• Title/Summary/Keyword: 화학저항

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A Study on the Anti-corrosion Properties of Organic and Inorganic Inhibitor by Electrochemical Evaluation Method in Saturated Aqueous Solution of Calcium Hydroxide (포화 수산화칼슘 수용액 내에서의 무기계 및 유기계 방청제의 전기화학적 방식 특성평가)

  • Kim, Soo-Young;Ryu, Hwa-Sung;Kim, Sung-Kil;Lee, Han-Seung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.4
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    • pp.66-74
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    • 2013
  • In this study, corrosion potential ($E_{corr}$), corrosion rate, and polarization resistance were measured aimed at inorganic inhibitors (passive film type) and organic inhibitors (absorption type). The experiment was conducted using potentiostat for the variable molar ratio and chloride ion concentration of the components of inhibitors in an aqueous solution of saturated calcium hydroxide targeting corrosion. As a result, it was possible to ensure an anticorrosive performance of at least a 1.2 molar ratio of inorganic inhibitors. Also, the organic inhibitors ensured the prevention of the anticorrosive performance of at least about a 0.3 molar ratio. It also showed the tendency that between polarization resistance and corrosion rate, Ecorr and corrosion rate is inversely proportional to the linear. Conversely, the tendency between polarization resistance and Ecorr is proportional to the linear. Also, a distinct difference in organic and inorganic inhibitors' relationship to Ecorr, corrosion rate, and polarization resistance was not shown.

Development of Acaricide Resistance and Cross-Resistance in Tetranychus urticae(Acarina: Tetranychidae) (점박이응애의 설비제정항성 발달과 교차저항성에 관한 연구)

  • 김상수;이승찬
    • Korean journal of applied entomology
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    • v.28 no.3
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    • pp.146-153
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    • 1989
  • These studies were conducted to investigate development of chemical resistance in two-spotted spider mite (Tetranychus urticae Koch) trough single selection for a given period of time with five acaricides including carbophenothion and ethion of organo-phosphate compound, dicofol of organo-chlorine compound, cyhexatin of organo-tin compound, biphenthrin of synthetic pyrethroid compound; and to examine cross-resistance among the acaricides to the selected populations. The development of chemical resistance of two-spotted spider mite was greatly varied under single selection of the each five acaricides. The carbophenothion- and the ethion-populations at the 22nd and the 24th selected generations showed 156- and 64.1-fold resistant levels, respectively, as compared with the susceptible population. However, the dicofol population at the 28th selected generation exhibited 39.7-fold resistant level, and the biphenthrin population at the 24th selected generation revealed 25.2-fold resistant level, while the cyhexatin population at the 20th selected generation showed 13-fold resistant level. The carbophenothion-selected population showed high cross-resistance to ethion, and low cross-resistance to dicofol and biphenthrin. The ethion-selected population revealed also high cross-resistance to carbophenothion. The dicofol-or the biphenthrin-selected populations, however, exhibited moderate cross-resistance to carbophenothion and ethion. Meantime, the cyhexatin-selected population showed high cross-resistance to ethion and carbophenothion.

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Geophysical and Geochemical Studies for the Saline Water Intrusion under the Paddy Field in Kyoung-gi area, Korea (경기 지역 농경지 하부로의 해수 침투에 관한 지구물리 및 지구화학적 연구)

  • Lee Sang-Ho;Kim Kyoung-Woong;Lee Sang-Kyu
    • Geophysics and Geophysical Exploration
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    • v.2 no.2
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    • pp.96-103
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    • 1999
  • Most of saline water inousions have been diagnosed by geophysical or geochemical approach independently. The objective of this study is to provide the effective method to detect the saline water intrusion on the ground water in the vicinity of seashore using these two methods. Schulumberger sounding, frequency domain electromagnetic sounding and geochemical analysis of ground water were carried out to explore saline water intrusion. Schulumberger sounding was implemented in dry surface condition before irrigation water was introduced into the field, while electromagnetic sounding was carried out in wet ground condition after the irrigation. The purpose of duplicated measurements on the equivalent spot at different times was to investigate the variation of anomaly zone depending on the amount of ground water. It was possible to discriminate the anomalous zone due to high water saturation from the low electric resistivity zone by high salt concentrations through this way. For the verification of the geophysical result, the ground water samples in the study area were collected and analysed at the 23 points near the measuring spots. The groundwater at the spot nearest to the sea water intrusion identified by geophysical method indicates higher salinity than the standard limit concentration for agricultural irrigation water (250 mg/1). Isotope analysis of $D({^2}H)$ vs. is ${^18}O$ and PCA analysis were used to discriminate the anthropogenic pollution from those of high salinity from sea water intrusion.

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The Utilization of Waste Foundry Sand as Backfill Material for Underground Electric Utility Systems (방식사의 지중 전력설비 되메움재로의 활용성 평가)

  • 이대수;홍성연;김경열;상현규
    • Journal of the Korean Geotechnical Society
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    • v.19 no.1
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    • pp.201-207
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    • 2003
  • In this paper, the utilization of waste foundry sand produced in the molding process is studied as a backfill material for underground electric utility systems such as concrete box structures and pipe lines for power supply. The physical, chemical and thermal properties for waste foundry sand are investigated far mechanical stability, environmental hazard and power transmission capacity Also its properties are compared with those of the natural river sand. The test results show that waste foundry sand can be utilized for underground concrete box structures as a backfill material; however, it can not be applied to underground pipe lines due to high thermal resistivity or low power transmission capacity.

Analysis of Abnormal Reduction in Electrical Resistivity by Temperature Increase of ZnO Semiconductor (산화아연 반도체의 온도 증가에 따른 비정상적인 비저항의 감소에 대한 해석)

  • Jang, Kyung-Soo;Park, Hyeong-Sik;Ryu, Kyung-Ryul;Jung, Sung-Wook;Jeong, Han-Wook;Yi, Jun-Sin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.144-144
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    • 2010
  • 투명 산화물 반도체로 가장 널리 사용되는 산화아연 반도체의 온도 증가에 따른 비정상적인 비저항의 감소를 보고 한다. 이는 직류 마그네트론 스퍼터링 시스템을 이용하여 연구를 진행하였으며, 공정 변수 중 압력 가변만 진행하였다. 상온에서의 전류 전압 곡선을 바탕으로 온도 증가에 따른 전류-전압 곡선 해석, 결정성 확인을 위하여 XRD 장비를 이용하였으며, 화학적인 조성 확인을 위해 EDS 장비를 이용하였다. 이를 통해 아연과 산소의 비율, (100) 결정성 방향 등의 결과를 통해 온도 증가에 따른 비정상적인 전기적 비저항 감소에 대한 현상을 확인하였다.

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Resistant Starch (저항전분)

  • 신말식
    • Korean Journal of Human Ecology
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    • v.2 no.2
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    • pp.29-38
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    • 1999
  • 저항전분(RS)은 건강한 사람의 소장에서 소화되지 않는 전분이나 전분질 식품의 부분이다. 저항전분은 4가지 형태로 구분하는데 RS 1은 물리적으로 효소와 만나지 않는 부분, RS 2는 생전분으로 감자, 바나나와 고아밀로오스 옥수수전분, RS 3는 노화된 전분 그리고 RS 4는 화학적으로 변성시킨 전분이다. RS 함량은 열에 안정한 $\alpha$ -아밀라아제나 pancreatin, pancreatic $\alpha$ -아밀라아제와 미생물에서 분리된 아밀라아제 등을 이용한 몇 가지 방법에 의해 분석되고 있다. RS는 대장에서 미생물에 의해 발효되어 단쇄지방산을 생성하는데 특히 부티릭산이 생성된다. 아세트산이나 프로피온산은 간의 대사에 영향을 주며 부티릭산은 항 종양(항 대장암) 특성이 있다. RS는 소화가 되지 않아 저열량원이므로 당뇨병 환자나 운동에 의한 혈당 조절이 필요할 때 조절능력을 갖는다. RS가 건강에 중요한 인자임이 알려지면, 건강을 위해 매일 섭취량의 증가를 권장해야 할 것이다.

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경남 상북면 양산단층 서부지역에 대한 습윤지수 특성 연구

  • 한지영;김성욱;강문기;김상현;김인수
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.447-453
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    • 2003
  • 연구지역은 경남 양산시 상북면 삼삼리 일원으로 양산단층과 인접하며 급한 경사의 자연사면으로 이루어져 있다. 수치지형자료를 이용하여 고도값을 갖는 자료층을 추출한 후 10m$\times$10m 크기의 격자별로 DEM으로 변환하고, 이로부터 단위 격자의 경사도, 경사방향도, 음영도를 작성하고 흐름분배 알고리즘을 이용하여 설정된 격자별로 상부사면의 기여면적과 습윤지수를 산정하였다. 높은 습윤지수를 보이는 지역은 북서-남동 방향의 선형구조로 나타나며, 국소지역의 전단단열 특성과 일치한다. 한편 연구지역에서 전기비저항 탐사를 실시하여 높은 습윤지수를 나타내는 지역과 저비저항 이상대의 분포를 비교한 결과 습윤지수가 높은 지역은 모두 낮은 전기비저항 이상대로 관찰된다. 즉 습윤지수는 암석의 화학적 풍화를 수반하는 파쇄대의 분포와 일치하며 이를 토대로 국소지역에서 파쇄대의 예측과 암석의 안정성을 예측하는 방법으로 이용될 수 있다.

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Relationship Between the Groundwater Resistivity and NaCl Equivalent Salinity in Western and Southern Coastal Areas, Korea (국내 서.남해 해안지역 지하수의 전기비저항과 등가 NaCl 염분도와의 관계)

  • Hwang, Se-Ho;Park, Kwon-Gyu;Shin, Je-Hyun;Lee, Sang-Kyu
    • Geophysics and Geophysical Exploration
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    • v.10 no.4
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    • pp.361-368
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    • 2007
  • In this paper, we suggested the relationship between resistivity of coastal groundwater and NaCl equivalent salinity for the quantitative interpretation the results of surface/borehole resistivity and electromagnetic data. 38 groundwater samples having electrical conductivity higher than about 1,000 ${\mu}S/cm$ were analyzed to derive the empirical relationship between groundwater resistivity and NaCl equivalent salinity. We used Schlumberger chart GEN-8 to convert ion concentration from hydrochemical analysis to the equivalent NaCl salinity, and the portable meter to measure the in situ electrical conductivity of groundwater samples. From the hydrochemical analysis, relationship between the groundwater resistivity $(R_w)$ and equivalent NaCl salinity (Eq_NaCl) is expressed as Eq_NaCl=$5935.3551{\times}R_w^{-1.0993}$, and relationship between the groundwater electrical conductivity (EC) and total dissolved solids (TDS) is expressed as TDS=0.721*EC. We believe these relationships are very useful to assess the seawater intrusion in western and southern coastal area.

Resistance Development and Cross-Resistance of Diamondback Moth (Lepidoptera: Plutellidae) by Single Selection of Several Insecticides (단제도태에 의한 배추좀나방(Plutella xylostella)의 약제저항성 발당과 교차저항성에 관한 연구)

  • 조영식;이승찬
    • Korean journal of applied entomology
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    • v.33 no.4
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    • pp.242-249
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    • 1994
  • These studles were conducted to investigate the development of chem~cal resistance and cross.resista. nce m dlarnondback moth (Piuteiia xylostella L). The resistance development of diamondback moth greatly vaned under single selection of five insectlades. The tnflumuron and lambda cyhalothnn strains at 8th selected generation showed 374- and 29.l.fold resistant levels. respectively, as compared with the susceptible strain. However, the Baciilus thuringiensis-seleded at 8th selected generatLon exhibited 240-fold resistant level. and the prothiophos-selected at 8th generation revealed 14.3-fold resistant !eve1 while the cartap hydrochloride-selected at 8th generailon showed 9.1-fold resistant level Prothiophos- selected strain showed low cross-resistance level to cartap hydrochloride, while this strain exhibited no cross-resistance of 1.3 to 2.8-fold to other msectlcides. Cartap hydrochlonde- seleded strain showed 19.9-fold. a high cross-resistance to lambda cyhalothrin, but this strain showed 2.2-34 fold, no cross resistance to other insecticide. Lambda cyhalothnn-selected strain exhibited cross-resistance to cartap hydrochlolide and prothiophas. Triflumuron-seleded strain showed 1.3-4.9 fold. no cross-resistance to other ~nsectic~dTe he B. ihuring~ensis-selededs train showed no cross-resistance to other insecticides.

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Acid Resistance Properties of RSLMC for Maintenance and Repair (유지 보수를 위한 RSLMC의 산성 저항성)

  • Hong, Chang-Woo;Kim, Dong-Ho;Lee, Hun-Jae;Kwon, Hyouk-Chan;Yun, Kyong-Ku
    • Journal of Industrial Technology
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    • v.22 no.A
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    • pp.161-168
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    • 2002
  • Latex modified concrete is governed by both cement hydration and polymer film formation processes in its binder phase. Such the reactions are expected to improve the polymer-cement co-matrixes themselves and the bond between the cement hydrates and aggregates, and to improve the properties of hardened latex-modified concrete. The purpose of this study was to study the strength and chemical resistance of Rapid-setting latex modified concrete(RSLMC) with the main experimental variables such as latex content(0, 5, 10, 15, 20%) and water-cement ratio(36, 38, 40%) at latex content 15%. Water absorption test was earned out to estimate water permeability resistance. Chemical resistance test was carried out to measure the weight change and to observe the appearance of RSLMC immersion in hydrochloric acid, sulfuric acid, and calcium choloride.

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