• Rubber Technology
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• v.20 no.4
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• pp.231-238
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• 2019

• Electrical & Electronic Materials
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• v.4 no.2
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• pp.105-113
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• 1991

본 연구에서는 도전성 고분자인 포리파라훼니렌, 포리파라훼니렐비닐렌 및 포리치오휀을 화학적 및 전기화학적 합성에 의해 필림으로 합성하였으며 각종 도판트가 이들 고분자의 특성에 미치는 영향을 조사하였다. 이들 고분자는 이상적인 도우핑의 조건에서 미량의 도우프영역에서도 도전율은 분자 구조에 의해서 $10^{-4}$~$10^{2}$[S/cm]까지 현저히 증가하는 특성을 나타내었으며 또한 광학적 성직도 변화하여 가전자대와 전도대 사이에 새로운 준위가 형성이 되어 스핀 밀도의 증가와 선폭의 감소를 나타내었다.

• Journal of the Korean Chemical Society
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• v.34 no.6
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• pp.646-651
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• 1990

New optically active phosphonodipeptides were synthesized by coupling reaction of amino acids with 2-amino-3-(diethylphosphono)propionic acid methyl ester, prepared from L-serine.

• Journal of the Korean Chemical Society
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• v.54 no.5
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• pp.589-593
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• 2010

TBACl (10 mol %) was found to be a useful catalyst for the synthesis of substituted benzimidazoles. The method was proved to be simple, convenient and the product was isolated with good yield.

• Journal of the Korean Chemical Society
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• v.23 no.1
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• pp.30-36
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• 1979

Methyl 3-hydroxymethylorsellinate was synthesized from orcinol and various acetylation methods were studied. Two of three possible diacetates were prepared by short-interval acetylation procedure.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 1992.06a
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• pp.21-59
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• 1992

1980년대에 접어들면서 반합성유, 합성유가 산업전반에 광범위하게 적용되기 시작하였으며 많은 화학회사들이 꾸준히 성장하는 합성유 추세에 대해 관심을 가지게 되었다. 또한 광유와 합성유의 가격차가 생각보다는 크지 않다는 이유로, 광유와 합성유를 혼합하면 좀더 경제적일 수 있다는 판단하에 꾸준히 개발되고 있는 추세이다. 좀더 구체적으로 말하면, 1980-1985년 사이에는 예상보다는 성장율이 저조하였다. 그 이유는 합성유 또는 반합성유 판매로부터 이익을 얻으려는 수많은 윤활유 제조사들이나, 기계제조업체, 소비자들에게 어떤 합성유가 가장 경제적이며 우수한 것인지에 대한 접합성을 놓고 치열한 경쟁을 벌였기 때문이다. 제품별 합성유 현황을 좀더 자세히 알기 위해서는 우선 합성기유에 대한 이해가 필요하다.

• Journal of the Korean Chemical Society
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• v.40 no.10
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• pp.656-662
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• 1996

Using low temperature and atmospheric pressure method, we synthesized Na, TPA-ZSM-5 with Si/Al ratio of about 100. We employed 27Al and 29Si MAS NMR spectroscopy and FT-IR to investigate the crystallization process as a function of time. The chemical shift depends on the initial composition of reactants and changes during the course of synthesis different from those reported by others earlier. However, the chemical shift of our final product showed in the range of typical ZSM-5. And the defect site was removed by the calcine. From XRD and SEM data, the formation of ZSM-5 was also confirmed.

• Applied Chemistry for Engineering
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• v.30 no.3
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• pp.313-315
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• 2019

A new synthetic method for N-hydroxysuccinimide (NHS), which is widely used in fine chemical and cosmetic industries, was developed. In a conventional synthesis, NHS is obtained by reacting $NH_2OH$ with succinic anhydride in a yield of about 70% using strong acid as a catalyst, which has an advantage of obtaining NHS relatively easily. However, it is expensive because of using a high cost succinic anhydride. In order to overcome this issue, we developed a new synthetic method for NHS with a moderate yield of 80% using a low cost succinic acid instead of succinic anhydride, alongside a stable Lewis acid catalyst, Zn acetate. As a result of the economic evaluation, it was confirmed that the cost reduction effect was about 15%.

• Applied Chemistry for Engineering
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• v.31 no.6
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• pp.697-700
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• 2020

We report the synthesis and characterization of quartz nanocrystals (NCs). Quartz NCs were synthesized from the dissolution of amorphous silica nanoparticle precursors under the mild hydrothermal condition of ~250 ℃ and autogenic pressure. It was confirmed that the average size of the nanostructure with a highly crystalline phase of α-quartz can be tuned in a relatively narrow range from 407.5 to 826.2 nm with respect to the reaction time. α-Quartz NCs have potential uses for technological applications in optoelectronics, sensing, and rechargeable battery devices.

• Applied Chemistry for Engineering
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• v.31 no.3
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• pp.299-304
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• 2020

Nanoparticles play an important role as a catalyst in many chemical syntheses. Colloidal nanoparticles were usually synthesized with reducing, capping, and shape directing agents which induce surface poisoning of catalysts. A new green synthesis for silver nanoparticles was developed by utilizing less additives which could be a hazardous waste. A crystallization technique was employed to reduce the amount of reducing and capping agents during synthesis resulting in less surface poisoning of the nanoparticle. The synthesized Ag nanoparticles using monosaccharides and disaccharides as reducing agents could be used as a catalyst for the redox reaction of resazurin and the mechanism of the reaction using Ag nanoparticles was studied.