• Journal of Korean Society of Environmental Engineers
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• v.30 no.10
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• pp.1039-1046
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• 2008

The combining process of UV irradiation and H$_2$O$_2$ was used to investigate characteristics of cefaclor decomposition in the aquatic environment. The separate mixing tank was used to minimize the decreasing effective of contact area caused by sampling. Four baffles were installed inside the UV reactor for the complete mixing of the sample and outside of the reactor was wrapped with aluminum foil to protect the emission of photon energy. Production of OH radical was measured using pCBA(p-Chlorobenzoic acid) indirectly and rate constants were withdrawn pseudo-frist order reaction. Optimum condition for the maximum production of OH radical was found to be pH 3, hydrogen peroxide of 5 mmol/L and recirculation rate of 400 mL/min. Pseudo-frist order reaction rate constant was 0.1051 min$^{-1}$. In the optimum condition, cefaclor was completely decomposed within 40 min and rate constant was 0.093 min$^{-1}$. Decomposition by OH radical producted intermediate anions such as chloride, nitrate, sulfite and acetic acid and phenylglycine. After 6 hr most cefaclor was decomposed by UV/H$_2$O$_2$ process and converted to CO$_2$ and H$_2$O, resulting of operation in the decrease of TOC and acetic acid and the disappearance of phenylglycine.

• Journal of Korean Society of Environmental Engineers
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• v.35 no.12
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• pp.877-882
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• 2013

The application of ultrafiltration (UF) and microfiltration (MF) membranes has been increased for drinking water purification. The advantages of UF/MF membrane process compared to conventional treatment processes are stable operation under varying feed water quality, smaller construction area, and automatic operation. Most membrane treatment plants are designed with polymeric membranes. Recently, some studies suggested that the process of treating surface water with ceramic membranes is competitive to the application of polymeric membranes. Higher water flux, less frequent cleaning, and much longer lifetime are the advantages of ceramic membrane comparing to polymeric membrane. Therefore, this research focused on the application of ceramic MF membrane pilot plant at the slow sand filtration plant. The ceramic membrane pilot plant has three trains that used raw water and sand filtered water as a feed water, respectively. For optimizing the pilot plant process, the coagulation with PACl coagulant was used as a pretreatment of ceramic membrane process. In addition, CEB (Chemical Enhanced Backwash) process using $H_2SO_4$ and NaOCl was used for 1.5 days, respectively. The experimental results showed that applying the optimum coagulant dose before membrane filtration showed enhancing membrane fluxes for both raw water and sand filtered water. Also, when using raw water as a feed of membrane, minimum fouling rate was 2.173 kPa/cycle with 25 mg/L of PACl and when using sand filtered water, the minimum fouling rate was 0.301 kPa/cycle with 5 mg/L of PACl.

• Korean Journal of Environmental Agriculture
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• v.3 no.2
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• pp.1-8
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• 1984

The present study was performed to elucidate pesticide residues in paddy rice applied with different application schedules and frequencies of pesticide formulations. Pungsanbyeo($Japonica{\times}Indica hybrid$) of rice(Oryza sativa L.) was chosen as target crop. Isoprothiolane(diisopropyl-l,3-dithiolan-2-ylidene malonate) 40EC (emulsifiable concentrates), 12G (granular), and chlorpyriphosmethyl [0,0-dimethyl 0-(3,5,6-trichloro-2-pyridyl) phosphorothioate] 25EC, 3G were selected as pesticide formulations. The closer the isoprothiolane EC application to harvest, the higher the residues in rice straw retained at harvest; however the G application on 30 days before harvest resulted in highest residue. Chlorpyriphosmethyl residues were higher as it was applied nearby to harvest. Degradation rate of chlorpyriphos-methyl in husked rice was quite similar to in rice straw, on the other hand isoprothiolane in the rice was more stable than that in rice straw. Translocated amount of applied G formulation to husked rice was meager irrespective to the chemicals. Percent reduction of isoprothiolane residues in husked rice by polishing was not related to application frequencies but to application date before harvest. Residual portions in rice straw, husked rice and polished rice of total input amount during rice cultivation were ranged from 0.19% to 0.99%, 0.01% to 0.48%, and 0.15%, respectively.

• Korean Journal of Environmental Biology
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• v.38 no.1
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• pp.71-81
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• 2020

In Korea, more than 70% of the ammonia(NH₃) released into the atmosphere is known to originate from livestock manure. The total emission (kg year^-1) is calculated by multiplying the emission factor (kg head^-1 yr^-1) and the activity data (head). To improve the accuracy and reliability of the NH₃ emission estimation process, an accurate account of livestock manure production, calculation of NH₃ conversion and generation during the composting and liquefaction of manure, estimation of NH₃ generation in the storage and transportation of manure and compost, and a comparative study of NH₃ emission during the soil spreading process must be performed. Compared to the US and EU-28, in particular, the domestic emission factor is relatively even and the spatial/temporal scale is not broken down sufficiently to reflect the domestic situation. As a way to improve the accuracy and expertise of estimating NH₃ emission factors, a 'dynamic chamber-capture system' can be utilized, which allows complex considerations of compost, liquid manure, soil, and climate characteristics. By reviewing and comparing the data related to domestic and foreign NH₃ emission, we identified shortcomings in the current domestic system and the directions to be taken and suggested a chamber system that could estimate NH₃ emission flux. It is also necessary to establish a methodology for mesocosm systems in the field, in addition to indoor chamber systems, to be linked with practical policies, such as the calculation of new emission factors for missing sources.

• Journal of Environmental Impact Assessment
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• v.27 no.1
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• pp.73-82
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• 2018

The purpose of this study is the evaluation of the impact of increase in impervious areas due to urbanization on the pollutant discharge using the HSPF model at Musim watershed. Model calibration and validation were performed based on the observed data 2015 and 2014, all simulation items have been successfully simulated such as flow, BOD, and TP. The land cover map used in the model reflected on the land use status of the Musim watershed in 2015 and the application of the development areas and locations. As a result of simulation, during rainfall daily pollutant load with the increased impervious land increased more than that before the development. However, the pollutant load decreased during the non-rainfall time. Annual pollutant load in rainfall time was significantly higher than that in non-rainfall time, BOD and TP increased. The simulation of non-point source pollutant load was applied under two assumptions, such as the increased area of impervious land and the non-change number of point source load before and after development. As the result of a simulation, the non-point source pollutant load after development was bigger than those before development. It was necessary to take measures to control non-point source pollution at the consideration status of development.

• Korean Journal of Ecology and Environment
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• v.53 no.1
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• pp.91-101
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• 2020

Stormwater runoff is known as a major non-point water pollution source that transports heavy metals, which have accumulated in road surface, to stream and coastal area. Dissolved and particulate metals in stormwater runoffs have been investigated to understand the outflow characteristics of heavy metals during rainfall events and to identify their pollution sources. The concentration of dissolved Co and Ni decreased after the outflow with high concentrations at the beginning of the rainfall, and other metals showed different characteristics depending on the rainfall and rate of discharge. Particulate metals showed a similar trend with the temporal variation of suspended solids concentration in stormwater runoffs. The results of geo-accumulation index (I_geo) indicated that the stormwater runoffs from industrial region were very highly polluted with Cu, Zn and Cd. As a result of comparing the metal concentrations of <125 ㎛ for road dust near the study area, Cu, Zn and Cd were originated from inside of metal manufacturing facilities rather than traffic activities at road surface and these metals accumulated on the surface area of facilities were transported to the water environments during stormwater event. The average discharged amounts of heavy metals for one rainfall event were Cr 128 g, Co 12.35 g, Ni 98.5 g, Cu 607.5 g, Zn 8,429.5 g, As 6.95 g, Cd 3.7 g, Pb 251.75 g, indicating that metal runoff loads in the stormwater runoffs are closely related to surrounding industry types.

• Journal of Korean Society on Water Environment
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• v.29 no.1
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• pp.107-113
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• 2013

The major tributaries in Sapgyo-reservoir watershed at Chungcheongnam-do were monitored for flowrate and water quality in order to analyze the characteristics of watershed and to prepare for implementation of total maximum daily load (TMDL). According to the analytical results of flowrate and water quality monitoring data of sixteen tributaries, the tributaries with the value of flowrate over $0.5m^3/s$ were 62.5% among the monitored tributaries and the value of flowrate in the Cheonancheon, Namwoncheon, Shinyangcheon except Gokgyocheon, Muhancheon, Sapgyocheon was relatively greater than the other tributaries. However, 37.5% of the tributaries were exceeded the water quality standards of Sapgyocheon sub-basin ($BOD_5$ 5 mg/L and/or below) and the concentration of water pollutants regardless of water quality parameters in Cheonancheon, Maegokcheon, Oncheoncheon including Gokgyocheon located in Gokgyocheon catchment were relatively higher than the other tributaries. The tributaries for improving the water quality, according to stream grouping method based on the results of flowrate and water quality monitoring data, were selected. In the Sapgyo-reservoir watershed, the tributaries for improving water quality, which has a large flowrate and a high concentration of water pollutants, were selected at Cheonancheon, Gokgyocheon, Maegokcheon, Namwoncheon, Oncheoncheon. The various water quality improving plans for those tributaries, in accordance with the reduction of point source pollution by population and livestock, should be established and implemented.

• Proceedings of the Korea Water Resources Association Conference
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• 2007.05a
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• pp.1076-1080
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• 2007

최근 국내에서는 하천변 생태계를 대상으로 생태구조 및 서식처 평가 등 많은 연구가 진행되었음에도 불구하고 생태적 변화를 예측하고 예측된 결과에 따라 생태복원 대책을 수립할 수 있는 연구는 현재까지 미흡하다고 볼 수 있으며, 이는 생태복원 연구에 있어 주요과제라고 할 수 있다. 이에 반해 유럽과 미국에서는 수문학적 서식처 조건에 따른 식생 반응 예측 등 수문생태 모형에 대한 연구가 꾸준히 이루어져 왔으며, 최근에는 습지, 홍수터 등을 대상으로 생태보전 복원분야에 널리 응용되고 있다. 본 연구에서는 국외의 수문생태모형 적용사례를 분석하여 국내 적용가능성 및 문제점에 대한 타당성을 제시하고자 하였다. 그 대상으로는 유역 내에 홍수량 분담을 위한 천변저류지를 적용하였으며, 의미상으로 홍수터(범람원), 습지 역시 해당 범위에 포함할 수 있다. 천변저류지는 홍수기와 비홍수기에 따라 활용 측면을 구분할 수 있으며, 이런 맥락에서 천변저류지의 수위변화는 식생 변화의 중요한 요소(factor)가 될 수 있다. 그 외 범람시기, 범람일수, 건조기간 등을 포함한 수문요소 역시 수문생태 모델의 예측 변수인 식생 성장에 영향을 미치게 된다. 이러한 수문/생태시스템의 상호관계를 활용하고 모형의 형태를 국내 식생에 대한 생리학적 특성에 맞게 변화시킬 수 있다면 국내 천변저류지에도 충분히 적용 가능할 것으로 판단된다. 또한 잠재적으로 식생 성장에 영향을 줄 수 있는 다양한 환경조건 예를 들면 영양물질, 토양구조, 토사 퇴적 등을 적용대상지 환경에 맞게 포함하거나 고려할 수 있다면 모형의 재현성을 더욱 높일 수 있을 것이다.의 기대효과를 가져올 수 있으리라 생각되며 분석된 인자들은 수달 서식지를 위한 하천정비의 기초자료에 유용할 것으로 보인다.따른 유량측정망을 구축하는 것이다.의 의사결정 지원 도구가 될 것이다. 따라서, 본 연구에서는 도시유역의 물순환 해석을 위한 일련의 과정, 즉 자료의 조사 및 취득에서부터 물순환 해석 모형을 이용한 정량적 현황파악, 물순환 개선 기법 및 평가를 수행함에 있어 주요 착안점 및 실무에서의 기술적 가이드를 제공하고자 하였으며, 보다 세밀한 도시유역의 물순환 해석을 위하여 우리나라와 일본에서 적용이 활발한 물리적 기반의 분포형 모형(WEP, SHER, SWMM)의 적용사례를 통하여 국내 도시하천의 물순환 해석에 활용함에 있어서의 실질적인 적용절차 등을 제시하고자 하였다. 한다.호강유역의 급격한 수질개선을 알 수 있다.世宗實錄) $\ulcorner$지리지$\lrcorner$(地理志)와 동년대에 동일한 목적으로 찬술되었음을 알 수 있다. $\ulcorner$경상도실록지리지$\lrcorner$(慶尙道實錄地理志)에는 $\ulcorner$세종실록$\lrcorner$(世宗實錄) $\ulcorner$지리지$\lrcorner$(地理志)와의 비교를 해보면 상 중 하품의 통합 9개소가 삭제되어 있고, $\ulcorner$동국여지승람$\lrcorner$(東國與地勝覽) 에서는 자기소와 도기소의 위치가 완전히 삭제되어 있다.

• Korean Journal of Agricultural and Forest Meteorology
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• v.12 no.3
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• pp.197-206
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• 2010

To provide baseline information essential for assessing environmental impacts of monsoon rainfalls in a mountainous watershed under mixed land use, we investigated spatiotemporal variations in water quality using a combined approach of seasonal water quality survey and intensive storm samplings. Biannual water sampling at nine locations encompassing major land use types showed generally lower electrical conductivity and Cl- concentrations during the typical wet period compared to the dry period, indicating rainfall-induced dilution of dissolved ions. Total metal concentrations, however, were significantly higher during the monsoon period, probably associated with rainfall-induced increases in suspended sediments. Intensive storm sampling during a small monsoon rainfall event (18 mm) and an extreme event (452 mm) showed rapid changes in both suspended sediments and dissolved solutes in an agricultural stream draining the Haean Basin where arable lands have expanded rapidly over the recent decades. By contrast, a nearby forest stream derived from North Korea showed little responses to the small event compared to larges changes during the extreme event. In the agricultural stream total Pb concentrations showed significant positive relationships with suspended sediments. Although limited sampling frequency and locations require a cautious interpretation, the overall results suggest that expansion of agricultural fields in steep mountainous watersheds can increase the susceptibility of soil erosion and its off-site environmental impacts under increasing rainfall variability and extremes.

• Korean Journal of Environmental Agriculture
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• v.20 no.3
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• pp.192-200
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• 2001

The event-based agricultural non-point source(AGNPS) pollution model was applied to estimate the loads of nitrogen and phosphorus in a stream draining small agricultural watersheds. Calibration and verification of the model were performed using observed data collected from rainfall events in the Imgo watersheds during 1997-1998. Parameter calibrations were made for the runoff curve number. The peak flow volumes in the watersheds were well reproduced by the modified model. Average deviation between observed and simulated values was 10%, and this match was confirmed by the coefficient of efficiency value of 0.97. The deviations tended to increase as the peak flows increased. The simulated total N concentrations in the stream water were fairly close to the measured values, and the coefficient of efficiency in the estimation was 0.93. However, there were relatively large variations between calculated and observed values of total P concentration, and the coefficient of efficiency in the estimation was 0.74. Any inaccuracies that arise in estimating runoff flow and nutrient loading can not be explained exactly and further adjustment and refinements may be needed for application of AGNPS in agricultural watersheds. With this restrictions in mind, it can be concluded that AGNPS can provide realistic estimates of nonpoint source nutrient yields.