• Title/Summary/Keyword: 환경지구화학

Search Result 680, Processing Time 0.029 seconds

Major, Rare-Earth and Trace Geochemistry of Ulleungdo Volcanic Rocks (울릉도 화산암의 주원소, 휘토류 및 미량원소 지구화학)

  • 송용선;박계헌;박맹언
    • The Journal of the Petrological Society of Korea
    • /
    • v.8 no.2
    • /
    • pp.57-70
    • /
    • 1999
  • The volcanic rocks of Ulleungdo reveal very high alkali element abundances and most of them have high K20/Na20 ratios and belong to potassium-series. Ulleungdo volcanics show very wide range of variation in their composition from basalts to trachytic basalt, basaltic trachyandesite, trachyandesite, and finally to trachyte on total alkali-silica diagram. Such a general trend of compositional variation can be explained well by differentiation due to fractional crystallization of various minerals. Olivine, clinopyroxene, plagioclase, ilmenite, and apatite are suggested as the major fractionated minerals. Ulleungdo volcanics show Nb/U and PbICe ratios similar to oceanic volcanics such as MORB and OIB, but significantly different .from volcanic rocks of island arc environments, which suggest that they are not directly related with subduction along the Japanese arc. LREE abundances of Ulleungdo volcanics are highly enriched compared with HREE abundances ((La)N=193-420, (L~)~=7.5-19.5).O nly trachyte-1 show appreciable negative Eu anomalies among various rock types, which suggests significant amount of plagioclase were fractionated. However, trachyte-2, trachyte-3, phonolite, and pumice reveal quite different variation trend of trace and rare earth element abundances from trachyte-1, which suggest that they have originated from different magma batches and have experienced different differentiation processes. A prominent bimodal distribution, thus lacking of intermediate composition, is observed from the Ulleundo volcanics.

  • PDF

Petrogenesis and Metamorphism of Charnockite of Eastern Jirisan Area (지리산 동부 지역에 분포하는 차노카이트의 변성작용과 성인에 관한 연구)

  • 김동연;송용선;박계헌
    • The Journal of the Petrological Society of Korea
    • /
    • v.11 no.3_4
    • /
    • pp.138-156
    • /
    • 2002
  • Precambrian metamorphic rocks of southwest Sobaeksan massif consist of mainly granitic gneiss, porphyroblastic gneiss and quartzofeldspathic gneiss. The orthopyroxene-bearing rocks(charnockites) are found in the west of Hadong-Sancheong anorthosite complex. The charnockites are 3km wide, 12km long and divided into massive and foliated types based on their texture. The compositions of charnockites are comparable to granodiorite to adamellite and subalkaline. Variations in major and trace elemental abundances show typical magmatic differentiation trends. The geochemical data plotted on tectonic discrimination diagrams reveal that these charnockites were formed in the active tectonic environment. The massive and folidated charnockites are mainly composed of plagioclase, orthopyroxene, microcline, quartz and disseminated garnet. Camels generally show characteristic zonal textures with decreasing $X_{alm}$(0.74~0.83), $X_{Py}$ (0.07~0.12) and $X_{Mg}$ (0.12~0.08) and increasing $X_{grs}$(0.03~0.15) from core to rim. Metamorphic temperature and pressure of the charnockites estimated from orthopyroxene-garnet-plagioclase-quartz assemblages show wide range of variation of $600~900^{\circ}C$ and 2.5~7.5 kbar respectively. The results of P-T estimates indicate an anticlockwise P-T evolution path.

Educational Implications of Pre-Service Science Teachers' Education by Analysis of Connection between Learning Contents Presented in the High School 'Science' and in the Pre-Service Science Textbooks of College of Education (고등학교 융합형 과학의 학습내용과 사범대학 예비과학교사 교육내용과의 연관성 분석을 통한 예비과학교사교육에 대한 시사점 고찰)

  • Kim, Nam-Hui;Shim, Kew-Cheol
    • Journal of The Korean Association For Science Education
    • /
    • v.35 no.3
    • /
    • pp.363-374
    • /
    • 2015
  • The purpose of this study is to investigate the learning contents presented in high school science and in pre-service science textbooks of college of education, and to examine educational implications for pre-service science teachers by analysing their connection to each other. High school science is called as 'convergence science.' Seven high school science textbooks and eleven science textbooks related to physics, chemistry, biological science, and earth science for pre-service teachers were selected to analyse learning contents. The relationship between high school science with those of college-level science textbooks for pre-service science teachers was found when the learning contents were compared. Science textbooks for pre-service science teachers have the biggest number of learning contents on the chapter 'Energy and Environment' of high school science. About 86.6% of learning contents of high school science were introduced on textbooks on science, but pre-service teachers should learn the remainder. The part of learning contents presented in high school science textbooks was higher than the college-level for pre-service science teachers. Moreover, the part of learning contents was included in Engineering & Technology. And these required a special teacher education. Accordingly, the results suggested that learning contents for high school science should be optimized and reduced. Also, various educational programs should be developed and educational curriculum for pre-service science teachers should be revised.

Rb-Sr Isotope Geochemistry in Seokmodo Granitoids and Hot Spring, Gangwha: An Application of Sr Isotope for Clarifying the Source of Hot Spring (강화 석모도 화강암류와 온천수의 지구화학: 온천수의 기원규명을 위한 Sr 동위원소의 응용)

  • Lee Seung-Gu;Kim Tong-Kwon;Lee Jin-Soo;Song Yoon-Ho
    • The Journal of the Petrological Society of Korea
    • /
    • v.15 no.2 s.44
    • /
    • pp.60-71
    • /
    • 2006
  • The Seokmodo consists mainly of biotite granite and granodiorite. The biotite granite is divided into the south and the north part by granodiorite. There occurs high temperature hot spring of which temperature is up to $72^{\circ}C$. The Rb-Sr isotopic data for the biotite granite define whole-rock isochron ages of $207{\pm}70$ Ma with initial Sr isotopic ratio of 0.7132 in north part and $132{\pm}50$ Ma with initial Sr isotopic ratio of 0.7125 in south part, suggesting that the magma be derived from the crustal source material. The geochemical characteristics of the biotite granite and hornblende granodiorite indicate that they were crystallized from calc-alkaline under syn-collisional tectonic environment. The samples of hot spring were collected at March 2005 and March 2006. The $^{87}Sr/^{86}Sr$ ratios of hot spring are 0.714507 and 0.714518, respectively and correspond to those oi the granite being occurred at the south part. The similarity of $^{87}Sr/^{86}Sr$ ratios between the granite and hot spring strongly suggests that the hot spring might be derived from the Seokmodo biotite granite.

Development of Reference Material Using Natural Seawater for Nutrient Analysis in Seawater (자연해수를 이용한 해수 중 영양염 분석용 표준물질 개발)

  • Rho, Taekeun;Kang, Dong-Jin;Kim, Eun-Soo;Kahng, Sung-Hyun;Cho, Sung Rok;Lee, Jung Moo;Park, Eun Ju;Moon, Cho-Rong
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
    • /
    • v.20 no.1
    • /
    • pp.29-35
    • /
    • 2015
  • Dissolved nutrients in seawater are recognized as an essential biogeochemical factor for detecting global environmental changes. The importance of nutrient reference material for seawater has been increased greatly for the comparison of nutrient data, measured in different time and space in global ocean by various researchers with different levels in nutrient analysis skill. In this study, we described the homogeneity and stability of nutrient reference material for seawater using natural seawater, collected at a station of Shihwa Lake, at a coastal station near Uljin (surface water), and at a station over the Ulleung Basin (surface water and 1500 m depth water) and sterilized. Based on the homogeneity data, the nutrient reference materials has similar homogeneity compared to other nutrient reference materials. During 3-13 month period, there was no unidirectional trend of increase or decrease in nutrient concentration of newly developed nutrient reference material for seawater. However, a sustained measurement is required to check stability for longer period.

Sustainable Block Copolymer-based Thermoplastic Elastomers (지속 가능한 블록 공중합체 기반 열가소성 탄성체)

  • Shin, Jihoon;Kim, Young-Wun;Kim, Geon-Joong
    • Applied Chemistry for Engineering
    • /
    • v.25 no.2
    • /
    • pp.121-133
    • /
    • 2014
  • Block copolymers including ABA triblock architectures are useful as thermoplastic elastomers and toughened plastics depending on the relative glassy and rubbery content. These materials can be blended with other polymers and utilized as additives, toughening agents, and compatibilizers. Most of commercially available block copolymers are derived from petroleum. Renewable alternatives are attractive considering the finite supply of fossil resources on earth and the overall economic and environmental expenses involved in the recovery and use of oil. Furthermore, tomorrow's sustainable materials are demanding the design and implementation with programmed end-of-life. The present review focuses on the preparation and evaluation of new classes of renewable ABA triblock copolymers and also emphasizes on the use of carbohydrate-derived poly(lactide) or plant-based poly(olefins) having a high glass transition temperature and/or high melting temperature for the hard phase in addition to the use of bio-based amorphous hydrocarbon polymers with a low glass transition temperature for the soft components. The combination of multiple controlled polymerizations has proven to be a powerful approach. Precision-controlled synthesis of these hybrid macromolecules has led to the development of new elastomers and tough plastics offering renewability, biodegradability, and high performance.

Selection of Integrated Concepts Across Science and Humanities Using the Delphi Method (과학과 인문학의 통합개념 선정을 위한 델파이 연구)

  • Kim, Jiyoung;Park, Jieun;Yoon, Heojeong;Park, Eunmi;Bang, Dami
    • Journal of The Korean Association For Science Education
    • /
    • v.34 no.6
    • /
    • pp.549-558
    • /
    • 2014
  • Integrated concepts that are broad enough to embrace facts, principles, laws, and concepts of multiple disciplines could become the core of integrated education. Integrated concept-centered education enables effective and practical learning. In this study, the Delphi Method was implemented targeting experts in science (physics, life science, chemistry, and earth science) and humanities (history, geology, economics, ethics, and politics) to find out the integrated concept that can be used to design the concept-centered integrated education in the Republic of Korea. 124 experts participated in this survey. Delphi survey was conducted for three rounds. In the first round, an open questionnaire was given to experts to collect feasible integrated concepts in each major field. Then, in the second round experts were asked to select integrated concepts that could be used practically in the field of their major. In the third round, the integrated concept with selection frequency over medium value were given. They were asked to evaluate the applicability of integrated concepts by using the Likert-scale questionnaire. Through this process, content validity was analyzed. As a result, five integrated concepts (change, interaction, space-time, energy, and equilibrium) were selected for the inter-science integration. And thirteen integrated concepts (conflict, community, relationship, structure, power, diversity, culture, change, society, interaction, freedom, justice, and equality) were chosen for the inter-humanities integration. Finally, for the science-humanities integration, seven integrated concepts (structure, diversity, change, interaction, cycle, system, and environment) were determined.

Characterization of a groundwater system by subsurface hydrogeological investigation data (지하공동굴착 시 수리지질조사 자료를 이용한 저장공동 심도의 지하수체계 특성 연구)

  • 조성일;김천수;김경수;송무영;전한석
    • The Journal of Engineering Geology
    • /
    • v.14 no.1
    • /
    • pp.93-104
    • /
    • 2004
  • This paper intended to assess the hydro-structure characteristics of volcanic rocks based on the hydrogeological data obtained from the underground storage cavern during construction. The variation of groundwater levels was periodically measured from the 28 surface monitoring holes(NX size) and the hydraulic pressures and injection rates were daily monitored from the water curtain holes(95 horizontal holes and 63 vertical holes). The hydraulic interference tests were performed in whole water curtain holes. The distribution patterns of hydraulic pressure are closely related to the dip angles of fracture intersected to the water curtain holes. Three domains can be grouped by the distribution of hydraulic pressures in the horizontal water curtain holes. The initial hydraulic pressures measured immediately after drilling of water crutain holes are high in ascending order of the cavern C-2, C-1, and C-3. The priliminary hydrochemical data also indicate that the portions of the deep groundwater composition is relatively great in the cavern C-3 area. Some of the horizontal water curtain holes in the cavern C-3 show a steady higher groundwater pressure with the composition of shallow groundwater indicating the outer boundary as constant hydraulic boundary. The water curtain holes in the cavern C-2 is characterized as low initial hydraulic pressure and less injection rates, suggesting poor hydraulic connectivity to a shallow groundwater system. The results of the study can help to understand a hydraulic compartment concept in a fracture hydro-geology and be utilized during the surface investigation for a groundwater system.

Feldspar Diagenesis and Reseuoir History of the Miocene Temblor Formation, Kettleman North Dome, California, U.S.A. (미국 캘리포니아주 케틀만 노스돔의 마이오세 템블러층에서 장석의 속성작용과 저류암의 발달사)

  • Lee Yong Il;Boles James R.
    • The Korean Journal of Petroleum Geology
    • /
    • v.3 no.1 s.4
    • /
    • pp.16-27
    • /
    • 1995
  • The Early Miocene Temblor Formation forms an important sandstone reservoir at Kettleman North Dome oil field, California. Sandstones are mostly arkosic in composition except deepest sandstones containing much volcanic rock fragments. Arranged in paragenetic sequence prior to feldspar alteration, the Temblor sandstones contain cements of early calcite, dolomite, quartz, albite, mixed-layer ohloriteismectite (C/S) and smectite, and anhydrite. Diagenetic changes associated with feldspar are albitization of plagioclase, late calcite and laumontite cementation and grain replacement, plagioclase dissolution, and kaolinite cementation. Plagioclase albitization and late calcite and laumontite cementation in Temblor sandstones occurred at the time of maximum burial with temperatures up to $130^{\circ}C$. Volcanic plagioclases were selectively albitized. Most diagenetic changes are interpreted to have occurred before the maior uplift which occurred within the last one million years ago. Since then to the time of hydrocarbon emplacement plagioclase dissolution and kaolinite cementation occurred. This reaction occurred in relatively closed system due to the occurrence of kaolinite next to the site of plagioclase dissolution. Unaltered part of volcanic plagioclase and plutonic plagioclase which escaped albitization during maximum burial were preferentially dissolved to make plagioclase porosity. Secondary porosity resulting from dissolution of plagioclase and carbonate and anhydrite cements was mainly produced by formation waters containing organic acids released during atagenesis of organic matter.

  • PDF

Recent Technological Advances in Optical Instruments and Future Applications for in Situ Stable Isotope Analysis of CH4 in the Surface Ocean and Marine Atmosphere (표층해수 내 용존 메탄 탄소동위원소 실시간 측정을 위한 광학기기의 개발 및 활용 전망)

  • PARK, MI-KYUNG;PARK, SUNYOUNG
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
    • /
    • v.23 no.1
    • /
    • pp.32-48
    • /
    • 2018
  • The mechanisms of $CH_4$ uptake into and release from the ocean are not well understood due mainly to complexity of the biogeochemical cycle and to lack of regional-scale and/or process-scale observations in the marine boundary layers. Without complete understanding of oceanic mechanisms to control the carbon balance and cycles on a various spatial and temporal scales, however, it is difficult to predict future perturbation of oceanic carbon levels and its influence on the global and regional climates. High frequency, high precision continuous measurements for carbon isotopic compositions from dissolved $CH_4$ in the surface ocean and marine atmosphere can provide additional information about the flux pathways and production/consumption processes occurring in the boundary of two large reservoirs. This paper introduces recent advances on optical instruments for real time $CH_4$ isotope analysis to diagnose potential applications for in situ, continuous measurements of carbon isotopic composition of dissolved $CH_4$. Commercially available, three laser absorption spectrometers - quantum cascade laser spectroscopy (QCLAS), off-axis integrated cavity output spectrometer (OA-ICOS), and cavity ring-down spectrometer (CRDS) are discussed in comparison with the conventional isotope ratio mass spectrometry (IRMS). Details of functioning and performance of a CRDS isotope instrument for atmospheric ${\delta}^{13}C-CH_4$ are also given, showing its capability to detect localized methane emission sources.