• Title/Summary/Keyword: 화학적 유형

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Origin of B, Br and Sr in Groundwater from Bukahn-myeon, Yeongcheon, Gyeongbuk Province, with Emphasis on Hydrochemistry (지하수의 수질화학적 특징과 붕소, 브롬, 스트론튬 성인에 대한 고찰)

  • Choo, Chang-Oh;Lee, Jin-Kook;Lee, Chang-Joo;Park, Ki-Ho;Jeong, Gyo-Cheol
    • The Journal of Engineering Geology
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    • v.19 no.2
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    • pp.235-250
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    • 2009
  • Environmental elements such as B, Br, and Sr in groundwater from Bukahn-myeon, Yeongcheon, Gyeongbuk Province, were investigated in order to know their origin with emphasis on hydrochemistry. pH ranges from 7.37 to 8.39. B content is 0.41${\sim}$4.62 mg/L with an average 1.74 mg/L and Br content is 0${\sim}$3.24 mg/L with an average 2.22 mg/L, and Sr content is 0.93${\sim}$8.64 mg/L with an average 2.76 mg/L. The water types plotted by the Piper diagram are different but mostly $Ca-HCO_3$. Some constituents contributing to EC are Na, $SO_4$, Cl with high determinative coefficients($R^2$) of 0.85, 0.70, 0.90, respectively. The coefficients($R^2$) of Cl to Na, K, $SO_4$ are 0.54, 0.68, 0.53, respectively. It should be noted that there are high cocfficients($R^2$) of B-Sr and $Sr-SO_4$ with 0.65, 0.64, respectively. The Cl/Br ratios are 5.21${\sim}$30.70 due to significant depletion of Cl. The $SO_4/Cl$ ratios are 1.32${\sim}$27.24 with an average of 5.92, ascribed to abundant introduction of $SO_4$ or significant depletion of Cl. Chemical speciation calculated shows that B exists mostly as $H_3BO_3$ with less $H_2BO^-_3$ and Br exists as only $Br^-$. Sr exists mostly as $Sr^2$ with less $SO_4$. Saturation index represents that goundwater is supersaturated with respect to barite, kaolinite, illite, K-mica, and smectite while it is slightly undersaturated with respect to silica, gypsum, anhydrite, talc, chrysotile, feldspar, kaolinite, illite, K-mica, and smectite. The saturation index of celestine is -2.23${\sim}$-0.13 indicating more Sr can be incorporated into groundwater. Groundwater is still much undersaturated to halite. It is likely that the origin of S and Sr was related to the Yucheon volcanic rocks. Br might be originated from the local geological features with introduction of anthropogenic matters.

Sulfide Chimney from the Cleft Segment, Juan de Fuca Ridge: Mineralogy and Fluid Inclusion (Juan de Fuca 해령 Cleft Segment에서 회수된 황화물 침니: 광물조성 및 유체포유물)

  • 윤성택;허철호;소칠섭;염승준;이경용
    • Economic and Environmental Geology
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    • v.35 no.3
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    • pp.203-210
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    • 2002
  • In order to elucidate the growth mechanism of sulfide chimney formed as a result of seafloor hydrothermal mineralization, we carried out the mineralogical and fluid inclusion studies on the inactive, sulfide- and silica-rich chimney which has been recovered from a hydrothermal field in the Cleft segment of the Juan de Fuca Ridge. According to previous studies, many active and inactive vents are present in the Cleft segment. The sulfide- and silica-rich chimney is composed of amorphous silica, pyrite, sphalerite and wurtzite with minor amounts of chalcopyrite and marcasite. The interior part of the chimney is highly porous and represents a flow channel. Open spaces within chimneys are typically coated with colloform layers of amorphous silica. The FeS content of Zn-sulfides varies widely from 13.9 to 34.3 mole% with Fe-rich core and Fe-poor rims. This variation possibly reflects the change of physicochemical characteristics of hydrothermal fluids. Chemical and mineralogical compositions of the each growth zone are also varied, possibly due to a thermal gradient. Based on the microthermometric measurements of liquid-rich, two-phase inclusions in amorphous silica that was precipitated in the late stage of mineralization, minimum trapping temperatures are estimated to be about 1140 to 145$^{\circ}$C with the salinities between 3.2 and 4.8 wt.% NaCI equiv. Although the actual fluid temperatures of the vent are not available, this study suggests that the lowtemperature conditions were predominant during the mineralization in the hydrothermal field at Cleft segment. Comparing with the previously reported chimney types, the morphology, colloform texture, bulk chemistry, and a characteristic mineral assemblage (pyrite + marcasite + wurtzite + amorphous silica) of this chimney indicate that the chimney have been formed from a relatively low-temperature (<250$^{\circ}$C) hydrothermal fluid that was changed by sluggish fluid flow and conductive cooling.

Local Control and Survival in Radiation Treatment of Locally Advanced Non-Small Cell Lung Cancer (III 병기 비소세포성 폐암의 방사선 치료성적)

  • Song, Mi-Hee;Yong, Jin-Young;Oh, Won-Young;Yoo, Nam-Soo;Whang, In-Soon
    • Radiation Oncology Journal
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    • v.11 no.2
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    • pp.311-319
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    • 1993
  • The retrospective analysis was performed on 37 patients with stage III non small cell lung cancer who received the radiotherapy from Feb. 1986 to Dec. 1990 at the Dept. of Radiation Oncology, National Medical Center. This analysis, with 29 patients $(78.4\%)$ having been followed from 10 to 60 months, was done to know the survival rate and significant prognostic factor. The actuarial 2,5-year survival rates were $20.6\%,6.9\%$ in our all patients and median survival time was 10 months. Of patients with KPS (Karnofsky prformance status) greater than $80\%,$ the 2, 5 year survival rate and median survival time were $29.2\%,9.7\%$ and 13 months, respectively. The 2-year survival rate and median survival time of patients with KPS less than $80\%\;were\;13.7\%$ and 7 months, respectively. The survival difference according to performance status was statisticaly significant $(29.2\%\;vs.\;13.7\%)(p<0.05).$ In stage IIIa, the 2,5-year survival rate and median survival rate and median survival time were $29.2\%,9.7\%$ and 12 months, respectively. The 2-year survival rate and metian survival time of stage IIIb were $8.6\%$ and 10 months, respectively. The survival difference between stage IIIa and IIIb did not show statistical significance (p>0.1). Of the prognostic factors, the difference of survival rate by initial performance status was statistically significant (p<0.05). But the difference of survival rates by pathologic cell type, stage, total radiation dose, radiotherapy response, and cmbination with chemotherapy were not statistically significant.

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Physicochemical Characteristics of Particulate Matter Emissions of Different Vehicles' Fuel Types (자동차 연료유형에 따른 배출 입자상 물질의 화학적 특성)

  • Son, Jihwan;Kim, Jounghwa;Park, Gyutae;Kim, Sunmoon;Hong, Heekyoung;Moon, Sunhee;Park, Taehyun;Kang, Seokwon;Sung, Kijae;Chung, Taekho;Kim, Ingu;Kim, KyungHoon;Yu, Dong-Gil;Choi, Kwangho;Kim, Jeong Soo;Lee, Taehyoung
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.6
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    • pp.593-602
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    • 2016
  • The physicochemical characteristics of particulate matter emissions from various vehicle's fuel types were studied at the facility of Transport Pollution Research Center(TPRC), National Institute of Environmental Research (NIER), Korea. Three different types of fuels such as gasoline, liquefied petroleum gas (LPG) and diesel were tested on the NIER driving mode and the constant speed modes(30, 70, and 110 km/h). Chemical composition of submicron particles from vehicle emissions was measured by the High Resolution Time of Flight Aerosol Mass Spectrometer (HR-ToF-AMS) during running cycles. Organics were dominant chemical species of particulate matter emissions for all three different vehicles' fuel types. Moreover, regardless of fuel types, emission rate of organics and inorganics decreased as the average speed of vehicle increased. The portion of fully oxidized fragment families of $C_xH_yO_z$ accounted for over 98% of organic aerosol(OA) in LPG and diesel vehicles, while the relatively high fraction of $C_xH_y$ in OA was observed in gasoline vehicle.

Analysis of Photoluminescence of Eu3+ in YOBr and Investigation of Critical Distance (YOBr:Eu3+ 형광체의 발광특성과 임계거리 연구)

  • Kim, Gyeong Hwa;Park, Jong Gyu;Park, Hui Dong;Han, Jeong Hwa
    • Journal of the Korean Chemical Society
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    • v.45 no.6
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    • pp.570-576
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    • 2001
  • The europium doped yttrium oxybromide phosphors were synthesized by solid-state reaction method. The YOBr: $Eu^{3+}$ phosphor showed a strong and narrow red emission band at 621 nm and maximum emission intensity obtained when 0.05 mol Eu ions were doped. The red emission of $Eu^{3+}$ originated from $^5D_0$ ${\rightarrow}$ $^7F_2$electric dipole transition. In order to investigate on photoluminescence behavior, several experimental skills and numerical fittings are conducted to the YOBr: $Eu^{3+}$ phosphor. The emission spectrum was measured in the UV range and then decay curve of $^5D_0$ ${\rightarrow}$ $^7F_j$transitions was examined. The energy interaction type of YOBr: $Eu^{3+}$ phosphor was dipole-dipole interaction. In addition to the calculating by critical concentration, the critical distance ($R_0$) was calculated by decay curve fitting parameter from Inokuti-Hirayamas equation, and spectral overlap method. The critical distance was 17.03, 10.51 and 7.18$\AA$ for those methods, respectively. As considering systematic error of measurements, these values are within the same order, so that the above fitting methods are plausible and recommendable.

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Stability of Tris(2-cyclohexylaminoethyl)amine-Zn(II) Complex (Tris(2-cyclohexylaminoethyl)amine-Zn(II) 착물의 안정성)

  • Yong Woon Shin;Hyun Sook Baek;Jae-Kyung Yang;Jineun Kim;Moo Lyong Seo
    • Journal of the Korean Chemical Society
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    • v.47 no.2
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    • pp.121-126
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    • 2003
  • Tris(2-cyclohexylaminoethyl)amine (L) was synthesized by the Schiff base condensation reaction of tris(2-aminoethyl)amine with cyclohexanone, followed by reduction. The thermodynamic characteristics, mole ratio and formation constant of [Zn(II)-L] complex were measured by the cyclic voltammetry and isothermal titration. In the case of Zn(II), well-defined cathodic and anodic peak were obtained at -1.02V and -0.48V vs Ag/AgCl , respectively. For the [Zn(II)-L] complex, both peaks were obtained at -1.19V and -0.45V vs Ag/AgCl, respectively. In addition, the peak height gradually increases as the scan rate increases, suggesting that the currents obtained were diffusion - controlled. The mole ratio and stability constant of the complex measured cyclic voltammerty were 1:1 and logK$_f$= 5.8, respectively. And the mole ratio and stability constant of the complexe calculated by isothermal titration method was 1:1 and logK =5.4, respectively. ${\Delta}$H, ${\Delta}$G and T${\Delta}$S for the complex formation were -53.0 kJ/mol, -31.1 kJ/mol, and -21.9 J/K at 25 ${\circ}$C, respectively.

Ultrastructural Study on the Parenchymal Cell of Korean Planaria (Dugesia japonica) (한국산 플라나리아(Dugesia japonica Ichikawa et Kawakatsu) 유조직의 미세구조에 관한 연구)

  • 장남섭
    • The Korean Journal of Zoology
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    • v.30 no.1
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    • pp.53-70
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    • 1987
  • The morphological study on the parenchymal cells in the adult planaria performed to observe their cytochemical and ultrastructural characteristics. The results are as follows. Nine types of cells are found in parenchyma. 1. Free parenchymal cell: These cells contain several chromatoid bodies around the nucleus. Heterochromatins are evenly dispersed in large nucleus. These cells are abundant in free ribosomes. 2. Fixed parenchymal cells: These cells have well-developed granular endoplasmic reticulum, mitochondria and Golgi complex but they contain the cytosols exhibiting electron-lucencies. 3. Rhabdite-forming cells: These cells contain the electron-dense rhabdite granules of up to about 0.3 x 0.9 $\mu$m in size. Rhabdite-forming cells have well-developed cell organelles, granular endolplasmic reticulum, mitochondria and Golgy complex. 4. A-type of basophilic granule cells: These cells contain irregularly-shaped granules exhibiting alcianophilia. These granules surrounded by a limited membrane, approximately 1.4 x 0.7 $\mu$m in size, are accumulated in the cytoplasm. 5. C-type of basophilic granule cells: These cells contain electron-dense granules of less than 0.2 $\mu$m in size, which exhibit PAS- positive reaction. This type of granule is also found in the muscle layer of parenchyma. 6. D-type of basophilic granule cells: This type of granule cell occurs only in the parenchyma around reproductive organ. The granules have cytochemical characteristics that they exhibit strongly positive reaction with PAS and weakly eosinophilic property. These electron-dense granules, which are 0.2 to 0.6 $\mu$m in length, have oval shapes. 7. E-type of basophilic granule cells: These cells are found only in the parenchyma around re productive organ. The granules contained in a small number in the cell, exhibit PAS-positive reaction and have an average size of 0. 2pm. 8. Eosinophilic granule cells: These cells contain a large number of eosinophilic granules which have relatively diverse sizes from 0.3 x 0.2 to 0.8 x 0.4 $\mu$m. Most of granules are round or irregularly-shaped and highly electrondense. These cells have an array of well-developed granular endoplasmic reticulum of which cisternae are distened. 9. Transparent granule cells contain electron-lucent granules which exhibit negative reactions with three kinds of cytochemical methods used in this experiment.

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동축형 분사기 분무특성 및 연소의 이론적 모델

  • 원영덕;윤웅섭;김영수;윤경택
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2000.04a
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    • pp.4-4
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    • 2000
  • 일반적인 액체추진제 로켓엔진의 연소는 분사제트의 미립화, 액적의 증발, 기상 추진제의 혼합, 화학반응 등, 일련의 물리적 과정들로 이루어지고, 여기서 특성속도 효율은 크게 분사특성 및 연소의 두 단계에서 결정되게 된다. 액체추진제 로켓엔진에 사용되는 여러 분무형태 중, 동축형 분사기에서는 액상과 기상 제트의 운동량 차에 의해 미립화가 이루어지며, 분무 액적들의 전개와 더불어 분사기 출구를 포함한 전 영역에서 연소가 발생되므로 매우 복잡한 물리적 특성들을 포함하게 된다. 본 연구에서는 기상 연료-액상 산화제의 동축형 분무연소를 JANNAF의 방법을 사용하여 수식화 하였으며, 이를 바탕으로 분무특성과 연소성능 예측을 위한 프로그램을 작성, 분사조건에 의한 분무특성과 그에 따른 연소성능을 계산하였다. 연속, 운동량, 에너지 및 혼합비 방정식의 지배방정식들을 바탕으로 기상 유동을 수식화 하였으며, 별도로 액적의 소산 및 연소과정을 모사하기 위한 별도의 수식들이 추가되었고, 이 식들을 결합하여 액적의 크기, 분포를 포함하는 액체 제트의 미립화 정도를 공간적으로 계산하였다. 미립화 모델의 검증을 위하여 계산 결과를 Reitz의 실험과 Giridharan의 모델 등과 비교하였으며 잘 일치하는 경향을 나타내었다. 또한 동축형 분사기에서의 분무 특성을 예측하기 위해 액체 산소, 기체 수소를 추진제 조합으로 하는 동축형 분무 연소장에서의 제트 길이, 액적의 크기, 액체 제트의 속도를 계산하였다. 계산 결과 액체 제트의 접촉길이는 분사공의 지름이 증가할수록 웨버수가 증가되므로 짧아지는 것으로 관찰되었으며 액적의 크기도 분사공의 지름이 증가할수록 작아지는 경향을 나타내었다. 액체 제트의 속도는 처음에는 일정하게 유지되다가 운동량을 보존하기 위해 가스로부터 운동량을 받아 점차 가속되어지는 것으로 나타났다.본 규격은 키, 총장, 어깨길이, 등길이, 머리길이, 머리둘레, 진동둘레, 목둘레, 가슴둘레, 허리둘레, 배둘레, 엉덩이둘레, 앞품, 뒤품, drop치를 포함하고 있고, 각 규격에서 호칭간 치수 간격도 함께 제시하고 있다. 본 연구 결과에서 보듯, 현행 8규격의 무진복의 각 호칭간 적정 허용범위를 고려해 합리적인 치수체계를 정립한다면 치수에 대한 적합도가 상당히 증가할 뿐 아니라 생산비용도 상당히 감축할 것으로 생각된다.나타났다. 4) 호감적 서비스능력 차원에서 세 독립변수간에 유의한 3원 상호작용이 존재하는 것으로 나타나( $F_{2,228}$=15.62, P<.001) 20대에 적합한 의복 착용시( $F_{2,228}$=3.98, P<.05)와 60대에 적합한 의복 착용시( $F_{2,228}$=16.55, P<.001) 점포유형과 격식차림간에는 유의한 상호작용이 존재하는 것으로 나타났다. 5) 호감을 구성하는 세 요인들이 구매의도에 미치는 영향을 조사한 결과 호감적 인상차원은 29%(P<.001), 호감적 서비스능력차원은 6%(P<.001)의 구매의도를 설명해 주는 것으로 나타났다. 본 연구결과 노년 소비자에게 호감을 주는 판매원의 외모는 구매의도에 영향을 주어 실버의류산업의 이익증대와 밀접한 연관을 갖는 서비스품질의 중요한 요인으로 밝혀졌다.중요한 요인으로 밝혀졌다.로운 단백질 EPSPS가 다른 여러 식물에 이미 존재하고 있는 단백질로서 우리가 이미 이러한 식품을 섭취할 때 이 단백질도 같이 섭취해오고 있었다는 점, 둘째. 이 단백질이 소화액 분해 실험에서 짧은 시간내에 분해가 되었다는 점, 셋째. 재조합 된 콩과 자연 콩이 성분 분석에서 차이를 나타내지 않았다는 점, 네 번째. 쥐를 통한 다양섭취 실험에서 아무런 이상 반응이 없었

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Interpretation of C.C.L.Hirschfeld's Theory of Garden Art in Contemporary Meaning and Its Significance (히르시펠트(C.C.L.Hirschfeld) 정원예술론의 의미와 가치의 현대적 해석)

  • Zoh, Kyung-Jin
    • Journal of the Korean Institute of Traditional Landscape Architecture
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    • v.32 no.3
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    • pp.58-68
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    • 2014
  • Christian Cay Lorenz Hirschfeld is often regarded as 'a father of landscape garden art.' He was an aesthetics professor and garden theoretician in the $18^{th}$ century. He put forth the most comprehensive garden theory book in five volumes between 1779 and 1785. His book, Theorie der Gartenkunst, was translated and widely circulated in his contemporary. The book, which dealt with diverse aspects of garden art such as history, design, material, and type, urged to promote the prevalence of landscape garden in European continents as well as in Germany. However, there have scarcely been discourses in the Hirschfeld's garden theory. This essay aims to review Hirschfeld's garden thoughts in his book critically and to reinterpret some issues in the contemporary landscape theory and practice. Hirschfeldian theory was the product of $18^{th}$ century German Enlightenment and romanticism. At that time, Nature was regarded as divine realm. There was a German affinity with natural world. The spread of reading culture and the fashion of travel literature were another background of the success of his garden literature. Several issues in Hirschfeld garden theory will discussed here. First, privileging garden art was the most significant contribution in his theory. He emphasized that garden art was the most advanced art form among all art genres. Second, garden art was grounded on the mimesis of nature. The ambiguous relationship between nature and art still existed in garden making. However, garden art can be flourished when utilizing the potency of nature in itself. Third, there was the association between the image and the idea in experiencing the garden. Some garden scenes stimulated the related emotional responses such as cheerful and merry, softly melancholic, romantic, solemn etc. Fourth, the movement was the essential aspect of garden art. Motion and emotion are come together in garden experience. To represent the landscape garden style in suitable way, the sketch or image seems to be preferable than the plans and views. Finally, garden art was composing of not only the physical space but also the spirit of place. He maintained the garden art as hortus moralis should be a social metaphor. Hirschfeldian garden theory has often been criticized as the lack of practical power and the old fashioned idea. However, his theory influenced on formulating the idea of public park in $19^{th}$ century. Moreover, there are still some visionary aspects of his theory such as the reevaluation of garden art, the emphasis of locality and the introduction of Mittelweg idea. Recently, gardening culture are prevalent in various realms of art and life. Hirschfeld's garden theory as humanistic landscape theory can provide us some insights in the contemporary practices.

Mineralogy of Size Fractions in Sancheong Kaolin and Its Origin (산청고령토 입도분리시료들의 광물조성 변화와 그 원인)

  • Jeong, Gi-Young;Kim, Soo-Jin
    • Journal of the Mineralogical Society of Korea
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    • v.5 no.1
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    • pp.22-31
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    • 1992
  • The Sancheong kaolin was fractionated into 9 size fractions by wet sieving, sedimentation, and centrifugation. The systematic X-ray diffraction combined with electron microscopy shows that the clay mineral composition of each size fraction is related to the original fabric of kaolin. Minerals such as halloysite (10${\AA}$), kaolinite, illite, and goethite which were formed by procipitation from solution are generally concentrated in the finer fractions, whereas verniculite which was formed by pseudomorphic transformation from other primary minerals are concentrated in the coarser factions. Kaolinits of various types which were formed by precipitation or transformation show a wide size range but they are generally concentrated in the coarser fractions. Halloysite or halloysite-kaolinite clusters in coarse fractions are the fragmentation products of the walls of original boxwork clusters in coarse fractions are the fragmentation products of the walls of original boxwork kaolin which escaped the complete dispersion even through the grinding, ultrasonic agitation, and chemical treatment. Separation of fully hydrated halloysite and kaolinite was possible by systematic wet size fractionation. The coarse-grained minerals such as vermiculite and kaolinite are usually removed during the preparation of clay fraction smaller than 2${\mu}m$, whereas the fine-grained minerals such as illite and goethite are overlooked in X-ray diffraction of the bulk samples because of their minor contents. The systematic wet size fractionation is needed for understanding of the exact mineralogy of kaolin of weathering origin.

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