• Title/Summary/Keyword: 화학섬유

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Effect of Preparation Conditions of PAN-based Carbon Fibers on Electrochemical Characteristics of Rechargeable Lithium ion Battery Anode (PAN계 탄소섬유 제조조건에 따른 리튬이온 이차전지 음극의 전기화학적 특성)

  • An K. W.;Lee J. K.;Lee S. W.;Kim Y. D.;Cho W. I.;Ju J. B.;Cho B. W.;Park D. G.;Yun K. S.
    • Journal of the Korean Electrochemical Society
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    • v.2 no.2
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    • pp.81-87
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    • 1999
  • Poly-acrylonitrile (PAN) based carbon fibers were stabilized under various tensions in the presence of air at about $200^{\circ}C$ and sequentially carbonized under some different gas environments in the range of 700 to $1500^{\circ}C$. The prepared carbon fibers were used for rechargeable lithium ion battery anode to investigate preparation parameters effects on electrochemical characteristics. It was found that the tension during stabilization, carbonization temperature and gas atmospheres affect the carbon fiber properties such as conductivity, mechanical strength, surface morphology and diffusion coefficient of lithium ion, which are closely related to the on electrolchemical properties as well as the charge/discharge characteristics.

Preparation of Zeolite Membranes on Papers or Fibers (종이나 섬유를 지지체로 이용한 제올라이트 박막의 제조)

  • Song, Kyeong-Keun;Ha, Kwang
    • Korean Chemical Engineering Research
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    • v.43 no.6
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    • pp.691-695
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    • 2005
  • Zeolite membranes on various supports such as filter paper, cotton fiber, and glass fiber filter were prepared by secondary growth hydrothermal synthesis. First, zeolite NaA (${\approx}0.5{\mu}m$) and silicalite-1 (${\approx}0.2{\mu}m$) crystals were synthesized as zeolite seed crystals, and they were attached to the surfaces of the supports via chemical bonding. Zeolite NaA or silicalite-1 membranes could be synthesized on the supports coated with the seed crystals. The prepared zeolite membranes were observed by scanning electron microscope and analyzed by X-ray diffraction.

Study of Histochemical Changes of Mouse Ovary Under X-ray Irradiation (방사선 조사선량에 따른 생쥐 난소의 조직화학적 변화)

  • Yoon, Chul-Ho
    • Journal of radiological science and technology
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    • v.29 no.4
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    • pp.275-284
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    • 2006
  • This research investigated the morphological changes of folliculus ovary according to the dose of the X-rays when mice were exposed to X-rays, in terms of histochemical reaction. Dyeing methods such as Masson's trichrome method and reticular fiber method were used. The morphological changes of growing folliculus ovary got distinct as the dose of X-rays increased. Especially, the nuclei of granular cells showed manifest condensation and the changes of the transparent zone were distinct. As a result of histochemical reaction according to Masson's trichrome method and reticular fiber method, the changed granular cells, the deformed basilar membrane of folliculus ovary and the abnormal arrangement of the reticular fiber were observed.

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Photodegradation of Cellulosics -Part 1: Effects of Temperature and Humidity on Tear Strength Reduction- (면섬유의 Photodegradation에 대한 연구 -온도, 습도가 인열강도 감소에 미치는 영향-)

  • Jeon Kyung Sook
    • Journal of the Korean Society of Clothing and Textiles
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    • v.16 no.2
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    • pp.181-187
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    • 1992
  • 일반적으로 면섬유는 햇빛에 의해서 변색되거나 약해지며 또 그 외에도 여러가지 물리적, 화학적인 변화를 일으키게 된다. 구체적인 화학반응의 메카니즘은 사용되는 광선의 스펙트럼, 대기조건(실내인 경우는 실내 환경조건) , 산소의 유무 그리고 염료 등 첨가물의 종류와 같은 여러 요소에 의해 크게 영향을 받게 된다. 환경조건 중에서 산소의 존재는 매우 중요하지만 open system에서 산소의 농도가 일정하다고 가정할 때 면섬유가 접하고 있는 환경조건 중에서 온도와 습도는 photodegradation의 속도를 결정짓는 중요한 요인으로 작용하게 된다. 박물관,:기념관, 도서관 등의 소장품이 자연광선이나 인공조명으로부터 손상되는 것을 막기 위해서는 먼저 이들의 photodegradation 현상에 대한 연구를 필요로 한다. 본 연구에서는 면시칩포를 자연광선과 가장 흡사한 스펙트럼을 가진 xenon arc lamp를 사용한 내후도 시험기내에서 온도와 습도를 조절하여 이에 따른 반응속도의 차이를 인열강도의 감소와 중합도 저하로 측정하였다. 1차 반응식은 실험결과를 설명하는데 유용하였으며 온 · 습도의 증가는 반응속도를 증가시키는 것으로 나타나 기존의 상반된 연구결과의 차이를 입증하였다. 또 온도와 습도는 상호관련이 있는 것으로 나타났으며 고온인 경우습도의 영향을 더 크게 받는 것으로 분석되었다. 반응의 활성에너지는 $30\~75\%$ RH에서는 12 kcal/mole 정도이며 수분의 함량이 낮을수록 활성화에너지는 커지는 것으로 나타나 수분은 섬유소 분자구조내에서 가소제 (plasticizer)의 역할을 하는 것으로 판명되었다.

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Preparation of Self-detoxifying Textile for Removal of Chemical Warfare Agents (군사목적의 유해화학물질 제거용 보호복 소재 제조를 위한 섬유 후가공 처리)

  • Kim, Hanil;Choi, Ik-Sung;Park, Seong-Woo;Han, Yo-han;Kim, Sung-Hun;Park, Hyun-Bae;Min, Mun-hong
    • Textile Coloration and Finishing
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    • v.31 no.1
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    • pp.33-41
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    • 2019
  • In this report, nano-sized catalysts were introduced onto fabric surface to eliminate toxic chemicals assisted by physical adsorption. For chemical removal of toxic compounds, a series of zirconium-containing catalysts were synthesized and treated on fabric to catalyze the hydrolysis and oxidation of target molecules. Antimicrobial was also introduced for the research purpose to prove the compatibility of as-synthesized catalysts with other solutions. Zirconium ligated with hydroxyl group and MOF(Metal-Organic Frameworks) were exploited as catalyst for removal of toxic compounds, while zinc complex was used for an antimicrobial to culminate in a chemical shield. Once fabrics were functionalized, fabrics were washed 2 or 5 times for a washing durability test. The amount of catalyst in textile were measured by ICP-MS and weight increasing ratio of fabrics.

A study on Sliding Friction and Wear Characteristics of Hybrid Composites at Medium Sliding Speed (중속에서의 하이브리드 복합재료의 미끄럼 마찰 및 마모 특성에 관한 연구)

  • 정형범;윤재륜
    • Composites Research
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    • v.13 no.1
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    • pp.78-88
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    • 2000
  • Tribological properties of fiber composite materials were measured and wear resistant hybrid structure was proposed based upon the understanding of tribological behavior of the composite materials. Unidirectional composites with glass fibers, carbon fibers, and aramid fibers were tested for tribological properties in order to propose a wear resistant hybrid structure. Hybrid composites which contain carbon and aramid fibers were prepared, the specimens were sliced by a water-jet cutter, and friction and wear properties were measured. An experimental set-up was designed and built for the friction and wear test of the composite specimens. Unidirectional fiber composite and hybrid composite specimens were tested to evaluated the tribological behavior for biomimetic applications. It is observed that the friction and wear behavior of fiber composites depends upon fiber orientation, sliding speed, and type of reinforcing fibers.

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Development of Adhesive Resins Formulated with Rapeseed Flour Hydrolyzates for Medium Density Fiberboard (MDF) (유채박 가수분해물을 이용한 중밀도섬유판(MDF) 제조용 접착제의 개발)

  • Yang, In;Han, Gyu-Seong;Choi, In-Gyu;Kim, Yong-Hyun;Ahn, Sye-Hee;Oh, Sei-Chang
    • Journal of the Korean Wood Science and Technology
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    • v.40 no.3
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    • pp.177-185
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    • 2012
  • The interest to develop adhesives from renewable resources is growing to substitute petroleum-based adhesive resins in the manufacture of wood based panels. In our study, rapeseed flour (RSF), which is the by-product of bio-diesel produced from rapeseed, were hydrolyzed with acid and alkali. As a crosslinking agents of the RSF hydrolyzates, phenol-formaldehyde prepolymers (PF) were prepared. The RSF hydrolyzates and PF were mixed to complete the formulation of RSF-based adhesive resins, and the resins were applied to make the medium density fiberboard (MDF). The physical and mechanical properties of the MDF were measured to examine whether RSF can be used as raw materials of adhesive resins for the manufacture of MDF or not. The average moisture content and density of the MDF made with RSF-based adhesive resins satisfied the minimum requirement of KS standard, but the thickness swelling was not. The bending strengths of the MDF made with RSF-based adhesive resins were lower than that of the MDF made with commercial UF resins, but the internal bonding strengths of tested MDF in some make-up conditions of RSF-based adhesive resins were higher than that of MDF made with commercial UF resins. These results showed the potential of RSF as a raw material of adhesives for the production of MDF. Future works on the optimal manufacturing process conditions of MDF made with RSF-based adhesive resins are required to improve the performance of MDF made with RSF-based resins.

A Study of Finishing Conditions influencing Spandex Quality

  • Park, Pyong Ki;Kim, Young Gyun
    • Journal of Korean Society for Quality Management
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    • v.12 no.1
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    • pp.35-44
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    • 1984
  • Spandex is a elastomeric fiber in which the-fiber-forming substance is a long chain polymer consisting of at least 85% segmented polyurethane. In the polyurethanes there are the additional oxygen atoms in the main chains of the molecule. The effect of these oxygen atoms is to make the molecule flexible. From a physical point of view, elasicity and recovery from stretch are the most important properties of polyurethane, so its use had now expanded into many knitting industry. In this paper, we wish to Test the effect of some finishing conditions on the quality of polyurethane.

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Photodegradation of Cellulosics(Part II) - Chemical Properties of Irradiated Cotton - (Cellulose의 광분해에 관한 연구(II) - 광조사된 면섬유의 화학적 성질을 중심으로 -)

  • 전경숙
    • Journal of the Korean Society of Clothing and Textiles
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    • v.18 no.1
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    • pp.15-22
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    • 1994
  • The formation of carbonyl group was dominant to other functional groups. Concentrations of both carboxyl and peroxide groups were found to rapidly reach low steady state values that increased slightly with increa-sing temperature and relatice humidity. Since the deg-radation of cellulose samples was in the initial stage and the conversion of glycosidic bonds and hydroxyl groups were very small, it was found that changes in the physical and chemical properties could be fitted to a first-order reaction model.

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Electrochemical Polymerization of Conducting PVC-g-Poly(methyl aniline) Copolymer and Properties (전기화학 중합에 의한 전도성 PVC-g-Poly(methyl aniline) 공중합체의 합성 및 성질)

  • 조현석;박연흠;박종민
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.355-358
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    • 2002
  • 고분자가 절연재료로서 사용되는 이유는 전기를 통하지 않는 절연특성을 지니고 있기 때문이며 이러한 성질은 고분자가 금속재료와 구별되는 가장 큰 특징이다. 그러나 1964년 W. A. Little 이 발표한 공액 이중결합구조를 가진 화합물은 전도성 고분자가 될 수 있다는 가설을 바탕으로 전도성 고분자에 관한 많은 연구가 진행 중에 있다. 전도성 고분자는 절연체로서의 응용에만 한정되어왔던 기존 고분자물질들과 달리 가볍고 저렴하며 단일결합과 이중결합을 교대로 하고 있는 공액 고분자 구조를 가지고 있어 다양한 화학적 합성방법에 의해 전기전도도, 유전상수, 결정 등의 물리적 성질을 조절할 수 있으며, 금속의 전기적, 자기적, 광학적 특성과 고분자의 기계적 성질을 동시에 가지므로 배터리, 축전기, 트랜지스터, 광전소자, 전자파 차폐제 등 플라스틱 전자소재의 실용적으로 인해 산업체에서도 높은 관심의 대상이다. (중략)

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