• Fire Science and Engineering
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• v.28 no.5
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• pp.1-7
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• 2014

The present study has been conducted to analyse the effects of various pool diameters on the measurement of heat release rate (HRR) of heptane fire using large scale cone calorimeter (LSC). The burning rate which is the major parameter for HRR compared with the previous model suggested by A. Hamins. The combustion efficiency for heptane by oxygen consumption method is about 91%, which is almost same with the previous results of 92% suggested by J. Gore. The convective HRR by enthalpy consumption method was 54% lower than HRR by oxygen consumption method. This results are practical use for establishing the reliability of heat release rate for fire experiment.

• Fire Science and Engineering
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• v.31 no.4
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• pp.43-51
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• 2017

In this study, new design fire curves were suggested for the utilization in fire simulations. Numerical simulations with the Fire Dynamics Simulator (FDS) were performed for the n-octane and n-heptane pool fires in the ISO 9705 compartment to evaluate the prediction performance of the previous quadratic, exponential design fire curves and newly suggested ones. The numerical results were compared with the experimental temperature and concentrations of $O_2$ and $CO_2$. The numerical results with the previous quadratic and exponential curves showed slow increase and decrease trend than experiments. However, the numerical results with the newly suggested 2 design fire curves showed more similar variation trend in temperature, $O_2$ and $CO_2$ concentrations than the quadratic and exponential curves. It was found that the newly suggested design fire curves can be possibly used in the numerical simulation of fires in a practical respect.

• Elastomers and Composites
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• v.39 no.4
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• pp.318-323
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• 2004

Cloud-point and bubble-point curves for poly(ethylene-co-13.8 mol% octene) ($PEO_{13.8}$) and Poly(ethylene-co-15.3 mol% octene) ($PEO_{15.3}$) were determined up to $150^{\circ}C$ and 450 bar in hydrocarbons which have different molecular size and structure. Whereas ($PEO_{15.3}$+ n-pentane) system has cloud-point and bubble-point type transitions, ($PEO_{15.3}$+ n-propane) and ($PEO_{15.3}$+ n-butane) systems do only cloud-point type transition. In cyclo-pentane, -hexane, -heptane, and -octane, $PEO_{15.3}$ has a bubble-point transition. ($PEO_{13.8}$+ n-butane) mixture has a critical mixture concentration at 5 wt% PEO. (PEO + hydrocarbon) mixtures exhibit LCST type behavior. Solubility of PEO increases with hydrocarbon size due to increasing dispersion interaction which is favorable to dissolve PEO.

• Fire Science and Engineering
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• v.26 no.2
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• pp.75-83
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• 2012

An experimental study was conducted to investigate the effects of change in heat release rate on unsteady fire characteristics of under-ventilated fire in a semi-closed compartment. A standard doorway width of the full-scale ISO 9705 room was modified to 0.1 m and the flow rate of heptane fuel was increased linearly with time using a spray nozzle located at the center of enclosure. Temperature, heat flux, species concentrations and heat release rate were continuously measured and then global equivalence ratio (GER) concept was adopted to represent the unsteady thermal and chemical characteristics inside the compartment. It was observed that there was a significant difference in unsteady behavior between global and local combustion efficiency, and the GERs predicted by ideal and measured heat release rate were also shown different results in time. The unsteady behaviors of temperature, heat flux and species concentrations were represented well using the GER concept. It was important to note that CO concentration was gradually decreased with the increase in GER after reaching its maximum value in the range of 2.0~3.0 of global equivalence ratio. In addition, the experimental data on unsteady thermal and chemical behaviors obtained in a semi-closed compartment will be usefully used to validate a realistic fire simulation.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.12
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• pp.1193-1199
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• 2012

A cup burner experiment was performed to investigate the effect of the oxidizer velocity and concentration on flame instability near extinction. Heptane was used as a fuel and air diluted by nitrogen and carbon dioxide was used in the oxidizer stream. Two types of flame instabilities at the flame base and at axial downstream were observed near extinction. The instability at the flame base could be characterized by cell, swing, and rotation modes, and the cell mode changed to the rotation mode through the swing mode as the oxidizer velocity increased. To assess the parameters for the flame instability, the initial mixture strengths, Lewis number, and adiabatic flame temperature were investigated under each condition. The Lewis number might be the most important among them, but it is impossible to generalize because of the insufficient number of cases. Furthermore, the axial periodic flickering motion disappeared at low and high oxidizer velocities near extinction. This resulted from the fact that low oxidizer velocity induced evaporated fuel velocity below the critical velocity and high velocity made the reacting fuel velocity comparable.

• Fire Science and Engineering
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• v.33 no.5
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• pp.28-36
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• 2019

In the present study, the effects of supply gas and water mist on the heptane pool fire extinguishing performance were investigated using the full cone and hollow cone twin-fluid atomizers. Air or nitrogen of 30 lpm (Liter per minute; L/min) was used as the supply gas, and the experiments were conducted under the water flow rate conditions of 0 lpm (i.e., discharge of air or nitrogen only) and 0.085 lpm (i.e., discharge of water mist with supply gas). Experimental results confirmed that the use of water mist discharge with the supply gas and full cone spray pattern reduced the fire extinguishing time as compared to that of only supply gas discharge and hollow cone spray pattern. In addition, for the discharge of water mist using the full cone twin-fluid atomizer, water mist significantly affected fire extinguishing performance, whereas the effect of the supply gas was less pronounced. On the other hand, for the discharge of water mist using the hollow cone twin-fluid atomizer, the fire extinguishing time was remarkably reduced by the supply of nitrogen, as compared with that of air, indicating that the supply gas as well as water mist can significantly affect fire extinguishing performance.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.10
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• pp.933-940
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• 2009

To evaluate characteristics in spray flame, laminar counterflow is investigated on the effects of equivalence ratio and fuel by a two-dimensional DNS (direct numerical simulation). For the gaseous phase, Eulerian mass, momentum, energy, and species conservation equations are solved. For the disperse phase, all individual droplets are calculated by the Lagrangian method without the parcel model. n-Decane ($C_{10}H_{22}$) and n-heptane ($C_7H_{16}$) is used as a liquid spray fuel, and a one-step global reaction is employed for the combustion reaction model. As equivalence ratio increases, the fuel ignites early and the high temperature region spreads wider. The peak value of temperature, however, tends to once increase and then decreases with increasing equivalence ratio. The decrease in the peak value of temperature for the higher equivalence ratio condition is caused by the cooling effect associated with droplet group combustion. Since the evaporation of n-heptane is early, the high temperature region spreads wider than ndecane, but the peak values of temperature for both n-heptane and n-decane is almost same.

• Analytical Science and Technology
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• v.18 no.6
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• pp.511-519
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• 2005

A method for determination of toluene diisocyanates (TDI) in toluene diisocynate (TDI)-based polyurethane (PUR) packing material was investigated, and also the migration of TDI to food was studied. TDI was extracted using food simulants such as n-haptane and 4% aqueous acetic acid. The determinations were performed using gas chromatography/mass spectrometry (GC/MS). One of major components for polyurethane, toluene diisocyanates, were detected in ten samples among twenty six food contact materials with the concentration range of $0.51{\sim}60.88{\mu}g/ml$. However the highest extracted amount was just 0.7% of $60.88{\mu}g/ml$ if the contact surface of food packing for extracting liquid was limited to the outer layer without exposure of the cutting edge of food packing multi-layers. The result of this study and the analysis method for TDI diisocyanate will be very useful for further study about food contact material, and the monitoring result could be used for evaluating the safety of food contact material before it is to be used for food, preservation.

• Polymer(Korea)
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• v.31 no.2
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• pp.98-104
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• 2007

The expansion behavior of polystyrene (PS) chains with various molecular weights has been investigated above Flory $\Theta$temperature by viscometry after dissolving in the three different mixed solvents systems such as benzene/n-heptane, 1,4-dioxane/isopropanol, and 1,4-dioxane/n-heptane. Two different regimes are observed as increasing temperature: one regime is for the expansion of chain and the other is for the contraction. For the higher molecular weight sample of PS, the higher peak temperature showing its maximum expansion is obtained. Within a certain system of Ps/mixed solvents, the $\tau/\tau_c$ parameter shows universality for the variation of molecular weight. But while each system of Ps/mixed solvents has shown its own different slope, the universality breaks down in the overall system of mixed solvents. However after introducing a new empirical $b^{2/3}\tau/\tau_c$ parameter, all data points of three different systems have dropt on one master curve and the universality of chain expansion has recovered again. Here $\tau$ and $\tau_c$ are defined as $(T-\Theta)/\Theta$ and $(\Theta-T_c)/T_c$, respectively and $T_c$ is the critical solution temperature, and b of Schultz-Flory equation is corresponding to the effective slope in the plot of $1/T_c$ against $1/M_w^{1/2}$.

• Fire Science and Engineering
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• v.32 no.3
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• pp.42-50
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• 2018

The effect of sub-grid turbulence and combustion models on the mean flame height in a heptane pool fire according to the Fire Dynamics Simulator (FDS) version (5 and 6) based on Large Eddy Simulation (LES) was examined. The heat release rate for the fire simulation was provided through experiments performed under identical conditions and the predictive performance of the mean flame height according to FDS version was evaluated by a comparison with the existing correlation. As a result, the Smagorinsky and Deardorff turbulence models applied to FDS 5 and 6, respectively, had no significant effects on the mean flow field, flame shape and flame height. On the other hand, the difference in pool fire characteristics including the mean flame height was due mainly to the difference in the mixture fraction and Eddy Dissipation Concept (EDC) combustion models applied to FDS 5 and 6, respectively. Finally, compared to FDS 6, FDS 5 provided the predictive result of a significantly longer flame height and more consistent mean flame height than the existing correlation.