• Title/Summary/Keyword: 해수양수

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Removal of I by Adsorption with AgX (Ag-impregnated X Zeolite) from High-Radioactive Seawater Waste (AgX (Ag-함침 X 제올라이트)에 의한 고방사성해수폐액으로부터 요오드(I)의 흡착 제거)

  • Lee, Eil-Hee;Lee, Keun-Young;Kim, Kwang-Wook;Kim, Hyung-Ju;Kim, Ik-Soo;Chung, Dong-Yong;Moon, Jei-Kwon;Choi, Jong-Won
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.14 no.3
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    • pp.223-234
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    • 2016
  • This study aimed to the adsorption-removal of high- radioactive iodide (I) contained in the initially generated high-radioactive seawater waste (HSW), with the use of AgX (Ag-impregnated X zeolite). Adsorption of I by AgX (hereafter denoted as AgX-I adsorption) was increased by increasing the Ag-impregnated concentration in AgX, and its concentration was suitable at about 30 wt%. Because of AgCl precipitation by chloride ions contained in seawater waste, the leaching yields of Ag from AgX (Ag-impregnated concentration : about 30~35 wt%) was less than those in distilled water (< 1 mg/L). AgX-I adsorption was above 99% in the initial iodide concentration ($C_i$) of 0.01~10 mg/L at m/V (ratio of weight of adsorbent to solution volume)=2.5 g/L. This shows that efficient removal of I is possible. AgX-I adsorption was found to be more effective in distilled water than in seawater waste, and the influence of solution temperature was insignificant. Ag-I adsorption was better described by a Freundlich isotherm rather than a Langmuir isotherm. AgX-I adsorption kinetics can be expressed by a pseudo-second order rate equation. The adsorption rate constants ($k_2$) decreased by increasing $C_i$, and conversely increased by increasing the ratio of m/V and the solution temperature. This time, the activation energy of AgX-I adsorption was about 6.3 kJ/mol. This suggests that AgX-I adsorption is dominated by physical adsorption with weaker bonds. The evaluation of thermodynamic parameters (a negative Gibbs free energy and a positive Enthalpy) indicates that AgX-I adsorption is a spontaneous reaction (forward reaction), and an endothermic reaction indicating that higher temperatures are favored.

Characteristics of Waterlevel Fluctuation in Riverside Alluvium of Daesan-myeon, Changwon City (창원시 대산면 강변충적층의 지하수위 변동 특성)

  • Cheong, Jae-Yeol;Hamm, Se-Yeong;Kim, Hyoun-Su;Son, Keon-Tae;Cha, Yong-Hoon;Jang, Seong;Baek, Keon-Ha
    • The Journal of Engineering Geology
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    • v.13 no.4
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    • pp.457-474
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    • 2003
  • This study aims to elucidate characteristics of groundwater level fluctuation at riverbank filtration sites in Daesan-myeon, Changwon City. Groundwater level fluctuation, river water level change and stream-aquifer interaction are very important to estimate optimal discharge rate of the pumping well. Water level contours from February 2003 to October 2003 show normal decreasing trend toward the Nakdong river with the hydraulic gradient of 0.008. However, flow reversion occurs when groundwater is discharged at the pumping wells or rise of the Nakdong river by rainfall. The fluctuation of the Nakdong river ranges 0 - 10 m msl. Autocorrelation analysis was conducted to the groundwater levels measured on the six monitoring wells (DS1, DS2, DS3, DS4, DS6 and DS7). The analyzed waterlevel data can be grouped into three: group 1 (DS1 and DS3) represents strong linearity and long memory effect, group 2 (DS1 and DS6) intermediate linearity and memory, and group 3 (DS4 and DS7) weak linearity and memory. Waterlevels of group 1 wells are relatively closely related to the change of river-water level. Those of group 2 wells are largely affected by the pumping and the river-water level, and those of group 3 wells are strongly linked to pumping.

Synthesis of Li1.6[MnM]1.6O4 (M=Cu, Ni, Co, Fe) and Their Physicochemical Properties as a New Precursor for Lithium Adsorbent (Li1.6[MnM]1.6O4(M=Cu, Ni, Co, Fe)의 합성 및 리튬 흡착제용 신규 전구체로서의 물리화학적 성질)

  • Kim, Yang-Soo;Moon, Won-Jin;Jeong, Soon-Ki;Won, Dae-Hee;Lee, Sang-Ro;Kim, Byoung-Gyu;Chung, Kang-Sup
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.10
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    • pp.4660-4665
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    • 2011
  • New precursors as a Li adsorbent, $Li_{1.6}(MnM)_{1.6}O_4$ (M=Cu, Ni, Co, Fe), were synthesized by hydrothermal method and their physicochemical properties were discussed. XRD and HRTEM results revealed that the original spinel structure was stabilized by cobalt-doping while Cu-, Ni- and Fe-doping led to structural changes. Such a structural stabilization by Cobalt-doping was maintained after lithium leaching by acid treatment. Li absorption efficiency from seawater was significantly enhanced by using the Cobalt-doped spinel manganese oxide, $Li_{1.6}[MnCo]_{1.6}O_4$, compared to the commercially available $Li_{1.33}Mn_{1.67}O_4$; the adsorbed amount of Li from 1g-adsorbent was 35 and 16 mg by $Li_{1.6}[MnCo]_{1.6}O_4$, and $Li_{1.33}Mn_{1.67}O_4$, respectively.

Evalution of Three Species of Haptophyte Algae for the Culture of the Marine Copepod Tigriopus japonicus (해산 요각류 Tigriopus japonicus 개체군 성장에 미치는 착편모조의 영향)

  • Kim, Hyeung-Sin;Jung, Min-Min
    • Journal of Aquaculture
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    • v.18 no.2
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    • pp.86-91
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    • 2005
  • Three haptophyte algae, Isochrysis galbana, Prymnesium parvum and P. patelliferum were offered to the marine copepod Tigriopus japonicus as food. Growth rate of larvae, egg production, mortality and comsumption rates of T. japonicus were measured for each of the haptophyte species offered. The growth rate of larvae, egg production and algal ingestion of T. japonicus fed on P. parvum and P. patelliferum were much lower than those fed on I. galbana and corresponding high mortality rates were also observed during the experimental period. The harmful effects observed during the present study indicate that bloom-forming haptophyte algae, P. parvum and P. patelliferum are not suitable feed species for culture of copepod, T. japonicus.

Agricultural Geophysics in South Korea: Case Histories and Future Advancements (우리나라 농업 물리탐사: 적용 사례와 향후 과제)

  • Song, Sung-Ho;Cho, In-Ky
    • Geophysics and Geophysical Exploration
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    • v.21 no.4
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    • pp.244-254
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    • 2018
  • The first geophysical technique applied to the agricultural sector in Korea was electrical resistivity sounding and conducted in purpose of groundwater exploitation in the 1970s. According to the diversity of agricultural activities since the 1990s, various geophysical methods including electrical resistivity, electromagnetic induction, and self-potential method were applied to several agricultural fields such as soil characterization with saline concentration in vast reclaimed area, delineation of seawater intrusion regions in costal aquifer, safety inspection of embankment dikes with leakage problem, detection of ground subsidence from overpumping and tracing of groundwater aquifer contamination by leachate from livestock mortality burial or waste burial site. This paper introduces representative geophysical techniques that have been utilized in various agricultural fields and suggests several ways to develop the geophysical methods required for the precision agriculture field in the near future based on the past achievements.

Performance Evaluation of a Closed-Loop Pressure Retarded Membrane Distillation for Brackish Water Desalination and Power Generation (기수담수화와 전력 생산을 위한 폐루프형 압력 지연식 막 증류 공정의 성능 평가)

  • Cho, Gyu Sang;Lee, Jun-Seo;Park, Kiho
    • Korean Chemical Engineering Research
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    • v.60 no.4
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    • pp.525-534
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    • 2022
  • In this study, we investigated the applicability and optimal operating strategy of a closed-loop pressure retarded membrane distillation (PRMD) for brackish water desalination. For effective operation with net power generation, high temperature of heat source over 90 ℃ and feed flow rate at 0.6 kg/s are recommended. At 3 g/L of feed concentration, the average permeate flux and net energy density showed 8.04 kg/m2/hr and 2.56 W/m2, respectively. The average permeate flux and net energy density were almost constant in the range of feed concentration from 1 to 3 g/L. Compared to the case with seawater feed, the PRMD with brackish water feed showed higher average permeate flux and net energy density. Thus, PRMD application using brackish water feed can be more effective than that using seawater feed in terms of power generation.

A Laboratory Study for Settling Velocities of Cohesive Sediments Entering in Semi-closed Channel (준 폐수로로 유입되는 점착성 퇴적물의 침강속도 산정을 위한 실험적 연구)

  • Kim, Dong-Ho;Yang, Su-Hyun;Hwang, Kyu-Nam
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.26 no.5
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    • pp.327-334
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    • 2014
  • This study aims to estimate settling velocity ($W_s$) for cohesive sediments from water bodies (Incheon Coast, Kulpo Stream and Han River) mainly connected to the Kyeongin Ara-waterway through the laboratory settling experiments. Results of settling tests for these sediments show that $W_s$ values for sediments are quite different each other: $W_s$ values of Kulpo Stream sediments (0.01 < $W_s$ < 3.07 mm/s) are quite similar with those of Han River sediments (0.01 < $W_s$ < 2.97 mm/s) over the whole range of suspension concentration C (0.1 < C < 90 g/ L), while they are quite different with those for Incheon Coast sediments (0.01 < $W_s$ <0.92 mm/s). Qualitative analyses on test results for physico- chemical properties of sediments and waters with respect to settling velocities show that these differences in settling velocities are mainly due to the salinity difference in the water.

Analysis of groundwater level change using groundwater monitoring network in Miryang area. (지하수관측망을 이용한 밀양지역의 지하수 변화 분석)

  • Baek, Mi Kyung;Sim, Gyu Sung;Kim, Sang Min
    • Proceedings of the Korea Water Resources Association Conference
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    • 2019.05a
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    • pp.221-221
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    • 2019
  • 기후변화로 인한 가뭄대비가 상시체제가 된 요즈음, 농업용수의 안정적인 공급을 위하여 가뭄 등의 비상시 지표수는 물론이고 지하수의 공급 가능량에 대해서도 국가적 관리가 필요한 실정이다. 지하수관리를 위해 국가 최상위 계획인'지하수관리기본계획(2012~2021)'이 수립되었고, 지하수의 장기적인 수량, 수질 관리를 위해 국가지하수관측망, 지역지하수관측망(보조지하수관측망), 수질측정망, 해수침투관측망 등 광역과 지역단위로 크게 나누어 지하수관측이 이루어지고 있다. 국가지하수관측망은 지하수법에 의거하여 전국의 주요지점(2016년 말 기준 412개소)에 관측소를 설치하여 수위 및 수질의 변동실태를 광역적으로 분석함이 목적이며, 보조지하수관측망은 국가지하수관측망과 연계하고 보완하기 위한 기능으로서, 지역별 주요 관측지점의 수위, 수질자료를 획득하며, 2018년 9월 현재 3,429개소가 설치되어있다. 본 연구에서는 지역지하수 관측망 중 경남밀양지역에 설치된 관측정 31개소에 대해 수위와 수질을 장기 분석하였다. 밀양지역의 보조지하수관측망 설치는 지하수관리계획의 하부계획인'경상남도 지하수관리계획(2015~2025)'에 의거 2012년에 6개소의 관측공이 설치를 시작으로, 2013년 7개소, 2014년 10개소, 2015년 8개소를 설치하여 총 31개소의 설치를 완료하였고, 2016년부터 2019년 현재까지 전체 관측정 31개소에 대하여 관측 운영 중이다. 본 연구에서는 2013년 1월~2019년 1월까지 지역의 누적강수량과 지하수위 및 수질변화를 관측하였다. 전 관측정에 대해 수위(GL.m), 수질(온도, EC)은 1시간 주기로 관측하였으며, 연 2회 생활용수 기준(19항목)의 수질검사를 실시하고, 지하수성분의 지질학적 기원분석을 위한 양음이온 분석을 연 1회 실시하였다. 관측정의 양수능력 변화관측을 위해 대수성 시험을 연 1회 실시하였고, 관측정의 특성상 장기간 미사용 관정이므로 최적의 상태유지를 위해 연1회 공내세척을 실시하였다. 또한, 관측정의 지형별 차이를 분석하기 위해 관측정의 설치위치를 산악, 강변, 기타 지역으로 구분하고, 각각의 대표관정에 대해 지형에 의한 서로 다른 영향을 분석하였고, 관측정의 심도별 변화를 알기위해 동일지역에 충적, 안반 관측정을 따로 설치하고 관측하여 지표수와 지하수의 심도별 영향의 차이를 분석하였다. 동일지역의 관측결과 평균 5m이하의 수위변화를 보이나, 5m 이상의 수위변동을 보이는 관측망은 15년 14개소 17년 19개소로 증가추세를 보이며, 이는 주로 밀집된 시설하우스 단지의 수막재배를 위한 겨울철 지하수 사용량 증가가 원인인 것으로 판단된다. 밀양지역은 강변지역에 밀집된 시설하우스단지의 동절기 수막재배를 위한 지하수 과다사용으로 수위급감 및 수량부족현상이 반복되고 있어, 예방과 대책강구를 위해 지표수의 함양과 지하수사용량의 상관관계 분석과 자료축적 및 추가연구를 위한 장기관측이 요구된다.

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Variation in Cartenoid Pigment and lipids of the Arkshell, (Anadara broughtonii) according to the Environmental Factors of the Growing Area (서식환경요인에 따른 피조개육의 Carotenoid색소와 지질성분의 변화)

  • Ha, Bong-Senk;Kang, Dong-Soo;Kim, Yung-Gwan;Kim, Kui-Shik
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.18 no.1
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    • pp.71-92
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    • 1989
  • The seasonal variations of environmental sea water, arid carotenoid and lipid composition of reddish muscle tissue of arkshell, Anadara broughtonii in Chungmu and $Y{\check{o}}su-area$ were investigated. In the sea water, pH value, salinity, electrical conductivity of Chungmu and $Y{\check{o}}su-area$ were similar tendency, but water temperature in annual average at Chungmu-area was about $2^{\circ}C$ higher than that of $Y{\check{o}}su-area$. The concentration of nitrite-nitrogen, ammonia-nitrogen, phosphate-phosphours at Chungmu-area were slightly higher than those at $Y{\check{o}}su-area$. Meanwhile the concentration of silicate-silicious at $Y{\check{o}}su-area$ was about 2 times higher than that of Chungmu-area. The bacterial density of the sea water was ranged from 3.6 to 93/100ml for coliform and 3.0 to 15/100ml for fecal colifrom at Chungmu-area, but the coliform was ranged 7.3 to 150/100ml and the fecal coliform was ranged 3.6 to 20/100ml at $Y{\check{o}}su-area$. Among the coliform, 8.9% Escherichia coli, 33.9% Citrobacter freundii, 41.1% Enterobacter aerogenes groups were classified and 16.1% was not identified. In the hemoglobin content of reddish muscle tissue of arkshell, one from Chungmu-area was ranged from 1.1 to 2.5 g /dl and one from $Y{\check{o}}su-area$ was ranged from 1.7 to 4.4 g /dl. In total carotenoid content, 0.80 to 1.28mg/100 g muscle was in Chungmu-area and 0.45 to 0.99mg/100 g muscle was in $Y{\check{o}}su-area$. Among the carotenoid compositions, pectenolone content was 63.0% in annual average from Chungmu area and 59.6% from $Y{\check{o}}su-area$, 6.5% from Chungmu area and 18.9% from $Y{\check{o}}su-area$ in ${\beta}-carotene$, 9.9% from Chungmu-area and 9.1% from Yosu-area in pectenoxanthin, 11.2% from Chungmu-area and 5.2% from $Y{\check{o}}su-area$ in diatoxanthin monoester were observed. In the seasonal variation for the major carotenoids, the content of pectenolone was continuously incresedbefore spawning period and showed the maximum in July, but decresed after spawning period. Diatoxanthin monoester was gradually incresed during all growing period from March to next January. And ${\beta}-carotene$ was decresed before spawning period and showed the maximum in July but incresed after spawning period. The major fatty acids of total lipid and fractionated lipid classes from total lipid namely neutral-, glyco- and phospholipid were $C_{16:0},\;C_{18:1},\;C_{22:6},\;C_{20:2},\;C_{18:2},\;C_{20:5}\;and\;C_{18:3}$ acid in the muscle tissue of arkshell. The content of neutral lipid showed about 2 times higher than polar lipid in the muscle tissue of arkshell from both Chungmu and, $Y{\check{o}}su-area$. The content of total and neutral lipid was decresed during spawning period. In the seasonal variation for fatty acid compositions, the content of polyenenoic acid in total and neutral lipid was decresed and saturated acid was incresed. On contrary, polyenoic acid in glyco and phospholipid was incresed and saturated acid was decresed during spawning period from July to September. The sterol composition in total lipid were mainly consisted of cholesterol, campesterol, brassicasterol and ${\beta}-sitosterol$. Especially, the rate of content in cholesterol showed decrese during spawning period butcampesterol showed increse from March to November.

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