• Title/Summary/Keyword: 화학I

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The Effects of Taking Elective Science Courses in High School on Studying Science at the University Level (고등학교 과학 선택과목 이수가 대학에서의 과학 학습에 미치는 영향)

  • Hong, Mi-Young;Kim, Joo-Ah;Park, Hyun-Ju
    • Journal of The Korean Association For Science Education
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    • v.31 no.6
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    • pp.836-847
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    • 2011
  • This study investigated the effects of taking elective science courses in high school on studying science at the university level. The research methods undertaken for this study included surveys of college students in science areas. For physics and biology major students, no significant differences in achievement in the basic courses at the university level were found between the groups that took only Science I courses and the group took Science I and II courses. For chemistry major students, achievement for the group that took Chemistry I and II courses was significantly higher in the basic courses, while no significant differences between the two groups was found in the advanced courses. The perceptions of college students regarding the effects of their science learning experience in high school on learning science at the university level were investigated. All the college students perceived that whether or not they took Science II courses in high school, it did not affect their learning in basic science courses in college. They also perceived that students were able to overcome difficulties by making extra effort even if they did not take Science II courses in high school.

Voltage-Activated Electrochemical Reaction for Electrochemical Mechanical Polishing (ECMP) Application (ECMP 적용을 위한 전압활성영역의 전기화학적 반응 고찰)

  • Han, Sang-Jun;Lee, Young-Kyun;Seo, Yong-Jin;Lee, Woo-Sun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.163-163
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    • 2008
  • 반도체 소자가 고집적화 되고 고속화를 필요로 하게 됨에 따라, 기존에 사용되었던 알루미늄이나 텅스텐보다 낮은 전기저항, 높은 electro-migration resistance으로 미세한 금속배선 처리가 가능한 Cu가 주목받게 되었다. 하지만 과잉 디싱 현상과 에로젼을 유도하여 메탈라인 브리징과 단락을 초래할 있고 Cu의 단락인 islands를 남김으로서 표면 결함을 제거하는데 효과적이지 못다는 단점을 가지고 있었다. 특히 평탄화 공정시 높은 압력으로 인하여 Cu막의 하부인 ILD막의 다공성의 low-k 물질의 손상을 초래 할 수 있는 문제점을 해결하기 위하여 기존의 CMP에 전기화학을 결합시킴으로서 낮은 하력에서의 Cu 평탄화를 달성 할 수 있는 기존의 CMP 기술에 전기화학을 접목한 새로운 개념의 ECMP (electrochemical-mechanical polishing) 기술이 생겨나게 되었다. 따라서 본 논문에서는 최적화된 ECMP 공정을 위하여 I-V곡선과 CV법을 이용하여 active. passive. trans-passive 영역의 전기화학적 특징을 알아보았고. Cu막의 표면 형상을 알아보기 위해 Scanning Electron Microscopy (SEM) 측정과 Energy Dispersive Spectroscopy (EDS) 분석을 통해 금속 화학적 조성을 조사하였다.

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Electrical Conductance and Electrode Reaction of $RbAg_4I_5$ Single Crystals (고체전해질 $RbAg_4I_5$ 단결정의 전기전도성과 전극반응)

  • Jong Hee Park;Woon-Kie Paik
    • Journal of the Korean Chemical Society
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    • v.24 no.4
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    • pp.295-301
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    • 1980
  • The electrical conductivity of solid electrolyte $RbAg_4I_5$ single crystal was studied at various temperatures. The four-probe method was used in measuring the conductance with an ac signal imposed on the specimen. The ionic conductivity was $0.284 ohm^{-1} cm^{-1}\;at\;25^{\circ}C$, and the activation energy for $Ag^+$ ion migration was calulated to be 1.70 kcal/mole. These values agree well with those reported for polycrystalline samples. Reactions at $Ag/RbAg_4I_5$ interface were studied by cyclic voltammetry with a silver reference electrode. It was found that silver ion is reversibly reduced at silver surfaces below zero volt, and iodide was oxidized above +0.67 volt.The anodic current arising from the oxidation of the electrode was small in magnitude initially over a wide range of potential, but, after silver was cathodically deposited on the electrode, reversing the potential sweep to the anodic direction resulted in a sharp peak of anodic current.

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Evaluation of the OECD Biodegradability Tests for Chemicals (화학물질의 생분해성 측정을 위한 OECD 시험법의 평가)

  • Kim, Ha-Kang;Kim, Kyun;Kim, Yong-Hwa;Lee, Young-Ha
    • Korean Journal of Environmental Biology
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    • v.17 no.2
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    • pp.147-152
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    • 1999
  • The efficiency of the OECD MITI(I) test which is designated as a standard method for measuring the biodegradability of chemicals by the Korean Ministry of Environment was evaluated and compared with those of two other OECD ready biodegradability tests: the manometric respirometry test and the closed bottle test. All the tests were applicable to a wide variety of organic chemicals and there were no significant differences in biodegradation rates of eight test chemicals and a reference chemical with three methods. However, the MITI(I) test had unnecessary expense and complexity in preparation of a mixed inoculum. Decrease in bacterial diversity during pre-conditioning of the inoculum for 1 month was observed and therefore the mixed inoculum did not ensure the presence of a variety of species in the test. Based on the simplicity, cost-effectiveness and reproducibility of the test procedure, it is considered that the manometric respirometry test is the most adequate method which can replace the MITI(I) test method.

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Application of Pine Peroxidase to the Amperometric Determination of Hydrogen Peroxidase (과산화수소의 전류법적 정량을 위한 소나무 과산화효소의 활용)

  • Yoon, Kil-Joong
    • Journal of the Korean Chemical Society
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    • v.57 no.3
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    • pp.329-334
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    • 2013
  • A pine needle-embedded graphite enzyme electrode, of which bonding agent is CSM rubber, was newly designed and its electrochemistry was studied based on the amperometry. It involved a ground green leaves of pine tree as a zymogen together with electrochemical mediator, ferrocene within the paste. The plots of ln($i(1-e^{nf{\eta}})$) vs. ${\eta}$ and Lineweaver-Burk at the low potential (-100 to -500 mV) showed good linearities indicating that the amperometric response is by the catalytic power of pine peroxidase. Electrochemical parameters obtained, symmetry factor (${\alpha}$, 0.17), limiting current ($i_1$, 1.99 $A/cm^2$), exchange current density ($i_0$, $5.86{\times}10^{-5}\;A/cm^2$), Michaelis constant ($K_M$, $1.68{\times}10^{-3}$ M) and many others showed that pine peroxidase discharges the role of catalyst quantitatively on the electrode surface. Those proved that the practical use of pine peroxidase is promising in place of the marketed.

Oxidation of trans-[FeH(NCS(Me)-S)(dppe)2]I to trans trans-[FeNCS)2(Ph2P(O)CH2CH2P(O)Ph2)2][I3](dppe=PPh2CH2CH2PPh2) (trans-[FeH(NCS(Me)-S)(dppe)2]I 화합물의 trans-[FeNCS)2(Ph2P(O)CH2CH2P(O)Ph2)2][I3]로 산화)

  • Lee, Ji Hwa;Lee, Soon W.
    • Journal of the Korean Chemical Society
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    • v.44 no.4
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    • pp.311-315
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    • 2000
  • The Fe(II)-isothiocyanato complex $trans-[FeH(NCS)(dppe)_2]$ (1) eactedwith iodomethane(Mel) to give methyl isothiocyanide-Fe(n) complex, $trans-FeH(NCS(Me)-S)(dppe)_2]I(2)$. Compound 2 was oxidized to $trans-[Fe(NCS)_2(Ph_2P(O)CH_2CH_2P(O)Ph_2)_2][I_3]$ (3), which was structurally characterized by X-ray diffraction. The molecular structure of 3 showed a bent Fe-NCS group, Crystallographic data for 3: triclinic space group P1,a=11.071(2) A,b=12.054(2)A,c=12.121(1)A, $\alpha=101.02(1){\circ}C{\beta}=95.887(9){\circ}Cr=110.34(1){\circ}C$, $Z=1R(wR_2)=0.0567(0.1294)$.

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Ag(Ⅰ) Ion Selective Macrocyclic Ligands: The Complexation and Liquid Membrane Transport Phenomena of Benzylated Nitrogen-Oxygen Donor Macrocyclic Ligands (Ag(Ⅰ) 이온 선택성을 갖는 거대고리 리간드: 벤질 치환기를 갖는 질소-산소 주개 거대고리 리간드의 착물 형성과 액체막 이동 현상)

  • Kim, Jeong;Ahn, Tae Ho;Lee, Myoung Ro;Cho, Moon Hwan;Kim, Si Joong
    • Journal of the Korean Chemical Society
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    • v.43 no.2
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    • pp.167-171
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    • 1999
  • An investigation of the interaction of Co(II), Ni(II), Cu(II), Zn(II), Cd(II), Pb(II) and Ag(I) with two N,N'-dibenzylated nitrogen-oxygen mixed donor macrocyclic ligands, has been carried out. Tle log K values for the respective complexes in 95% methanol have been determined potentiometrically. Both ligands have formed stable complex with only Cu(II) and Ag(I) ion. Transport measurements in a bulk liquid membrane system exhibited a very high selectivity of Ag(I) ion over the other metal ions used.

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A Study on Solid Electrolyte for New Type Cell (고체 전해질을 이용한 새로운 전지에 관한 연구)

  • Soung Ho Park;Seung Gu Cho;Keu Hong Kim;Yong Bae Kim;Jae Shi Choi
    • Journal of the Korean Chemical Society
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    • v.30 no.6
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    • pp.500-509
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    • 1986
  • For the development of new type cell, a study on new electrolyte, $AgI-Ag_8S_3SO_4$ system has been carried out by using electrical conductivity measurement, DTA and X-ray powder diffraction method. From both X-ray powder diffraction and DTA method, it is clearly known that 20mole% $ Ag_8S_3SO_4$-AgI system forms single phase, having monoclinic structure. It is also found that 20mole% $Ag_8S_3SO_4$-AgI system is purely $ Ag^+ $cation conduction from results of conductivity measurement by applying 4-probe method.

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