• Title/Summary/Keyword: 화학섬유

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DISPLACEMENT OF MAXILLARY LATERAL INCISOR CAUSED BY IDIOPATHIC GINGIVAL FIBROMATOSIS (특발성 치은 섬유종증에 의한 상악 측절치의 변위)

  • Jung, Ji-Sook;Park, Ho-Won;Lee, Ju-Hyun;Seo, Hyun-Woo;Lee, Suk-Keun
    • Journal of the korean academy of Pediatric Dentistry
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    • v.38 no.3
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    • pp.296-302
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    • 2011
  • Idiopathic gingival fibromatosisrarely occurs, but frequently recurred after surgical removal. It usually occurs in generalized symmetrical pattern but sometimes in localized unilateral pattern. The localized pattern usually affects the maxillary molar and tuberosity area. This disease usually causes tooth migration, malocclusion, and problems in eating, speech, and esthetics. A boy showed dense gingival fibromatosis localized at primary maxillary right lateral incisor area at the age of 5 years, and his maxillary right lateral incisor become severely displaced at the age of 9 years. He had no medical and hereditary factors relevant to the gingival fibromatosis. However, the dense fibrous tissue was dominant in his labial gingiva of maxillary right incisors. In order to realign the displaced incisors by orthodontic treatment, the dense fibrous tissue covered the defect space between the central incisor and the displaced lateral incisor was surgically removed. The removed specimen was examined by simple immunohistochemical(IHC) array method. IHC array showed increased expression of CTGF, HSP-70, MMP-1, PCNA, CMG2, and TNF-${\alpha}$ in keratinocytes, fibroblasts, endothelial cells, and macrophages of gingival fibromatosis tissue. Therefore, it was suggested that the gingival fibromatosis be caused by the concomitant overexpression of CTGF, HSP-70, MMP-1, PCNA, CMG2, and TNF-${\alpha}$, and resulted in the fibroepithelial proliferation and the inflammatory reaction of gingival tissue.

Flux Melting Route to 2-and 3-dimensional Fibrous Potassium Titanates, K$_2Ti_{2n}O_{4n+1}$ (n = 2 and 3) (Flux 용융법에 의한 2차원 및 3 차원 구조의 티탄산칼륨 섬유의 합성)

  • Jin-Ho Choy;Yang Su Han;Seung Wan Song
    • Journal of the Korean Chemical Society
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    • v.37 no.8
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    • pp.765-772
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    • 1993
  • Two-dimensional potassium tetratitanate ($K_2Ti_4O_9$) and three-dimensional potassium hexatitanate ($K_2Ti_6O_{13}$) fibers have been prepared by the combined method consisting of the flux melting (1150$^{\circ}C$)-slow cooling (cooling rate = 5$^{\circ}C$/h) process from the starting raw materials of $K_2CO_3$, and $TiO_2$ with the flux of $K_2MoO_4$. It was found that the fiber growth reaction is strongly dependent upon the mole ratio of flux (F) to raw material (R), which is 7 : 3 (F : R) as for the optimum growth condition. Relatively long fibers (average length ${\thickapprox}$ 4 mm) with a mixture of $K_2Ti_4O_9$ (major) and $K_2Ti_6O_{13}$ (minor) could be obtained when the reaction was carried out for the $K_2MoO_4-$K_2O{\cdot}4TiO_2$ (F : R = 7 : 3) system, but for the $K_2$MoO_4$-$K_2O{\cdot}6TiO_2$ (F : R = 7: 3) one, only the short fibers with ${\thickapprox}$ 2 mm long could be grown as the mixed phase of $K_2Ti_6O_{13}$ and $K_2Ti_4O_9$.

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Fatigue Crack Growth Behavior of a Magnesium-Based Composite (마그네슘 금속복합재의 피로균열거동해석)

  • Kim, Doo Hwan;Park, Yong Gul;Kim, Sung Hoon;Han, Suk Kyu
    • Journal of Korean Society of Steel Construction
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    • v.9 no.4 s.33
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    • pp.515-521
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    • 1997
  • The effects of heat treatment and fiber orientation on tensile strength and fatigue behavior were studied in a continuously reinforced. magnesium-based composite Following an earlier TEM investigation, specimens were thermally aged to modified the interfacial zone between the alumina fibers and the magnesium alloy matrix. From the tensile experimental results, the ultimate tensile strength of the aged specimens were lower than that of the as-fabricated due to weak fiber-matrix interfacial strength with chemical reaction during the thermal processing. The fatigue crack growth experiments were conducted with specimens having the fiber orientation normal to the crack growth direction (longitudinal) and also specimens with the fibers oriented parallel to the crack growth direction(transverse). A comparison of the fatigue crack growth behavior indicates that aged longitudinal specimens are more resistant to fatigue crack growth the as-fabricated longitudinal specimens. Conversely, as-fabricated transverse specimens are more resistant to fatigue crack growth than aged transverse specimens.

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A Study of New water-soluble 3-D Binders on Water Washability by PH and the Debossing effect to property of Blowing Agents for Polyester fabrics (폴리에스테르 섬유용 수용성 입체가공 바인더의 PH에 따른 수세성과 발포제 양에 따른 디보싱 효과에 대한 고찰)

  • Kim, Moon-Jeong;Kim, Jong-Hoon;Kim, In-Tae;Lee, Ki-Jung;Chul, Dae-Sik;Lee, Hee-Jun;Hwang, Tea-Yeon
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.11a
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    • pp.50-50
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    • 2011
  • 국내 섬유산업은 해외로부터의 저가 섬유제품이 대량으로 유입되는 속에서도 수출의 상당한 부분을 차지하며, 꾸준히 양에서 질로의 전환을 도모해 왔으며, 특히 최근에는 섬유 전반에 걸쳐 고부가 가치화를 지향하고 있다. 이러한 소비자의 요구에 부응하여 섬유소재에도 다양한 신개념과 이를 충족시킬 수 있는 기술이 요구되고 있으며, 그 가운데 하나의 영역을 구축해 나가고 있는 분야가 면 리플가공과 같은 표면 형태 가공이며, 최근 들어 폴리에스테르 입체(3D)가공제의 개발 및 가공 방법도 이런 흐름에 부응하여 업계에서 절실한 개발을 요구하고 있는 분야이다. 기존의 폴리에스테르 및 합성섬유의 입체 가공에 적용된 화학제품보다 성능은 우수하면서, 가공 공정이나 완성된 섬유제품에 전혀 잔존하지 않아 인체친화적(기존의 제품들은 인체에 유해한 재료이면서 가공 후 잔존함)이며, 환경적인 측면에서도 친환경을 유지하면서 새로운 폴리에스테르섬유, 좀 더 폭넓게는 열가소성인 모든 합성섬유의 입체가공이 가능한 약품의 개발 및 이를 이용한 가공방법의 개발은 매우 중요한 의의를 가지게 된다. 본 연구에서는 폴리에스테르의 3D입체 디보싱을 부여하는 합성바인더가 물에 의한 용해도를 확인하기 위하여 용액의 PH에 따른 용해성 시험을 진행하였으며, 합성한 발포제의 양에 따른 3D입체형성 정도를 이미지로 형상화 하였다.

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The Syntheses of charge transfer dyes and nanofiber formation for recognition and sensing (진단/감응용 전하 이동형 색소의 합성 및 나노 섬유의 제조)

  • Jung, Young-Sun;Park, Joon-Bae;Moon, Hee-Jung;Kim, Sung-Hoon;Bae, Jin-Seok
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2012.03a
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    • pp.48-48
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    • 2012
  • 화학센서는 분석물질과 감응물질간의 화학적 반응을 통해 분석물질을 선택적으로 인지하고 이를 통하여 특정물질을 실시간으로 분석할 수 있는 기술이다. 최근 화학센서로 색소를 이용하여 음이온을 진단/감응하는 기술이 각광 받고 있으며, 더불어 음이온을 선택적으로 인지함에 있어 검출하고자 하는 특정 음이온에 대한 민감도를 높이기 위한 노력이 계속되고 있다. 감응물질로 이용되는 색소는 주로 분자 내 전하 이동형 색소(intramolecular charge transfer dye)로 주위 환경 변화에 민감하게 반응하며, 자극에 따른 변화를 흡수와 발광, 굴절률의 변화 등으로 나타낸다. 또한 다양한 음이온 중 분석물질로써 연구 가치가 큰 음이온에는 플루오린화물(fluoride)이 있다. 이는 플루오린화물이 치아 보호와 골다공증에 중요한 역할을 하는 순기능을 가지는 반면 고농도 상태에서는 불소증(fluorosis)을 비롯한 악영향을 잠재적으로 가지기 때문에 그 양을 인지하는 것이 중요하게 여겨지기 때문이다. 따라서 본 연구에서는 2-(3,5,5-trimethylcyclohex-2-enylidene)-malononitirle과 indole-3-carboxaldehyde를 통하여 분자 내 전하 이동형 색소를 합성하고, $^1H$ NMR, GC-mas, EA로 합성된 색소의 물성을 분석하였다. 우선 반응물인 2-(3,5,5-trimethylcyclohex-2-enylidene)-malononitirle을 합성하기 위해 dimethylfor mamide(DMF) 용매 하에서 isophorone과 malononitrile을 12시간 반응시키고, 얻어진 결과물을 정제한다. 이후 indole-3-carboxaldehyde와 10시간 환류시켜 색소를 얻는다. 합성된 색소는 F 이온 검출에 이용되며, UV-vis 분광법을 이용하여 분석물질에 따른 흡수 정도와 강도 변화를 살펴본다. 연구의 최종적인 목적은 비단 진단/감응 색소의 합성이 아니라 나노 섬유 소재와 색소의 접합을 통해 진단/감응형 나노 섬유를 개발하는 것으로 이를 위해 전기방사법이 이용된다.

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Fibrosarcoma in the Scapula of a Maltese Dog (말티즈 견의 견갑부에서 발생한 섬유육종)

  • Lee, Jae-Hoon;Chung, Dai-Jung;Kang, Eun-Hee;Chang, Hwa-Seok;Choi, Chi-Bong;Yu, Chi-Ho;Sur, Jung-Hyang;Kim, Hwi-Yool
    • Journal of Veterinary Clinics
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    • v.25 no.2
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    • pp.126-130
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    • 2008
  • A six year-old male Maltese dog was presented to the Konkuk University Veterinary Teaching Hospital (KUVTH) with mass in right scapula region. Physical examination, radiography, magnetic resonance imaging (MRI), complete blood count (CBC), serum biochemistry, cytological analysis of fine needle aspiration and histopathological examination were performed. There was no remarkable finding in CBC. Alkaline phosphatase (ALP) was found to be increased in serum chemistry profile. Osteolysis was seen on radiographs of the scapula. MRI revealed mixed signal intensity in scapula. Cytological examination of fine-needle aspirate (FNA) was suggestive of sarcoma. We confirmed that the neoplastic cells were fibrosarcoma by immunohistochemical and Masson's trichrome staining.

Separation of Non-Metallic Components in Waste Printed Circuit Boards (WPCBs) using Organic Solvent and Potassium Phosphate Solution (유기용매와 인산칼륨 용액을 이용한 폐 인쇄회로기판에서 비금속성분의 분리)

  • Lee, Jae-Cheon;Jeong, Jin Ki;Kim, Jong Seok
    • Applied Chemistry for Engineering
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    • v.23 no.4
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    • pp.367-371
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    • 2012
  • Waste printed circuit boards (WPCBs) contain valuable metals such as Cu, Ni, Au, Ag, and Pd. For an effective recycling of WPCBs, it is essential to recover the valuable metals. In recent years, recycling processes have come to be necessary for separating noble metals from WPCBs due to an increasing amount of electronic device wastes. However, it is well known that glass reinforced epoxy resins in the WPCBs are difficult materials to separate into elemental components, namely metals, glass fibers and epoxy resins in the chemical recycling process. $K_3PO_4$ as a catalyst in dimethylformamide (DMF) and N-Methyl-2-pyrrolidone (NMP) was used to depolymerize epoxy resins for recovering metallic and non-metallic components from WPCBs. Reactions of WPCBs were carried out at temperatures $160{\sim}200^{\circ}C$ for 2~12 h. The recycled glass fiber from WPCBs was analyzed by thermogravimetric analyzer (TGA) and evaluated the degree of solubility of the epoxy resin for separation efficiencies of the WPCBs.

A Study For The Simple Method In Dividing The Layers of Fiber-reinforced Plastic (폐 FRP선박의 재활용공정에서 용이한 면포추출공정을 위한 화학적 처리 방법에 관한 연구)

  • Lee, Seung-Hee;Kim, Yong-Seop;Yoon, Koo-Young
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.13 no.1
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    • pp.43-46
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    • 2010
  • As one of the methods for recycling the FRP used for the small and medium-sized waste ships, separation of the roving layer from the mat has some merit in a sense of the recycling energy and the environmental effects. Similar characteristics between the roving and the mat make the mechanically automatic differentiation difficult. They, however, contain different ratio of the resin and the glass and the thickness. In this study photo physical differentiation between the two layers has been made using (1) boiling concentrated sulfuric acid which can dissolve the resin in the FRP layer and (2) hydrogen fluoride(HF) solution which can reacts with $SiO_2$ fragments of the glass. Furthermore coloring the FRP sample with water-soluble dye following the HF treatment makes the roving layer more distinguishable photophysically. The implementation of HF treatment has been successfully tested in this study.