• Title/Summary/Keyword: 화학적 상호작용

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Basic Studies on the Native Colored-Soybean Cultivars IV. Sensory Analysis and Interpretation of Related Component in Seeds of Collected Colored-Soybean Cultivars (유색 대두수집종의 특성 연구 제4보 유색 대두수집종의 식미특성과 관련형질간 상호작용)

  • Ghu, J.O.;Ha, K.Y.;Hong, E.H.
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.28 no.4
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    • pp.462-468
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    • 1983
  • Collected 38 colored soybeans, which was cultivated under the conventional field conditions, were investigated about their organeloptic parameters and correlations among factors such as organeloptic score, texturometer parameters and chemical components of seeds. Most of the organeloptic parameters were affect much more by the characteristics of each cultivars than by grain weight, and then showed significant differences with the effect of interactinon between grain weight and cultivar, too. Also among contribution degrees of texturometer scores to overall acceptance, cohesiveness was higher in small, medium and super grains, however in large grains, hardness. And among sensory attributes, suitable toughness was contribute most positively to acceptance.

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Rheology and Morphology of PP/ionomer/clay Nancomposites Depending on Selective Dispersion of Organoclays (유기클레이의 선택적 분산에 의한 폴리프로필렌/아이오노머/클레이 나노복합체의 유변학 및 형태학적 특성 연구)

  • Kim, Doohyun;Ock, Hyun Geun;Ahn, Kyung Hyun;Lee, Seung Jong
    • Korean Chemical Engineering Research
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    • v.53 no.6
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    • pp.709-716
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    • 2015
  • In this study, structural developments of polypropylene / ionomer / clay ternary composites were investigated depending on the dispersion and localization of clay. The changes in physical properties were observed adding organoclays 1~10wt% to 90% polypropylene and 10% ionomer blends. The organoclays were localized inside of the dispersed phase under the composition of 3wt%, however, over that composition, clay particles formed stiff network structure in the dispersed phase and additional clays were localized at the interface between two phases. According to the developments of microstructure, the interaction of ternary composites changed from polypropylene-ionomer to polypropylene-ionomer and ionomer-clay which affected rheological properties. The storage modulus (G') of the composites was similar to the blends when clays were localized inside of dispersed phase but increased when clays were localized at interface. Also, the fractured morphology of the composites showed phase boundary and growing radius of dispersed phase depending on addition of fillers when clays were found inside. However, when fillers found at the interface between blends, the radius of the dispersed phase decreased and compatibilized morphology were observed. The interfacial interaction of the ternary composite was quantified depending on the structural development of dispersed phase and localization of clay particles by the rheological properties. The interaction of composites at solid state which was measured through peel adhesion strength increased by growth of interfacial interaction of each component. Furthermore, the crystallinity of the composites was decreased when the clay particles were localized at the interface.

Effect of Genistein on the Aryl Hydrocarbon Receptor and Cytochrome P450 1A1 in MCF-7 Human Breast Carcinoma Cells (인체유방암 세포주 MCF-7 세포에서 genistein의 Aryl Hydrocarbon Receptor와 Cytochrome P450 1A1에 대한 영향)

  • Han Eun-Hee;Kim Ji-Young;Jeong Hye-Gwang
    • Environmental Analysis Health and Toxicology
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    • v.21 no.1 s.52
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    • pp.13-19
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    • 2006
  • 화학적 예방효과가 있는 식물성 에스트로젠은 다양한 환성을 나타내며 여러 세포 수용체와 상호작용한다. Genistein은 isoflavone의 주요물질 중의 하나로 콩류에 존재하며 대표적인 식물성 에스트로젠이다. 본 논문에서는 유방암 세포주인 MCF-7에서 aryl hydrocarbon receptor(AhR)에 의해 매개되는 발암물질 활성화 경로에 대한 genistein의 영향을 살펴보았다. 세포에 genistein을 처리할 경우 cytochrome P450 1A1(CYP1A1) 약물대사효소의 특이적인 효소반응인 7-ethoxyresorufin O-deethylase (EROD) 활성도와 CYP1A1의 유전자 발현이 genistein의 농도 의존적으로 증가하였다. Genistein과 발암물질인 방향족탄화 수소 7, 12-dimethylbenz[a]anthracene(DMBA)를 동시 처리하였을 경우 DMBA에 의해 유도되어 증가된 EROD활성도와 CYP1A1의 유전자 발현이 genistein에 의해 감소하였다. 랫트의 간에서 분리한 세포질을 이용하여 genistein과 AhR의 대표적인 ligand인 2,3,7,8-tetrachlorodibenzo-p-dioxin과 경쟁적 결합에 대한 영향을 조사한 결과 genistein이 AhR에 경쟁적으로 결합함을 알 수 있었다. 이러한 결과들은 genistein이 천연 AhR ligand임을 암시한다. 따라서, 식물성 에스트로젠인 genistein은 AhR경로의 길항제/항진제로 작용할 수 있을 것으로 사료된다.

고무소재의 열응력

  • Gang, Sin-Yeong;Hong, Chang-Guk
    • Rubber Technology
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    • v.11 no.1
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    • pp.12-26
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    • 2010
  • 각종 산업제품의 주요 부품으로 사용되고 있는 고무재료는 사용 중 온도변화에 의해 체적 또는 길이 변화를 수반할 수 있어 결과적으로 고무제품의 성능이나 효율이 영향을 받게 된다. 특히 고온에서 고무제품의 치수변화를 제한하거나 일정치수를 강제할 경우 열수축이나 열팽창에 의해 응력이 발생하게 된다. 따라서 온도 변화에 따른 열응력의 측정은 고무제품의 정밀성과 성능을 평가하는 중요한 수단을 제공한다. 본 연구에서는 고무소재의 열응력 측정을 위한 새로운 측정방법을 개발하였고 이와 관련 새로운 시험장치를 설계, 제작하였다. 고무시편에 일정 변형의 인장을 준 상태에서 가열하면 열응력이 발생한다. 이 때의 열응력은 고무분자 사슬들의 운동성에 기인하며 배향된 고무분자 사슬들이 열역학적으로 랜덤 사슬형태로 돌아가려는 엔트로피적 힘이다. 따라서 온도가 높을수록 그 수축력은 증가하게 된다. 또한 고무분자 사슬의 사전 변형이 증가하면 그 열응력은 증가한다. 이때 열응력은 측정시간이 지남에 따라 최대치에 도달한 후 완화되며 그 완화속도는 설정온도에 의해 영향을 받는다. 여기서는 온도변화에 따른 고무시편의 열응력 측정결과를 소개하고, 고무분자 사슬의 엔트로피 변화와 점탄성적 흐름, 그리고 가열에 따른 고무 시편의 팽창 또는 수축이 열응력에 미치는 영향 등을 논의하였다. 특히 천연고무와 SBR 고무시편의 열응력 차이를 분자사슬의 운동과 연관하여 검토하였고, 가교밀도와 가교시스템이 각각 다른 고무시편에 대해 열응력 발생과에 따른 상관관계를 고찰하였다. 또한 시편의 형태와 두께가 열응력 발생에 미치는 영향도 검토하였다. 충전 배합고무의 경우 열응력에 영향을 미치는 인자로 고무분자 사슬의 운동성과 가교밀도 외에 고무재료와 충전제 사이의 물리 화학적 상호작용도 매우 중요한 요소가 된다. 배합고무에서 충전제의 영향을 검토하기 위해 실리카와 카본블랙을 선택하였고 배합고무의 열응력을 각각 측정하여 이들의 보강효과가 열응력에 미치는 영향에 대해 논하였다.

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소성가공에서 Tribology

  • 오박균
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1988.06a
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    • pp.1-11
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    • 1988
  • Tribology라는 용어는 마찰, 마모, 윤활의 과학, 기술을 한마디로 나타내는 말이다. 우리들의 일상생홀, 산업활동, 특히 소성가공에서 Tribology의 역활의 중요성은 새삼 강조할 필요가 없다. 소성가공에서 가공방식, 공구, 소재, 온도, 속도에는 무수한 조합이 있고, 마찰-마모-윤활의 상효연관 또한 복잡하다. 역학, 열전달, 물리학, 화학적과정이 동시에 상호작용을 하면서 진행하는 이 시스템에서는 크게는 공작기계로부터 작게는 micron정도의 표면과 윤활막 뿐만 아니라, 경우에 따라서는 ${\AA}$ 정도의 정체불명체가 결정적인 역활을 한다. 본 고에서는 냉간압연, 단조, 인발등에 Tribology를 응용하는 입장에서 Tribology system의 일부를 공구와 재료의 윤활제를 개재한 micro 접촉상황을 중심으로 분류정리하고, 이것과 공업적 소성가공에서 공구 - 재료접촉면현상과 그 연계를 가능한 한 이해하기 쉽게 서술하였다. 이를 통하여 소성가공기술자 및 연구자가 소성가공의 목적을 달성하는 가운데, Tribology 적으로 양호한 결과를 경제적으로 얻고자하는 시행, 개발, 연구에 대해 도움이 되고자 한다.

Electrophoretic Characteristics of the Clay Particles Affected by Chemical Species of Leachate (매립지 침출수 화학종에 따른 점토입자의 전기영동 특성)

  • Kim, Jong-Yun;Han, Sang-Jae;Kim, Soo-Sam;Park, Jea-Man
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.5C
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    • pp.217-228
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    • 2009
  • In case of application of electrophoresis method for leakage restoration of waste impoundment, main points of consideration were to evaluate the mobility of clay particles by electrophoretic force and capacity of leakage repair in leachate electrolyte system contained with various chemical species. However, the flocculation phenomena of clay particles induced by electrochemical interaction between various chemical species and clay particles would cause the big problems in electrophoresis method. Therefore, a series of laboratory tests such as one-dimensional electrophoresis and gravitational experiments were carried out in order to identify the specific chemical species affected flocculation of clay particles and the range of chemical concentration in leachate. In addition, the characteristics of clay particle behavior with chemical species and concentration range in leachate were analized using the concept of the settling velocity, zeta potential, and electrophoretic velocity.

The Wondong magmatic system : its petrochemical evolution (원동 마그마계 : 암석화학적 진화)

  • 황상구
    • The Journal of the Petrological Society of Korea
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    • v.6 no.3
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    • pp.166-184
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    • 1997
  • The Wondong caldea is a deeply eroded structure that offers spectacular exposures through the core and margins of a resurgent caldera. The Wondong Tuff and the postcollapse intrusions range from medium-silica rhyolite to rhyodacite in composition and the postcollapse lava and tuff, preresurgent and resurgent intrusions also range from medium-silica rhyolite to an-desite, which jump to gap dacite composition. The continuous compositional zonations generally define a large stratified magma system in the postcollapse and resurgent magma chamber. Isotopic and trace element evidence suggest that the compositional zonations might have resulted from the differentiations from crystal fractionations of a parental andesitic magma, accompanying a little contamination from the crustal assimilations near the chamber roof and wall. But chemically and isotopically distinct late intusions might have resulted from emplacement of any different magma batch.

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Accepting the Interculural Perspective for Multicultural Services in Public Libraries (공공도서관 다문화서비스를 위한 상호문화 관점의 수용)

  • Park, Seong-Woo
    • Journal of the Korean Society for Library and Information Science
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    • v.49 no.3
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    • pp.371-392
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    • 2015
  • This research attempted to provide new philosophical perspective to be taken in the public libraries as an institution which should support the social inclusion in the multicultural society. As deepening on dichotomous system of culture in modern society, It is referred to the need for an intercultural discourse on mulitcultural services in the public libraries. The process of social Integration suggested by Esser indicated the interactive transformation between actors and society. The conception serves the standard perspective on immigrants. Accordingly, This research analyzed a multicultural program of public libraries based on the classification of policy about immigrants by Castles. And it is based on the intercultural philosophy of Mall, It suggested the roles of public libraries in social integration and the process to support immigrants through the framework by Esser.

A Study on the Effectiveness and Possibility of General Chemistry Experiment Lecture with Flipped Classroom (거꾸로 교실을 적용한 일반화학실험 강좌의 효과 및 가능성 탐색 연구)

  • Yoon, Jihyun;Son, E Nok;Kang, Seong-Joo
    • Journal of the Korean Chemical Society
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    • v.62 no.2
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    • pp.124-136
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    • 2018
  • In this study, we applied the flipped-classroom to the general chemistry experiment lecture of the domestic university with strong teacher-led, and explored the effects and possibilities of the course. For this purpose, 30 students who were enrolled in the Science Education Department of the College of Education in the metropolitan area were randomly assigned to two groups, namely, the flipped-classroom group and the traditional class group. Then, we developed a general chemistry experiment lessons based on the flipped-classroom along with visual materials and we applied the lessons for 15 weeks. After all the classes, we conducted a survey to see the students' perception of the general chemistry experiment lecture by flipped classroom. As a result of analysis, the students of the flipped-classroom group were more positive than the students of the traditional class group in terms of the usefulness of the class activity, the importance of each activity element for the successful learning, the learning level, and the intention for another lesson. As a result of analyzing students' perceptions in terms of general chemical experiment activities such as conducting experiments or writing reports and understanding the contents of experiments, the average score of the flippedclassroom group was higher than the traditional class group, and the main cause of this result was the video material provided by prior learning activities. In addition, as a result of analyzing students' perceptions in terms of interactions and self-directed learning in class, the average score of the flipped-classroom group was generally higher than the traditional class group. In particular, students' interactions and self-directed learning were statistically significant differences between the two groups. And the students' perception of video material was very positive, and it was analyzed that the video that the instructor directly explained experiment theory and method was the most favorite videos of students. We discussed educational implications of these findings.

Filler-Elastomer Interactions. 2. Cure Behaviors and Mechanical Interfacial Properties of Carbon Black/Rubber Composites (충전재-탄성체 상호작용. 2. 카본블랙/고무 복합재료의 경화 거동 및 기계적 계면 물성)

  • Kim, Jeong-Soon;Park, Soo-Jin
    • Elastomers and Composites
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    • v.35 no.2
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    • pp.122-131
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    • 2000
  • In this work, the effect of chemical surface treatments on morphology of carbon blacks was investigated in terms of cure behavior and tearing energy ($G_T$) of carbon blacks/rubber composites. As experimental results, the polar or nonpolar chemical treatment led to a significant physical change of carbon black morphology. The cure activation energies (Ea) and frequency factor (A) obtained from Kissinger equation decreased with improving the dispersion of carbon flacks, resulting in high reactivity. However, a significant advantage of carbon black/rubber composites is gained by carbon blacks treated in basic (BCB) or nonpolar (NCB) chemical solution, resulting in increasing the tearing energy. These results could be explained by changes of dispersion, agglomerate, surface functional group, void volume, and cross-linking density of carbon black/rubber composites.

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