• Title/Summary/Keyword: 화학 수축

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A Study on the Hydration Characteristics and Fundamental Properties of Ternary Blended Cement Using Ferronickel Slag (페로니켈슬래그 및 고로슬래그 미분말을 결합재로 사용한 삼성분계 시멘트의 수화 특성 및 기초물성에 관한 연구)

  • Cho, Won-Jung;Kim, Han-Sol;Ann, Ki-Yong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.1
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    • pp.39-48
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    • 2020
  • The present study investigates the chemical reaction and performance of ternary blended binders by mixing ferronickel slag. Cement was replaced using ground granulated blast furnace slag and ferronickel slag, combined up to 50% of the replacement rate. The blended cements were tested by setting times, length change, compressive strength at 1, 3, 7, 28 days. X-ray diffraction and scanning electron microscope were conducted for detecting hydration products while the MIP and microhydation heat were used for examining morphological characteristics. The results showed that by adding ferronickel slag, Pozzolanic reaction occurred, forming a dense pore structure and the effect of reducing hydration heat and dry shrinkage was also found. The compressive strength at 28 days was lower than that of 100% OPC control specimen (OSP0), but ternary blended cements showed no significant difference compared to binary blended (OSP50). If the optimal mix is derived later and used for the purpose, the potential for use as a cement binder is expected.

Effect of Metal Oxide Additives on Hydrogen Production in the Steam-Iron Process (철-수증기 반응에 의한 수소생성에 미치는 금속산화물의 첨가효과)

  • Lee, Dae-Haeng;Moon, Hee;Park, Heung-Chul
    • Applied Chemistry for Engineering
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    • v.2 no.1
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    • pp.30-37
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    • 1991
  • The production of hydrogen from steam by reduced iron with additives such as CuO, $In_2O_3$, $MoO_3$ and $WO_3$ has been kinetically investigated. It was shown that all additives have a promoting effect on reaction activity in the order of $$MoO_3{\gg}In_2O_3{\sim_=}WO_3{\sim_=}CuO$$. The shrinking core model was applied to predict the complete conversion time and the results were quite comparable with experimental values. The reaction was carried out in a fixed flow reactor packed with reduced iron with 1 wt % of additives under the conditions, $600-750^{\circ}C$, Ar flow rate of 1 L/min and steam partial pressure of 0.085 atm. The apparent activation energies were 14.2, 20.9, 21.3, 22.4 and 27.9 kJ/mol with $MoO_3$, $In_2O_3$, $WO_3$, CuO and without additive, respectively.

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Electromechanical Behaviors and Application of Carbon Nanotube Composite Actuators Consisting of Bundles and Mats (다발/매트로 구성된 탄소나노튜브 복합재 엑츄에이터의 거동특성 및 응용연구)

  • Kim, Cheol;Liu, Xinyun
    • Composites Research
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    • v.18 no.5
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    • pp.34-39
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    • 2005
  • The relationship between strain and applied potential was derived for composite actuators consisting of single-wall carbon nanotubes (SWNTs) and conductive polymers (CPs). During deriving the relationship, an electrochemical ionic approach is utilized to formulate the electromechanical actuation of the composite film actuator. This relationship can give us a direct understanding of the actuation of a nanoactuator. The results show that the well-aligned SWNTs composite actuator can give good actuation responses and high actuating forces available. The actuation is found to be affected by both SWNTs and CPs components and the actuation of SWNTs component has two kinds of influences on that of the CPs component: reinforcement at the positive voltage and abatement at the negative voltage. Optimizations of SWNTs-CPs composite actuator may be achieved by using well-aligned nanotubes as well as choosing suitable electrolyte and input voltage range.

The Effective Control of Hot Weather Concreting by Optimum Mineral and Chemical Admixtures (혼화재 및 혼화제의 조절에 의한 서중 콘크리트의 효과적 관리)

  • Lee, Dongyule;Ham, Suyun;Oh, Taekeun
    • Journal of the Korean Society of Safety
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    • v.30 no.3
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    • pp.59-66
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    • 2015
  • The undesirable effects of elevated external temperatures at placement on the properties of the fresh and hardened concrete are discussed briefly, and the possible use of the mineral admixtures to mitigate them and the association with water-reducing and retarding admixtures in terms of the mix design which are critical for minimizing slump loss and entrained air loss are examined in this study. To investigate the effects of such the mineral and chemical admixtures on the fresh and hardened properties of concrete exposed to high temperature, a series of concrete mixtures subjected to the high temperature were carried out and then fresh and hardened properties of the mixtures were analyzed and evaluated. Based on the results, new guide lines concerning the appropriate admixtures for hot weather are suggested.

Thermomechanical Analysis of Composite Structures in Pyrolysis and Ablation Environments (열분해 및 삭마 환경의 복합재 구조물의 열기계적 연계 해석)

  • Choi, Youn Gyu;Kim, Sung Jun;Shin, Eui Sup
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.41 no.8
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    • pp.597-604
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    • 2013
  • A coupled thermomechanical analysis of composite structures in pyrolysis and ablation environments is performed. The pyrolysis and ablation models include the effects of mass loss, pore gas diffusion, endothermic reaction energy, surface recession, etc. The thermal and structural analysis interface is based upon a staggered coupling algorithm by using a commercial finite element code. The characteristics of the proposed method are investigated through numerical experiments with carbon/phenolic composites. The numerical studies are carried out to examine the surface recession rate by chemical and mechanical ablation. In addition, the effects of shrinkage or intumescence during the pyrolysis process are shown.

Effect of Lidocaine Compounds on the Expansion of Lipid Monolayer at the Air/Water Interface (국부 마취제로 이용되는 Lidocaine 화합물들이 공기/물 계면에 형성된 지질 단분자 막의 팽창효과에 미치는 영향)

  • Choi, Suk-Young;Oh, Seong-Geun;Lee, Ju-Seong
    • Applied Chemistry for Engineering
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    • v.9 no.7
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    • pp.1090-1097
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    • 1998
  • Lidocaine compounds have widely been used as local anesthetics. Regarding the molecular mechanism for anesthesia by lidocaine, it is proposed that lidocaine molecules penetrate to the hydrophobic region of cell membrane and expand the membrane volume, producing a change in protein conformation that blocks sodium permeability or lidocaine molecules directly adsorb into lidocaine receptor in the protein channel without expanding the cell membrane. But these proposals have never been proven experimentally. In this study, the expansion of cell membrane by lidocaine compounds was investigated by employing lipid monolayer at the air/water interface as the mimetic system of cell membrane. It was found that oil-soluble lidocaine contracted the area/molecule of lipid in the monolayer of phosphatidyl choline, sphingomyelin, DS-PL95E and lipoid, but expanded the monolayer of phosphatidyl ethanolamine only in a certain range of mixing ratios. On the contrary, water-soluble lidocaine-HCl salt expanded the monolayers of all lipids used in this study.

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A Study on the Low-Temperature Sintering Characteristic of the Mg-Zn ferrite which added CuO (CuO를 첨가한 Mg-Zn 페라이트의 저온소결 특성에 관한 연구)

  • Kwon, Oh-Heung;Kim, Do-Hwan;Choi, Young-Ji
    • Resources Recycling
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    • v.14 no.3
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    • pp.63-67
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    • 2005
  • As there are recent tendencies to raise horizontal frequencies so as to improve screen definition for high-quality TV and high definition display, ferrite core for deflective yokes requires materials with low coreloss in the areas of high frequencies. The researcher added CuO to low-loss Mg-Zn ferrite. After choosing MgO, ZnO, Fe$_2O_3$ and CuO, the researcher changed a ratio of composition, substituting MgO for CuO. These samples were sintered for three hours up to 980$^{\circ}C$~1350$^{\circ}C$. Measure magnetic permeability, electric loss, core loss and a rate of contraction.

Preparation and Characterization of Sulfonated Poly (Arylene Ether Sulfone) Random Copolymer-Polyolefin Pore-filling Separators with Metal Ion Trap Capability for Li-ion Secondary Battery (리튬이온 이차전지용 금속이온 선택성 술폰화 폴리아릴렌에테르술폰 공중합체-폴리올레핀 함침격리막 제조 및 특성)

  • Jeong, Yeon Tae;Ahn, Juhee;Lee, Chang Hyun
    • Membrane Journal
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    • v.26 no.4
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    • pp.310-317
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    • 2016
  • Lithium ion secondary battery (LISB) is an energy conversion system operated via charging-discharging cycle based on Lithium ion migration. LISB has a lot of advantages such as high energy density, low self-discharge rate, and a relatively high lifetime. Recently, increasing demands of electric vehicles have been encouraging the development of LISB with high capacity. Unfortunately, it causes some critical safety issues. It includes dendrite formation on negative electrode, resulting in electric shortage problems and battery explosion. Also, the elevated temperatures occurred during the LISB operation induces thermal shrinkage of polyolefin (e.g., polyethylene and polypropylene) separators. Consequently, the low thermal stability leads to decay of LISB performances and the reduction of lifetime. In this study, sulfonated poly (arylene ether sulfone) (SPAES) random copolymers were used as key materials to prepare polyolefin pore-filling separator. The resulting separators were evaluated in the term of metal ion chelation capability associated with dendrite formation, $Li^+$ ion conductivity and thermal durability.

A Study of Relations of Chain Lengths and Properties for Bifunctional linear DGEBF/Linear Amino (EDA, HMDA) Cure Systems (선형 이관능성 DGEBF/선형아민(EDA, HMDA) 경화계의 경화제 사슬길이와 물성과의 관계에 대한 연구)

  • Myung In-Ho;Lee Jae-Rock
    • Composites Research
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    • v.17 no.6
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    • pp.37-43
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    • 2004
  • To determine the effect of chain length and chemical structure of linear amine curing agents on thermal and mechanical properties, a standard bifunctional linear DGEBF epoxy resin was cured with EDA and HMDA having amine group at the both ends of main chain in a stoichiometrically equivalent ratio in condition of preliminary and post cure. From this work, the effect of linear amine curing agents on the thermal and mechanical properties is significantly influenced by numbers of carbon atoms of main chain. In contrast, the results show that the DCEBF/EDA system having two carbons had higher values in the thermal stability, density, shrinkage (%), grass transition temperature, tensile modulus and strength, flexural modulus and strength than the DGEBF/HMDA system having six carbons, whereas the DGEBF/EDA cure system had relatively low values in maximum ekothermic temperature, maximum conversion of epoxide, thermal expansion coefficient than the DGEBF/HDMA cure system. These findings indicate that the packing capability (rigid property) in the EDA structure affects the thermal and mechanical properties predominantly. It shows that flexural fracture properties have a close relation to flexural modulus and strength.

Evaluation of Diuretic and Hemodynamic Effect of Extract from Akebia quinata Decaisne in Dogs (개에서 목통(Akebia quinata Decaisne) 추출물의 이뇨효과 평가)

  • Han, Suk-Hee;Kim, Ye-Won;Hyun, Chang-Baig
    • Journal of Veterinary Clinics
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    • v.29 no.3
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    • pp.203-206
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    • 2012
  • Treatment for heart failure is directed to reduce atrial volume overload by diuretic agents, to lessen ventricular pressure overload by vasodilatory agents and to increase myocardial performance through inotropic agents. Of those cardiac therapeutics, diuretic agents are the most important to control heart failure in dogs, although long-term use often causes detrimental side-effects such as acute renal failure and electrolyte abnormalities. Thus, this study was designed to find a new diuretic agent from medicinal herbs which has better diuretic effect and less unfavorable complications in dogs. In a preliminary study performed with 5 normal healthy dogs, the extract from Akebia quinata Decaisne showed mild to moderate diuretic effect (0.3-0.5 potency of furosemide 2 mg/kg) and minimal changes in serum chemistry and electrolyte. Although the study population was not large enough and study period was not sufficient enough, this study found a good alternative diuretic agent which can replace or reduce the use of furosemide in dogs with heart failure.