• Title/Summary/Keyword: 확산실험

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박막형 태양전지 효율 향상을 위한 광확산 패턴을 갖는 기판 제작

  • Kim, Yang-Du;Han, Gang-Su;Lee, Seong-Hwan;Sin, Ju-Hyeon;Lee, Heon
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.30.2-30.2
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    • 2011
  • 태양광을 이용하는 태양전지의 경우, 태양전지에 도달하는 입사광량은 태양전지의 효율과 직접적인 연관이 있다. 이러한 입사광량을 증가시키기 위해서 다양한 연구가 진행되고 있다. 표면에서의 광손실을 줄이기 위해 반사방지층을 형성하고, 광경로 확장 및 광트랩을 위한 기판 텍스처링 방법은 태양전지의 효율을 증가시키기 위해 꾸준히 연구되어 왔다. 본 연구에서는 불규칙적인 배열을 갖는 마이크로-나노급 패턴을 박막 태양전지용 유리기판 위에 형성함으로써 기판의 확산 투과율을 향상시키고, 광확산에 의한 내부 광경로 확장 효과로 태양전지의 효율을 증가시키고자 한다. 박막 태양전지용 유리기판에 불규칙적인 배열을 갖는 마이크로-나노급 패턴을 형성하기 위해, 기존의 패턴 형성 기술에 비해 공정이 간단하고 비용이 저렴한 나노 임프린트 리소그래피 기술을 이용하였다. 실험순서는 제작된 마스터 템플릿의 확산 패턴을 역상을 복제 하여 임프린트용 mold를 제작하고, 이 mold를 이용하여 박막 태양전지용 유리기판 위에 확산 패턴을 형성하였다.

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Hydrodynamic Diffusivity of Spherical Particles Suspended in Polymer Solution (고분자용액에 분산된 구형입자의 수력학적 확산계수)

  • 한민수
    • The Korean Journal of Rheology
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    • v.9 no.4
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    • pp.183-189
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    • 1997
  • 본 연구에서는 고분자용액을 분산매로한 현탁액 내에서 입자의 수력학적확산에 관 한 실험적인 연구를 수행하여다. 입자로는 평균직경 275마이크론의 polymethlmethacrylate (PMMA)구형입자를 사용하였고, 분산매로는 PMMA 입자와 밀도르 맞춘 글리세린과 에틸 렌글리콜의 혼합용액에 고분자를 첨가하여 사용하였다. 고분자로는 분자량 6백만의 시약용 폴리아크릴아마이드를 사용하였다. 입자농도는 50%이었다. 용액의 농도는 0∼700ppm이었으 며 이러한 용액은 전단박화현상을 나타내지 않았다. 확산계수는 쿠엣장치 내에서 입자가 두 원통사이에서 아래쪽의 빈 공간으로 확산할 때 시간에 따른 점도측정결과로부터 예측하여 다. 본 연구의 결과 뉴튼성유체의 경우와는 달리 무차원확산계수(D/2)가 일정하지 않으며 전단율이 증가될수록 점점 감소하는 현상을 나타내었다. 고분자의 농도가 증가하는 경우에 는 무차원 확산계수가 감솨는 것을 볼수있었다. 이러한 무차원 확산계수의 감소는 유동하는 현탁액 내에서 입자간의 상호작용이 뉴튼성유체에 비하여 가역적인 것에 기인하는 것으로 판단된다.

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Two-Step Diffusion of Boron into silicon by Spin-on source (스핀온 쏘스에 의한 실리콘내의 붕소의 이단계 확산)

  • 정태원
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.17 no.5
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    • pp.22-27
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    • 1980
  • The two-step diffusion process of boron into silicon has been investigated using a new diffusion source coiled "Spin-on Source". A simple method is proposei which can estimate the junction depth after the two -step diffusion for the cases where the junction depth after the predeposition is not negligible compared with the junction depth after the two-step diffusion. The estimated junction depths are, then, compared with the experimental measurements.surements.

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An Experimental Study on the Influence of the Spread of Firebrand on Building Exterior Materials and Roofing Materials in Urban Areas (도심지 인접 산불의 불티 확산이 건축물 외장재와 지붕재에 미치는 영향에 관한 실험적 연구)

  • Min, Jeong-Ki
    • Journal of the Society of Disaster Information
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    • v.17 no.3
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    • pp.617-626
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    • 2021
  • Purpose: The purpose of this study is to evaluate the fire srpead risk of building exterior and roofing materials due to the firebrand of forest fire occurring in the urban areas. Method: In order to achieve this research purpose, by selecting building materials used for exterior and roofing materials of buildings, the time to ignition, total heat release, and heat release rate were investigated, and a forest fire firebrand system was established to the possibility of fire spread was confirmed. Result: As a result of the cone calorimeter test, the roofing material had a similar or faster ignition time due to radiant heat compared to the exterior material with the steel plate exposed to the outside, and showed a higher heat release rate and total heat release than the exterior material. Although it was affected by the flammable material, it was confirmed that it did not spread easily due to the limited amount of combustible material, and carbonization marks appeared inside. Conclusion: The cone calorimeter test method has been shown to be useful in understanding the combustion characteristics of building materials by radiant heat, but the fire spread due to a firebrand in a forest fire is directly affected by the flame due to the ignition of surrounding combustibles, so finding a direct correlation with the cone calorimeter method is difficult. It is judged that the roof material may be more vulnerable to the spread of fire due to the fire than the exterior material.

Quantitative Analysis for the Effects of Hydraulic Variables on the Formation of Freshwater-Saltwater Transition Zones in Aquifers (수리 변수들이 대수층 내의 담수 해수 - 확산대의 형성에 미치는 영향에 대한 정량적 분석)

  • 박남식
    • Water for future
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    • v.28 no.2
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    • pp.137-143
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    • 1995
  • The location and the shape of freshwater-saltwater transition zones in coastal aquifers are affected by many hydraulic variables. To date most work to determine the effects of these variables are limited to qualitative comparison of transition zones. In this work characteristics of transition zones (maximum intrusion length, thickness, and degree of stratification) are quantified, and effects of principal hydraulic variables(velocity and dispersivity) on these characteristics are studied using a numerical model. Dimensional analysis is used to assemble entire model results. Effects of velocity and dispersivity are seen clearly. From this study, increase in velocity is found to cause shrinkage of transition zones. This observation contradicts claims by some that, because dispersion is proportional to velocity, increase in velocity would cause expansion of transition zones.

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Application of Diffusion Models to Anomalous Sorption in Fluoropolymer-aromatic Solvent Systems (불소고분자-방향족 용매계의 비이상적 흡수에 대한 확산 모델식의 적용)

  • 이상화
    • Membrane Journal
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    • v.10 no.3
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    • pp.139-147
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    • 2000
  • Non-Fickian (or anomalous) diffusion was observed in transient sorption of aromatic solvents(such as benzene, toluene, and chlorobenzene) in fluoropolymers (such as ETFE, ECTFE and PVDF). In this study, five other transient sorption models (Crank, Long & Richman, Berens & Hopfenberg, Neogi, Li) based on Fick's law were employed to fit the anomalous sorption data for aromatic solvents. The adjustable parameters were determined by least square analysis of the measured and predicted fractional uptake. For ETFE sorption data slightly deviating from Fickian behavior, all the models exhibited satisfactory results in fitting the anomalous sorption data. In particular, Neogj model predicted intrinsic diffusivity (0.4~0.8$\times$10$^{-5}$ $\textrm{cm}^2$/day) and equilibrium diffusivity (0.13~0.31$\times$10$^{-4}$ $\textrm{cm}^2$/day) as well as relaxation kinetics related to non-Fickain diffusion. For a typical sigmoidal sorption behavior in PVDF, only Crank's model could give the reasonable evaluation on transport properties. The ratio of intial diffusivity (D$_{i}$) to final equilibrium diffusivity (D$_{\infty}$) was ranged from 80 to 200. For the final stage of uptake In ECTFE with drastic acceleration, all the models exhibited significant deviations from the sorption data. New diffusion models based on thermodynamics and continuum mechanics should be employed to get valuable information on transport properties as well as relaxation kinetics coupled with non-Fickian diffusion.

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Simulation of salt intrusion and mixing influence for Yongsan estuary regarding Seawater exchange (해수교환에 따른 영산강 하구역 염분 확산 영향 범위 수치 실험)

  • Park, Yong-Woo;Cho, Yang-Ki;Sin, Yong-Sik;Lee, Chang-Hee
    • Proceedings of the Korea Water Resources Association Conference
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    • 2006.05a
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    • pp.557-561
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    • 2006
  • 매년 영산강 본류 수질이 악화되고 있는 영산강 유역주변은 최근 전남도청 이전에 따른 남악 신도시개발, J-Project 및 환경 문화 복원사업의 추진, 기업도시개발등과 관련하여 수질관리개선 및 주요환경현안으로 대두되고 있다. 따라서 영산강 하구역 관리방안 중 담수호 수질개선대책의 일환으로 수문개방을 통한 해수 유입에 의한 수질 개선을 효과를 도모하는 방안이 제시되고 있다. 이에 하구호 방조제의 수문 개통 및 완전 개방에 따른 수질개선 문제에 앞서 발생할 수 있는 환경변화 중 영산강 및 연안역 염분의 확산범위를 평가하기 위하여 수치모형 실험이 실시되었다. 담수 유입에 따른 염분 확산 범위 및 해수 유입에 따른 염분의 역상 범위를 평가 하기위해 수치 모델로는 EFDC를 적용하였고, 하천형상과 연안역을 동시에 고려하기 위해 수평좌표계는 직교곡선좌표로 격자 크기는 $120{\sim}1000m$, 연직방향으로 시그마좌표를 사용하였다. 담수 방류 및 염분역상 효과를 알아보기 위해 1997년부터 2005년까지의 하구 수문 방류량 및 하천 유입량으로부터 홍수기와 갈수기를 선택하여 현재 상황 및 수문의 부분 개통 하구둑 완전 개방에 시나리오를 설정하여 실시하였다. 수문의 부분개통과 하구둑 완전 개방에 따른 염분 확산 범위는 영산강 하구둑을 기준으로 홍수기에는 $13{\sim}17km$, 갈수기에는 36km 이상의 상류지역에서 해수와 담수의 분리 기준인 0.3 psu 범위가 계산됨을 알 수 있다.

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Chloride Diffusion in Hardened Concrete with Concrete Properties and Testing Method (콘크리트 물성 및 시험법에 따른 콘크리트 염화물 확산)

  • Yang Eun-Ik;Kim Myung-Yu;Min Seok-Hong
    • Journal of the Korea Concrete Institute
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    • v.16 no.2 s.80
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    • pp.261-268
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    • 2004
  • Corrosion of reinforcement is the main cause of damage and early failure of reinforced concrete structures. The corrosion is mainly progressed by the chloride ingress. In this paper, an experimental study is executed to investigate the effect of concrete properties and testing methods on the coefficients of chloride diffusion. Also, it is surveyed the relationship between total chloride and free chloride in concrete. According to this experiment results, W/C ratio and testing method affect chloride diffusion coefficient of concrete. As W/C ratio is increased, diffusion coefficient in concrete is also increased. Diffusion coefficient obtained by each testing method show the different values, respectively. The model equation of diffusion coefficient with W/C ratio is proposed.

An Experimental Study of Transient Hot-wire Sensor Module for Measuring Thermal Diffusivity of Nanofluids (나노유체의 열확산율 측정을 위한 비정상열선법 센서모듈 실험)

  • Lee, Shin-Pyo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.2
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    • pp.113-120
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    • 2011
  • A technique for measuring the thermal diffusivity of nanofluids is proposed in this study. In theory, it has been well known that the transient hot-wire method can be used to measure the thermal conductivity and diffusivity of fluids simultaneously. However, when traditional methods were employed, the accuracy of the calculated thermal conductivity was considerably higher than that of diffusivity. The proposed method has two advantages for practical use: it only needs a simple data-conversion process for calculating the diffusivity, and it can skip the tedious calibration process involved in the case of a wire sensor. A validation experiment for the new system has been performed with the basic fluids, and the comparison experiment to compare the change in diffusivity of the base oil and the change in diffusivity of the nano oil has been carried out. It is expected that the present system will provide numerous methods for investigating the variation in the thermal properties other than thermal conductivity.

Numerical Analysis of Surface Thermal Jets by Three-Dimensional Numerical Model (3차원(次元) 수치모형(數値模型)에 의한 표면온배수(表面溫排水) 확산(擴散)의 수치해석(數値解析))

  • Jung, Tae Sung;Lee, Kil Seong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.14 no.6
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    • pp.1385-1394
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    • 1994
  • A three-dimensional numerical model of surface buoyant jets with variable density was established. The model uses fully nonlinear, time-dependent, three-dimensional, ${\sigma}$-transformed equations of motion and equation of heat transport. A semi-implicit numerical scheme in time has been adopted for computational efficiency. The model was applied for thermal jets discharging into a stagnant water and the simulated results were compared with a hydraulic experimental data set showing good agreement. Comparative studies of exchange coefficients and stability functions indicated that spatial variation of exchange coefficients should be considered and the existing stability functions should be modified to simulate surface buoyant jets accurately.

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