• Title/Summary/Keyword: 혼합열

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염화탄화수소의 화재 및 폭발 위험성 평가

  • 하동명;이수경
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2002.05a
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    • pp.433-438
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    • 2002
  • 화재 및 폭발 특성치로 인화점, 최소발화온도, 폭발한계, 최소발화에너지, 연소열 등을 들 수 있다 이 가운데 폭발한계(explosive limits)는 가연성물질(가스 및 증기)을 다루는 공정 설계 시 고려해야 할 중요한 변수로써, 발화원이 존재할 때 가연성가스와 공기가 혼합하여 일정 농도범위 내에서만 연소가 이루어지는 혼합범위를 말한다/sup 1)/. 특히 폭발범위는 온도, 압력, 불활성가스의 농도, 화임전과 방향, 용기의 크기, 무리리적 상태 등에 의해 변한다/sup 2)/.(중략)

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On A Hybrid Binary Sequence Generator (혼합형 이진 수열 발생기)

  • 이훈재
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.7 no.4
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    • pp.81-90
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    • 1997
  • 키 수열 발생기는 함수 조합 형태에 따라 여러 가지로 분류될 수 있으며, 비도 기본 요소(랜덤 특성, 주기, 선형 복잡도, 상관 면역도, 키 수열의 수 등)는 비선형 함수에 따라 달라진다. 모든 기본 요소를 잘 만족하는 키 수열 발생기는 설계가 어렵지만, 각 요소별로 특성이 뛰어난 발생기를 잘 조합하면 고비도 시스템을 설계할 수 있다. 본 논문에서는 선형 복잡도와 상관 면역도 측면에서 강한 개선된 합산 수열 발생기와 키 수열 수사 많은 일반화된 메모리 다수열 발생기를 조합하여 혼합형 수열 발생기를 제안하고, 비도 수준을 분석하였다.

Effect of Reaction Temperature Program on Thermal Degradation of Low-quality Pyrolytic Oil for Bench-scale Continuous Reaction System (벤치 규모 연속반응시스템에서 저급 열분해유 분해반응에 대한 반응온도 프로그램의 영향)

  • Lee, Kyong-Hwan;Nam, Ki-Yun
    • Clean Technology
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    • v.15 no.3
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    • pp.186-193
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    • 2009
  • The characteristics of product materials obtained from thermal degradation of low-qualify pyrolytic oil were investigated in this study. The reactants were produced by pyrolysis of mixed plastic waste with film type in a commercial rotary kiln reaction system. The properties of reactants were measured by elemental analysis, calorimetry analysis and SIMDIST analyst. The result of degradation experiments with different reaction temperature programs was discussed through product yields, cumulative yields and production rates of oil products. The multi-step reaction temperature program resulted in higher yields of product oils and lower yields of residues than one-step reaction temperature program. The product characteristics such as production yield and the rate of oil products etc. were influenced by reaction temperature program in the continuous thermal degradation.

Cure Kinetics, Thermal Stabilities and Rheological Properties of Epoxy/phenol Resin Blend System Initiated by Cationic Thermal Latent Catalyst (양이온 열잠재성 개시제에 의한 에폭시/페놀 수지 브랜드 시스템의 경화 동력학.열안정성 및 유변학적 특성)

  • 박수진;서민강;이재락
    • The Korean Journal of Rheology
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    • v.11 no.2
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    • pp.135-142
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    • 1999
  • The effects of 1 wt.% N-benzylpyrazinium hexafluoroantimonate (BPH) as a thermal latent initiator and blend compositions composed of 0, 5, 10, 20 and 40 wt.% of phenol-novolac resin to epoxy resin were investigated in terms of cure kinetics, thermal stabilities and rheological properties. Thermal latent properties of BPH were measured from the conversion as a function of reaction temperature on a dynamic DSC. This cationic BPH system turned out to be an effective thermal latent initiator in the epoxy-phenol curing system. And the increase of phenol-novolac resin concentration led to the decrease in the latent temperature and to the increase of cure activation energy ($E_a$) of the blend system. The thermal stability and activation energy ($E_t$) for decomposition, gel-time and activation energy ($E_c$) for cross-linking from rheometer increased within the composition range of 20~40 wt.% of phenol-novolac resin. This implies that the three-dimensional cross-linking may take place among hydroxyl group within phenol resin, epoxide ring within epoxy resin and BPH.

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A Study of Mixed Convection on a Flat Plate with an Unheated Starting Length (비가열부가 있는 평판에서의 혼합대류에 관한 연구)

  • 김민수;강영규;백병준;박복춘
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.5
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    • pp.1304-1312
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    • 1993
  • The buoyancy effects on mixed convection heat transfer over a flat plate surface with unheated starting length is reported. The governing equations are solved by a finite difference method using Patankar scheme and the solution was numerically obtained for various mixed convection parametr $Gr_{x}/Re_{x}^3$, and Prandtl number of 0.7 Local heat flux was measured by using Schilieren Interferometer. The local heat transfer results show that the presence of the unheated starting length can significantly accentuate the effects of buoyancy. The degree of accentuation of the buoyancy effects is strongly influenced by the magnitude of $Gr_{x}/Re_{x}^3$. When the parameter is larger than the order of $10^{-3}$, the contribution of natural convection to the heat transfer coefficients increased significantly due to the unheated starting length. In contrast, when $Gr_{x}/Re_{x}^3$ is smaller then about $10^{-5}$ , the buoyancy contribution is essentially unaffected by the unheated starting length. The shape of the velocity profile is also found to be highly responsive to the interaction between the buoyancy and the starting length.

Evaluation of Combustion Mechanism of Droplet Cluster in Premixed Spray Flame by Simultaneous Time-Series Measurement (동시 시계열 계측에 의한 예혼합 분무화염 내 유적군 연소기구의 평가)

  • Hwang, Seung-Min
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.6
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    • pp.442-448
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    • 2009
  • To evaluate the combustion mechanism of each droplet cluster downstream of the premixed spray flame, the simultaneous time-series measurements were conducted by using optical measurement system consisting of laser tomography, multi-color integrated Cassegrain receiving optics (MICRO) and phase Doppler anemometer (PDA). Furthermore, the group combustion number of droplet cluster was estimated experimentally, and the combustion mechanism of droplet cluster was examined applying the theoretical analysis. The group combustion number, $G_c$, was experimentally estimated about all droplet cluster verified by planar images, and it was classified into the internal group combustion mode and the external group combustion mode according to the theoretical analysis. It is found that there are cases in which the group combustion number estimated experimentally for droplet cluster agree or disagree with the classification by theoretical analysis. The reason of disagreement is considered due to that the group combustion number was only estimated by the geometrical arrangement of droplets in cluster, and that the actual phenomenon is three-dimensional but the measurement system is two-dimensional.

Combustion Characteristics of Fire Retardants Treated Wood (I) (난연처리 목재의 연소특성 분석(I))

  • Son, Dong Won;Kang, Mee Ran
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.1
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    • pp.96-103
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    • 2015
  • The aim of this paper is to analyze combustion characteristics of treated woods by fire retardants which are prepared by several borate and phosphate compound solutions. The combustion characteristics for flame retardant treated wood were carried out using thermogravimetric analysis (TGA) to measure their combustion heat and flame retardant test using cone-calorimeter. The result of TGA and flame retardant test showed that single chemical solution affected the char forming and flame delay. The mixed retardants solutions was believed to be related to the efficacy and property of single chemical. The retention value and concentration of the retardants also affected the performance of fire retardant treated woods. The fire retardants FR1 and FR2 satisfied the requirement of The 3 Grade of Korean building codes.

Characterization of Thermal Properties for Glass Beads - Rubber Mixture (글라스 비즈 - 고무 분말 혼합물의 열전달 특성 연구)

  • Lee, Jung-Hwoon;Yun, Tae-Sup;Evans, T. Matthew
    • Journal of the Korean Geotechnical Society
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    • v.27 no.11
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    • pp.39-45
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    • 2011
  • This study presents the thermal behaviors of glass beads-rubber mixtures depending on the volumetric fraction of each constituent and relative size between them. The transient plane source method is used to measure the effective thermal conductivity of mixtures. The discrete element method (DEM) and the thermal network model are integrated to investigate the particle-scale mechanism of heat transfer in granular packings. Results show that 1) the effective thermal conductivity decreases as the rubber fraction increases, and 2) the relative size between two solid particles dominates the spatial configuration of inter-particle contact condition that in tum determines the majority of heat propagation path through particle contacts. For the mixtures whose volumetric fraction of rubber is identical, the less conductive materials (e.g., rubber particles) with a large size facilitate heat transfer in granular materials. The experimental results and particle-scale observation highlight that the thermal conduction behavior is dominated not only by the volumetric fraction but also the spatial configuration of each constituent.

Analysis of pollutant mixing on the water surface in rivers with GPS floaters (GPS부자를 이용한 하천 표면에서의 오염물질 혼합 거동 해석)

  • Seo, Il Won;Park, Inhwan;Kim, Young Do;Han, Eun Jin
    • Proceedings of the Korea Water Resources Association Conference
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    • 2015.05a
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    • pp.103-103
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    • 2015
  • 유류유출사고와 같이 하천 수표면의 흐름에 따라 이동 확산하는 부유성 오염물질의 혼합해석을 위해 많은 연구자들은 입자추적모형을 사용한 혼합모의를 수행해왔다. 입자추적모형에서 오염물질의 혼합은 평균 유속 분포에 의한 결정론적인 이동과 난류유동에 의한 무작위적인 혼합으로 나타내며, 난류혼합에 의한 수평확산은 난류확산계수로 조절한다. 따라서 표면흐름에 의한 난류확산계수의 산정을 위해 많은 연구자들은 부유성 입자를 이용한 실내실험을 수행하여 수평확산계수를 산정했고(Engelund, 1969; Cederwall, 1971), 최근에는 GPS의 발전으로 인해 해양영역에서 GPS를 장착한 표면부자를 활용한 확산실험을 통해 수평확산계수를 산정한 바 있다(Kjellson and $D{\ddot{o}}{\ddot{o}}s$, 2012; Alpers 등, 2013). 하천수질오염사고의 약 43.5%가 유류유출에 의한 것이며(환경부, 2013), 이에 따라 표면흐름에 의한 오염물질 혼합해석이 필요하나, 하천에서 수평확산계수 산정을 위한 현장실험연구는 부족한 상황이다. 따라서 본 연구에서는 낙동강 본류에서 GPS부자를 이용한 입자추적실험을 수행하여 표면흐름에 의한 확산계수를 산정했다. GPS부자를 이용한 입자추적실험은 낙동강의 강정고령보 하류와 구미보 하류의 각각 세 지점에서 수행되었다. GPS부자는 바람에 의한 교란을 최소화하기 위해 지름 10 cm의 구형으로 제작하였으며 시범테스트를 통해 입자의 주 궤적 변화가 크지 않은 지점에 GPS부자를 투입했다. GPS부자는 오염물질의 사고유출을 가정하여 한 지점에 투입했고 GPS부자 사이의 간섭을 최소화하기 위해 25 ~ 35개의 GPS부자를 이용했다. 표면흐름에 의해 이동하는 부자의 위치는 GPS에 시계열로 저장됐고 ADCP를 이용하여 실험당시의 수리량을 측정했다. 입자위치의 시계열자료로부터 GPS부자의 확산범위의 시간변화를 계산했고 단순 모멘트법을 이용하여 종, 횡 방향 확산계수를 계산했다. 그 결과, 종 방향 확산계수는 $0.003{\sim}0.041m^2/s$로 계산되었고 횡 방향 확산 계수는 $0.001{\sim}0.012m^2/s$로 계산되어, 흐름방향의 유속성분에 의한 확산이 지배적인 것으로 나타났다. 지류 합류부에서는 이송이 지배적인 혼합이 발생되었고(Pe>1) Pe의 증가에 따라 수평확산계수가 감소되었다. 25~35개 GPS부자 궤적의 앙상블 평균으로부터 계산한 Integral time scale은 모멘트법으로부터 계산한 종, 횡 방향 확산계수와 비례하는 것으로 나타나, Taylor(1921)의 이론과 일치했다. 또한 실험수로에서 수행된 기존연구결과와 비교한 결과, 하폭 대 수심비, 마찰항의 증가에 따라 수평확산계수가 증가하는 경향을 나타내었다.

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Study on Hydration Heat of Blended Belite Binder (벨라이트계 혼합 결합재의 수화열 특성에 관한 연구)

  • Lee, Kewn-Chu;Cho, Jae-Woo;Jung, Sang-Hwa;Kim, Jang-Ho Jay
    • Journal of the Korea Concrete Institute
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    • v.23 no.2
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    • pp.145-150
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    • 2011
  • Presently, mass concrete structures are being built in federal and private projects of civil infrastructures and building structures. The hydration heat of mass concrete structures is the most important factor in the quality of concrete matrix and construction period. Moreover, internal cracks caused by hydration heat degrades durability, water tightness, and strength of concrete. To reduce hydration heat, it is necessary to blend belite cement (${\beta}-C_2S$) with industrial by-products (i.e. granulated slag and fly ash). In this experiment, 14 levels of binary binders and 4 levels of ternary binders were used to understand the effect of different replacement ratio on hydration heat, strength and microstructure (i.e. SEM and XRD) of mortar. Cumulative hydration heat at 28 days for the binary and ternary binders was affected by replacement ratio of fly ash and/or granulated slag. As fly ash content increased, hydration heat decreased. As granulated slag content increased, reduction rate of the hydration heat was lower than when fly ash was used. Especially, the hydration heat of ternary binder blended with 40% flyash and 30% granulated slag showed about 50% of hydration heat from using belite cement (P). The study results showed that the temperature rise of concrete matrix can be decreased by using blended belite binders producing low hydration heat and reasonable strength.