• Journal of Soil and Groundwater Environment
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• v.19 no.3
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• pp.56-65
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• 2014

Contamination of explosive compounds in the soils of military shooting range may pose risks to human and ecosystems. As shooting ranges are located at remote places, active remediation processes with hardwares and equipments are less practical to implement than natural solutions such as bioremediaton. In this study, a series of experiments was conducted to select a suitable carbon source and to optimize dosing rate for the enhanced bioremediation of explosive compounds in surface soils and sediments of shooting ranges with indigenous microorganisms activated by external carbon source. Treatability study using slurry phase reactors showed that the presence of indigenous microbial community capable of explosive compounds degradation in the shooting range soils, and starch was a more effective carbon source than glucose and acetic acid in the removal of TNT. However, at higher starch/soil ratio, i.e., 2.0, the acute toxicity of the liquid phase increased possibly due to transformation products of TNT. RDX degradation by indigenous microorganisms was also stimulated by the addition of starch but the acute toxicity of the liquid phase decreased with the increase of starch/soil ratio. Taken together, the optimum range of starch/soil ratio for the degradation of explosive compounds without significant increase in acute toxicity was found to be 0.2 of starch/soil.

• Journal of Soil and Groundwater Environment
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• v.19 no.3
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• pp.82-93
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• 2014

A starch ball was devised to conveniently supply carbon source to indigenous microorganisms and to enhance biotransformation of explosive compounds(TNT and RDX) in the sediments of settling basins installed in military shooting ranges. To identify optimum dose/sediment ratio for degradation of explosives in the basin, a series of bench scale settling basin experiments were performed for 30 days while monitoring supernatant pH, DO, concentrations of nitrite, nitrate, sulfate, explosive compounds, and acute toxicity measured by bacterial luminescence. Addition of starch ball induced changes in oxidation conditions from oxic to anoxic in the benthic zone of the basin, which resulted in subsequent reductive degradation of both TNT and RDX in the liquid and solid phase of basin. However, fermentation products of excess starch, acetic acid and formic acid, caused acute toxicity in the liquid phase. The optimum ratio of starch ball/sediment for explosive compounds degradation by inducing changes in bio-geochemical environments without increase in acute toxicity, was found to be 0.009~0.017.

• Explosives and Blasting
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• v.40 no.2
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• pp.1-14
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• 2022

Numerical simulation is the most widely used methods for evaluating blasting performance. This study, conducted the numerical analysis of shock chamber model to evaluate the pressure confine effect of the stemming material and plug device. The stemming effect was compared and evaluated with that of the STF-based stemming material currently under development and sand, which is a commonly used blast stemming material. Furthermore, to verify of enhancement the confine effect inside blast hole pressure, three types of stemming plugs were adopted for the numerical analysis. The numerical simulation results revealed that the STF-based stemming materials were superior to the general stemming material. Also, It is evaluated that the STF-based stemming and Plug system can not only prevent detonation gas from overflowing the borehole prematurely, but also prolong the action time and scope of detonation gas in the borehole effective.

• Explosives and Blasting
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• v.41 no.1
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• pp.1-18
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• 2023

Stemming is a process applied to blast holes to prevent gases from escaping during detonation. A stemming material helps confine the explosive energy for longer and increases rock fragmentation. This study developed a stemming material based on a shear-thickening fluid (STF) that reacts to dynamic shock. Two blasting experiments were conducted to Field-verify the performance of the STF-based stemming material. In the first experiment, the pressure inside the blast hole was directly measured based on applying the stemming material. In the second field verification, tunnel blasting was performed, and the blasting results of sand stemming and, that of the STF-based stemming case were compared. The measurement results of the pressure in the blast hole showed that when the STF-based stemming material was applied, the pressure at the top of the blast hole was lower than in the sand stemming case, and the stemming ejection was also lower. The results of the field application verify that the excavation performance of the STF-based stemming case in the tunnel blasting was superior to that of the sand stemming case.

• Journal of the Korean GEO-environmental Society
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• v.16 no.4
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• pp.13-22
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• 2015

The combined impact of Dissolved Organic Matter (DOM) fouling and inorganic ($CaSO_4,Ca_3(PO_4)_2$) scaling on the retention of TNT (2, 4, 6-Trinitrotoluene), RDX (Hexahydro-1, 3, 5-trinitro-1, 3, 5-triazine) and HMX (1, 3, 5, 7-Tetranitro-1, 3, 5, 7-tetrazocane) explosive contaminants by nano-filtration membrane were studied, since organic fouling and salt scaling are the major limitations for membrane filtration. Results reported here indicate that DOM fouling layer with a humic acid does not necessarily lead to an immediate loss of permeate flux but can result in a severe impact on the flux loss when both humic acid and inorganic scaltants were presented simultaneously. The $Ca_3(PO_4)_2$ mixed with humic acid showd most sever flux loss (42%) compared to that of only humic acid presence (8%). It could be a result that the scaling formation of the NF membrane was dominated by cake layer formation of DOM and it was along with pore blocking by the formation of crystals inside the porous active matrix of the NF membrane. In addition, these results indicated that the membrane selectivity of the explosives retention trended correlated with respect to increasing explosives size (listed by MW) based on greater steric interactions and followed the order (MW, g $mol^{-1}$; removal, %): HMX (296.15; 83%) ${\gg}$ RDX (222.12; 49%) ≋ TNT (227.13; 32%). Because the scaling and fouling layer could lead to a additional cake-enhanced concentration polarisation effect, the retention of explosives with the presence of humic acid in the feed solution and inorganic scaling formation on top of an organic fouling layer do not differ substantially retention from that of pure DI feed and NaCl solution.

• Journal of Korean Society of Environmental Engineers
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• v.36 no.4
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• pp.237-245
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• 2014

Amur silver grass (Miscanthus sacchariflorus) and reed canary grass (Phalaris arundinacea) were selected for RDX removal experiments in hydroponic culture conditions based on vegetation survey at three shooting ranges in northern Kyunggi province. Seedling of two plants were grown in 1/4 strength Hoagland solution in quadruplicates containing 10, 20, 30, 40 mg/L RDX for 15 days along with control and blank treatments. During the 15 days of incubation, pH and RDX concentration in medium were routinely analyzed and RDX contents in the shoot and the root were determined after solvent extraction at the end of the experiments. Both plant species showed no symptoms of RDX phyto-toxicity. The pseudo first order RDX-removal constants for amur silver grass and reed canary grass were in the range of $0.0143{\sim}0.0484day^{-1}$ and $0.0971{\sim}0.1853^{-1}$, respectively. Plant biomass normalized RDX removal rates, which decreased with the increase of initial RDX concentration, were in the range of $0.27{\sim}1.01mL{\cdot}g^{-1}day^{-1}$ and $0.87{\sim}1.66mL{\cdot}g^{-1}day^{-1}$ for amur silver grass and reed canary grass, respectively. After 15 days of treatment, RDX removal from the medium decreased from 49.0% to 23.7% with increase in the initial RDX concentration in amur silver grass and 7.3% of the initial RDX remained in the plant. In reed canary grass planted medium, less than 16.8% and 5% of the initial RDX remained in the medium and in the plant, respectively. Large quantities of unidentified polar compound, which was not detected in amur silver grass, accumulated in the root and shoot of reed silver grass.

• Explosives and Blasting
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• v.29 no.1
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• pp.17-26
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• 2011

In this study, the pollutants contained in water and soil samples taken from the explosive demolition site were examined to investigate the effects on environment, and management plan of non-point source pollution in the demolition site was suggested through characterizing the movement of the pollutant with time. As results, pH value of the water and soil samples after the demolition work was 8.5~9.3 which exceeds the Korean environmental criterion of water and soil range due to calcium hydroxide compounds in the concrete. The concentration level of heavy metals caused by the explosive demolition doesn't exceed the environmental criterion of water and soil doesn't exceed the environmental criterion of water and soil quality, and the influence of water and soil pollution on the environment was not considered. The concentration of the heavy metals was analyzed and that of Cr, Cu, Zn and Hg among the heavy metals increased after the drilling and explosive demolition. This says that concentration of the heavy metals during explosive demolition works needs to be monitored. The most pollutants with time or rain dilution into the demolition site decreased and this means that the pollutants caused by the explosive demolition might have influenced to vicinity of the demolition sites as non-point pollution.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.172-178
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• 2017

Thermal property is one of the important characteristic in the field of energetic materials. As the energy material is released during decomposition, DSC(Differential Scanning Calorimetry) is frequently used for the thermal analysis. In case of the dynamic DSC measurements, thermal dynamic change like melting is prevented from the thermal property measurements. And due to the predicting kg scale, the conditions of the heat exchange with the environment significantly is changed. In this study, As the method to resolve the problem, we predict the thermal aging property using the AKTS thermokinetic program from DSC measurements which performed isothermal method. Predicting the thermal aging properties from ARC(Accelerating Rate Calorimetry) measurement, we compare two results.

• Journal of Soil and Groundwater Environment
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• v.17 no.6
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• pp.119-128
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• 2012

The applicability and accuracy of Revised Universal Soil Loss Equation (RUSLE) model on the estimation of soil loss at impacted area of shooting range was tested to further the understanding of soil erosion at shooting ranges by using RUSLE. At a shooting range located in northern Kyunggi, the amount of soil loss was estimated by RUSLE model and compared with that estimated by Global Positioning System-Total Station survey. As results, the annual soil loss at a study site (202 m long by 79 m wide) was estimated to be 2,915 ton/ha/year by RUSLE and 3,058 ton/ha/year by GPS-TS survey, respectively. The error between two different estimations was less than 5%, however, information on site conditions should be collected more to adjust model coefficients accurately. At the study shooting range, sediments generated by rainfall was transported from the top to near the bottom of the sloping face through sheet erosion as well as rill erosion, forming a gully along the direction of the storm water flow. Coarser fractions of the sediments were redeposited in the limited area along the channel. Distribution characteristics of explosive compounds in soil before and after summer monsoon rainfall in the study area were compared with the erosion patterns. Soil sampling and analyses results showed that the dispersion of explosive compounds in surface soil was consistent with the characteristics of soil erosion and redeposition pattern of sediment movements after rainfalls.

• Journal of Soil and Groundwater Environment
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• v.20 no.6
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• pp.73-84
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• 2015

Nine plant species were selected through vegetation survey at three military shooting ranges at northern Gyeonggi Province. Plants were germinated in normal soil and three seedlings were transplanted to a bottom sealed pot containing sandy loam soils contaminated with either RDX (291 mg/kg) or TNT (207 mg/kg). Planted, blank (without plant), and control (without explosive compound) pots were grown in triplicate at a green house for 134 days. During cultivation, transplanted plants exhibited chlorosis and necrosis in flower and leaf by explosive toxicity and stress. Only three plants, Wild soybean, Amur silver grass, Reed canary grass, survived in TNT treated pot, while seven plant species except for field penny cress and jimson weed, thrived in RDX treated pot. Appreciable amount of TNT (61.6~241.2 mg/g-D.W.) was detected only in plant roots. Up to 763.3 mg/g-D.W. along with 4-amino-2,6-dinitrotoluene, an intermediate of TNT, accumulated in the root of wild soybean. In addition, azoxy compounds, abiotic intermediates of TNT, were detected in TNT treated soils. RDX absorbed average 1,839.95 mg/kg in shoot and 204.83 mg/kg in root. Most of TNT in plant was accumulated in underground part whereas RDX was localized in aerial part. Material balance calculation showed that more than 95% of the initial TNT was removed in the planted pots whereas only 60% was removed in the blank pot. The amount of RDX removed from soil was in the order of Amur Silver Grass (51%) > Chickweed (43%) > Evening primrose (38%). Based on the results of pot cultures, Amur silver grass and Reed canary grass are selected as tolerant remedial plants for explosive toxicity.