• Title/Summary/Keyword: 현장측정용 전기화학셀

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Degradation Degree Evaluation of Heat Resisting Steel by Electrochemical Technique (Part I : Mechanism and Its Possibility of Field Application) (電氣化學的 方法에 의한 耐熱鋼의 劣化度 測定 제1보)

  • 정희돈;권녕각
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.3
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    • pp.598-607
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    • 1992
  • The environment degradation of structural steel under high temperature is one of the key phenomena governing the availability and life of plant. This degradation resulted from the microstructural changes due to the long exposure at high temperature affect the mechanical properties such as creep strength and toughness. For instance, boiler tube materials usually tend to degrade, after long term operation, by precipitates, spherodizing, coarsening, and change in chemical composition of carbides. In this study, the material degradation under high temperature exposure was investigated by evaluating the carbide precipitation. The electrochemical polarization method was facilitated to investigate the precipitation and coarsening of carbides. It was shown by the modified electrochemical potentiokinetic reactivation (EPR) tests that the passivation of Mo-rich carbides did not occur even in the anodic peak current (Ip) which indicates the precipitation of Mo$_{6}$C was also observed. And it was assured that special electrolytic cell assembled in this research can be used for the detection of Mo$_{6}$C precipitation in the field.eld.