• Title/Summary/Keyword: 혼합 활성화제

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Compressive Strength and Optimal Mixing Ratio of Alkali Activated Cement Concrete Containing Fly Ash (플라이 애쉬를 활용한 알칼리 활성시멘트 콘크리트의 압축강도와 최적혼합비)

  • Han, Sang-Ho;Park, Sang-Sook;Kang, Hwa-Young
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.11 no.4
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    • pp.152-158
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    • 2007
  • This is a fundamental research to utilize alkali activated cement(AAC) in concrete. The compressive strength of AAC concrete were measured for the various mixing ratios of activator/fly ash, and the mixing ratios of water glass, NaOH, and water among the activators. The mixing ratio of fine and coarse aggregates was maintained constantly. The relationships between the compressive strength and mixing ratios were analyzed to find the optimal mixing ratio of AAC concrete. As the results, the optimal mixing ratio of activator/fly ash in AAC concrete was 0.7, and that of water glass, NaOH, water among the activator was 4.0:1.0:2.5 for the maximum compressive strength.

Influence of Blended Activators on the Physical Properties of Alkali-activated Slag Mortar (알칼리 활성화 슬래그 모르타르의 특성에 미치는 혼합 활성화제의 영향)

  • Kim, Tae Wan;Park, Hyun Jae;Seo, Ki Young
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.6
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    • pp.26-33
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    • 2012
  • This paper reported on the effect of blended activator on the physical properties of alkali-activated slag mortar. Five different activators(caustic alkalis) were used: sodium hydroxide(NaOH, A Case), calsium hydroxide($Ca(OH)_2$, B Case), magnesium hydroxide($Mg(OH)_2$, C Case), aluminum hydroxide($Al(OH)_3$, D Case), and potassium hydroxide(KOH, E Case). We blended five caustic alkalis with sodium carbonate($Na_2CO_3$). The dosage of five caustic alkalis was 3M and sodium carbonate was 1M, 2M and 3M. The result of flow and setting time was decrease as the dosage of sodium carbonate increase. But the compressive strength was increase as the dosage of sodium carbonate increase. It was shown that there is a good effect of blended caustic alkalis with sodium carbonate in alkali-activated slag mortar.

The Strength Properties of Alkali-Activated Slag Mortars by Combined Caustic Alkali with Sodium Carbonate as Activator (가성알칼리와 탄산나트륨을 혼합한 활성화제를 사용한 알칼리 활성화 고로슬래그 모르타르의 강도 특성)

  • Kim, Tae-Wan
    • Journal of the Korea Concrete Institute
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    • v.24 no.6
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    • pp.745-752
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    • 2012
  • This paper studies the effect of the compressive strength for combined alkali-activated slag mortars. The effect of activators such as alkali type and dosage factor on the strength was investigated. The alkalis combinations made using five caustic alkalis (sodium hydroxide (NaOH, A series), calcium hydroxide ($Ca(OH)_2$, B series), magnesium hydroxide ($Mg(OH)_2$, C series), aluminum hydroxide ($Al(OH)_3$, D series), and potassium hydroxide (KOH, E series)) with sodium carbonate ($Na_2CO_3$) were evaluated. The mixtures were combined in different dosage at 1M, 2M, and 3M. The study results showed that the compressive strength of combined alkali-activated slag mortars tended to increase with increasing sodium carbonate. The strength of combined alkali-activated slag mortars was better than that of control cases (without sodium carbonate). The result from scanning electron microscopy (SEM) analysis confirmed that there were reaction products of calcium silicate hydrate (C-S-H) and alumina-silicate gels from combined alkali-activated slag specimens.

A Study on Cementation of Sand Using Blast Furnace Slag and Extreme Microorganism (고로슬래그와 극한미생물을 이용한 모래의 고결화 연구)

  • Park, Sung-Sik;Choi, Sun-Gyu;Nam, In-Hyun
    • Journal of the Korean Geotechnical Society
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    • v.30 no.1
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    • pp.93-101
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    • 2014
  • In this study, a blast furnace slag having latent hydraulic property with an alkaline activator for resource recycling was used to solidify sand without using cement. Existing chemical alkaline activators such as $Ca(OH)_2$ and NaOH were used for cementing soils. An alkaliphilic microorganism, which is active at higher than pH 10, is tested for a new alkaline activator. The alkaliphilic microorganism was added into sand with a blast furnace slag and a chemical alkaline activator. This is called the microorganism alkaline activator. Four different ratios of blast furnace slag (4, 8, 12, 16%) and two different chemical alkaline activators ($Ca(OH)_2$ and NaOH) were used for preparing cemented specimens with or without the alkaliphilic microorganism. The specimens were air-cured for 7 days and then tested for the experiment of unconfined compressive strength (UCS). Experimental results showed that as a blast furnace slag increased, the water content and dry density increased. The UCS of a specimen increased from 178 kPa to 2,435 kPa. The UCS of a specimen mixed with $Ca(OH)_2$ was 5-54% greater than that with NaOH. When the microorganism was added into the specimen, the UCS of a specimen with $Ca(OH)_2$ decreased by 11-60% but one with NaOH increased by 19-121%. The C-S-H hydrates were found in the cemented specimens, and their amounts increased as the amount of blast furnace slag increased through SEM analysis.

Compressive and Tensile Properties of Fiber-Reinforced Cementless Composites According to the Combination of Sodium-Type Alkali-Activators (나트륨계 알칼리 활성화제 조합에 따른 섬유보강 무시멘트 복합재료의 압축 및 인장특성)

  • Choi, Jeong-Il;Park, Se-Eon;Lee, Bang-Yeon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.1
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    • pp.29-36
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    • 2017
  • The purpose of this study is to investigate experimentally the effect of types of alkali-activators and curing conditions on the compressive and tensile behavior of fiber-reinforced cementless composites. Two types of alkali-activators and two curing conditions were determined and density test, compressive strength test, and uniaxial tension test were performed. Test results showed that the cementless composite with sodium silicate showed higher performance in terms of strength, tensile strain capacity, and toughness than that with calcium hydroxide and sodium carbonate. The effect of curing conditions depends on the types of alkali-activators.

Development activator for physical properties of slag Cement (슬래그 시멘트의 물성제어를 위한 활성화제 개발)

  • Park, Nam-Kyu;Lee, Jong-Kyu;Chu, Yong-Sik;Song, Hun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.545-548
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    • 2008
  • In this study aluminium sulfate, Ca(OH)$_2$, K-R Slag and $Na_2SO_4$ were used as active admixtures and their concentration 1, 3, 5, 7 weight percent in cement. The physical properties of active admixtures cement mortar were investigated by flow test and compressive strength. It was found that the resulting active admixtures exhibited the higher compressive strength than OPC mortar up. From the test results, cement mortars added active admixture have a good fundamental property.

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The Effect on the Alkali-Activator Mixture Ratio of fly Ash Mortar (알칼리 활성화제 혼합비가 플라이애시 모르타르에 미치는 영향)

  • Kang, Hyun-Jin;Kang, Su-Tae;Ko, Kyung-Taek;Ryu, Gum-Sung;Park, Jung-Jun;Lee, Jang-Hwa
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.395-396
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    • 2009
  • The purpose of this study is to observe the effect of mixture ratio of alkali-activator on workability and compressive strength of alkali-activated mortar that using 100% fly ash.

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Mechanical Properties of Granulated Ground Blast Furnace Slag on Blended Activator of Sulfate and Alkali (황산염 및 알칼리계의 혼합 활성화제에 대한 고로슬래그미분말의 역학적 특성)

  • Kim, Tae-Wan;Jun, Yu-Bin;Eom, Jang-Sub
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.5
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    • pp.104-111
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    • 2015
  • This study shows the mechanical properties of alkali-activated slag cement (AASC) synthesized using sulfate with NaOH solution. The used sulfates were calcium sulfate ($CaSO_4$, denoted CS) and sodium sulfate ($Na_2SO_4$, denoted SS). The replacement ratio of sulfates was 2.5, 5.0, 7.5 and 10.0% by weight of slag. NaOH solution of 2M and 4M concentration was used. A sample was activated with sulfate and activated with blended activator (blending NaOH solution with sulfate) respectively. 24 mix ratios were used and the water-binder weight ratio for the test was set 0.5. This research carried out the compressive strength, flexural strength, ultrasonic pulse velocity (UPV), absorption and X-ray diffraction (XRD). In the case of samples with CS, sample with 7.5% CS, sample with 2M NaOH+5.0% CS and sample with 4M NaOH+5.0% CS showed the good performance in the strength development. In the case of samples with SS, sample with 10.0% SS, sample with 2M NaOH+7.5% SS and sample with 4M NaOH+2.5% SS obtained good performance in strength. The results of UPV and water absorption showed a similar tendency to the strength properties. The XRD analysis of samples indicated that the hydration products formed in samples were ettringite, CSH and silicate phases. In this study, it is indicated that when compared to the use of sulfate only, the use of both sulfate and NaOH solution makes mechanical properties of AASC better.

Investigation of the Adsorption Properties of Activated Carbon Made by Chemical Activation of Mixed Waste Plastic Pyrolysis Residues (혼합 폐플라스틱 열분해 잔류물의 화학적 활성화를 통해 제조한 활성탄의 흡착 특성 조사)

  • Eun-Jin Moon;Yunsuk Kang;Byoungsun Park
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.4
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    • pp.391-399
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    • 2023
  • Recently, low-temperature pyrolysis technology has been studied as a recycling method for waste plastic. Low-temperature pyrolysis technology for waste plastic produces pyrolysis oil that can be used as an energy resource, but solid residue remains. Waste plastic pyrolysis residues are mostly landfilled due to their limited use. In this study, it is investigated that mixed waste plastic pyrolysis residues could be recycled into activated carbon. It was confirmed that the fixed carbon content of the residue was 33.69 % from proximate Analysis. Chemical activation was used to manufacture activated carbon. KOH was used as an activator. To investigate the effect of the mixing ratio of KOH and residue, samples were mixed at ratios of 0.5, 1.0, and 2.0. The mixed sample was chemically activated at an activation temperature of 800 ℃ for 1 hour. As a result of analyzing the characteristics of activated carbon through BET, it was confirmed that the specific surface area increased as the mixing ratio of KOH increased.

Add to activator for physical properties of slag Cement (활성화제를 첨가한 사멘트 및 콘크리트의 물리적 특성)

  • Park, Nam-Kyu;Lee, Jong-Kyu;Chu, Yong-Sik;Song, Hun;Lee, Jung-Hui;Kwon, Choon-Woo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.323-324
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    • 2009
  • In this study aluminium sulfate, Ca(OH)$_2$, K-R Slag and Na$_2$SO$_4$ were used as active admixtures. The physical properties of active admixtures cement mortar were investigated by flow test and compressive strength. It was found that the resulting active admixtures exhibited the higher compressive strength than OPC mortar up. From the test results, cement mortars added active admixture have a good fundamental property.

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