• Journal of the Korean Society of Marine Environment & Safety
• /
• v.18 no.1
• /
• pp.55-60
• /
• 2012

In order to investigate the effect of n-heptane mixing on PAH and soot formation, small amount of n-heptane has been mixed in counterflow ethylene diffusion flame. Laser-induced incandescene and laser-induced fluorescene techniques were employed to measure soot volume fraction and polycyclic aromatic hydrocarbon(PAH) concentration, respectively. Results showed that the mixing of n-heptane in ethylene diffusion flame produces more PAHs and soot than those of pure ethylene flame. However, signals of LIF for 20% n-heptane mixture flame were lower than that of pure ethylene flame. It can be considered that the enhancement of PAH and soot formation by the n-heptane mixing of ethylene can be explained by methyl($CH_3$) radical in the low temperature region. And it can be found that reaction rate of H radical for 10% n-heptane plays a crucial role for benzene formation.

• Clean Technology
• /
• v.21 no.4
• /
• pp.217-223
• /
• 2015

In the present study, modelling and optimization of ethanol-n-heptane separation process were performed using pressure-swing distillation. The pressure-swing distillation process optimization was performed to obtain high purity ethanol and high purity n-heptane into a low-high pressure columns configuration and a high-low pressure columns configuration. The results of pressure-swing distillation process simulation and optimization using high-low pressure column configuration showed a reduced total reboiler heat duty at 5.8% which confirmed a more economical energy consumption.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.33 no.4
• /
• pp.71-78
• /
• 2005

The vaporization characteristics of a liquid heptane droplet in a supercritical nitrogen flow is numerically analyzed. The present model can account for real gas effects, liquid-phase internal circulation, variable thermodynamic properties and high-pressure effects. Time marching method with preconditioning scheme is employed to handle the low Mach number flows in dense heptane droplet region. Computations are made for the wide range of convective velocity and ambient pressure. Numerical results indicate that the droplet deformation becomes stronger by increasing the Reynolds number and it becomes relatively weak by increasing the pressure.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
• /
• 2004.11a
• /
• pp.19-24
• /
• 2004

• Journal of the Korean Chemical Society
• /
• v.34 no.4
• /
• pp.384-386
• /
• 1990

• 한국연소학회:학술대회논문집
• /
• 2015.12a
• /
• pp.153-156
• /
• 2015

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
• /
• 2013.04a
• /
• pp.171-172
• /
• 2013

본 연구에서는 국내 화재시험기관에 3개소에 설치되어 있는 룸코너 시험기에 대하여 시험소간 비교시험을 수행하고 결과를 정리하였다. 비교시험에 사용된 표준시료의 제작 절차, 비교시험 수행 방법 및 각 평가결과에 대하여 소개하고자 한다.

• Journal of Korean Tunnelling and Underground Space Association
• /
• v.7 no.2
• /
• pp.109-117
• /
• 2005

In this study, the 1/20 reduced-scale experiments using Froude scaling were conducted to investigate the ventilation velocity of the variation of burning rate in tunnel fires. The heptane square pool fire with heat release rate ranging from 3.71~15.6 kW were used. The burning rate of fuel was obtained by measuring mass using load cell and temperature distributions were measured by K-type theomocouples in order to investigate smoke movement. The ventilation velocity in the tested tunnel was controlled by inverter of the wind tunnel. In heptane pool fire case, the increase in ventilation velocity incresed the burning rate due to the direct supply of oxygen to the fire plume. For the same dimensionless velocity($\bar{V}$), burning rate increased as the size of pool fire decreased.

• Fire Science and Engineering
• /
• v.24 no.5
• /
• pp.128-135
• /
• 2010

In this study, a mixture fraction analysis was performed to investigate the characteristics of chemical species production in compartment fires burning hydrocarbon fuels such as methane, heptane, and toluene. A series of fire experiments was conducted in the ISO 9705 standard room, and gas species concentration and soot fraction were measured at two locations in the upper layer of the compartment. The mass fractions of measured chemical species, such as unburned hydrocarbons (UHC), carbon monoxide (CO), carbon dioxide ($CO_2$), oxygen ($O_2$), and soot were presented as a function of mixture fraction and compared with state relationships based on the idealized reaction of hydrocarbon fuels. The mixture fraction analysis made it possible to rearrange hundreds of species measurements, which were done under various fire conditions and at two locations of the upper layer, in term of the unified parameter, i.e. the mixture fraction. The results also showed that inclusion of soot in the mixture fraction calculation could improve the performance of analysis, especially for the sooty fuels such as heptane and toluene.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.19 no.4
• /
• pp.64-71
• /
• 2011

Homogeneous charge compression ignition (HCCI) was the best concept able to provide low NOx and PM in diesel engine emissions. This new alternative combustion process was mainly controlled by chemical kinetics in comparison with the conventional combustion in internal combustion engine. In this paper, detailed kinetic reaction mechanisms of diesel surrogate was investigated to understand the diesel HCCI engine combustion. It was tested two existing mechanisms and two new mechanisms for the comparison of experimental result. The best mechanism for diesel surrogate was suggested through this comparison.