• Journal of Korean Ophthalmic Optics Society
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• v.16 no.3
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• pp.237-245
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• 2011

Purpose: The present study was conducted to investigate whether certain repeated physical and/or chemical stimuli added on ophthalmic lenses might induce any changes of the functions of lens coatings. Methods: The changes in lens surface, light transmittance, foggy duration, durability of ophthalmic lenses were determined after the application of tearing-off with tape, rubbing with acetone, soaking in acetone or distilled water of ophthalmic lens (CR-39 material) as physical and/or chemical stimuli. Results: The change of ophthalmic lens surface was detected after soaking in acetone for longer than 30 minutes by observing the lens surface to figure out the functional change of hard coating. The ophthalmic lens soaked in distilled water for 180 minutes showed little functional change of anti-reflection coating as 1% by measuring light transmittance of lens. However, the function of anti-reflection coating was almost disappeared after the ophthalmic lens was soaked in acetone for 60 minutes. The foggy duration of ophthalmic lens soaked in acetone was increased by estimating foggy duration of lens. The lens coating was shown to be defected when the pre-damaged ophthalmic lenses were torn off with tape, rubbed with acetone and soaked in distilled water or acetone by observing pre-damaged lens surface to evaluate its durability. Conclusions: The careful management during ophthalmic lens dispensing or usual eyeglass wearing is needed since the change in ophthalmic lens coatings was shown by repeated physical and/or chemical stimuli.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2022.06a
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• pp.141-142
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• 2022

열화란 윤활유의 물리적, 화학적 성질이 변하면서 성능이 저하되는 현상을 말합니다. 물리적 변화는 연료유, 수분, 금속 등 이물질 혼입으로 발생되며 화학적 변화는 산화 현상이 대표적이며 슬러지 등을 발생합니다. 해경 경비함정은 장시간 항해, 해상조건등에 따라 엔진의 부하변동이 많습니다. 따라서 윤활유의 역할이 매우 중요합니다. 그러나 연료혼입 등으로 윤활유가 열화되면서 수명이 단축되게 됩니다. 따라서 본 연구에서는 대표적 물리적 변화의 요인인 연료혼입를 실험적으로 고찰하고자 윤활유에 연료를 일정비율로 혼합하여 물성시험 등을 수행하였습니다. 실험결과 동점도는 윤활유에 점도가 낮은 연료유 혼입량이 증가함에 따라 점진적으로 감소하는 경향을 보였습니다.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.371-371
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• 2010

탄소나노튜브(CNT)는 기계적인 특성이 뛰어나며, 화학적으로 안정하고, 전기적으로 도체 및 반도체성을 가지고 있을 뿐만이 아니라 직경이 최소 1nm 수준으로 종횡비 및 비표면적이 매우 큰 특성을 가지고 있다. CNT는 투명전극, 유연성 디스플레이, 전자종이 분야 등 투명 전극 응용 분야에서 ITO 대체 신소재로 각광을 받고 있다. 본 발표에서는 SWCNT 전도막의 특성을 향상시키기 위해 PET 기판에 다양한 전처리 방법을 적용하여 SWCNT의 부착력 및 접착력, 투명전극의 면저항, 투과도 및 균일도 향상을 통해 SWCNT 투명전극 특성향상 연구를 진행했다. 접촉각과 표면에너지 제어를 통한 박막특성과의 상관관계 분석, 전처리 방법에 따른 표면에너지 및 제타포텐셜 변화와 박막특성과의 관계를 규명, Roughness 조절을 통한 기판의 면저항과 투과도 향상, 플라즈마 및 polymer 처리를 통해 물리적, 화학적 기판 전처리에 따른 SWCNT 투명전극 특성 향상을 목적으로 실험을 진행했다. 플라즈마 처리 후 polymer 처리된 박막에서는 친,소수 작용기 양의 변화에 따른 상관관계를 보이지 않았지만, 플리즈마 처리 후 친,소수 작용기 양과 Roughness 변화정도에 대해서는 면저항과 투과도의 변화를 보였다.

• Journal of the Korean Geotechnical Society
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• v.18 no.1
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• pp.49-57
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• 2002

During the electrokinetic remediation, direct current applied to a soil-water-electrolyte system derives the variations of fluid transport phenomena in soil-water system and soil-water interface characteristics. Therefore, these variations affect the electrokinetic reaction. In this study, lab-scale electrokinetic remediation tests were performed to characterize the electrical and chemical parameters variation in soil. During the test, voltage gradient, electrical current, zeta potential and pH variations were measured. On the basis of experimental results, computer modeling techniques predicting the variations of these parameters are suggested.

• Journal of the Korean Vacuum Society
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• v.6 no.4
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• pp.314-320
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• 1997

A chemical reaction and electronic structure change at the interface between copper and titanium nitride were investigated by XPS. A thin Cu layer was deposited on a TiN substrate oxidized by exposure to air at room temperature. We observed the Ti(2p), O(1s), N(1s), Cu(2p) core-level, and Cu LMM Auger line spectra. With increasing of the thickness of Cu layer, these spectra do not show any changes in the line shape as well as in peak position. In addition, the valence band spectra in XPS do not show any changes, which indicates that Cu does not react with Ti, N, and O. This inreactivity of Cu might cause a poor adhesion between Cu and TiN.

• Applied Chemistry for Engineering
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• v.21 no.5
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• pp.495-499
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• 2010

To develop chemical and biosensors, this paper studies sensing characteristics of bulk carbon nanotube (CNT) electrodes by means of their electrical impedance properties due to their large surface area and excellence chemical absorptivity. The sensors were fabricated in the form of film and nano web style by using composite process for mass production. The bulk composite electrodes were fabricated with singlewall and multi-wall carbon nanotubes based on host polymers such as Nafion and PAN, using a solution-casting and an electrospinning technique. The resistance and the capacitance of electrodes were measured with LCR meter under the various amounts of buffer solution to study the electrical impedance change properties of them. On the experimental of sensor electrode, impedance characteristics of the composite electrode are affected by its host polymer and nanofiller and its sensing response showed saturated result after applying some amounts of buffer solution for test chemical. Especially, the capacitance values showed drastic changes while the resistance values only changed within few percent range. It is deduced that the ions in the solution penetrated and diffused into the electrodes surface changed the electrical properties of the electrodes much like a doping effect.

• Proceedings of the Korea Water Resources Association Conference
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• 2020.06a
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• pp.142-142
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• 2020

하천에서의 화학사고는 자연적 및 인위적인 원인으로 인해 발생할 수 있으며, 대량의 화학물질이 하천으로 유입되는 것을 말한다. 이러한 화학사고는 수환경의 변화를 야기해 생태계나 인간에게 악영향을 초래하여 심각한 문제가 발생 될 수 있다. 하천으로 유입된 화학물질의 정량적 평가에 대한 연구는 활발하게 진행되고 있지만, 화학사고 초기 대응을 위한 하천에서의 화학물질 감지에 대한 연구는 미비한 실정이다. 한국 하천의 주요 지점에는 pH 및 EC 등을 실시간으로 측정하는 자동측정망을 운영하고 있기 때문에 이러한 측정항목들을 활용하여 화학물질을 감지하거나 식별 가능성에 대한 평가 연구는 하천 화학사고 대응을 위한 중요한 기초자료로 활용될 수 있다. 또한 분석된 결과를 바탕으로 미지의 화학물질을 다른 용매에 적용 시켰을 때 변화되는 pH 및 EC 결과와 통계적 수치비교를 통해 미지의 화학물질 식별 가능성을 평가하였다. 이를 통해 본 연구에서 선정한 pH 및 EC 항목이 화학물질 감지 및 식별을 위한 대체지표로써의 활용 가능성을 실험적 연구를 통해 평가하고자 하였다. 본 연구의 결과는 현장에서 쉽고, 신속하게 화학물질 감지 및 식별을 위한 정보를 제공할 수 있다는데 의미가 있으며, 화학사고의 신속한 대응을 위한 기초자료로 활용될 수 있을 것으로 판단된다.

• Applied Chemistry for Engineering
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• v.24 no.2
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• pp.138-143
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• 2013

This paper studied the possibility to predict a mechanical property variation from changes in created carbonyl bands by irradiating the surface of high-density polyethylene with short-wavelength ultraviolet radiation of 254 nm to induce a fast chemical degradation. The meaning of this study lies in checking whether a mechanical property change with the same chemical property as the induced optical deterioration is caused by using a UVC lamp with high photon energy instead of optical deterioration via xenon arc light source and outdoor exposure test via natural sunlight requiring a long time. The mechanical strength of high-density polyethylene checked by a tensile test and a creep destruction test showed a similar tendency with CI changes. In particular, the yield strength and elongation had a close relationship with the exposure time to ultraviolet radiation. Accordingly, this paper presented a method to grasp the mechanical property change outdoors requiring a long time more fast through the relationship between the mechanical property change and the carbonyl index using a UVC lamp causing the fast surface degradation.

• Tunnel and Underground Space
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• v.19 no.3
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• pp.213-225
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• 2009

The purpose of the study is to evaluate the effects of chemical weathering on the granite and orthogneiss in Wonju area based on accelerated artificial chemical weathering. The rock samples were scrutinized the variation of index properties and ion exchanges caused by artificial chemical weathering which was implemented with leaching test for 170 days using double soxhlet extractor. The differential weathering and decrease of p wave velocity were obtained by weathering process without significant changes of porosity. In case of granite samples, the uniaxial compression strength was reduced by 20% and 16% for the F-grade and SW-grade, respectively. For MW-grade granite, however, was not able to examine the effect of strength reduction due to lack of sample number. Also, for orthogneiss, it is difficult to compare the values of uniaxial compressive strength between before and after the test because of its strong anisotropy.

• The Journal of the Korea Contents Association
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• v.2 no.1
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• pp.120-124
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• 2002

It is the purpose of the present to report result of a preliminary electrochemical characterization of the as-cast Mg-Ca alloys. Electrochemical data will be correlated with chemical composition of impurities, and the microstructural change before and after Ca is added. This paper shows that small addition of Ca imparts beneficial effect in electrochemical properties of Mg alloy, primarily, through microstructural modifications.