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An Experimental Study on the Properties of High Flowing Concrete according to Water/Binder Ratio(W/B) (물결합재비에 따른 고유동콘크리트의 특성에 관한 실험적 연구)

  • 김무한;최세진
    • Journal of the Korea Concrete Institute
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    • v.13 no.4
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    • pp.329-335
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    • 2001
  • Recently, in many laboratories and institutes it is being studied on the high flowing concrete widely, which has high fluidity, non-segregation ability and fillingability, and sometimes being applied to the construction field actually. And the fluidity properties of high flowing concrete are influenced according to the several factors ; binder content, water/binder ratio and water content etc. This is an experimental study to compare and analyze the effect of water/binder ratio and water content on the properties of high flowing concrete. For this purpose, the mix proportion of high flowing concrete according to water/binder ratio(W/B : 0.30, 0.35, 0.40, 0.45) and water content (W : 155, 165, 175, 185 kg/㎥) was selected. And then slump-flow, V-lot, L-passing test in fresh concrete, and compressive strength, freezing and thawing test in hardened concrete were peformed. According to test results, it was found that the viscosity of all those high flowing concrete with the water content 175 kg/㎥ was satisfied with 50 cm pass time of slump flow prescribed by Japanese Architectural Standard Specification (JASS 5) - from 3 to 8 seconds. And non-segregation ability of concrete with W/B 0.35 was better than the other mix proportions. Especially, the compressive strength after curing 24 hours(1 day) of all high flowing concrete was higher than that prescribed by JASS 5(50 kgf/㎠).

Treatment of TNT Red Water by the Ozone-based Advanced Oxidation Processes (오존을 산화제로 사용한 다양한 고급산화 공정에 의한 TNT Red Water의 처리)

  • Jun, Jun Chul;Kwon, Tae Ouk;Moon, Il Shik
    • Korean Chemical Engineering Research
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    • v.45 no.3
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    • pp.298-303
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    • 2007
  • Several combinations of ozone based advanced oxidation processes were tested for the treatment of red water (RW) containing recalcitrant chemical pollutants produced from 2,4,6-trinitrotoluene (TNT) manufacturing process. $O_3$, $UV/O_3$, $UV/O_3/H_2O_2$, $UV/O_3/H_2O_2/Fe^{2+}$ processes were tested for the treatment of RW. The order of organic and color removal efficiency was found to be : $O_3{\leq}UV/O_3$ < $UV/O_3/H_2O_2$ < $UV/O_3/H_2O_2/Fe^{2+}$. The optimum conditions for the removal of organic and color in the $UV/O_3/H_2O_2/Fe^{2+}$ process were 0.053 g/min of ozone flow rate, 10 mM of $H_2O_2$ concentration and 0.1 mM of $FeSO_4$ concentration. Organic and color removal efficiencies were 96 and 100 % respectively in the $UV/O_3/H_2O_2/Fe^{2+}$ process. tert-butyl alcohol (t-buOH) was used as the hydroxyl radical scavenger. Enhancement of hydroxyl radical production was achieved by the combination of ozone with several oxidants such as UV, $H_2O_2$, $Fe^{2+}$.

A Study on the Removal of Refractory Organic Matter in Leachate sampled at Kimpo Landfill by means of Fenton Oxidation Process (Fenton 산화를 이용한 김포매립지 침출수내 난분해성)

  • 정동환;조일형;김익수;한인규;정문호
    • Journal of Environmental Health Sciences
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    • v.26 no.4
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    • pp.49-57
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    • 2000
  • This study was carried out to find the optimal condition to treat refractory organic matter which can’t treat clearly with biological treatment and to find the optimal division dosage and division dose timing in the modification of Fenton oxidation which is used resolve the problem that hydrogen peroxide is too expensive. The results are following; 1. The highest TOC removal efficiency was 41% and color removal efficiency was 64% when the dilution magnitude of leachate is fold. This suggests that dilution is efficiency when high concentration of leachate is treated. 2. The removal efficiency of TOC and color increased up to the molar ratio between ferrate and hydrogen peroxide was 1:1. However above that ratio, removal efficiency hardly increased. The highest removal efficiency of TOC and color were 38% and 71% when the mole ratio of ferrate to hydrogen peroxide was 1.5:1. 3. When the mole ratio between ferrate and hydrogen peroxide was fixed, the removal efficiency of TOC and color increased as the dosage of hydrogen peroxide increased. 4. pH of samples were adjusted at pH 3, 5, 7, 9, 11. After oxidation reaction, pH of samples were dropped to 2.59, 2.54, 5.34, 6.36 and 9.68. The highest color removal efficiency was 75.7% when initial pH was at pH 7. 5. The removal of TOC and color was ended within 10. min. and the removal efficiency increased logarithmically within 10min. However after 10 min., the removal efficiency of hardly increased. 6. The color removal efficiency was higher with modification of fentone oxidation than that with fentone oxidation by 5%. Optimal division dosage ratio was 1:1 and optimal dose timing ratio was 2:1. However the TOC removal efficiency was not higher with modification of Fenton oxidation than that with Fenton oxidation.7. The CO $D_{Mn}$ /BO $D_{5}$ Ratio decreased with the time went by. It meant bioresolution increased as time went by. However, after 15 min., the CO $D_{Mn}$ /BO $D_{5}$ Ratio did not decrease any more. 8. In the case of $H_2O$$_2$ Divisiom Dose experiment, the increase of bioresolution was highest at the $H_2O$$_2$ Division dosage Ratio of 3:7.3:7.

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Simple and Rapid Evaluation System for Endosulfan Toxicity and Selection of Endosulfan Detoxifying Microorganism Based on Lumbricus rubellus (Lumbricus rubellus를 이용한 endosulfan의 간편, 신속 독성 평가 및 endosulfan 분해 미생물의 선별)

  • Sohn Ho-Yong;Kim Hong-Ju;Kum Eun-Joo;Lee Jung-Bok;Kwon Gi-Seok
    • Journal of Life Science
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    • v.16 no.1
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    • pp.108-113
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    • 2006
  • To compensate the problems of chemical assay in detoxification of recalcitrant and a practical approach in selection of bioremediation bacteria, a simple and rapid toxicity evaluation system was constructed based on Lumbricus rubellus. Long term-culture and specific equipment are not necessary, and semi-quantitative analysis of toxicity at sub-lethal concentration is possible by measuring of dose-dependent increased yellowish secreted compounds. When the toxicity of endosulfan, its metabolites and structurally related chemicals were measured for 24 h, the results were coincided with previous reports. Toxicity was found in endosulfan, endosulfan sulfate, aldrin, and dieldrin, respectively. Rapid and economic selection of endosulfan-detoxifying bacteria was possible using our system. Klebsiella pneumoniae KE-1, K. oxytoca KE-8 and Pseudomonas sp. KS-2P, reported endosulfan degrading bacteria, ameliorated the endosulfan toxicity, whereas E. coli, B. subtilis and other bacteria failed to protect the toxicity of endosulfan in L. rubellus. Our results suggest that the constructed system is useful to selection of microorganism as well as toxicity evaluation against toxic recalcitrants.

Degradation of Polyvinyl Alcohol in Dye-Processing Wastewater by Agar-Acrylamide Microbial Immobilization Method (한천-아크릴아마이드 미생물 고정화법에 의한 폐수 중 폴리비닐알콜의 분해)

  • 김재훈;김정목조무환
    • KSBB Journal
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    • v.10 no.3
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    • pp.241-248
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    • 1995
  • For the treatment of poorly biodegradable polyvinyl alcohol(PVA) in dye-processing wastewater, immobilized microbial beads were prepared by uslng agar-acrylamide method. PVA removal efficiency for the synthetic wastewater was 85% at the PVA volume loading rate of $3.1g/\ell$.day. In case of real desizing wastewater, PVA removal efficiency was 81.3% at the PVA volume loading rate of $3.25g/\ell$.day. In observation of cross section of immobilized bead passed 5 months with diameter of 2.4mm, the growth of cell was limited by the resistance of substrate and oxygen transfer for the inners region of more than 48% of bead radius from the surface. It was estimated that 70% of total removed PVA was degraded by the immobilized cells in the continuous immobilized reactor. Substrate utilization rate in the suspended reactor was decreased with increasing dilution rates above 0.083 hr-1, but that in the immobilized reactor was increased with increasing dilution rates up to 0.125hr-1. The substrate removal efficiency of immobilized reactor was much superior to that of suspended reactor with increasing dilution rates. Saturation constant of substrate utilization rate equation, Ks was $6.6 g PVA/\ell$, and maximum specific substrate utilization. k was 0.175g PVA/g cell.hr

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Effects of Consumer Innovativeness on the Evaluation of the Online Fashion Advertisement Sustainability (온라인 패션광고의 지속가능성 평가에 대한 소비자 혁신성 효과)

  • Son, Mi Young;Yoon, Namhee
    • Science of Emotion and Sensibility
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    • v.19 no.2
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    • pp.43-54
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    • 2016
  • The purpose of this research was to analyze the effect of consumer innovativeness on the evaluation of online fashion advertisement sustainability and on purchase intentions of advertising products. Online survey have been conducted of 573 people who had experience of online advertisements. The data collected from the surveys were analyzed by the factor analysis, the t-test and the multiple regression analysis. the results are as follows: Firstly, it has been identified that the concept of sustainability of online fashion advertisement consists of four sub-elements of the objectivity of advertisement expressions, the non-harmfulness of advertisement expressions, the protection of personal information, and the non-infringement of web use. Secondly, the group that has a higher consumer innovativeness shows a significantly higher experience of online advertisements as well as more many internet use hours than those who have a lower consumer innovativeness. In addition, comparing with the group that shows lower consumer innovativeness, the group who has higher consumer innovativeness shows a significantly higher recognition of the protection of personal information, the non-infringement of web use and the objectiveness of advertisement expressions among the sub-elements of online fashion advertisement. Lastly, the objectiveness of advertisement expressions and the non-infringement of web use significantly affect the intentions of the group that has high consumer innovativeness to purchase advertised products, and the purchase intentions of those who have low consumer innovativeness are significantly affected by the objectiveness of advertisement expressions and the protection of personal information.

Effect of Wollastonite and Nitrogen Application on the Growth of Rice Plant (퇴화염토에서 수도생육에 대한 질소와 규회석의 시용효과)

  • 김규진;이주열
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.26 no.4
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    • pp.279-286
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    • 1981
  • This study was conducted to find out the effect of wollastonite application in degraded saline soil condition on the growth of japonica rice variety. The variety, Palgweng was tested with 4 levels of wollastonite (200, 400, 600 and 400/200 kg/l0a) and two nitrogen levels (12 and 16 kg/l0a). The effect of wollastonite was higher in 16 than 12 kg of nitrogen application. The wollastonite application reduced rice leaf blast and dead left at lower nodal position, and increased percentage of effective tillers, percentage of ripened grains and 1, 000 grain weight. The SiO$_2$ content of upper leaf was higher than lower leaf in 200 kg of wollastonite application, but there was no difference under high wollastonite application (400 kg/l0a). Highly significant positive correlationships were obtained between SiO_2 content of plant at heading and percentage of ripened grains, (r=0.613) and SiO_2 content of flag leaf and percentage of ripened grains (r=0.407). Wollastonite application did not affect the development and degeneration of primary and secondary rachis branches of panicles, but it increased the number of spikelets. The highest grain yield was obtained with 16 kg of nitrogen and 600 kg of wollastonite.

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Molecular Ecological Characterization of Wastewater Bacterial Communities in Response to Algal Growth (조류성장에 따른 하수 박테리아 군집 변화에 관한 분자생태학적 연구)

  • Lee, Ju-Youn;Lee, Jang-Ho;Park, Joon-Hong
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.11
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    • pp.847-854
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    • 2011
  • To deal with issues from global climate changes, renewable bioenergy has become important. Algae have been regarded as a good resource for biorefinery and bioenergy, and also have potential capability to remove nutrient and non-decompositional pollutants for wastewater advanced treatment. Although algal-bacterial ecological interaction would be a crucially important factor in using algae for wastewater advanced treatment and resource recovery from wastewater, very little is known about ecological interaction between algae and bacteria in a real wastewater environment. In this study, under a real municipal wastewater condition, we characterized wastewater pollutant treatability and bacterial communities in response to growth of Ankistrodesmus gracilis SAG278-2, which can grow in wastewater and has a high lipid contents. The growth of algal population using the wastewater was inhibited by increase in wastewater bacteria while bacterial survival and cellular decay rate were not influenced by the algal growth. Removals of recalcitrant organic matters and total nitrogen were improved in the presence of algal growth. According to T-RFLP and statistical analysis, algal growth affected time-course changes in bacterial community structures. The following 16S rRNA gene amplicon, cloning results showed that the algal growth changes in bacterial community structure, and that bacterial populations belonging to Sediminibacterium, Sphingobacterium, Mucilaginibacter genera were identified as cooperative with the algal growth in the wastewater.

The Effect of Pre-Treatment Methods for the Life Time of the Insoluble Electrodes (불용성 전극의 전처리 방법이 전극의 수명에 미치는 영향)

  • Park, Mi-Jung;Lee, Taek-Soon;Kang, Meea;Han, Chi-Bok
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.6
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    • pp.291-298
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    • 2016
  • Electrochemical water treatment process as a useful treatment method for the removal of non-degradable matter has been consistently studied for several decades. Key process of electrochemical water treatment are oxidation reaction from an anode and reduction from a cathode. In this study, the effect of pre-treatment methods in the insoluble electrode manufacturing process for the water treatment has been evaluated for the life time of electrode The results of this study showed that pre-treatment methods of a base metal such as surface roughness, clean method and interlayer formation influenced to life time of electrode when the same condition (catalyst electrode layer coating method and material system) was applied for pre-treatment methods. This study was conducted by using $IrO_2/Ti$ electrode In the test of sand-blasting process, an electrode manufactured by using sanding media of different sizes resulted in the most effective electrode life time when the size of alumina was used for $212{\sim}180{\mu}m$ praticle size (#80). The most effective method was considered using arc plasma in the additional roughness control and cleaning process, sputtering method to form Ta type interlayer formation process.

Purification and Properties of the Polyvinyl alcohol oxidase from Xanthomonas campestris J2Y (폴리비닐 알콜 분해균 Xanthomonas campestris J2Y의 Polyvinyl alcohol oxidase 정제 및 성질)

  • Kwoen, Dae-Jun;Jo, Youl-Lae
    • Applied Biological Chemistry
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    • v.39 no.5
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    • pp.349-354
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    • 1996
  • The Polyvinyl alcohol(PVA) oxidase involved in PVA degradation by microorganism has been purified to homogeneity from culture broth of Xanthomonas campestris J2Y grown in a minimal medium containing PVA as a sole carbon source. The enzyme was purified by DEAE-cellulose chromatograpy and Sephadex G-150 gel filtration. The purified PVA oxidase was electrophoretically homogeneous both in the absence and presence of SDS. The molecular weight of the enzyme was estimated to be about 55,000 daltons by SDS-polyacrylamide gel electrophoresis and Sephadex G-150 gel filtration. The native enzyme existed as a monomer. The optimal pH and temperature was shown to be pH 7 and $37^{\circ}C$ respectively. The activity of enzyme was stable below $55^{\circ}C$ and between pH range of $5{\sim}11$. The enzyme activity was significantly inhibited by metal compounds such as $Ag^{2+},\;Hg^{2+}$. While, metal ions such as $Mn^{2+},\;and\;Cu^{2+}$ stimulated the reaction. Km value of the enzyme for PVA was $7.04{\times}10^{-2}mmol/{\ell}$.

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