• Analytical Science and Technology
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• v.18 no.4
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• pp.329-337
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• 2005

TL dating using pre-dose effect is concerned with the sensitivity increase of $110^{\circ}C$ TL peak in quartz following the pre-exposure of irradiation (pre-dose) in antiquity and heating to thermal activation temperature. Using the multiple activation (MA) method for determining an equivalent dose, the activation temperature was selected to $500^{\circ}C$ and the region of interest was selected from $85^{\circ}C$ to $105^{\circ}C$ on quartz sample from archaeological remains, roof-tile kiln. which was excavated at Chudong-Ri cultural site. It was concluded that the resultant date was determined to the age of $1725{\pm}25years$ AD (l ${\sigma}$ SD), which had more improved precision considering with e radiocarbon dates and was in good agreement with the age derived by archaeological assessment. Also it was concluded that the pre-dose dating should contribute significantly to future archaeological dating work in the range of the last 2000 years.

• The Journal of the Petrological Society of Korea
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• v.10 no.3
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• pp.179-189
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• 2001

The determination of trace concentration of U, Th and Pb was carried out for chemical dating of zircon and monazite by electron microprobe. Detection limit and error range should be considered to measure characteristic X-rays of M-line from those minerals, which are low in the ionization of atom and low peak intensity in the spectrum. The element of U, Th and Pb were simultaneously measured with 3 spectrometers equipped with PET crystal to reduce a total counting time and error due to drift of instrumental operating condition. Detection limit could be improved from increase of the peak/background ratio through adjusting pulse height analyzer about 1000 mv baseline. Under permissible maximum analytical conditions, theoretical detection limit of U, Th and Pb is down to 30 ppm (99% confidence level). The analytical result was maintained at a relative error $\pm$10% ($2{\sigma}$) in 800 ppm Pb, $\pm$5% ($2{\sigma}$) in 2330 ppm U and $\pm$10% ($2{\sigma}$) in dating from a single measurement of zircon at 15 keV and 100 nA. However, for the precise dating of zircon and monazite, if it is considered a 3 $\mu\textrm{m}$ spatial resolution, <100 ppm ($3{\sigma}$) detection limit and <$\pm$10% ($2{\sigma}$) relative error, optimum analytical conditions are given as 15~20 keV accelerating voltage, 100~200 nA beam current and 300~1200 sec total counting time. To reduce material damage by high current, there is need to be up to 3~5 $\mu\textrm{m}$ of electron beam diameter, or to use arithmetic average of multiple measuring at a shorter counting time. A younger or relatively low concentration rocks can be dated chemically by lower detection limit and improved precision resulted from increase of current and measuring time.

• The Korean Journal of Quaternary Research
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• v.12 no.1
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• pp.63-76
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• 1998

한반도는 산악지형이 우세하기 때문에 늪지나 호수의 발달이 불량하다. 현재 소규모 의 자연늪지는 낙동가 하류지역에 분포하며 동해안을 따라 일부 해안지역에 발달하여 있을 뿐이다. 고산지역에도 소규모의 늪지가 최근에 발견되었는데 그중에서도 무제치늪이 국내의 가장 남동쪽에 위치하고 있다. 정족산 정상부를 향하여 4개의 늪지가 차례대로 발달하여있 는데 이들의 성인은 온도차이에 의한 기계적풍화와 암석 차이에 의한 화학적 풍화적작용의 결과로 해석된다, 이들의 형성시기는 제 2늪의 습원퇴적이 가장 오래되 지층으로서 100~ 105cm 심도에서 탄소동위원소 연대측정으로 5,960$\pm$110yr BP. 의결과를 보이고 있드며 제 1늪의 습원 퇴적은 지표로부터 64~69cm 심도의 토탄층 최하부 부분에서 1,785$\pm$120yr BP. 의 연대측정 결과를 확인하였다.

• Analytical Science and Technology
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• v.22 no.2
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• pp.136-140
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• 2009

To improve the carbon recovery yield of chemical pretreatment in soil and sediment for $^{14}C$ age dating using AMS (Accelerator Mass Spectrometry), we have developed ultrasonic method in chemical pretreatment to replace with stirring method which has been generally used in each step of humic acid extraction for soil and sediment samples. Extraction conditions such as ultrasonic power, temperature and reaction time have been optimized. Six times higher carbon recovery yield could be obtained from low carbon content samples using ultrasonic method. We also compared the dating results by AMS obtained using ultrasonic method with the ages of samples treated by the stirring method. It was found that this new method could be applied to the pretreatment process of low carbon content samples for AMS age dating without effects on the dated ages, and with highly improved carbon recovery yields.

• Journal of the Korean Chemical Society
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• v.36 no.5
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• pp.727-737
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• 1992

The water chemical characteristics and age dating of springwater in Cheju island had been investigated. C_1, C_4, C_7, C_9 springwaters were not affected by seawater intrusion by TDS and electrical conductivity, relationship of Cl and tritium, Cl and HCO_3 ratio, and total hardness and pseudo hardness. In this case only C_7 springwater was evaluated tasty and healthy mineral springwater by Hahimoto's Mineral Balance Index. On the basis of the mean tritium content of rainfalls and springwater, the average residence time of it, were calculated. Considering the hydrogeologic and hydrochemical condition, completely mixed model seems to be very fit. It was obtained the result that C_9 group springwater (C_{10}, C_{12}, C_{14}) was 1.2 months, C_7 springwater was 5.6 months, and deep groundwater C_{17} was 4 years.

• The Journal of the Petrological Society of Korea
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• v.11 no.3_4
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• pp.157-168
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• 2002

In Gimcheon area of the central Yeongnam massif granite gneiss occurrs with intercalated biotite gneiss at xenolith or restite. In order to understand the evolution of the central Yeongnam massif, it is essential to have absolute age information, but not many age data are available yet. Furthermore the previous age determinations from the study area are not compatible with the outcrop relationship. In this study we determined chemical ages from the zircon grains. We obtained ages of $1970\pm$ 78(l$\sigma$)Ma from the granite gneiss, $1814\pm$77(l$\sigma$)Ma from the outer rim of a rounded zircon and 1973$\pm$97(l$\sigma$)Ma from a longish zircon, both from the biotite gneiss. These ages seem to indicate the timing of granitic magma intrusion and subsequent metamorphism. Ages of $2954\pm$ 158($l\sigma$)Ma, 2440$\pm$58(l$\sigma$)Ma, and 2219$\pm$36($l\sigma$)Ma obtained from zoned core of the rounded zircon grain from the biotite gneiss suggest various geological events before such metamorphism of the biotite gneiss. Ages in the range of 1450~1670 Ma observed in zircons of both gniesses suggest later metamorphism that the granite gneiss and the biotite gneiss experienced together. The chemical age determination by electron probe micro-analyzer of this study utilized 1$\mu\textrm{m}$ beam diameter and it seems to be a very useful age determination from the zircons with complex growth history because of superior spatial resolution.

• Economic and Environmental Geology
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• v.37 no.5
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• pp.459-475
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• 2004

The geology of the Kualakulun area in Middle Kalimantan, Indonesia comprises Permian to Carboniferous Pinoh Metamorphic Rocks and Cretaceous Sepauk Plutonics of the Sunda Shield, late Eocene Tanjung Formation, Oligocene Malasan Volcanics, Oligocene to early Miocene Sintang Intrusives and Quaternary alluvium. Sepauk Plutonic rocks are classified as the calc-alkaline series and the S-type granite. Sintang Intrusive rocks are basic-intermediate and intermediate rocks, and consists of basalt, basaltic andesite, basaltic trachyandesite and trachyandesite. The Malasan Volcanics are characterized by intermediate dacitic pyroclasticl and minor lavas and belong to the subalkaline (calc-alkaline and tholeiitic) series. The whole-rock K-Ar ages of the fine-grained biotite granites and medium-grained granitoids were determined to be 100.5-106.5 Ma and 91.9-102.6 Ma, respectively. The whole-rock K-Ar age of the diorite is 89.1 Ma. K-Ar ages of the Malasan Volcanics and Shintang intrusives show 31.5-36.8 Ma and 24.6-34.5 Ma, respectively, and correspond to the Tertiary time.

• Journal of the Korean earth science society
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• v.27 no.5
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• pp.521-527
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• 2006

The EPMA analysis for CHIME dating requires standard materials, which include nuclear fuel materials that are rare and sensitive to handle. Any laboratory that does not meet these standards has had difficulties adopting the CHIME dating method. We have developed a working standard technique for CHIME dating to prepare standard materials without use of nuclear fuel materials. Mineral samples, such as small pieces of monazite that are homogeneous in X-ray intensities, are calibrated using well-characterized primary standards in one laboratory. Once this procedure is done, they can be readily usable as working standards in the other laboratories, only with measurement of X-ray intensities. This method is applicable in preparing standard materials for both chemical compositions and determination of X-ray interference correction factors, and it is independent from chemical composition of mineral standard.

• Journal of the Korean Chemical Society
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• v.40 no.2
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• pp.101-108
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• 1996

The chemical characteristics and age dating of the thermal springwater developed recently in Chullabukdo were investigated. The temperature range of the thermal springwater was found 27∼29$^{\circ}C$, indicating a low temperature thermal springwater. The concentration of $F^-$ ion in the springwater was found relatively high in the range of 2∼3 ppm, but $NO_3^-$ ion was nearly not detected. The concentration range of $SO_4^{2-}$ ion was 0.02∼23 ppm, among which $SO_4^{2-}$ content of $Y_3$ was found very high compared to that of other springwater, since this site is known as a sulfur spring. $HCO_3^-$ ion content was found 2∼5 times higher than that of groundwater. $Y_1,\;Y_3,\;Y_5,\;Y_2,\;Y_4,\;and\;Y_8$, were classified as $HCO_3^-$ type, $Y_6$ as $CI^-$type, and $Y_7$, as no domonant type by classification diagram for anion and cation facies. From the results of age dating on the basis of the mean tritium level of precipitation and thermal springs, $Y_1$ was identified as the oldest thermal spring (-89 years) and $Y_7$ was identified as -89 years and $Y_7$ was -1 year using dispersive model. The results calculated by two models agreed well each other.

• Korean Journal of Mineralogy and Petrology
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• v.36 no.2
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• pp.125-134
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• 2023

The Naedeokri and Nonggeori granites are early Proterozoic granites of the Taebaek-Sangdong area in the northeastern part of the Yeongnam Massif. In this paper, rare earth elements (REEs) concentrations of the minerals in Naedeokri and Nonggeori granites and Rb-Sr mineral isochron age are reported. Except zircon, the constituent minerals such as mica, feldspar, quartz, and tourmaline show LREE-enriched and HREE-depleted REE patterns with relatively large Eu negative anomaly. However, zircon has geochemical characteristic of LREE- and HREE-enriched REE pattern with large Eu positive anomaly. This pattern suggests that zircon should be hydrothermal zircon due to deuteric hydrothermal alteration. In addition, the Rb-Sr mineral age of Naedeokri granite indicates an age value of 1.814±142(2σ) Ma. The Rb-Sr whole rock age including pervious data of Naedeokri and Nogggeori granite indicates an age value of 1,707±74(2σ) Ma. This value is younger than the Sm-Nd isochron of 1.87 Ga, indicating that the Rb-Sr isotope system may be re-homogenized by hydrothermal alteration during the transition from a magmatic to a hydrothermal system.