• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.6 no.1
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• pp.17-27
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• 1996

This study was designed to survey exposure levels of formaldehyde among workplaces in some plywood industries and to compare three sampling methods including the impinger method(IM, NIOSH method No. 3500), the solid sorbent tube method(SS, NIOSH method No. 2541), and the passive bubbler monitor method(PB, SKC). The survey was conducted in seven particle board manufacturing factories, two resin manufacturing factories and two plywood manufacturing factories in Incheon area during the period from March 6 to April 20, 1995. The workplaces included were the hot/cold press, the roller/spreader, the soaking/drying, and the reaction/mixing areas. The results were as follows; 1. The average(GM, GSD) concentrations of formaldehyde by sampling methods were 0.11(4.43) ppm by IM, 0.27(2.03) ppm by SS, and 0.29(2.04) ppm by PB, respectively. The concentrations by 1M method were statistically very significantly lower than those of SS and PB methods, particularly at low air borne concentrations of formaldehyde (p<0.001). 2. The area average concentrations of formaldehyde by workplaces measured with PB bubblers were 0.23(2.08) ppm from the press, 0.23(1.77) ppm from the spreader, 0.24(1.51) ppm from the soaking, and 0.46(1.96) ppm from the reaction areas, respectively. The personal average concentrations of formaldehyde by workplaces measured with PB bubblers were 0.30(1.77) ppm from the press, 0.33(1.54) ppm from the spreader, 0.36(1.46) ppm from the soaking, and 0.84(1.19) ppm from the reaction areas, respectively. 3. No statistically significant differences of formaldehyde concentrations among workplaces except the reaction area(p<0.001) were found. 4. Formaldehyde concentrations from personal samples were higher than those of from area sam pies in all workplaces studied. But no statistically significant differences of formaldehyde concentrations both area and personal samples were found. In conclusion, this study found that although formaldehyde concentrations in some plywood industries in Incheon area were below the regulatory limit of 1 ppm, they were over the limits recommended by NIOSH and ACGIH. This study also suggests that the impinger method may underestimate true formaldehyde concentrations. It implies that there will be more workplaces not meeting current regulatory limit if either the solid sorbent or passive bubbler methods were used instead of the impinger method. It is suggested that passive monitors will be a reasonable alternative for area and personal sampling of formaldehyde if the accuracy and validity of passive monitors be verified before use.

• Journal of Korea Soil Environment Society
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• v.5 no.1
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• pp.13-23
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• 2000

The effects of operating condition of soil vapor extraction system and the characteristics of site on the remediation of oil contaminated soil were investigated. Thorough investigation showed that the site was contaminated with gasoline leaked from underground storage tank and the maximum concentration of BTEX and TPH were 1,081 ppm and 5,548 ppm respectively. The leaked gasoline were diffused to 6m deep and the area and volume of the polluted soil were assumed to 170$m^2$ and 1,000$\textrm{m}^3$respectively. The site were consisted of three different vertitical layers, the top reclaimed sandy soil between the earth surface and 3~4m deep, middle silty sand between 3~4m and 6m deep, and the bottom bedrock below the 6m deep. The air pemeability of soil was measured to 1.058-1.077$\times$10$^{-6}$ $\textrm{mm}^2$ by vacuum pump tests. The groundwater which level was 3~4m deep was observed in some areas of this site. The soil vapor extraction system which had 7.5 HP vacuum pump and 8 extraction wells was constructed in this site and operated at 8 hrs/day for 100 days. The BTEX was removed with above 90% efficiency where no groundwater and silty sand were observed. On the contrary, the efficiency of BTEX and TPH were dramatically decreased where groundwater and silty sand were observed. The flow rate of soil air induced by soil vapor extraction system was reduced in deeper soil.

• Korean Journal of Soil Science and Fertilizer
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• v.43 no.2
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• pp.242-251
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• 2010

In comparison with other terrestrial ecosystems, rice paddies are unique because they provide the primary food source for over 50% of the world's population, and act as major sources of global methane. The present paper summerizes a long-term field study that combine carbon isotopes, and canopy-scale flux measurements in an irrigated rice paddy, in conjugation with continuous monitoring of environmental, and vegetational factors. Both $CO_2$, and methane fluxes were largely influenced by soil temperature, and moisture conditions, especially across drainage events. Soil-entrapped $CO_2$, and methane showed a gradually increasing trend throughout growing season, but rapidly decreased upon flood water drainage. These variations in flux were well correlated with changes in concentration, and isotope ratio of soil $CO_2$, and methane, and of atmospheric $CO_2$, and methane within, and above the canopy. The isotopic signature of the gas exchange process varied markedly in response to change in contribution of soil respiration, belowground storage, fraction of $CO_2$ recycled, magnitude, and direction of $CO_2$ exchange, transport mechanism, and fraction of methane oxidized. Our results clearly demonstrate that stable isotope analysis can be a useful tool to study underlying mechanisms of gas exchange processes under natural conditions.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.37 no.3
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• pp.541-547
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• 2017

In Yongwon channel, its natural flow of seawater is blocked by the construction of Busan Newport including the container berth. The channel was transformed into a narrow and long one, where it is possible that ships are only allowed to pass through the north-side channel of Gyeonmado located at the point of river mouth to Songjeongcheon. So it is considered that the changes in the terrain characteristics of Yongwon channel is likely to alter the circulation of sea water, thereby changing its water quality. Contaminants are accumulated from the sediment release. In this study, before and after dredging the sediment release test was performed. As a result, after the sediment dredging is performed, the reduction rate was higher at the same point. The results show that the water quality can be improved by dredging. Each group (A~C) reduction rate of the evaluation of the reduction rate of 4.64% T-N, 18.00%, 18.59%, respectively. T-P rate of 24.75% reduction, 24.17%, 44.08%, respectively. COD reduction rate was 18.57%, 19.76%, 38.08%, respectively. These results can be used as basic data for controlling the contamination by dredging in Yongwon channel.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.5 no.1
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• pp.91-99
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• 2007

It was intended in this study to investigate the effects of various parameters on the chemical reaction or mass transfer yield in a tubular-type nuclear waste treatment equipment. Since such equipments, as a tubular reactor, multistage solvent extractor, and adsorption column, accompany chemical reaction or mass transfer along the fluid-flowing direction, mathematical modeling for each equipment was carried out first. Then their behaviors of the chemical reaction or mass transfer were predicted through computer simulations. The inherent major parameters for each equipment were chosen and their sensitivities. affecting the reaction or mass transfer yield were analyzed. For the tubular reactor, the effects of axial diffusion coefficient and reaction rate constant on the reaction yield were investigated. As for the multistage solvent extractor, the backmixing of continuous phase and the distribution coefficient between fluid and solvent were considered as the major parameters affecting the extraction yield as well as concentration profiles throughout the axial direction of the extractor. For the adsorption column, the equilibrium constant between fluid and adsorbent surface, and the overall mass transfer coefficient between the two phases were taken as the major factors that affect the adsorption rate.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.7
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• pp.667-674
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• 2020

The adsorption of reactive orange 16 (RO 16) dye by activated carbon was investigated using the amount of adsorbent, pH, initial concentration, contact time and temperature as adsorption variables. The investigated process parameters were separation coefficient, rate constant, rate controlling step, activation energy, enthalpy, entropy, and free energy. The adsorption of RO 16 was the highest at pH 3 due to the electrostatic attraction between the cations (H⁺) on the surface of the activated carbon and the sulfonate ions and hydroxy ions possessed by RO 16. Isotherm data were fitted into Langmuir, Freundlich and Temkin isotherm models by applying the evaluated separation factor of Langmuir (RL=0.459~0.491) and Freundlich (1/n=0.398~0.441). Therefore, the adsorption operation of RO 16 by activated carbon was confirmed as an appropriate removal method. Temkin's adsorption energy indicated that this adsorption process was physical adsorption. The adsorption kinetics studies showed that the adsorption of RO 16 follows the pseudo-second-order kinetic model and that the rate controlling step in the adsorption process was the intraparticle diffusion step. The positive enthalpy change indicated an endothermic process. The negative Gibbs free energy change decreased in the order of -3.16 <-11.60 <-14.01 kJ/mol as the temperature increased. Therefore, it was shown that the spontaneity of the adsorption process of RO 16 increases with increasing temperature.

• Journal of the Korean Society for Marine Environment & Energy
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• v.13 no.4
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• pp.279-287
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• 2010

To identify characteristics of the water quality at Goseong bay, we analyzed long term monitoring data collected at surface and bottom water which was accumulated during the period of 1987~2009. The result showed that the waters of Goseong bay represented mesotrophic level that is based on chlorophyll-a, DIP and DIN and seasonal average of COD that indicates level by the COD criteria. This analysis can be translated that the waters is comparatively clean even though the waters is in the closed bay that slowly diffuses influx mass. We also did the time series analysis, correlation analysis and regression analysis on the moving average of the water parameter at Goseong bay. According to the results, DIP showed a increasing trend as time passed while DIN was on a decreasing trend under the same condition. In the waters of Goseong bay, the phyto-plankton growth was shown to be limited by DIN concentration. The chlrophyll-a was at the peak in August, at $4.60{\mu}g/L$. As the seasonal average and index were the highest in November, it was understood that the balance of nutrient at Goseong bay was dependent more on inner factors, ie, mass farming of aquatic species and release of bottom sediment rather than on inflow of fresh water. Accordingly, it is needed to consider the balance of nutrient like DIP and DIN to manage the water quality or estuaries at Goseong bay.

• Journal of Satellite, Information and Communications
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• v.3 no.1
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• pp.48-54
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• 2008

With the increasing events of natural disasters caused by unpredictable atmospheric movements, the importance of weather forecasting is increasingly emphasized. In this paper, we adopt satellite radar imageries to deal with unusual weather events over Korean region including yellow sand that swept over Korea in spring 2007 and typhoon EWNIAR in 2006. Korea has suffered from these natural events with increasing frequencies over last decades and the satellite radar imaging is considered the most appropriate method to track and analyze the characteristics of the events spanning from mainland China to Japan. The yellow sand mostly comes from Manju area in China and consists of tiny particles so that they move with high speed resulting in difficulty in predicting their moving paths. With the use of various radar images taken at regular time intervals, we could possibly derive the expected movement of the yellow sand particles. In the future, with the help of radar images taken at very short intervals, satellite radar image analysis will become a very useful tool to predict and prepare for the natural disastrous events caused by abrupt change in the atmosphere and deserts around Korea.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.5
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• pp.667-673
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• 2017

This study was carried out to verify the antimicrobial effect of Graviola leaves against pathogenic bacteria for the purpose of developing an antibacterial material. The extraction conditions of graviola leaves were $60^{\circ}C$, $80^{\circ}C$ and $98^{\circ}C$, and graviloa leaves werewater extracted at $60^{\circ}C$, $80^{\circ}C$ and $98^{\circ}C$.The extraction yields and extraction conditions were determined. The antimicrobial activity against S. epidermidis, S. aureus and E. coli TOP10 was evaluated by agar diffusion method. The extraction yields were 3.02%, 14.73% and 20.76% at $60^{\circ}C$, $80^{\circ}C$ and $98^{\circ}C$, respectively. The antimicrobial activity against S. epidermidis, S. aureus and E. coli TOP10 was found in S. epidermidis.In the samples extracted at $98^{\circ}C$, a clear zone of 13 mm was observed at 200 mg/mL and of 20 mm at 500 mg/mL. The MIC was 100 mg/mL. The higher the extraction temperature and concentration, the better was the growth inhibition effect. As a result, the natural antimicrobial activity contained in natural materials can solve the problem of resistance to antibiotics. It is considered that antimicrobial activity against S. epidermidis in skin is highly applicable to basic cosmetics and cosmetic materials.

• Korean Journal of Weed Science
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• v.18 no.4
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• pp.341-347
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• 1998

This study was carried out to investigate the effect of U-Granule formulation of molinate(S-ethylhexaphdro-1H-azepine-1-carbothioate) mixtures in green house and paddy field, Five minutes were taken for U-Granule to spread out 7m in irrigated water of direct seeded on flooded paddy surface. The concentration of active ingredient of molinate in molinate U-Granule application was similar to molinate+simetryn U-Granule application. But weeding effect of molinate+simetryn U-Granule on Echinochlor crus-galli was 23% higher Than single application of molinate at 7m from application point. Bioefficacy of molinate+simetryn+imazosulfuron U-Granule on control of Echinochloa crus-galli was higher than that of molinzte+imazosulfuton U-Granule, but those effect on Eleochairs kuroguwai was not significantly different. Only slight rice phytotoxicity was observed at 5m and 2m from application point of U-Granule molinate+simetryn+imazosulfuron and molinate+imazosulfuron, respectively. So it is concluded that there is little phytotoxicity problem in practical application of U-Granule of molinate mixtures.