• Title/Summary/Keyword: 혼합제

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Characteristic of Permeability with the Sand, Calcium Bentonite and Solidifier Mixtures according to Selective Reaction of TCE (트리클로로에틸렌(TCE) 선택적 반응에 따른 모래, 칼슘-벤토나이트 및 겔화제 혼합차수물의 투수 특성)

  • Yun, Seong Yeol;Choi, Jeong Woo;Oh, Minah;Lee, Jai-Young
    • Journal of the Korean Geosynthetics Society
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    • v.19 no.1
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    • pp.25-33
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    • 2020
  • To improvement the swelling characteristics of the existing cutoff wall against the moisture, the permeability of the sand, calcium bentonite and solidifier mixture according to the contact with trichloroethylene (TCE) was evaluated. Characteristics analysis and the permeability test of the research materials were performed. The permeability was decreased as the mixing ratio of the calcium bentonite was increased and it was increased as the mixing ratio of the solidifier was increased. In conclusion, when mixing 15% of calcium bentonite and more than 30% of solidifier, the permeability coefficient in the underground water movement was analyzed as more than α × 10-4 cm/sec showing that it does not block the underground water movement. In addition, as the permeability coefficient of mixtures after TCE reaction was analyzed as less than α ×10-7 cm/sec, it satisfied the condition of blocking layer (less than 1.0 × 10-6 cm/sec). Therefore, the calcium bentonite and solidifier can be utilized as barrier that showing the characteristic of percolation ability conversion in soil and underground water contaminated with TCE.

Laboratory Study on Changes in Hydraulic Conductivity and Chemical Properties of effluent of Soil During Desalinization (간척지(干拓地) 제염과정(除鹽過程)에서 일어나는 토양(土壤)의 수리전도도(水理傳道度)와 유출액(流出液)의 화학적(化學的) 특성변화(特性變化)에 관(關)한 실험적(實驗的) 연구(硏究))

  • Yoo, Sun-Ho;Lee, Sang-Mo
    • Korean Journal of Soil Science and Fertilizer
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    • v.21 no.1
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    • pp.3-10
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    • 1988
  • A laboratory study was carried out to investigate the effects of application level of soil amendments, mixing method of soil amendments, and compost treatment on desalinization by examining the changes in hydraulic conductivity and chemical properties of effluent of the soil during desalinization. 1. The treatment of soil amendments brought about the increase in hydraulic conductivity. 2. The higher the application level of a soil amendment, the higher the hydraulic conductivity and the shorter the time elapsed to complete the desalinization. 3. Complete mixing of calcium compounds was more effective for desalinization than surface mixing. 4. The compost treatment induced the rise in pH and therefore brought about the remarkable drop in hydraulic conductivity. 5. During the desalinization, the changes in physical and chemical properties of the soil were influenced by the kind and application level of soil amendments, mixing method of soil amendment, and compost treatment.

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A Study on the Mechanical Properties Optimization of Solid Propellant (고체 추진제의 기계물성 최적화 연구)

  • Choi, Yongkyu;Ryu, Taeha;Kim, Nakhyun;Kim, Jeongeun
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.6
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    • pp.91-97
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    • 2015
  • The limit values of mechanical properties(MPs) of HTPB/AP/Al Solid Propellant was reviewed according to the rocket motor development procedures and the in-process values of MPs were analyzed by the tool of Process Capability Index. Based on finding the dependency among MPs, the optimization is proposed for reducing the properties defects and for improving the rocket grain safeties.

Preparation and Characterization of Lightweight Fillers and Inorganic Flame Retardants are Added Polyurethane Composite Foam (경량 충진제 및 무기계 난연제 첨가 polyurethane 복합발포체 제조 및 특성)

  • Kang, Dong-Rak
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.3
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    • pp.955-960
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    • 2012
  • In this study, pure Polyurethane and commonly used flame retardants $Al(OH)_3$ and $Mg(OH)_2$, the add-in sample and Cloisite Na+, Cloisite 15A added sample of flammability and mechanical properties are compared. Sodium silicate and a mixture of polyurethane that the lightweight filler Vermiculite, Perlite addition of flame retardant and mechanical properties of the sample was confirmed. As a result, the flame retardant additive in the Vermiculite and Perlite in a flame-retardant grade sample except sample were identified. Tensile strength is degrade accord to the filler amount. But, Sodium silicate in the case of the sample add-in, other than confirmed that the sample strength increases.

고연소속도 추진제용 연소촉매 연구

  • 황갑성;임유진;김창기
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 1996.11a
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    • pp.193-198
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    • 1996
  • 고연소속도 HTPB/AP 추진제를 얻기 위하여 현재 각광받고 있는 3종의 철화합물 연소촉매를 선정하여 연소속도 증진효과와 기계적 특성, 공정성 및 노화특성에 미치는 영향을 검토하였다. 사용한 철 화합물은 HTPB 프리폴리머에 silicone-ferrocene이 그라프트된 $BUTACENE^$\circledR$$ 과 결합제 역할을 하는 acylaziridinyl ferrocene(AAF), 그리고 입자크기가 30nm인 $NANOCAT^$\circledR$$ superfine iron oxide(SFIO)이었다. 이들 철 화합물을 추진제에 적용한 결과 공정성의 경우 $BUTACENE^$\circledR$$ 은 혼합점도가 높았으나 pot life의 감소는 없었으며 AAF와 SFIO는 혼합점도는 비교적 낮은 반면 pot life가 현저히 감소하는 경향을 보였다. 추진제의 노화거동은 연소촉매를 사용하지 않았을 때보다 저하되었으나 metal deactivating 산화방지제인 $PRO-TECH^$\circledR$$ 과 함께 사용할 경우 공정성 및 노화특성 모두 바람직한 수준으로 향상되었다. 기계적 특성은 SFIO를 제외하고는 저하되었으며 $BUTACENE^$\circledR$$ 은 프리폴리머로서, AAF는 결합제로서의 기능이 다소 미흡하였다. 한편 연소촉매의 함량에 따른 촉매효과는 AAF>SFIO>$BUTACENE^$\circledR$$ 순이었고 철 함량 측면에서는 AAF>$BUTACENE^$\circledR$$ >SFIO 순이었다.

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Green-house GAS Reduction Through the Environmental Policy Mixes Both Environmental Trading and Carbon Taxes (온실가스 감축을 위한 배출권거래제와 탄소세의 정책혼합 효과 분석)

  • Lim, Jae-Ku;Kim, Jeong-In
    • Environmental and Resource Economics Review
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    • v.12 no.2
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    • pp.245-274
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    • 2003
  • This paper analyzes the economic and environmental impacts of domestic policy to reduce greenhouse gas emissions by focusing on carbon tax, domestic emissions trading and the mixture of these policies. By utilizing a dynamic CGE model, KORTEM, this study shows that the economic cost under carbon tax is projected to be higher than that under emission trading. It is because under carbon tax scheme each emitter in economy must meet its emission target regardless of the abatement cost. On the other hand, emission trading allows emitters to reduce the marginal cost of abatement through trading of emission permits. In designing policy portfolio to address the climate change problem in Korea, therefore, this paper proposes the introduction of domestic emission trading scheme as the main domestic policy Instrument.

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Optimal Selection of Fuel Bias and Propellant Residual Analysis of a Liquid Rocket (액체 추진 로켓의 최적 연료 바이어스 산정 및 추진제 잔류량 분석)

  • Song, Eun-Jung;Cho, Sangbum;Roh, Woong-Rae
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.43 no.1
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    • pp.88-95
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    • 2015
  • This paper considers the effects of propellant mixture ratio and loading errors on the performance of a liquid rocket. Propellant residuals generated by error sources are analyzed for a launch vehicle model whose first stage consists of a cluster rocket of four 75-tonf class engines using a statistical Monte-Carlo approach and then the optimal fuel biases minimizing residuals are computed. The results are validated through comparison with analytic method using approximate formula, which have been applied for other space launch vehicles.

The study of ignition characteristics of solid propellant using Arc Image Furnace (광학특성을 이용한 고체추진제 점화특성 연구)

  • Yoo, Ji-Chang;Kim, In-Chul;Jung, Jung-Yong;Ko, Seung-Won;Lee, Kyung-Joo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.11 no.6
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    • pp.1-8
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    • 2007
  • The objective of the present work is to characterize design parameters of solid propellant ignitor for composite, double base, and nitramine propellants using arc image furnace. Arc image furnace and fiber optics surface reflectometer were used to measure ignition delay time and reflected optical energy of several compositions of composite, double base and nitramine base rocket propellant at different pressure levels each other. The order of ignitability was double base > composite> nitramine propellants at initial pressure of over 75 psia. The highest ignition energy was needed to ignite nitramine propellant, however, the ignition delay time decreased abruptly as the pressure increased up to the range of $75{\sim}400$ psia. The absorbtion of radiation energy could be increased by the addition of small amount of opacifiers as carbon black, ZrC, WC and burning catalyst.

Numerical Study for the Optimal Operation of Semi Dry Reactor(SDR) (SDR 반응의 운전 최적화를 위한 전산 해석)

  • Park, Ki-Woo;Jung, Yu-Jin;Jeong, Moon-Heon;Hong, Sung-Gil;Jung, Jong-Hyeon;Lim, Ki-Hyuk;Shon, Byung-Hyun
    • Proceedings of the KAIS Fall Conference
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    • 2012.05a
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    • pp.426-430
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    • 2012
  • 본 연구에서는 3차원 수치 해석 기법으로 SDR 반응기 내 유동 특성을 모사하여 유동 분포 및 체류 시간등을 확인하고 혼합 특성 개선을 위한 방법에 대해 연구하였다. 본 연구 대상 SDR 반응기는 입구 덕트와 반응기 본체의 접속 구간에 가이드 베인(Guide vane)이 설치되어 있고 그 바로 하부 지점에 흡수제를 분무하는 노즐이 설치되어 있다. 이는 처리가스가 반응기로 유입될 때 가이드 베인에 의해 선회류를 형성하여 분무된 흡수제와의 혼합을 촉진시키기 위한 목적으로 설치하였다. 시간당 1,971$m^3/min$ at $260^{\circ}C$의 처리가스가 반응기 상부로 유입되어 가이드 베인을 거쳐 선회류를 형성한 후흡수제와 혼합되어 하부로 배출되는 구조이다. 유동 특성을 분석한 결과, 처리가스가 반응기 중앙으로 강하게 편중되고 있었으며 반응기 양 측면으로 부상 기류가 형성되고 있음을 확인할 수 있다. 또한 강한 편류에 의해 체류시간도 매우 짧은 것으로 판단되는 바, 가이드 베인의 기류 안내 각도가 적합하지 못함을 확인할 수 있었다. 이는 곧 혼합 특성 저하에 따른 미반응 액적의 다량 발생과 함께 고착에 의한 스케일 형성 가능성이 매우 클 것으로 예상되므로 혼합 특성을 개선할 수 있는 설계 변경이 필요할 것으로 판단되었다. 따라서 편류를 해소하고 노즐 근처에서의 체공시간을 확보할 수 있도록 가이드 베인의 안내 각도를 더 크게 변경한 결과, 기존 설계상에서 본체 중앙에 형성되는 편류가 해소되고 선회류의 전개 각도가 커지면서 체류시간 역시 약 5초 이상으로 유지되고 있음을 확인할 수 있었다. 따라서 가이드 베인의 각도만 변경하더라도 본체 형상의 추가적인 변경없이 유동의 혼합 특성을 개선시킬 수 있을 것으로 판단되었다.

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Studies on Mixed Micellizations of Sodium Dodecanoate and Sodium Octanoate by Means of Electric Conductivity and Light Scattering (전기 전도도 및 광산란법에 의한 나트륨 도데카노에이트와 나트륨 옥타노에이트의 혼합미셀화 연구)

  • Park, Il Hyun;Jang, Han Woong;Baek, Seung Hwan
    • Journal of the Korean Chemical Society
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    • v.59 no.4
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    • pp.271-279
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    • 2015
  • The critical micelle concentration (CMC), the counter ion binding constant (B) and the aggregation number (N* ) for the mixed micellization of sodium dodecanoate and sodium n-octanoate as two anionic surfactants have been investigated by means of electric conductivity and light scattering. As its experimental results are found to be deviated from ideal mixed model, thus two different kinds of regular solution models such as Rubingh and Motomura are used for interpreting our experimental data. The stability of the mixed micelles has been confirmed from the negative values of the standard Gibbs energy of mixed micellization ΔGmicel,0 over all compositions and the measured values of ΔGmicel,0 agreed with the theoretical ones within the experimental error.