• Applied Chemistry for Engineering
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• v.10 no.3
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• pp.349-353
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• 1999

A study was carried out to see the effects of phenol on the biological degradation of a wastewater containing 2,4-dichlorophenol and 2,4-dinitrophenol and the biodegradation kinetic coefficients of Eckenfelder's modified model for the activated sludge process. The system containing base mix (BM) which was formulated with essential energy sources and nutrients was run down and washed out when 2,4-dichlorophenol and 2,4-dinitrophenol was introduced into the base mix unit without acclimation to phenol. Whereas for the system acclimated to phenol, the treatment efficiency was 91.9% in terms of $BOD_5$ and treatability for each chemical of phenol, 2,4-dichlorophenol, and 2,4-dinitrophenol was 99.8%, 43.3% and 62.5% based on concentration, respectively. Additional BM was added into the combined unit containing phenol, 2,4-dichlorophenol, 2,4-dinitrophenol so that the better treatment efficiency was achieved for each compound. The biokinetic coefficient of Eckenfelder's modified model without phenol acclimation was not estimated because the system did not reach the steady state. Thc coefficient for the phenol acclimation was 12.44 /day, however it was changed as 46.91 /day in addition of both of phenol acclimation and 47 mg/l of BM. The results presented above could be useful for the process design and further study in the field of biodegradation of benzene derivatives.

• Magazine of the Korean Society of Agricultural Engineers
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• v.35 no.4
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• pp.67-75
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• 1993

This study was carried out to investigate the applicability of Solid Contact Process for the improvement of Moving Media Complete Mixing Activated Sludge(MMCMAS) effluents. Laboratory MMCMAS Reactor and MMCMAS/Solid Contact were operated at the hydraulic loading of 122~340 L/m$^2$/d. The conclusions from this study were as follows ; The addition of Solid Contact tank to the MMCMAS reactor has increased the SCOD and SBOD removal efficiencies of 4 to 67% and 2 to 41%, respectively. In addition, the increments of nitrification rates were about 13 to 46%. It was also observed that the addition of Solid Contact tank has greatly increased the organic removal efficiencies at the higher hydraulic loading rates and also decrement of sludge production rates was 0.1 gVSS/gBODrem. It was therefore concluded that the addition of Solid Contact tank could have polished the effluent of MMCMAS at the higher hydraulic loading rates.

• Journal of Korean Society of Water and Wastewater
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• v.26 no.6
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• pp.889-896
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• 2012

In this study, simulation results of nitrogen and phosphorus removals and microbial activities for an $A_2O$ process in wastewater treatment plant are presented by using Activated Sludge Models (ASMs). Simulations were performed using pre-calibrated model and layout implemented in GPS-X simulation software. The models were used to investigate variations of SRT, water temperature, DO and C/N ratio effect on nutrients removal and microbial activity. According to the simulated results, the successful nitrification required SRT higher than 10.3 days, whereas increase of $NO_3$-N loading in the anaerobic reactor caused phosphorus release by PAOs; the effluent $NH_4$-N showed rapid change between $12^{\circ}C$(21.7 mg/L) and $13^{\circ}C$(3.2 mg/L); the effluent phosphorus was increased up to 1.9 mg/L at water temperature of $25^{\circ}C$; the DO increase was positive for heterotrophs and autotrophs growths but negative for PAOs growth; the PAOs showed low activity when C/N ratio was lower than 2.5. The experimental results indicated that the calibrated models can assure the prediction quality of the ASMs and can be used to optimize the $A_2O$ process.

• Korean Chemical Engineering Research
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• v.48 no.5
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• pp.589-597
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• 2010

Strengthening the regulation standard of biological nutrient in wastewater treatment plant(WWTP), the necessity of repair of WWTP which is operated in conventional activated sludge process to advanced nutrient removal treatment is increased. However, in full-scale wastewater treatment system, it is not easy to fine the optimized operational condition of the advanced nutrient removal treatment through experiment due to the complex response of various influent conditions and operational conditions. Therefore, in this study, an upgrading design of conventional activated sludge process to advanced nutrient removal process using the modeling and simulation method based on activated sludge model(ASMs) is executed. And a design optimization of advanced treatment process using the response surface method(RSM) is carried out for statistical and systematic approach. In addition, for the operational optimization of full-scale WWTP, a correct analysis about kinetic variables of wastewater treatment is necessary. In this study, through partial least square(PLS) analysis which is one of the multivariable statistical analysis methods, a correlation between the kinetic variables of wastewater treatment system is comprehended, and the most effective variables to the advanced treatment operation result is deducted. Through this study, the methodology for upgrading design and operational optimization of advanced treatment process is provided, and an efficient repair of WWTP to advanced treatment can be expected reducing the design time and costs.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.8 no.3
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• pp.627-631
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• 2007

The factors affecting on sludge sedimentation are reported as F/M ratio, ingredient, composition of influent substrate, dissolved oxygen concentration, temperature, pH, filamentous bacteria and SRT. Aeration tank applying Bacillus sp. has an important role for maintaining the dominant microorganism species to make steady progress for spore growth affecting sedimentation. This research aims to investigate the affecting factor for the sedimentation in B3 system and RABC system with aeration tank applying tapered aeration. Extracellular polymeric substances(EPS), protein and carbohydrate can be produced for the extreme condition, that is down to 0.2 mg/L of dissolved oxygen in the aeration tank. This research found out the relation between the sedimentation and the EPS production, especially the ratio of protein/carbohydrate. The spore of Bacillus sp. was formed at the low DO then microorganisms produced EPS. The results showed that the production of EPS was 109.95 mgEPS/gSS at 1.6 mg/L of DO, however it was 131.77 mgEPS/gSS at 0.5 mg/L of DO. The sedimentation was affected by protein content in EPS and the ratio of protein and carbohydrate. The settleability of sludge was not affected by the ratio of protein/carbohydrate in B3 process, meanwhile settleability was affected by the ratio of it in RABC process, respectively.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.7 no.3
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• pp.45-53
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• 1987

The purpose of this research was to study the kinetics of a packed bed aerobic biofilm process. Experiments were carried out by feeding an aerated packed bed reactor with a synthetic wastewater. The reactor packed with glass beads as media had a nominal hydraulic detention time of 5 hours. The flow pattern in the reactor was determined by a tracer test using a NaCl solution to be a completely-mixed type. The results of the research showed that the F/M ratio in the reactor was almost constant since the the biomass increased due to the growth of biofilm as the volumetric organic loading increased. It was also proved theoretically and experimentally that packed bed aerobic biofilm process could be analyzed by the kinetics of completely-mixed activated sludge process with sludge recycle.

• Membrane Journal
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• v.22 no.2
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• pp.95-103
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• 2012

To treat nitrate and non-biodegradable organics effectively in sewage, industrial wastewater and livestock wastewater, the activated sludge process integrated by a membrane separation and a porous electrode- electrolysis was proposed and its efficiency was investigated. The proposed system was consisted of 3 processes; activated sludge, membrane filtration and electrolysis. In the study, the membrane filtration played a role in reducing the load of the electrolysis to operate the proposed process stably. The electrolysis consisted of a porous electrode to increase the efficiency due to the extension of the specific surface area. Additionally, redox reaction in the electrolysis was induced by decomposing influent water as current was applied. As a result, hydrogen free radicals and oxygen radicals as intermediates were produced and they acted as oxidants to play a role in decomposing non-degradable organics. It was environmentally-friendly process because intermediates produced by porous electrode were used to treat waste matters without supplying external reagent. Experimental data showed that the proposed process was more excellent than activated sludge process. SS removal efficiencies of the proposed process, membrane filtration and activated sludge process were about 100%, about 100% and about 90%, respectively. COD removal efficiencies of the proposed system, membrane filtration and activated sludge process were about 92%, about 84% and about 78%, respectively. T-N removal efficiencies of the proposed system, membrane filtration and activated sludge process were about 88%, about 67%, and about 58%, respectively. The SS data showed that SS was efficiently removed in the single of the membrane filtration. The COD/T-N data showed that COD/T-N of membrane hybrid process was treated by removing a little soluble organics and SS, and that COD/T-N of electrolysis hybrid process was treated by oxidize organics with high removal rate.

• KSBB Journal
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• v.22 no.3
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• pp.157-161
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• 2007

This study is to investigate the biological degradation and the characteristics of MEA, a pH regulator to be put in the cooling water circulation system for power plants, loading to elevate concentrations of COD and N when eluted into the water environment. MEA, $NH_4^+$ and CODcr were monitored in flask cultures and in a batch aerator. MEA was found to be biologically degradable, producing substantial amount of ammonia (max. 78.1%) in a form of $NH_4^+$ and other carboneous intermediates. The degradation reaction rates were similar one another over all MEA concentrations tested as the activated sludge (microbial consortium) was acclimated to MEA with the gradual and stepwise increase in MEA input into the batch aerator. Also, MLVSS kept increasing with increasing MEA input. The COD-based degradation reaction order was determined to be 1.

• Journal of Environmental Health Sciences
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• v.18 no.2
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• pp.57-61
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• 1992

This study was made for enhanced removal of N and P by intermittented aeration Activated Sludge Process. Experiment were conducted to find the effects of aeration interval and nutrient removal efficiency. When applied aeration interval were 30~60 min, 2~4 h, 4~8 h, organic matter was not affected while phosphorous removal was aeration interval 30~60 min. Also, when applied mixing intensity were 15, 30, 45 and 60 rpm, organic matter was not affected while removal was maximum at 15 rpm. Total nitrogen and phosphorous removal were in the range of 76 and 85%. Density and MLSS of Sludge were in the range of 2.3~2.6 and 7198~7810 mg/l. Release of phosphorous from activated sludge under unaerobic condition was increased as pass time.

• Journal of environmental and Sanitary engineering
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• v.12 no.3
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• pp.1-7
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• 1997

이 연구에서는 SBR 공법을 이용하여 질소, 인 동시제거기장에 대해 관찰하고 BOD-SS loading변화에 따른 오염물질 제거효율에 대해 검토하였다. BOD, TN 및 TP 제거율은 $20^{\circ}C$에서 95%, 74% and 81%로 나타났으며, Phosphorus luxury uptake는 호기성이 시작된후 1,2시간후에 각각 67% 및 84%를 흡수 하는 것으로 관찰 되었으며, 호기성 말기의 농도는 $0.9mg/{\ell}$ 이하를 유지하였다. 80% 및 85% 이상의 안정된 질소 제거효율을 유지하기 위해서는 BOD-SS loading 값을 0.15 및 0.08 kg-BOD/kg-SS.day 이하로 유지하여야 하는 것으로 나타났다. 또한 1회 방류수량의 변화에 따른 관찰에서, 반응조 유효용량의 30%, 40% 및 50%를 유출할 경우 TN은 각각 78%, 72% 및 58%를 TP는 각각 81%, 77% 및 66%의 제거효율을 보였다.