastes. The reaction products were amorphous or low-ordered calcium silicate hydrate and aluminosilicate gel produced from alkali activation of blast furnace slag and fly ash, respectively. On the basis of this investigation, waterglass solution with a modulus(Ms) of 1.0 and 1.2 is recommended for alkali activation of fly ash and blast furnace slag. Morphology of FSC pastes alkali-activated with Ms of 1.0 and 1.2 shows a more solid and continuous matrix due to restructuring of gel-like reaction products from alkali-activated fly ash and blast furnace slag together with another hydrolysis product(i.e., silica gel) from water glass.

• Journal of the Korea Institute of Building Construction
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• v.10 no.5
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• pp.37-44
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• 2010

This study examined the practical application of ground granulated blast-furnace slag (GGBS) based alkali-activated (AA) binders for the development of cementless environmental-friendly secondary products of concrete, such as brick, shore protection blocks and interlocking blocks. The addition amount and type of alkaline ion to activate GGBS varied according to the diverse qualities of the secondary products of concrete required in Korean industrial standards (KS) and other specifications. Test results showed that the secondary products of concrete using GGBS-based AA binders surpassed the demanded capacities of KS and other specifications. In addition, shore protection block had a pH value close to neutral, enabling an advantageous environment for marine life. Therefore, the GGBS-based AA binders can be effectively applied to develop eco-friendly secondary products of concrete with reduced $CO_2$.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2015.07a
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• pp.218-219
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• 2015

Precast concrete produced in the industry is advantage that easy to manage, and it save construction period in the field. The specimens according to the type of activator for AAS(Alkali-Activated Slag) mortar cured in an autoclave. The specimens of AAS mortar with sodium was shown the high rate of increase of the compressive strength.

• Journal of the Korea Concrete Institute
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• v.24 no.5
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• pp.577-584
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• 2012

Carbonation resistance is one of the most influencing factors on durability of concrete. Alkali activated slag (AAS) is known to have weaker resistance for carbonation than OPC due to the low calcium contents. In this paper, the carbonation characteristic of AAS mortar which is related to the basicity (CaO/$SiO_2$) was investigated. In order to give the various basicity conditions, SM (source material) was blended with quicklime (CaO) and silicon dioxide ($SiO_2$) by adopting mechano-chemical treatment method. Experiments including flow test, compressive strength test, carbonation depth test, together with XRD, FTIR and TGA were employed to evaluate the effects of basicity of SM on the carbonation characteristics. The test results showed that the carbonation resistance effectively increased with the increase of the basicity of SM.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.4
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• pp.302-309
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• 2019

This paper shows an experimental study for fundamental characteristics of alkali activated fly ash-slag cement paste exposed to seawater of 5℃. Fly ash and slag were blended in three different ratios; 6:4, 7:3, and 8:2. Activators (NaOH and Na2SiO3) used 5% of the binder weight. It was shown that as the fly ash substitution rate in creased, compressive strength and density decreased, and water absorption rate increased. The results of X-ray diffraction and thermogravimetry showed that hydration reactants formed in samples did not differ significantly, however, C-S-H gel increased as the slag substitution rate increased. It showed that mechanical properties of fly ash-slag cement pastes under 5℃ seawater condition were affected by the slag substitution rate rather than fly ash.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.2
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• pp.63-69
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• 2012

Recently, the cement industries brought very severe environment problems such as resource depletion and global warming with massive carbon dioxide during its production. The number of cases using industrial by-products such as the ground granulated blast furnace slag (GGBFS) in concrete mixtures is increasing to resolve the environmental issue. GGBFS is mainly used in the range between 20 to 50% to replace cement, but nowadays lots of researches are carried out to develop the alkali-activated slag (AAS) concrete with no cement. In this study, the early age properties of alkali activated slag (AAS) mortar are investigated to obtain the fundamental data for AAS concrete application to structural members. The experimental variables were the water-binder ratios of 0.3, 0.4, and 0.5 and NaOH as the alkali activator of 4%, 8%, and 12% by the mass of GGBFS, and compressive strength, flow, setting time, and ultrasonic pulse velocity of AAS mortars were measured and analyzed. It is found from the test results that as the normal concrete the lower W/B, the higher compressive strength. However, superplasticizer has to be used for producing high strength AAS concrete because the workability of AAS mortar are significantly lowered.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.4
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• pp.114-121
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• 2010

Portland cement production is under critical review due to high amount of CO2 gas released to the atmosphere. Attempts to increase the utilization of a by-products such as fly ash and ground granulated blast-furnace slag to partially replace the cement in concrete are gathering momentum. But most of by-products is currently dumped in landfills, thus creating a threat to the environment. Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. However, most study deal only with alkali-activated ground granulated blast furnace slag or fly ash, as for the combined use of the both, little information is reported. In this study, we investigated the influence of mixture ratio of fly ash/ blast furnace slag tand curing condition on the flowability and compressive strength of mortar in oder to develop cementless alkali-activated concrete. In view of the results, we found out that the mixture ratio of fly ash/blast furnace slag always results to be significant factors. But the influence of curing temperature in the strength development of mortar is lower than the contribution due to other factors. At the age of 28days, the mixture 50% fly ash and 50% ground granulated blast furnace slag activated with 1:1 the mass ratio of 9M NaOH and sodium silicate, develop compressive strength of about 65 MPa under $20^{\circ}C$ curing.