• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.12 no.11
• /
• pp.1004-1011
• /
• 2000

Experimental and computational studies were carried out to confirm the turbulent enhancement of the cooling system of nuclear reactor by large scale vortex generation in nuclear fuel bundle. The large scale vortex motions were generated by rearranging the inclination angles of mixing vanes to the coordinate directions. Axial development of mean and turbulent velocities in the subchannels were measured by the 2-color LDV system. Eddy diffusivity heat flux model and $k-varepsilon$ model were employed to analyze the turbulent heat and fluid flows in the subchannel. The turbulence generated by split mixing vanes has small length scales so that they maintain only about $10 D_H$ after the spacer grid. On the other hand, the turbulences generated by the large scale vortex continue more and remain up to $25 D_H$after the spacer gird.

• Journal of the korean Society of Automotive Engineers
• /
• v.5 no.4
• /
• pp.17-22
• /
• 1983

금속재료의 성질은 상(phase)의 혼합된, 즉 금속학적인 지식으로 이해할 수 있는 부분과 상을 구성하고 있는 원자의 결합상태 혹은 전자의 존재상태를 생각하지 않으면 안되는 부분이 있다. 예를 들면 철과 동을 비교할 경우 동의 경우가 전기전도성이 좋은 이유라든가 대기중에 방치한 경우의 내식성이 좋은 이유, 또는 철이 강자성을 나타내는 이유 등 어느 것도 금속중의 전자의 거동에 의해서 설명하지 않으면 안된다. 그리고 원자로에 사용되는 재료로써 문제시되는 중 성자의 흡취능과 같은 것은 원자핵의 구조를 이해하는 입장에서 고찰하지 않으면 안된다. 이들의 분야는 어느 것이든 금속물리학의 중요한 분야이지만 여기에서는 취급하지 않고 다만 금속학적인 지식도 재료의 물리적, 화학적 성질을 이해하는 데에 있어서 중요하다는 것을 예를 들어 기술 하는 데에 그쳤다.

• Journal of the Korean Chemical Society
• /
• v.38 no.12
• /
• pp.873-879
• /
• 1994

A series of samples of solid solutions in the $Sr_xEu_{1-x}FeO_{3-y}(0.00{\leq}x{\leq}1.00)$ system has been prepared at $1200^{\circ}C$ under an atmospheric air pressure. The structures of solid solutions are studied by X-ray diffraction, thermal, Mohr salt, and Mossbauer spectroscopic analyses. Their physical properties are also discussed with the electrical conductivities. X-ray diffraction data for the compositions of x = 0.00, 0.25, and 1.00 are assigned to the orthorhombic and the compositions of x = 0.50 and 0.75 to the cubic systems. The lattice volume reduced to cubic cell increases with the x value. The mole ratio of $Fe^{4+}$ iometric chemical formulas of the system are formulated from the x, $\tau$, and y values. The mixed valency state of Fe ions, the oxygen coordination, and covalent bond character are discussed with the Mossbauer spectroscopic data. The activation enegy of the electrical conductivities depends on the $\tau$ value in the temperature range of -$100^{\circ}C$ to $600\circC$ under the air pressure. The Mossbauer spectrum and electrical conductivity of the solid solutions are discussed with nonstoichiometric chemical compositions.

• Journal of the Korean Chemical Society
• /
• v.32 no.1
• /
• pp.3-8
• /
• 1988

Nonstoichiometric solid solutions of the $Sr_{1+x}Dy_{1-x}FeO_{4-y}$ system (x = 0. 00, 0. 25, 0. 50, 0. 75 and 1. 00) with layered $K-2NiF_4$ type structure were prepared at 1200$^{\circ}$C under atmospheric pressure. X-ray powder diffraction spectra show that the crystallographic phases of the samples are tetragonal within the x range. Nonstoichiometric chemical formulas have been determined by Mohr salt analysis and it shows that the amount of $Fe^{4+}$ ion or ${\tau}$ value increases with increasing x. Electrical conductivities of the samples which were measured in the temperature range of $-100{\sim}200^{\circ}$C under atmospheric air pressure are varied within the semiconductivity range of $l0^{-8}{\sim}10^{-2}(ohm^{-1}{\cdot}cm^{-1}$) and the activation energies are also varied from 0.02 to 0.08 eV. Mixed valency state of $Fe^{3+}$ and $Fe^{4+}$ in the sample of $Sr_{1.00}Dy_{1.00}FeO_{4.04}$ was identified again by Mossbauer spectrum at 200K.

• Journal of the Korean Chemical Society
• /
• v.20 no.5
• /
• pp.333-339
• /
• 1976

The rates of solvolysis for 2-thenoyl chloride have been measured in aqueous acetone and aqueous ethanol at various temperatures ranging from 20 to $40^{circ}C$. The activation parameters and the Grundwald-Winstein's slope are determined by the analysis of solvolysis rates. The results indicated that the reaction rates of solvolysis are considerably slower than those of the reaction for benzoyl chloride due to the electron donating effect of thiophene nucleus. The results also showed that the reaction proceeds with the $S_N1$ mechanism in water-rich solvents whereas the $S_N2$ character increases with the decrease of water content, and overall reaction is subject to entropy control.

• Applied Chemistry for Engineering
• /
• v.8 no.4
• /
• pp.582-588
• /
• 1997

Synthetic reaction of TAME, ETBE, and MTBE compounds used largely for gasoline octane number enhancer to prevent air pollution was investigated using heteropolyacid catalyst in a fixed bed flow reactor. In the synthetic reaction of TAME, ETBE and MTBE, after hetero atom being replaced with poly atom, the activity of the catalyst, $H_4SiW_{12}O_{40}$ with coordinated bond with W and an hetero atom of Si was the highest among the catalysts tested. Also the activity depended upon the metals replaced which are related to the catalyst acidity. $FeHPW_{12}O_{40}$ and $K_3PM_{o12}O_{40}$ catalysts showed high activity in TAME synthesis, while they were not effective in ETBE and MTBE synthesis. In this study catalysts showing high activity were selected and mixed with equal weight combination of $H_4SiW_{12}O_{40}$ and $Sr_2SiW_{12}O_{40}$ ;$H_4SiW_{12}O_{40}$ and $NaH_2PW_{12}O_{40}$ ; $Fe_{1.5}PW_{12}O_{40}$ and $Mg_2SiW_{12}O_{40}$ ; $Mg_2SiW_{12}O_{40}$ and $Ba_2SiW_{12}O_{40}$. The mixed heteropolyacid catalysts showed higher TBA conversion rate and better selectivity of ETBE and MTBE than the single catalysts.

• Proceedings of the Korean Nuclear Society Conference
• /
• 1996.05b
• /
• pp.556-561
• /
• 1996

주증기관 파단사고가 발생하여 서로 다른 온도 및 유속을 갖는 냉각재가 원자로 용기에 유입 될 때 downcomer 및 lower plenum 에서의 혼합현상을 3차원 열수력 분석코드 COMMIX-lB［1］로 모사하여 노심입구에서의 온도분포를 결정하고, 결정된 온도분포를 이용하여 주증기관 파단사고에 대한 열적여유도를 분석하였다. 분석은 주증기관 파단사고시 노심입구온도의 비대칭성이 가장 큰 고리 1호기를 선택하여 수행되었으며, 15주기 교체노심 설계 결과와 비교하여 열적 여유도가 다소 증가함을 확인하였다.

• The Bulletin of The Korean Astronomical Society
• /
• v.32 no.1
• /
• pp.41.2-41.2
• /
• 2007

• The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
• /
• v.7 no.2
• /
• pp.31-35
• /
• 1993

The radial density distributions of the positive column of strongly modulated low -pressure gas discharges in mercury - rare gas mixtures at 10 tom pressure have been studied theoretically. The current was modulated inusoidally with a modulation depth of 50%. Calculations have shown that the radial profile of the excited atoms is ditferent form 0th Bessel function $J_0$(2.4r/R) and the invertion of the radial distribution of the excited atom can occur at some frequency. The hybrid method of FDM and 2nd order Runge-Kutta meth od is used for solving differenzial equations.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
• /
• v.19 no.2
• /
• pp.23-27
• /
• 2005

A fluorescent lamp which uses low pressure mercury-argon gas discharge shows the maximum current and minimum lamp voltage near 1(kHz) source frequency at constant power. For explain these phenomena theoretically, in this paper a atomic level discharge model was made and particle density and electron temperature variation were calculated using numerical method.