• Title/Summary/Keyword: 화학섬유

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An Analysis on the Korea Market Competitiveness of Japan Materials Industry -Focus on the Compound and Chemical Products- (일본 소재산업의 대 한국시장 경쟁력 분석 -화합물 및 화학제품을 중심으로-)

  • Kim, Ji-Yong
    • International Commerce and Information Review
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    • v.16 no.4
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    • pp.439-455
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    • 2014
  • Korea-Japan trade has been trade deficit for a long time and therefore this matter must be a settled urgently for continuous economic growth of Korea. For reasons mentioned above, this study pays attention to Japan materials industry which has induced trade deficit in the Korea-Japan trade and this study analyzed competitiveness of Japan materials industry in the Korea market. This study special regard will be paid to the Compound and Chemical Products in Japan materials industry. For attaining the purpose of study, we collected related statistical data and Market Share Index, Trade Specialization Index and Market Comparative Advantage Index used in study methodology From this analysis, we found that most of Japan material products have competitiveness in Korea market and chemical products used in photography & photo sensitized materials, paint & printing ink products particularly have very strong competitiveness in Korea Market.

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A Study on the Change of Strength of FRP Member Immersed in Chemical Solution (화학약품용액에 침지한 FRP 부재의 강도 변화에 대한 연구)

  • Kim, Ho-Sun;Kim, Woo-Jong;Jang, Hwa-Sup;Kwak, Kae-Hwan
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.6
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    • pp.117-123
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    • 2010
  • If FRP materials that have been known as high durability materials are exposed to harmful environmental factors, deterioration and characteristics of materials can be reduced due to chemical reaction such as hydrolysis. Therefore, to use FRP materials as building major materials, it is important to exactly grasp dynamic properties by use condition. Accordingly, this study stored FRP materials in a strong acid and alkali compound solution for a certain period to conduct simulation for acute or chronic, extreme changes by chemicals, and conducted a test for compressive, tensile, shear and bending strength to analyze changes in strength by kinds and storage days of chemicals. In conclusion, the study findings indicate excellent chemical resistance of FRP materials.

Changes in CGRP-immunoreactive Nerve Fibers during Expansion of Midpalatal Suture of the Rat (백서 정중구개봉합 확대후의 CGRP 면역반응 신경섬유의 변화)

  • Kim, Bo-Kyung;Park, Kuk-Pil;Kyung, Hee-Moon;Kwon, Oh-Won;Sung, Jae-Hyun
    • The korean journal of orthodontics
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    • v.29 no.1 s.72
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    • pp.73-81
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    • 1999
  • Midpalatal suture expansion is often used for patients haying narrow maxillary arch, cleft palate, respiratory handicap with narrow nasal cavity. CGRP has been known as a modulator of pain transmission in central nervous system and a local effector to peripheral tissue causing vasodilation, increase of blood flow, modulation of immune system, regulation of macrophagic function and stimulation of bone formation. To investigate changes of CGRP-immunoreactive nerve fibers in midpalatal suture during the expansion, immunohistochemical study was performed by using rats. Experimental rats (10 weeks, 250 gm) were divided into five groups (control, 1, 4, 7, 14 days group (each n=4) and applied orthodontic force (approximately 200gm) to upper anterior incisors. Frozen sections of midpalatal suture area were immunostained by using rabbit antisera. The results were as follows. ${\cdot}$ The CGRP-immunoreactive nerve fibers were hardly observed in control group. ${\cdot}$ In 1 day group, the CGRP-immunoreactive nerve fibers were more increased around the vessels than control group. ${\cdot}$ In 4 days group, the CGRP-immunoreactive nerve fibers were more increased than control group, but not more increased than 1 day group. Vascular diameter was more enlarged. ${\cdot}$ In 7 days group, especially, hematoxilin affinity of cells was remarkable and cells were arranged along the bone margin. The CGRP-immunoreactive nerve fibers were more reduced than 4 days group and vascular diameter was also reduced. ${\cdot}$ In 14 days group, the CGRP-immunoreactive nerve fibers were similar to those of 7 days group and the irregularity of bone margin was almost recoverd. In Conclusion, the CGRP-immunoreactive nerve fibers nay be related to initial neurogenic inflammatory reaction in expanding mid-palatal suture.

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Development of Polymer-derived Silicon Carbide Fiber with Low Oxygen Content Using a Cyclohexene Vapor Process (싸이클로헥센 증기 공정에 의한 산소량이 적은 실리콘카바이드 섬유의 개발)

  • Yoon, Byungil;Choi, Woo Chul;Kim, Myeong Ju;Kim, Jae Sung;Kim, Jung il;Kang, Hong Gu
    • Journal of the Korea Institute of Military Science and Technology
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    • v.20 no.5
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    • pp.620-632
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    • 2017
  • A chemical vapor curing method(CVC) was developed to cure polycarbosilane(PCS) fibers by using cyclohexene vapour as a non-oxygen active reactant, instead of air in oder to prepare the silicon carbide(SiC) fiber with low oxygen content. A cross-linked PCS fibers by cyclohexene vapor showed a completely different variation in IR spectra in comparison to the air-cured PCS fiber. CVC method resulted in less than 3 wt% in oxygen content. In this experiment conditions, The average tensile strength and modulus of SiC fiber obtained by CVC had 1995 MPa and 183 GPa respectively, which is higher than that of SiC fiber prepared by air-curing process.

Effect of oxyfluorination on activated electrospun carbon nanofibers for $CO_2$ storage (함산소불소화 효과에 의한 전기방사 활성탄소나노섬유의 $CO_2$ 저장)

  • Bai, Byong Chol;Kim, Jong Gu;Im, Ji Sun;Lee, Young-Seak
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.219.2-219.2
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    • 2011
  • The oxyfluorination effects of electrospun carbon nanofibers (OFACFs) were investigated for $CO_2$ storage. Carbon nanofibers were prepared form poly acrylonitrile / N,N-dimethylformamide solution through electrospinning method and heat treatment. Chemical activation of carbon nanofibers were carried out in order to improve the pore structure. And the surface modification of activated carbon nanofibers was conducted by oxyfluorination to improve the $CO_2$ storage on effect of introduced functional groups. The samples were labeled CF (electrospun carbon nanofiber), ACF (activated carbon nanofibers), OFACF-1 ($F_2:O_2$ = 3:7), OFACF-2 ($F_2:O_2$ = 5:5) and OFACF-3 ($F_2:O_2$ = 7:3). The functional group of OFACFs was investigated by x-ray photoelectron spectroscopy analysis. The specific surface area, pore volume and pore size of OFACFs were calculated and pore shape was estimated by the BET equation. Through the adsorption isotherm, the specific surface area and pore volume significantly decreased by oxyfluorination.

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Rheological Properties of Soyprotein Dope (알칼리를 처리한 콩단백질 용액의 물성)

  • Kim, Jee-Cheon;Cho, Sook-Ja;Byun, Pyung-Hwa;Byun, Si-Myung
    • Korean Journal of Food Science and Technology
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    • v.23 no.6
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    • pp.759-763
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    • 1991
  • The dynamic rheological properties of the dope and the hydrated disperson of the soyprotein, as a starting material of soyprotein fiber, were studied to investigate their viscoelastic properties. The increase of protein concentration in the both cases of the dope and the dispersion resulted in the establishment of intermolecular reaction of the protein. With the addition of alkali solution to the dispersion, the dope shows the characteristics of very lightly cross-linked high molecular weight polymer. In constrast, the dispersion shows the properties of an amorphorous polymer. The effects of chemical modification of the dispersion on the dynamic properties were also investigated.

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Development of Metal Filter with Nanoporous Structure by Adhesion of Metal Nanoparticles Sintered onto a Micor-Filter (마이크로-필터 상에 소결 처리된 금속 나노입자 고착에 의한 나노기공체 금속 필터 개발)

  • Lee, Dong Geun;Park, Seok Joo;Park, Young Ok;Ryu, Jeong In
    • Korean Chemical Engineering Research
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    • v.46 no.2
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    • pp.397-401
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    • 2008
  • The nanoparticle-agglomerates are synthesized by laser ablation, which have the morphology of dendrite structure. The filtration performance of a conventional micron-fibrous metal filter was improved by adhering nanoparticle-agglomerates onto the filter surface. The Sintered-Nanoparticle-Agglomerates-adhered Filter (SNAF) adhered with nanostructured material was made by heat treatment after deposition of nanoparticle-agglomerates sintered in aerosol phase onto the micron-fibrous metal filter. As the sintering temperature increases, the pressure drop of the filter increases a little but the filtration efficiency increases remarkably. This is due to increase of surface area of nanoparticle-agglomerates adhered onto the micron-fibrous metal filter.

Electrochemical Characterization of Electrospun LaCoO3 Perovskite Nanofibers Prepared at Different Temperature for Oxygen Reduction and Evolution in Alkaline Solution (다양한 온도에서 합성한 전기방사 LaCoO3 페롭스카이트 나노섬유의 알칼리용액에서 산소환원 및 발생반응에 대한 전기화학 특성)

  • Lopez, Kareen J.;Sun, Ho-Jung;Park, Gyungse;Eom, Seungwook;Shim, Joongpyo
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.2
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    • pp.148-155
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    • 2015
  • Electrospun $LaCoO_3$ perovskite nanofibers were produced for the air electrode in Zn-air rechargeable batteries using electrospinning technique with sequential calcination. The final calcination temperature was varied from 500 to $800^{\circ}C$ in order to determine its effect on the physical and electrochemical properties of the prepared $LaCoO_3$ perovskite nanofibers. The surface area of the electrospun $LaCoO_3$ perovskite nanofibers were observed to decrease with increasing final calcination temperature. Electrospun $LaCoO_3$ perovskite nanofibers calcined with final calcination temperature of $700^{\circ}C$ had the best electrocatalytic activity among the prepared perovskite nanofibers.

Electrochemical Energy Storage of Milled Carbon Nanofiber (탄소나노섬유의 밀링에 따른 전기화학적 에너지 저장 특성)

  • Lee, Hye-Min;Jeon, Hyeon;Choi, Weon-Kyung;Cho, Tae-Hwan
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.4
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    • pp.527-533
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    • 2011
  • CNFs had been well addressed due to numerous promising applications in science and technology. Besides the same physicochemical properties of ordinary carbon materials such as active carbons and carbon black, they exhibit specific, e.g., tubular or fibrous structures, a large surface area, high electrical conductivity stability, as well as extremely high mechanical strengh and modulus, which make them a superior material for electrochemical capacitors. In this study, CNFs were pretreated by mechanical milling with different time in mortar and pestle. The milled CNFs were used as active material of electrode whose electrochemical property was tested to find physicochemical characterization variation. CNF electrode milled for 5 min has the highest electric capacitance. XPS spectrum were employed to explore changes in functional group induced from mechanical milling. Crystal size was calculated to analyze change of peak from different milling time by XRD. The CNF milled for 5 min has the largest crystal size and the highest electric capacitance.

Characteristics of Pore Development for Activated Carbon Fiber from Polyacrylonitrile(II) -Activation- (PAN계 활성탄소 섬유의 세공발달 특성(II) -활성화-)

  • Park, Jong-Hak;Cho, Byung-Rin
    • Applied Chemistry for Engineering
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    • v.4 no.1
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    • pp.113-124
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    • 1993
  • Thermogravimetric analysis of copolymer of acrylonitrile(95%) and methyl acrylate(5%) have been carried out to investigate the activation under $H_2O$(30%) -$N_2$atmosphere at various heating rates. The kinetic equation [$f=1-\exp(-a{\Delta}T)^b$] which was derived on the basis of the nonisothermal activation process of carbon fiber in the $H_2O$(30%)-$N_2$system showed good agreement with experimetal results. The pore volume upon conversion was in good agreement with the model of theoretical pore volume. The pore structures of the activated carbon fiber were influenced by the heating rate, activation temperature and internal-external conversions.

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