• Title/Summary/Keyword: 해양 오염

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Content characteristics of persistent organic pollutants waste from paint, iron making and steel making process (국내 도료 및 제철·제강산업 발생 폐기물 중 잔류성 유기오염물질류의 함량 특성 -PCDD/DFs, PAHs, PCBs-)

  • Kim, Dong-Un;Kim, Woo-Il;Kang, Young-Yeul;Lee, Dong-Jin;Jeong, Seong-Kyeong;Cho, Yoon-A;Yeon, Jin-Mo;Shin, Sun-Kyoung;Oh, Gil-Jong
    • Analytical Science and Technology
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    • v.24 no.5
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    • pp.395-400
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    • 2011
  • This study has been carried out in order to effectively manage three groups of unregulated hazardous organic substances (PCDD/DFs, PAHs, PCBs) in South Korea. The investigated substances have been analyzed according to the test methods for hazardous substances in specified wastes provided by the National Institute of Environmental Research, Korea. Total contents of the organic compounds have been determined for hazardous wastes from three major industrial categories (paint, iron removal, steelmaking), such as waste organic solvent, waste paint or dust. By investigating the waste samples for 7 PAHs using GC/MSD, Naphthalene has been detected (N.D~1631.33 mg/kg). The highest Naphthalene concentration, which exceeded the korean marine dumping waste standard, was found in waste organic solvents and waste paints. Although a content analysis of 7 PCB isomers has been conducted, none of these compounds was detected. The analysis of PCDD/DFs has revealed that all samples meet the criterion for low POP content defined in the technical guidelines developed under the Basel Convention. The PCDD/DFs content in dust samples deriving from 10 manufacturing processes (billet, bloom) was determined to be in the range of N.D~5.66 ng I-TEQ/g waste.

TRANSPORT AND DIFFUSION OF POLLUTANTS IN THE COASTAL WATERS OF ONSAN INDUSTRIAL COMPLEX (온산공단 부근의 해양오염물질 이동)

  • CHANG Sun-duck;LEE Jong-Sub;HAN Kyeong-Hwa
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.13 no.4
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    • pp.151-162
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    • 1980
  • To clarify the dispersion of pollutants introduced in the coastal region, a series of current measurements, the drogue and drift bottle experiments as well as the dye diffusion experiments were carried out in Onsan Bay and in the coastal waters of Ubong-ri near Ulsan. In the southeastern coastal region of Korean peninsula, that is, in the outside of Onsan Bay, the flood tidal current flows south-south-westward, and the ebb current flows north-north-eastward at a maximum speed of 1.0-1.1 knots at spring tide. In an inlet south of Cape Ubong, an anticyclonic eddy of 1 km in diameter is usually formed during both flood and ebb flows. The tidal current predominates in Onsan Bay at around spring tide. The maximum speed around spring tide was observed to be approximately 0.14 knot, while it was slower than 0.1 knot and variable at neap tide when the wind drift current played an important role. The flood tidal current flows westward while the ebb flow flows eastward in the northern region of the bay. The flood tidal current in the southern region of the bay flows west-north-westward, while the ebb current east-north-eastward. Wind drift currents in the coastal region of southern Korea are generally deduced to be southward in winter, the monthly mean speed being approximately 0.1 knot. Dye solution released at the northwestern corner in Onsan Bay was transported by eastward ebb tidal current toward the mouth of the bay dispersing by the wind. The apparent diffusion coefficient at 150 minutes after release in the bay was calculated to be $4.4\times10^4\;cm^2.sec^{-1}$, whereas that in the anticyclonic eddy was more or less smaller.

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Biodegradation of Bunker-C Oil by the Mixed Enrichment Culture of Marine Bacteria (혼합배양 해양세균에 의한 Bunker-C유의 생물분해)

  • PARK In-Sick;PARK Jung-Youn;SUH Kuen-Hack;HONG Yong-Ki
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.20 no.2
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    • pp.152-156
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    • 1987
  • A mixed population of marine bacteria was obtained to catalize the biodegradation of bunker-C fuel oil by means of the enrichment culture technique. Samples used for the enrichment culture were collected from sea water and sediments in the vicinity of Pusan, Chungmu, and Ulsan in Korea. As the biodegradation of bunker-C oil proceeded, the number of bacteria increased from $1.1\times10^6\;to\;8.7\times10^8$ cells per ml when pH was bufferized by 0.1 M Tris-HCl buffer to 7.6, then oil dispersion increased to $OD^{540}$ 2.2 and approximately $48\%$ of the oil was biodegradated in 10 days. Oil dispersion was absolutely dependent on the addition of nitrogen and phosphate sources in sea water. High and low sulfur-containing bunker-C and crude oil could be dispersed similarly. Bunker-C oil was dispersed rapidly at the pH ranging from 7.0 to 8.0 and dispersed to the amount of 7.5 g per liter of sea water medium.

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Algorithm Deciding Offshore Cable Layout Valid for Integrated Power Supply Between Adjacent Islands (근거리 도서간 통합전력공급에 유효한 해저케이블 포설 방안 결정 알고리즘)

  • Kim, Mi-Young;Rho, Dae-Seok;Moon, Guk-Hyun;Seo, In-Yong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.2
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    • pp.28-36
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    • 2018
  • Islands are supplied with power from diesel generation or from photovoltaic power generation, and problems with offshore environmental impacts (age deterioration, salt pollution), environmental pollution (exhaust gas, noise, dust) and power generation costs (installation, maintenance) have increasingly emerged. In 2016, the cost recovery rate was only 27%, and deficits reached 73% on 65 islands managed by KEPCO. In terms of deficits, the costs incurred in the power generation sector accounted for 91%, with the ratio of fixed costs at about 60%. Analysis suggests that operating costs can be reduced with an optimal power supply system that improves power generation efficiency and makes operating systems more efficient. Therefore, it is possible to simplify fuel transportation and facility maintenance, because one island integrates the power plants of remote islands, and offshore cable is used to supply power to the other islands. From the economic evaluations in this paper, an algorithm deciding offshore cable layout validity for an integrated power supply between adjacent islands is presented. Simulation results based on the proposed algorithm confirmed that an integrated power supply is economical for existing stand-alone operations on islands having diesel generation, low peak power, and near distances.

Livestock liquid fertilizer Utilization study of Zoysiagrass growing in the field (한국잔디 재배지에서 가축분뇨액비의 활용 연구)

  • Ham, Suon Kyu;Lim, JiYeon;Lee, YeongMin
    • Journal of the Korea Organic Resources Recycling Association
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    • v.22 no.4
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    • pp.11-20
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    • 2014
  • Recently, manure emissions associated with the numerical increment of the domestic hog-breeding have increased, but it has been banned from ocean dumping by the United Nations Convention in 2012. To find out the site for spraying in large quantity of liquid manure fertilizer, we selected one grass plantation, which has the largest amount of grass production, in Jangsung, South Korea. We spread not only chemical fertilizer but also liquid manure fertilizer on the zoysiagrass plantation and researched the effect on the grass growth and development, soil chemical property, and seepage water of dike. As the test results, spread by compounding chemical fertilizer and liquid manure fertilizer and it is possible to substitute for some chemical fertilizer in terms of nutrients accumulation and the grass growth and development. Additionally, it gives less effects to soil chemical property and is efficacious to effective microorganism growth of soil. Therefore, adding liquid manure fertilizer will lead to reduce almost all the amount of chemical fertilizer usage. It is also expected to help for livestock manure management and to influence reducing the production cost of the grass plantation. However, to spread liquid manure fertilizer contaminates water system. For this reason, monitoring continuously, we need to find out improvement plans of the fertilization method in order to increase the usage of liquid manure fertilizer.

Mineralogical Properties of Asian Dust Sampled at Deokjeok Island, Incheon, Korea in February 22, 2015 (2015년 2월 22일 인천광역시 덕적도에서 포집된 황사의 광물학적 특성)

  • Park, Mi Yeon;Jeong, Gi Young
    • Journal of the Mineralogical Society of Korea
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    • v.29 no.2
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    • pp.79-87
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    • 2016
  • Asian dust (Hwangsa) interacts with light, atmospheric gas, aerosol, and marine ecosystem, affecting Earth climate. Mineralogical properties are essential to understand the interaction between the dust and environments. In this study, we examined the mineralogical properties of Asian dust collected at Deokjeok Island, Incheon, Korea in February 22, 2015. X-ray diffraction (XRD) analyses showed that phyllosilicate minerals (62 wt%) dominate the Asian dust. Illite-smectite series clay minerals (55%) were common with minor chlorite (5%) and kaolinite (2%). Non-phyllosilicate minerals were quartz (18%), plagioclase (10%), K-feldspar (4%), calcite (4%), and gypsum (1%). Similar results were obtained by mineral quantification using scanning electron microscopy (SEM) and energy dispersive X-ray spectrometry (EDS). Transmission electron microscopy combined with EDS confirmed illite-smectite series clay minerals as the dominant phyllosilicate type. Morphological analyses using SEM showed clay agglomerates, clay-coated quartz, feldspars, and micas. Gypsum grains were common on the particle surface, while calcite nanofibers, previously reported as common on the surface, were rare, indicating the reaction of calcite and acidic atmospheric pollutants to form gypsum. The analytical result of 2015 Asian dust would contribute to the establishment of mineralogical base for the modeling of the interaction between Asian dust and environments.

A Biogeochemical Study on the Heavy Metal Leaching from Coal Fly Ash Disposed by Dangjin Fire Plant in the Coastal Environment (당진화력발전소의 석탄회 연안매립과 중금속 원소의 용출에 대한 생지화학적 연구)

  • Cho, Kyu-Seong;Roh, Yul;Chung, Duk-Ho
    • Journal of the Korean earth science society
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    • v.28 no.1
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    • pp.112-122
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    • 2007
  • It is known that coal-derived fly ashes have the unique chemical composition and mineralogical characteristics. Since iron oxides in coal fly ash are enriched with heavy metals, the subsurface media including soils, underground water, and sea water are highly likely contaminated with heavy metals when the heavy metals are leached from fly ashes by water-fly ash interactions. The purpose of this study was to investigate how indigenous bacteria affect heavy metal leaching and mineralogy in fly ash slurry during the fly ash-seawater interactions in the ash pond located in Dangjin seashore, Korea. The average pH of ash pond seawater was 8.97 in nature. Geochemical data showed that microbial activity sharply increased after the 7th day of the 60-day course batch experiments. Compared with other samples including autoclaved and natural samples, ${SO_4}^{2-}$ was likely to decrease considerably in the fly ash slurry samples when glucose was added to stimulate the microbial activity. Geochemical data including Eh/pH, alkalinity, and major and trace elements showed that the bacteria not only immobilize metals from the ash pond by facilitating the chemical reaction with Mn, Fe, and Zn but may also be able to play an important role in sequestration of carbon dioxide by carbonate mineral precipitation.

The Study on the Countermeasure Plans about Leakage, Explosion and Fire Accidents of Atmospheric Storage Tank (옥외저장탱크 누출, 폭발 및 화재사고 대응방안에 관한 고찰)

  • Lee, Gab-Kyoo
    • Fire Science and Engineering
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    • v.30 no.6
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    • pp.48-56
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    • 2016
  • A crude oil leakage from a large atmospheric storage tank occurred on 4 April 2014 at 14:50 in Ulsan City, while storing the crude oil in the tank. Emergency Rescue Control Group was deployed in the scene. The company, Fire Service Headquarters and associated agencies got together in Command Post (CP) for discussing an effective corresponding strategy. Many solution plans were drafted in the debate such as power down, stopping the facilities, checking the density of inflammable gas, suppressing oil evaporation, moving the leaked crude oil to a nearby tank and a processing plant and avoiding marine pollution. All the solutions were carried out in cooperation with several agencies and partners. The oil leakage accident was successfully settled up within the process of responding, The Fire Service Headquarters and the company thought that the most important thing was the suppression of oil evaporation and the elimination of ignition source. With Fire Service Headquarters and several agencies' every effort, an explosion and a fire didn't occurred in the scene. This study suggest the improvement of the operating system in Emergency Rescue Control Group in case of petroleum leakage, explosion and fire accidents of atmospheric storage tank, different from a ordinary disaster. Assuming that petroleum leakage in atmospheric storage tank develop the explosion and fire accidents, the spreading speed of the flame and the burning time was experimented and compared with each other. Furthermore, this study concentrates on the effective field response plan prepared for the afterward explosion and fire accidents from petroleum leak in a storage tank, with the database experimented and analyzed in accordance with the angle of radiation in the foam nozzle and the pressure of pumping in a fire engine.

Cellular Immune Responses of the Manila Clam, Ruditapes philippinarum, Exposed to Cadmium Chloride (카드뮴에 노출된 바지락 (Ruditapes philippinarum) 의 세포성 면역 반응)

  • Park, Kyung-Il;Choi, Min-Soon;Park, Sung-Woo;Park, Kwan-Ha;Choi, Sang-Hoon;Yoon, Jong-Man
    • The Korean Journal of Malacology
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    • v.25 no.2
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    • pp.135-143
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    • 2009
  • The Manila clam, Ruditapes philippinarum, has been considered as a sentinel species due to dominant distribution along the coast of Korea and well developed regulatory system. In order to develop and understand immune responses of the Manila clams, clams were exposed to $50\;{\mu}g/L$ of cadmium chloride (Cd) for 8 days and monitored the cellular immune parameters of the hemocytes including blast cell composition, DNA damage, necrosis, apoptosis and hemocyte mortality using a flow cytometer. The results showed that all immune parameters analyzed in the present study increased remarkably compared to the controls and the increases were statistically significant. Apoptosis rate was higher than necrosis rate in the clams exposed to Cd suggesting that apoptosis was preferably induced by the concentration of Cd used in the present study. Our study indicates that the measurement of cellular immune responses of the Manila clam using flow cytometer will be a useful technique for assessment of heavy metal contamination in marine environment.

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Sampling Procedure of Black-tailed Gull (Larus crassirostris)'s eggs in National Environmental Specimen Bank for Monitoring Long-term Marine Environmental Pollution (해양 환경오염 모니터링을 위한 국가환경시료은행 괭이갈매기(Larus crassirostris) 알 시료 채취 절차)

  • Lee, Jangho;Lee, Jongchun;Lee, Sang Hee;Kim, Myungjin;Lee, Eugene;Han, Areum
    • Journal of Environmental Impact Assessment
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    • v.22 no.6
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    • pp.745-751
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    • 2013
  • Environmental Specimen Banks (ESBs) have been established widely in the world since 1979 for monitoring long-term bio-accumulation of environmental pollutants. The ESBs perform the retrospective analysis of representative biological samples collected regularly and store them in cryogenic condition. In Korea, National Environmental Specimen Bank (NESB) was established in 2009. Since then, NESB had prepared the standard operating procedures (SOPs) for the seven kinds of specimens (Red Pine (Pinus densiflora), Common Carp (Cyprinus carpio), and etc.) for monitoring the effect of environmental pollution on the terrestrial ecosystem and river ecosystem. In 2012, NESB added Black-tailed Gull (Larus crassirostris)'s eggs to the list of the environmental specimen for monitoring marine environmental pollution. In this study, we sampled the eggs of the Black-tailed Gull on two islands (Baekryeongdo of the West Sea and Hongdo of the South Sea). Especially, we selected eggs which remained in the early stages of embryo development for certifying the consistent and stable monitoring for environmental pollutants in egg contents. However, it was not considered to classify an order of eggs per clutch in this study. It is known that the concentration variations of pollutants exist among eggs in one clutch. Therefore, it is needed to consider the positions of eggs in the laying sequences to meet the objective of bioaccumulation monitoring. We collected 30 eggs in each site but the amount may be insufficient to achieve storage target (over 2,000 g). Therefore, we need to consider an optimal sampling size.