• Title/Summary/Keyword: 환상형(環相型)

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Vinyl Addition Copolymerization of Norbornene/5-Vinyl-2-norbornene with Cationic $\eta^{3_}$-Allyl Palladium Catalyst and Their Post-Reaction (양이온성 $\eta^{3_}$알릴 팔라듐 촉매를 사용한 노보넨/5-비닐-2-노보넨의 비닐 부가 공중합과 이를 이용한 고분자 후반응)

  • 안재철;박수현;이광희;박기홍
    • Polymer(Korea)
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    • v.27 no.5
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    • pp.429-435
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    • 2003
  • Vinyl addition copolymerizations of norbornene (NB) and 5-vinyl-2-norbomene (VNB) were carried out using a cationic η$^3$-allyl palladium catalyst in the various mole ratio of comonomers. The copolymers could be obtained in good yield (65∼85%) with high weight-average molecular weights (M$_{w}$ > 760,000). Depending on increasing VNB contents, the molecular weight and yield of the copolymers decreased. FT-IR analysis confirmed that actual contents of VNB in polymer were proportional to the feeding content of VNB. From $^1$H-NMR spectroscopy, we found that both exo and endo VNB isomer were copolymerized with NB. Thermal stabilities of NB-VNB copolymers were independent on the VNB content and their initial decomposition temperatures were about 300 C. The NB-VNB copolymers were followed by epoxidation by using m-CPBA and hydroxylation by 9-BBN, respectively, and these post-polymers were characterized by FT-IR spectroscopy and $^1$H-NMR analysis..

Light, Scanning and Transmission Electron Microscopic Studies on the Structure of the Pigment Cells of the Pisces (어류 피부 색소세포에 관한 광학, 주사 및 전자현미경적 연구)

  • 지영득
    • The Korean Journal of Zoology
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    • v.33 no.1
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    • pp.12-21
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    • 1990
  • When a piece of the dorsal skin(cat fish) was observed under a light microscope, melanophores were horizontally expanded and had a few processes filled with melanosomes. They were isolated from one another. Some melanophores looked black, while others were d&k brown. On observation with a transmission electron microscope, the epidermal melanophore of cat fish was highly branched and small segments of processes were found frequendy m the vidnity of the interecellular spaces. The cross section of the processes of melanophore was almost circular, and often invested by a thin layer of epidermal cells. Some processes, however, occurred free m the wide interecellular spaces or at the cytoplasm of the superilcial layers. In the mature melanophore, the cell organelles including melanosomes, mitochondria and free ribosomes were prominent in the perinuclear portions. Many melanosomes were spherical or elipsoidal in shape. Each melanosomes was surrounded by a limiting membrane. The processes of the mature melanophore were well developed, but the processes of the immature melanophores were incompletely developed.

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A New Needle Rust Fungus Coleosporium neocacaliae on the Needles of Pinus koraiensis in Korea (국내 미기록 잣나무 잎녹병균, Coleosporium neocacaliae)

  • Lee, Seung-Kyu;Kim, Dong-Won;Moon, Yil-Seong;Kim, Jong-Jin
    • Research in Plant Disease
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    • v.14 no.3
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    • pp.214-218
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    • 2008
  • Coleosporium neocacaliae, a needle rust fungus, was described and illustrated for the first time on the needles of Pinus koraiensis (Korean pine) in Korea. Detailed descriptions of the species were verified based on symptoms and signs, and light and scanning electron microscopic observations on aecia, aeciospores and peridial cells. The present needle rust fungus was apparently different from C. eupatorii, a solely recorded Coleosporium species on P. Koraiensis in Korea until this time, in having comparatively large sized aeciospores as $20-39{\times}14-27\;{\mu}m$ than those of latter species (size of aeciospores $15-27{\times}10-20\;{\mu}m$). Verrucose surface structure of aeciospores in light microscopy was revealed to be annulated with three to four rings and root-like base in scanning electron microscopy. Aecial stage of C. neocacaliae were formed on the middle days of April to the early days of June and collected around the central parts of Korean peninsula, including high mountains of about 1,000 m above sea level.

Development of a visual-data processing system for a polyhedral object recognition by the projection of laser ring beam (다면체 물체 인식을 위한 환상레이져 빔 투사형 시각 정보 처리 시스템 개발)

  • 김종형;조용철;조형석
    • 제어로봇시스템학회:학술대회논문집
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    • 1988.10a
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    • pp.428-432
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    • 1988
  • In this study, some issues on 3- dimentional object recognition and pose determination are discussed. The method employs a laser projector which projects a cyliderical light beam on the object plane where it produces a bright ring pattern. The picture is then taken by a T.V camera. The ring pattern is mathmetically the ellipse of which the geometrical parameters have the 3-dimentional feature of the object plane. This paper gives the mathematical aspects of 3-dimentional recognition method and shows experimentally the variations of ellipse parameters as the spatial deviation of the plane object.

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The Strain of Flexible Ring Type Valve used for Refrigeration Compressor (냉동압축기용(冷凍壓縮機用) 환상형토출(環狀型吐出)밸브의 변형(變形))

  • Jeong, J.W.;Jo, K.O.
    • The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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    • v.17 no.2
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    • pp.150-158
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    • 1988
  • On a refrigeration compressor, damage of a discharge valve is one of the annoying troubles for an engineer. Small size compressors, having ring plate type discharge valve are recently used. Therefore, it is very important for engineers to measure and analyze strains of discharge valve. The purpose of this study is to obtain the basic data of the strain of the flexible ring valve. Measurements were performed by the strain gauge bonded on the surface of the flexible ring valve. Stress and strain of the valve were calculated by the method of uniformly loaded circular plates with a central hole. The results obtained are as follows; (1) the strain of flexible ring discharge valve in refrigeration compressor was influenced by tension and compression strain simultaneously. (2) for a given discharge pressure, the tangential and radial strains was increased with increasing discharge pressure. (3) the valve of radial strain was larger than that of tangential strain.

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홍수시 저수지운영을 위한 시우량 모형 - Hyetograph model for Reservoir operation during Flash flood

  • Lee, Jae-Hyeong;;Jeong, Dong-Guk
    • Water for future
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    • v.23 no.3
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    • pp.341-350
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    • 1990
  • Precise run-off forecasting depends on the ability to predict quantitative rainfall intensity. This study suggests a stochastic model for 1 hour order rainfall prediction. The model simultaneously predicts rainfall intensity at all telemetered rain-gauge locations. All model parameters, velocity and direction of storm movement, radial spectrum, dimensionless time distribution of rainfall, are estimated from telemetered and historical data for the basin being predicted. Also the estimated parameters are based on the previous study. The results are the influence of dimensionless time distributions on the prediction and the model on run-off.

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Adhesion and Friction Forces of Micro Surface Bumps (마이크로 표면돌기의 응착력과 마찰력)

  • Cho Sung-San;Lim Je-Sung;Park Seungho;Lee Seungseop
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.28 no.8 s.227
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    • pp.1087-1092
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    • 2004
  • Adhesion and friction forces influence adversely on performance and durability of MEMS. It has been reported that the adhesion and friction forces can be reduced with the introduction of micro surface bumps into the contacting interfaces. In this study experiments were conducted to investigate comparatively the effect of hemispherical and torus micro bumps on the adhesion and friction forces. It is confirmed that micro bumps reduce the adhesion and friction forces, and their effect is more pronounced with the bumps of smaller outer boundary radius. Moreover, the results shows that the torus bumps exhibit more rapid decrease of the adhesion and friction forces with the decrease in the outer boundary radius of bump than the hemispherical bumps. When the magnitude of adhesion force is same, the torus bumps generate smaller friction force than the hemispherical bumps. The usage of hemispherical and torus bumps to reduce the adhesion and friction forces in MEMS is discussed.

The Principles of Learning and Education involved in Xugua zhuan, the Sequence of the Hexagrams in I Ching (「서괘전」에 함의된 공부의 관점 - 태괘(泰卦)에서 이괘(離卦)까지를 중심으로 -)

  • Kim, Jeong-Nae
    • The Journal of Korean Philosophical History
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    • no.59
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    • pp.155-190
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    • 2018
  • The paper has focused on the 20 Iching-hexagrams from the eleventh t'ai[ ] to the final one of the Upper Book li[離] to examine the principles of learning and education involved in Xugua zhuan[序卦傳], the Ordinal Sequence of the Hexagrams as one among Ten Wings in I Ching. Some implications involved in this part of the Book of Change provides us with numerous teachings and educational principles. I try to concisely note the three teachings of the major argument as shown in the paper. Firstly, we should take the process of learning as the circular system of thought[環 相型], not as the linear system assuming the final destination like the Final Cause in the Aristotelian teleology. In the same token, the process of learning should be regarded as 'initiation', which has been initially adopted to justify the concept of education by R. S. Peters. As a circular system, there are two kinds of initiation. The one sense is 'crossing the threshold of illiteracy' seen as 'small initiation', which apprehends the points of argument in the previous paper, namely, on hexagrams from ch'ien[乾] to t'ai[泰]. The other sense is 'getting on the inside of the worthwhile activities', seen as 'Grand Initiation', which apprehend the present points of argument. Secondly, as shown in the paper, the Book enables us to recognize the process of learning as 'Seeing What Is There'. This requires us the Principles of Mean and Perfection, which are to be taken differently from the Western ones. For this a learner should always hold the endless self-reflection and attitude to re-examine the original intention of one's own, whilst he is involved in the task of learning. Finally, we should take the Principles of Change seriously, such as extremity-reversibility[物極必反] and the sense of conformity, in order that we can establish the proper educational principles to tackle the social domains of learning as well as the personal ones.

Comparative Anatomy of the Secondary Xylem in the stem of Araliaceous Plants in Korea (한국산 두릅나무과 식물 줄기에서 2기목부의 비교 해부)

  • 박동옥
    • Journal of Plant Biology
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    • v.36 no.4
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    • pp.345-355
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    • 1993
  • Anatomical study of the secondary xylem in Araliaceous plants, induding 7 genera and 11 species grown in Korea, was carried out to elucidate the relationship among genera in the family. Wood of Hedera has difbse porous and shows ulmiform pattern of angular vessels, simple perforation plate, and alternate pitting. In addition, its ray is homogeneous type II with only procumbent ray cell. Ring porous wood of Dendropanax shows ulmiform of angular vessels, simple perforation plate, alternate pitting, and heterogeneous type II ray, which has sometimes horizontal secretory cavity. Fatsia has diffuse porous wood, which shows ulmiform of angular vessels, scalariform perforation plate (3-9 bars), scalariform pitting, spiral thickening in the lateral wall of vessel, and heterogeneous type II ray with sheath cells. Kalopanax has ring porous wood, which shows ulmiform of circular vessels, simple perforation plate and alternate pitting, and heterogeneous type II ray. While K pictum appears tylose with septum, K pictum var. maximowczii appears tylose without septum. Echinopanax shows ring porous wood, ulmiform of angular vessels, simple perforation plate, scalariform pitting, and tylose with septum. And the ray of Echinopanax is paedomorphic type I composed of only upright cells. Acanthopanax genus is composed of diffuse porous wood, ulmiform of angular vessels, simple perforation plate and alternate pitting. In this genus, A. sessiliflorus has heterogeneous type II ray, apotracheal axial parenchyma and tylose with septum. A. senticosus appears paedomorphic type I with only upright cells, and tylose with septum. A. koreanum and A. sieboldianum have heterogeneous type II ray but have not tylose. Aralia is composed of ring porous wood, ulmiform of circular vessels, simple perforation plate, alternate pitting, heterogeneous type II ray, and tylose contained both septum and reticulate. On the basis of arrangement, shape, length and diameter of vessel element, the angle of end wall to vessel axis, and ray type, the line of specialization in these genera is as follow: from Fatsia, the most primitive, to the most highly specialized Aralia, throughout Hedera, Acanthopanax, Echinopanax, Dendropanax, and Kalopanax by turns. turns.

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