• Title/Summary/Keyword: 화학제품

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The Low Temperature Plasma Treatment and Sputte Treatment Compare with Function of One-side Water Repellentcy (저온 Plasma가공과 Sputter가공에 의한 편발수 기능의 비교)

  • Ma, Jae-Hyuk;Koo, Kang
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.11a
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    • pp.31-31
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    • 2011
  • 섬유제품은 대부분은 흡수성 또는 흡유성을 가지고 있어 물이나 기름이 등을 쉽게 흡수하는 성질이 있다. 이러한 성질 때문에 물이나 기름 등의 접촉에 의한 얼룩과 오염이 잘 되는 단점을 가지고 있다. 이러한 문제점을 해소하기 위하여 원단에 대한 발수, 발유, 방오가공 등이 연구되어 왔으며 섬유의 고유한 화학적, 기계적 물성을 유지하면서 표면과 이면이 다른 특성을 가지도록 유도하여 기능성을 부여하는 편면가공을 주목을 받게 되었다. 본 연구에서는 불소계로 발수처리 된 PET직물에 저온 Plasma와 Sputter을 이용하여 직물의 한쪽 면에는 친수성과 다른 면에는 발수성이 동시에 나타나는 편발수에 관한 실험을 했다. 불소계로 발수처리 된 시료와 저온 Plasma처리된 시료와 Sputter처리된 시료(처리면, 미처리면)를 접촉각 5회 측정하여 평균값을 나타냈다. 발수처리 된 시료의 평균 접촉각 값은 $149^{\circ}$이며, 저온 Plasma의 평균값은 $45^{\circ}$(처리면) $128^{\circ}$(미처리면), Sputter는 $74^{\circ}$(처리면) $144^{\circ}$(미처리면) 으로 가공처리 된 시료에는 양면의 접촉각이 확연한 차이가 나타난 걸로 미루어 보아 편면발수효과가 얻어졌다고 판단된다. SEM 측정을 통하여 관찰한 경우, 발수처리 된 시료에서는 불소계 발수제의 흔적이 보였다. 저온 Plasma, Sputter 처리된 시료에서는 처리시간이 높아짐에 따라서 시료표면에 코팅된 불소계 발수제 막들이 점점 파괴되는 것을 관찰할 수 있었다. 그리고 건식가공으로 인하여 처리된 표면에는 Etching작용이 일어나 표면적이 넓어져 친수화가 일어난 것으로 생각된다. 이처럼 저온 Plasma가공과 Sputter가공으로 편발수를 얻을 수 있다면 에너지 절약, 처리공정과 시간단축 등 여러 가지 장점이 기대된다.

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Current State of Use and the Risks of Bisphenols: A Minireview (비스페놀류의 사용 현황과 위해성: 소고)

  • Song, Chang Yeob;Kim, Woong;Gye, Myung Chan
    • Korean Journal of Environmental Biology
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    • v.35 no.4
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    • pp.581-594
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    • 2017
  • Bisphenol A(BPA), known as a typical endocrine disruptor, has been used commercially and widely for plastics and epoxy resins. BPA-based plastic is used extensively for the production of water bottles, food containers, CDs, DVDs, and panels that can be applied in construction. Epoxy resins containing BPA are used for coatings on the insides of water pipes, food cans, and thermal papers that are used in sales receipts. As its estrogenic effects and other adverse health effects have published, BPA has been regulated in many countries, and there have been efforts made to replace BPA. Other bisphenols substitutes such as bisphenol S(BPS) and bisphenol F(BPF) have been used. Currently, BPS- and BPF-based products labeled BPA-free products have been widely consumed. Because of structural similarities with BPA, however, these alternatives also show endocrine disruption effects like BPA, and many studies on adverse health effects of these alternatives are being reported. In this review, we describe the adverse health effects of bisphenols and the current status of regulation.

Isolation of Chitin from Crab Shell Waste (게 가공 폐기물로부터 키틴의 분리)

  • 노홍균;이문이
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.24 no.1
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    • pp.105-113
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    • 1995
  • Procedures for isolatin of chitin have been developed from crab(Chionoecetes opilio) shell waste with 26. 65% chitin on a dry basis. Optimal conditions for demineralization of crab shell were 1N HCl at ambient temperature for 30min with a solids to solbent ratio of 1 : 15(w/v). Optimal deproteinization involved treatment with 5% NaOH at $65^{\circ}C$ for 1 hr with a solids to solvent ratio of 1 : 15(w/v). Effective decoloration was achieved by bleaching with 0.32% sodium hypochlorite solution for 3min with a solids to solvent ratio of 1 : 10(w/v). Particular attentin was given to characterization of the physicochemical properties of the crab chitin. Chitins, from four different mesh sizes of crab shell, did not show significant differences in nitrogen and ash compositions. Bleaching decreased the viscosity of chitin but did not affect its solubility.

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Effect of Cooking Conditions on Quality Changes of Braised Kidney Beans during Storage (가열조리조건에 따른 강낭콩조림의 저장 중 품질변화)

  • Chung, Sun-Kyung;Lee, Dong-Sun;Lyu, Eun-Soon
    • Food Science and Preservation
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    • v.14 no.2
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    • pp.142-147
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    • 2007
  • We optimized braising time to improve the storage quality of braised kidney beans. The beans were prepared with different heating times between 25 and 50 min. and then stored at $10^{\circ}C$ for 20 day. Physical, chemical, microbiological, and organoleptic quality indices were monitored throughout storage. Longer braising times yielded products with lower concentrated brine coverage. Bis resulted in higher soluble contents and slightly lower water activities. Excessive heating time exposed the kidney beans to air and caused rapid microbial growth on the surfaces of the beans, which negatively affected product quality. The longest heating time of 50 min. also resulted in a large increase in product hardness. A braising time of 30 min. was best for preservation, as good sensory quality was mainatained.

A Study on the Stern Bearing Damage and Shaft Alignment for 37K DWT Product/Chemical Tanker (37K DWT 석유화학제품 운반선의 선미관 베어링 발열 사고 및 축계정렬에 대한 연구)

  • Park, Geumsung;Koh, Changik;Chung, Jaewook;Nam, Gunsik;Chae, Junsik
    • Journal of the Society of Naval Architects of Korea
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    • v.58 no.2
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    • pp.97-104
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    • 2021
  • Together with the emerging of the Eco-ship, the application of large-diameter and high-efficiency propeller required more careful attention than before in the design of the shafting system. After the adoption of Environmentally Acceptable Lubricants (EAL) to the stern tube lubrication oil, a number of aft stern tube bearing accidents have been reported, and a variety of institutions have actively conducted research on the cause relationship. This study attempted to find the cause of the accident by measuring the alignment of the shafting system of a medium-sized product/chemical tanker with aft stern tube bearing damage and analyzing the reaction force of each bearing. In addition, a reasonable solution to the correction of the shaft alignment was suggested and the feasibility was reviewed. Through various measured data and analysis, the actual installation of shafting system was slightly different from the design drawing condition, but it was found that each bearing load distribution was within the allowable range. Therefore, it was confirmed that the cause of this accident was due to the dissatisfaction the misalignment slope of aft stern tube bearing rather than the effect of the bearing overload. As a solution to this cause, countermeasures such as double slope were suggested in the aft stern tube bearing, and the characteristics of EAL also seem to have an indirect effect.

Determination of Capsaicin, Dihydrocapsaicin and Nonivamide by Gas Chromatography (기체크로마토그래피에 의한 캡사이신, 디하이드로캡사이신 및 노니바마이드(PAVA)의 정량)

  • Kim, Sang-Soo;Yoon, Joong-Soo
    • Journal of the Health Care and Life Science
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    • v.9 no.1
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    • pp.141-146
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    • 2021
  • Determination of capsaicin, dihydrocapsaicin and nonivamide in pungent liquids of self-defense spray were studied. The nonivamide having almost same spicy taste with capsaicin have been containing a few amounts in natural products, it had called as synthetic capsaicin or PAVA, have used to flavorings for foodstuffs and incapacitating agents of riot controls. Nowadays, it has been occasionally found that the quality controls of a self-defense sprays were not properly due to flood of illegal self-defense sprays. Thus, the simple analytical method with gas chromatography is developed, it is identified whether the products which have contained synthetic capsaicin were marked like natural materials as well as the pungent ingredients in it obeyed with permissible concentration to human or not was investigated. Finally, the pungent components and amounts in some kinds of self-defense spray were investigated.

Structural and Physicochemical Properties of Dried Aloe Vera Gel Using DIS (Dewatering & Impregnation Soaking) Process (삼투탈수 알로에 건조제품의 구조적 및 물리화학적 특성)

  • Kim, Sung-A;Baek, Jin-Hong;Lee, Shin-Young
    • Food Engineering Progress
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    • v.13 no.1
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    • pp.24-31
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    • 2009
  • The structural and physicochemical properties of dried aloe vera gel by DIS (dewatering impregnation soaking) process under optimum conditions were investigated. FT-IR spectra for dried samples of DIS aloes showed the typical patterns of standard aloe polysaccharide, and surface structures by SEM (scanning electron microscopy) were similar to a gel-like structure. In case of physicochemical properties of dried aloe samples by DIS process, solubilities and swelling powers of control (not osmotic treated aloe), DIS (S) and DIS (G), samples treated by osmotic solution of 60% sucrose/0.25% NaCl and 50% glucose/0.5% NaCl, were 48.3-57.3% and 8.3-11.7%, respectively, showing no significant differences among samples, but swelling power of DIS (PEG), sample treated by using 50% polyethylene glycol as an osmotic agent was about 5 times higher that of control. Also, water holding capacities of control, DIS (S) and DIS (G) were similar to each other, but that of DIS (PEG) was about 5 times higher that of control. Oil holding capacities of control and DIS aloes maintained the 50.9-86.4% levels of water holding capacities showing no significant differences among samples. Rehydration ratio of DIS (PEG) aloes were significantly dependent on the temperature of rehydrated solvent (water), and rehydration ratio of not-fileted aloe was about two folds higher than that of fileted aloe.

Hair Protection Effect by Adding Mask Pack Active Ingredients to the End Paper During Permanent Wave Treatment (퍼머넌트 웨이브 시술시 엔드 페이퍼에 마스크팩 유효성분 첨가에 따른 모발 보호효과)

  • Lee, Bo-Lim;Ko, Kyoung-Sook
    • Journal of Convergence for Information Technology
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    • v.11 no.11
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    • pp.288-295
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    • 2021
  • This study was conducted to investigate the effect of end paper adsorbed with mask pack active ingredients on hair during permanent wave treatment. Permanent wave was performed with purchasing mask packs containing green tangerine, collagen, and Houttuynia cordate active ingredients among commercially available mask packs and adsorbing them to the end paper. As experimental methods, hair thickness, hair moisturizing power, tensile strength, hair epidermis observation using SEM, and hair constituent element analysis using EDS were performed. As a result of the experiment, it was confirmed that the experimental group treated with Houttuynia cordate active ingredient on the end paper had a hair protection effect as a result of hair thickness, tensile strength, hair epidermis observation, and hair component analysis. In addition, it was confirmed that the experimental group treated with green tangerine active ingredient on the end paper contained a relatively large amount of moisture in the hair moisturizing power test result. It is hoped that the development and research of various materials and tools will proceed so that basic cosmetic products containing active ingredients can be developed and used as hair cosmetics, and applied during chemical treatment in the industrial field.

Establishment of Remote Meteor Spectroscopic Observation System and Observation Case Study (원격 유성 분광 관측 시스템 구축과 관측 사례 연구)

  • Choi, Dong-Yeol
    • Journal of the Korean earth science society
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    • v.43 no.1
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    • pp.1-22
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    • 2022
  • We provide a detailed description of the installation and operation of a remote spectroscopic meteor observation system at Unjangsan optical astronomy observatory. Three light-sensitive charge-coupled device cameras were installed, and two cameras had a diffraction grating attached to the front of the lens. Station employ sensitive "Watec-902H2" cameras in combination with f/1.2 lenses were installed in November 2019. Diffraction gratings for spectral observations were used at 500 l/mm. Observations were conducted from November 2019 to June 2020. We employed the SonotaCo UFO software suite for meteor detection. Subsequently, meteor spectra were analyzed using field-tested RSpec software. To analyze the observation images, astronomical calibration and photometric calibration were performed, and the chemical elements of the meteor were determined. The study results are presented along with the system setup installation and operation experience. Brief information regarding the origin of the meteor was also provided based on the results.

Characteristics and Co-Occurrence Patterns of Fragrance Allergens in Consumer Chemical Products (생활화학제품의 알레르기반응가능 향료성분 함유 현황 및 동시 출현 패턴 조사)

  • Kim, Soomin;Lee, Kiyoung;Lim, Miyoung
    • Journal of Environmental Health Sciences
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    • v.48 no.4
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    • pp.206-215
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    • 2022
  • Background: Fragrance substances in consumer products can cause adverse health effects such as contact allergy. In South Korea, consumer chemical products must list 26 known fragrance allergens on product labels when they contain more than 0.01%. Fragrance substances are mostly used in combination, so co-exposure can occur via use of a consumer chemical product. Co-exposure to fragrance allergens may show a synergistic effect on the human body. Objectives: The aims of the study were to analyze the characteristics of fragrance allergens in consumer chemical products available on public websites and to identify the co-occurrence patterns of fragrance allergens. Methods: The chemicals in 1,443 ingredient disclosures for consumer chemical products were collected through the Ecolife database. The 26 labelled fragrance allergens were identified by category of consumer chemical product. The co-occurrence patterns of the 26 labelled fragrance allergens were analyzed by frequent pattern mining. The unlabelled fragrance allergens presented by European Union Scientific Committee on Consumer Safety were also identified. Results: Consumer chemical products contained an average of 5.3±4.2 substances among the 26 labelled fragrance allergens. More than 85% of air fresheners, deodorizing agents, and fabric softeners contained at least one of the 26 labelled fragrance allergens. The most frequently contained fragrance allergens were limonene (50.5%), linalool (49.9%), hexyl cinnamal (34.0%), and citronellol (28.3%). 16.7% of consumer chemical products showed a co-occurrence of limonene, linalool, hexyl cinnamal, and citronellol. Thirty-eight unlabelled fragrance allergens were found in the consumer chemical products, with hexamethylindanopyran (25.2%) being the most frequently contained substance. Conclusions: The characteristics and co-occurrence patterns of 26 labelled fragrance allergens would be useful information for the management of co-exposure to fragrance allergens in consumer chemical products. It is necessary for attention to be paid to unlabelled fragrance allergens.