• Journal of the Korea Concrete Institute
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• v.26 no.4
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• pp.457-463
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• 2014

The permitted limit, ${\pm}12%$, of the change in solid contents based on ASTM C 494 as an interim standard in Korea Expressway Corporation, can not reflect the kind of chemical admixture and the characteristics of solid content so that it differed depending on the admixture types. In this study, effect of cement concrete quality was investigated by solid changes which can be used chemical admixtures acceptance criteria. As a result of an evaluation of a change in the quality of concrete due to solid content, since Ligno-sulfonate based (LG) had a low water reducing ratio, the range of the change in solid content was great while Naphthalene sulfonated based (PNS) and Poly-carboxylate based (PC) High Range Water-reducing Admixtures (HRWR) had a high water reducing ratio, the permitted limit of the difference in solid content currently used as the acceptance criterion should be readjusted. As a result, it is found that the acceptable range must be managed within 10% and 5% when the solid contents less than 25% and more than 25%, respectively.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.457-460
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• 2008

It was predicted that the most recent technological developments in concrete technology rely on enhanced admixture efficiency rather than on improvement in cement manufacturing. Four major commercially available of organic chemical admixtures are modified lignosulfonates (LS), sulfonated naphthalene-formaldehyde resins (SNF), sulfonated melamine-formaldehyde resins(SMF) and polycarboxylate(PC). In this study, various sulfonated melamine-formaldehyde (SMF) superplasticizers were synthesized via four synthetic steps and reaction conditions such as the mole ratio of melamine to formaldehyde was changed. After application of SMF superplasticizer to cement concrete, the physical properties including workability, slump loss, compressive strength were compared with SNF

• 레미콘
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• no.12 s.10
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• pp.88-96
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• 1986

• Journal of the Korea Concrete Institute
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• v.27 no.6
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• pp.695-703
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• 2015

Acceptance criteria for chemical admixtures of cement concrete were investigated in domestic and international specifications. The reliability was verified for solid content test method of chemical admixture examined statistical analysis by round robin test. The applicability of FT-IR spectroscopy for qualitative measurement of multi-compound chemical admixtures verified. From solid content experimental results, outlier analysed using Cochran, Grubbs and Dickson's Q test. Repeatability and reproducibility standard deviation for solid content results showed 0.25 and 0.098% respectively according to KS A ISO 5725-2 procedure, it can be confirmed reliability of test methods. FT-IR spectrum of liquefied or oven-dried chemical admixtures condition showed big differences. It is needed that the FT-IR analysis is performed on dry material. However there's no difference with the applicability of FT-IR spectroscopy for multi-compound chemical admixtures. So the utility of method analysis could not identify.

• Cement Symposium
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• no.30
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• pp.139-145
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• 2003

• Magazine of the Korea Concrete Institute
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• v.10 no.1
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• pp.65-72
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• 1998

• Cement Symposium
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• no.24
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• pp.11-18
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• 1996

• Journal of the Korea Institute of Building Construction
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• v.10 no.5
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• pp.95-102
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• 2010

In recent years, the demand for the development of high quality and cost effective materials, as well as the competition to ensure a diverse and sufficient amount of ready-mixed concrete, has been increasing rapidly. In this experiment, concretes made with different admixtures are blended with each other in different combinations and ratios, in order to identify potential problems. The first test was a slump level test, in which all of the concretes met the required numbers, as they also did in the test for air content. Plain organic acid concrete scored the highest in bleeding amount, but organic acid mix in general showed a similar outcome. In the early measurement of compressive strength, plain naphthalene concrete was the strongest. Of the blends, the 5:5 mix of organic acid and naphthalene was the strongest. In the standard measurement, the 5:5 mix of naphthalene and lignin was the strongest. Tensile strength tests revealed similar results. Length change rate proved to be greater in blended concrete than in plain concrete, and dry shrinkage rate was highest in the 7:3 ratio blends. Through SEM photo analysis, it was confirmed that the 7:3 ratio blends contained more micro-voids. In conclusion, with the exception of a specific few combinations, it was found that the blending of different types of concrete is undesirable due to the delayed coagulation time as well as the early decrease in strength.

• Applied Chemistry for Engineering
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• v.16 no.6
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• pp.815-821
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• 2005

Three major commercially available organic chemical admixtures are modified lignosulfonates (LS), sulfonated naphthalene-formaldehyde resins (SNF) and sulfonated melamine-formaldehyde (SMF). In this study, various sulfonated melamine-formaldehyde (SMF) superplasticizers were synthesized via four synthetic steps including hydroxymethylation (Step 1), sulfonation (Step 2), polymerization (Step 3) and neutralization and stabilization (Step 4). In this synthesis, mole ratio of melamine to formaline and the amount of acid catalyst used were varied. The obtained SMF superplasticizers were applied to cement paste and mortar and their physical properties including workability, slump loss, compressive strength were investigated. Also their hydrate shapes were investigated by examining SEM images of the cured paste. It was found that the fluidity properties of cement were significantly influenced by the structure of SMF condensates.

• Journal of the Korean Society of Safety
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• v.30 no.3
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• pp.59-66
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• 2015

The undesirable effects of elevated external temperatures at placement on the properties of the fresh and hardened concrete are discussed briefly, and the possible use of the mineral admixtures to mitigate them and the association with water-reducing and retarding admixtures in terms of the mix design which are critical for minimizing slump loss and entrained air loss are examined in this study. To investigate the effects of such the mineral and chemical admixtures on the fresh and hardened properties of concrete exposed to high temperature, a series of concrete mixtures subjected to the high temperature were carried out and then fresh and hardened properties of the mixtures were analyzed and evaluated. Based on the results, new guide lines concerning the appropriate admixtures for hot weather are suggested.