• Journal of the Korean Chemical Society
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• v.44 no.4
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• pp.316-321
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• 2000

We have constructed and tested a new reflectance spectrometer. Both the radiation source and the detector are embedded on the same side of the cell compartment..Its performance has been compared with that of the conventional absorption spectrometer ('Spectronic 20') using standard solutions of $Cu^{2+}$. The sen-sitivity of the reflectance spectrometer was found to be much higher than that of'Spectrortic 20' over the ana-lytical concentration range of l.00 ${\times}$$10^{-4}$M and 1.00 ${\times}$$10^{-1}$M of $Cu^{2+}$.

• Proceedings of the Korean Society for Bio-Environment Control Conference
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• 1996.10a
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• pp.64-66
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• 1996

수경재배에서 요구되는 최적의 배양액 pH는 5.5-6.5 이고, pH를 최적의 상태로 조절해 주는 방법으로 비료의 흡수생리를 이용하는 방법과 화학적인 산알칼리 용액을 이용하여 조절해 주는 방법이 있다. 이러한 pH 조절은 자동적으로 행해야 효과가 크며 본 실험은 흡수생리적인 면에서 산 혹은 알칼리 비료를 화학적인 산 알칼리와 비교하여 pH 조절효과의 차이를 보고자 하며 생육제어시스템 중 pH의 자동계측 및 제어를 통해서 계속적인 pH의 안정적인 수준을 유지하면서 상품성과 품질이 우수한 작물을 생산하고자 이 실험을 수행하였다. (중략)

• Journal of the Korean Vacuum Society
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• v.3 no.3
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• pp.346-354
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• 1994

삼원화합물 반도체 CuAlSe2 및 CuGaSe2 단결정의 solid solution 인 CuAl1-xGaxSe2 및 cobalt를 2.0 mol% 첨가한 CuAl1-xGaxSe2 : Co2+ 단결정을 iodine을 수송물질로 사용한 화학수송법으로 성장시켰 다. source material로는 CuAl1-xGaxSe2 의 화학조성비에서 Se를 3.0mol% 과잉으로 첨가하여 합성한 ingot를 사용하였으며 불순물이 첨가된 CuAl1-xGaxSe2:Co2+ 단결정성장시에는 source ma-terial 에 cobalt 분말을 2.0mol% 첨가하였다. X-선 회절무늬로부터 성장된 단결정들이 chalcopyrite 결정구조를 하고 있음을 확인하였으며 격자상수를 구하였다. 광흡수 spectra 측정으로부터 성장된 단결정에서 나타 는 cobalt 불순물에 의한 광흡수 peak가 Td 대칭점에위치한 Co2+ 이온의 에너지 준위들간 전자전이에 의해 나타남을 규명하였다.

• Proceedings of the Korean Society for Bio-Environment Control Conference
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• 1999.11a
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• pp.13-24
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• 1999

식물이 생장하고 발육하며 자신의 생명을 유지해 나가기 위해서는 끊임없이 에너지를 공급받아야 하는데, 이 에너지의 공급원은 태양으로부터 오는 광에너지이다. 이러한 광에너지는 엽록소(chlorophyll)를 함유한 녹색식물의 잎이나 줄기 등에서 기공(stomata)을 통하여 흡수되는 이산화탄소($CO_2$)와 뿌리에서 주로 흡수되는 물($H_2O$)로부터 당류ㆍ전분과 같은 탄수화물을 합성하고 산소를 방출하는데 이러한 광에너지가 화학에너지로 변환되는 과정을 광합성(photosynthesis) 또는 탄소동화작용(carbon assimilation)이라고 한다. (중략)

• Textile Coloration and Finishing
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• v.2 no.2
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• pp.43-50
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• 1990

색을 가지는 물질 즉 "색소" 란 인간의 눈에 시각으로서의 색을 인식 시키는 물질이다. 따라서 색소는 대상을 colorful하게 만들며 생활을 풍요롭게 하는데 필수불가결한 물질이다. 합성염료가 개발되기 이전부터 인간은 동물, 식물, 광물에서 색소를 추출해 사용해 왔다. 그러나 색소의 "색" 이외의 물성을 적극적으로 이용 할려고는 하지 않았다. 색소가 가지는 특성과 기능은 광흡수(색, 근적외 흡수, 다색성), 광방사(형광, 인광), 광 전도성, 가역변화(열, 광, pH), 화학 반응성 등이며, 이들의 특성과 기능이 색소를 광과 전자 분야에 관련되는 재료로 응용되게 유도 하였다.련되는 재료로 응용되게 유도 하였다.

• Applied Chemistry for Engineering
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• v.21 no.1
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• pp.71-75
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• 2010

The efficient performance of absorber is of great importance for the absorption heat pump cycle. The experimental study of absorber with spiral tube of tangential feeding of liquid phase has been investigated using methanol-glycerine as a working fluid. The effect of change in absorber operating conditions was analyzed to improve the performance. The increase in solution flow rate and cooling flow rate positively affects the absorber performance while an increse in the solution concentration negatively affects the absorber performance. The results showed that mass absorption flux was in the range of $0.2{\sim}0.6kgm^{-2}sec^{-1}$, the solution heat transfer coefficient between 1.6 and $4.2kwm^{-2}K^{-1}$, the absorber thermal load from 0.9 to 1.5kw and the mass transfer coefficient from 0.9 to 1.7 m/sec.

• Korean Chemical Engineering Research
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• v.54 no.5
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• pp.648-652
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• 2016

The study of $CO_2$ absorption in a packed column by 1,1,3,3-tetramethylguanidine (TMG) dissolved in ethylene glycol is presented. Absorption column of inner diameter 1 in and 0.6 m length was filled with Protruded-packing $0.16in{\times}0.16in$. We investigated the effect of operating conditions on overall mass transfer coefficients as well as on $CO_2$ removal efficiency. The loading values reached at about $1.0mol_{CO2}/mol_{TMG}$. In case of absorbent with lean $CO_2$ loading, the overall mass transfer coefficient was proportional to the concentration of TMG. However, in the range of more than ${\alpha}=0.5molCO_2/molTMG$, the overall mass transfer coefficients decreased with the concentration of TMG. It is due to the increasing of mass transfer resistance in liquid phase as increasing of viscosity at higher loading values.

• Korean Chemical Engineering Research
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• v.43 no.1
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• pp.161-169
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• 2005

Numerical simulation and experiments were carried out on the absorption of carbon dioxide using PVDF hollow-fiber membrane contactor. Water or monoethanolamine (MEA) aqueous soluton was used as absorbents. Simulation results showed that the concentration profile of carbon dioxide was less affected by the flow rate of MEA than that of water absorbent. The absorption rate and mass transfer coefficient of carbon dioxide increased as the concentration of MEA increased. The mass transfer coefficients obtained by experiments coincided with those obtained by numerical simulation and theoretical results for $CO_2-water$ system. However, for $CO_2-MEA$ system, the mass transfer coefficients obtained by experiments were lower than those obtained by simulation, while the simulation results agreed well with theoretical results. The durability of plasma-treated hollow fiber membranes was better than that of no plasma-treated ones.

• Applied Chemistry for Engineering
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• v.22 no.5
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• pp.526-531
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• 2011

The present study attempted to impregnate alkali metals to amino acid in order to improve $CO_2$ absorption capacity. A used amino acid was glycine, of which pH increased up to about 11 with the addition of alkalies. $CO_2$ absorption capacity of amino acid salts was evaluated in a batch and a continuous process. The absorption capacity appeared in turns as; Sodium Glycinate ${\geq}$ Lithium Glycinate > Potassium Glycinate. Amino acid salts showed lower absolute capacity of $CO_2$ absorption than primary amine (Monoethanolamine) at $20^{\circ}C$. In a continuous absorption with 10% $CO_2$ flow, the increasing the reaction temperature, the increasing rate of absorption for amino and was higher that of than amino absorbent.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.22 no.3
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• pp.763-769
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• 2021

In this study, ionic liquids were synthesized to remove carbon dioxide (CO2) on a laboratory scale. The vapor-liquid absorption equilibrium device (VLE) was used to investigate the carbon dioxide absorption capacity. In the regeneration study, the absorption capacity after regeneration was reduced by approximately 7% for all ionic liquids, in which the anion was sulfite-based, showing excellent regeneration. Ethyl sulfite showed the highest absorption capacity of CO2 among the ionic liquids based on the sulfite anion. In particular, the absorption capacity of [beim] ethyl sulfite was 1.1 mol CO2 / mol IL at an absorption equilibrium pressure of 22 bar. In the regeneration study, the absorption capacity after regeneration was reduced by approximately 7% for all ionic liquids, in which the anion was sulfite-based, from which regeneration is outstanding. After the absorption experiment, the viscosity of the sample tended to decrease by approximately 8% compared to that before the absorption experiment. On the other hand, the absorbent was synthesized in the first step. Moreover, the raw material used is also inexpensive and has excellent reproducibility and highly stable absorbent capacity.