• Title/Summary/Keyword: 해성

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Electrochemical Treatment of Dyeing Wastewater using Insoluble Catalyst Electrode (불용성 촉매전극을 이용한 염색폐수의 전기화학적 처리)

  • Um, Myeong-Heon;Ha, Bum-Yong;Kang, Hak-Chul
    • Clean Technology
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    • v.9 no.3
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    • pp.133-144
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    • 2003
  • In this study, Insoluble catalyst electrode for oxide systems were manufactured, by using of them, carried out experiments on electrolytic treatment of dyeing wastewater containing persistent organic compounds, and then made a comparative study of the efficiency of treatment for environmental pollutants and whether each of them is valuable of not as an electrode for soluble electrode(Fe, Al) and insoluble electrode(SUS, R.C.E; Replaced Catalyst Electrode) which were used in the electrolytic system. Besides, it was investigated the conditions for electrolytic treatment to find the maximum efficiency of electrolytic treatment. As the result of this study, by using of insoluble catalyst electrode for oxide can solved the stability of electrode that is one of the greatest problems in order to put to practical use of electrolysis process in the treatment of the sewage and wastewater and the result runs as follows; 1. The durability of insoluble catalyst electrode(R.C.E) can be verified the most favorable when the molar ratio of $RuO_2-SnO_2-IrO_2-TiO_2$(4 compounds system) is 70/20/5/5. 2. The efficiency of treatment was obtained a more than 90% goodness for CODMn and also a good results for T-N removal in the experimental conditions of the distance of electrode 5 mm, time of electrolysis 60 minutes, permissible voltage 10V, processing capacity $0.5{\ell}$.

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The Influence of Load Increment Ratio on the Secondary Consolidation (하중증가율(荷重增加率)이 이차압밀(二次壓密)에 미치는 영향(影響))

  • Chee, In Taeg;Kang, Yea Mook
    • Korean Journal of Agricultural Science
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    • v.10 no.1
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    • pp.110-117
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    • 1983
  • This study was conducted to investigate the influence of load increment ratio on the secondary consolidation for the marine clay at Asan bay by the hyperbola method. The results were summarized as follow: 1. Calculated secondary consolidation by the hyperbola method was slightly less than the value of Casagrande's log t method, but the difference was very little, and the secondary consolidation could be easily calculated by the hyperbola method even if load increment ratio was small. 2. The secondary consolidation ratio was increased with the decrement of load increment ratio, and the creep phenomenon of the settlement curve occurred under the condition of small load increment ratio seemed to be caused by the secondary consolidation. 3. The secondary consolidation ratio occurred during the primary consolidation was irregular in the overconsolidated range, but it was increased with the decrement of load increment ratio in the normally consolidated range. 4. The coefficient of secondary consolidation was increased with the increment of the consolidation load, made a point of the inflection near preconsolidation. And the coefficient of secondary consolidation was decreased from consolidation load $2kg/cm^2$, showed independent of load increment ratio. 5. The coefficient of secondary consolidation was showed in proportion to compression index.

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A Study on the Stress-Strain Prediction of Silty Clay (점성토(粘性土)의 응력(應力) - 변형(變形) 추정(推定)에 관(關)한 연구(硏究))

  • Cho, Seong Seup;Kang, Yea Mook;Chung, Seong Gyu;Yun, Hyun Chung
    • Korean Journal of Agricultural Science
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    • v.19 no.1
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    • pp.65-78
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    • 1992
  • The paper describes the comparison between observed and predicted stress-strain characteristics of marine silty clay in Dangjin district. For prediction, the hyperbolic model which is applied the parameters acquiring by physical and triaxial compression test was adopted, and the obtained results were summarized as follows: 1. The Young's modulus were increased with decreasing of moisture contents and increasing of dry density. 2. The most affective factor to hyperbolic model is lateral stress and dry density. and than cohesion and internal friction angle. 3. The comparision between the statistical and hyperbolic values of maximum deviator stress have few accordance. and the statisticals is lower than the hyperbolics. 4. Without. much labor and tiresome procedures, effective computer program was made and applied, but technical procedure for prevents test errors of parameter calculation is importants.

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Preparation and Characteristics of Ipriflavone-Loaded PLGA Microspheres (이프리플라본을 함유한 생분해성 미립구의 제조와 특성분석)

  • 이진수;강길선;이종문;신준현;정제교;이해방
    • Polymer(Korea)
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    • v.27 no.1
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    • pp.9-16
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    • 2003
  • Ipriflavone (IP) stimulates proliferation and differentiation of osteoblast and also enhances calcitonin secretion in the presence of estrogen. Poly(lactide-co-glycolide) (PLCA) due to its controllable biodegradability and relatively good biocompatibility is one of the most significant candidates for the study of drug controlled release system. In this study, IP-loaded PLGA microspheres (MSs) was prepared by using conventional O/W solvent evaporation method. The size of MSs was in the range of 5~200 $mu extrm{m}$. The morphology of MSs was characterized by SEM. And, in vitro release amounts of IP were analyzed by HPLC. The highest encapsulation efficiency were obtained by using gelatin and polyvinyl alcohol (PVA) as emulsifiers. The morphology, size distribution, and in vitro release pattern of MSs were changed by several preparation parameters such as molecular weights (8, 20, 33 and 90 kg/mol), polymer concentrations (2.5, 5, 10 and 20%), emulsifier types (PVA, gelatin and Tween 80), initial drug loading amount (5, 10, 20 and 30%) and stirring speed (250, 500 and 1000 rpm). The release of IP in vitro was more prolonged over 30 days, with close to zero-order pattern by controlling the preparation parameters. The physicochemical properties of IP-loaded PLGA MSs were investigated by XRD and DSC.

Effect of Sodium Hydroxide Treatment on Scaffold by Solid Freeform Fabrication (조형가공기술을 이용한 인공지지체의 수산화나트륨 개질 효과)

  • Park, SuA;Lee, JungBok;Kim, YangEun;Kim, JiEun;Kwon, IlKeun;Lee, JunHee;Kim, WanDoo;Kim, HyungKeun;Kim, MiEun;Lee, JunSik
    • Polymer(Korea)
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    • v.38 no.6
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    • pp.815-819
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    • 2014
  • Scaffolds of tissue engineering should be biocompatible and biodegradable for cell attachment, proliferation and differentiation. In the various scaffold fabrication, 3D printing technique can make the three dimensional scaffold with interconnected pores for cell ingrowth. Polycaprolactone (PCL) is biodegradable polyester with a low melting temperature and has been approved by the Food and Drug Administration (FDA). In this study, PCL scaffold was fabricated by 3D bioprinting system and surface modification of PCL scaffold was controlled by NaOH treatment. Morphological change and wetability of NaOH-treated scaffold were observed by SEM and contact angle measurement system. The remnant of PCL treated with NaOH was measured by ATR-FTIR. In vitro study of scaffolds was evaluated with WST-1 and ALP activity assay. NaOH treatment of PCL scaffolds increased surface roughness, hydrophilicity, cell proliferation and osteogenic differentiation. These results indicate that NaOH-treated PCL scaffold made by 3D bioprinting has tissue engineered potential for the development of biocompatible material.

Study on Encapsulation Efficiency and Preparation of SLN Using Conjugated New Whitening Agent(LA-PEG) and Its Cosmetic Application (새로운 미백물질을 함유하는 SLN의 제조와 봉입효율에 관한 연구)

  • Kang, Ki-Choon;Pyo, Hyeong-Bae;Lee, Cheong-Hee;Kim, Tae-Hoon;Ma, Sang-Chol;Im, Won-Cheol;Jeong, Noh-Hee
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.34 no.1
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    • pp.15-23
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    • 2008
  • This study is on encapsulation of a new whitening agent, LA-PEG using solid lipid nanoparticle(SLN) method, one of nanoparticle preparation method. Classical method has high capsulation efficiency for hydrophobic compounds but has demerit of low capsulation efficiency($2{\sim}3%$) for hydrophilic compounds. Purpose of this study is preparation of SLN that has higher skin penetration effect compared with general liposome, and also has higher encapsulation efficiency of hydrophilic compounds. For SLN preparation, coconut oil, macadamia oil, and jojoba oil were used. As a result, SLN preparation using coconut oil(include LA-PEG) has the most high encapsulation efficiency and also has the smallest average particle size(270 nm). SLN prepared with macadamia oil and 1% of Tween 60 has the largest particle size. Base made with coconut oil and 2% of Tween 60 showed the fastest release and base made with macadamia oil and 2% of Tween 20 showed the latest release.

Characteristics of Agronomy Traits to Transgenic Rice Selected by Molecular Breeding Method (분자육종기법에 의해 선발된 형질전환 벼 계통의 작물학적 특성)

  • Lee, Hyun-Suk;Kang, Hyun-Goo;Park, Young-Hie;Jung, Hee-Young;Kim, Chang-Kil;Han, Jeung-Sul;Sohn, Jae-Keun;Kim, Kyung-Min;Park, Gyu-Hwan
    • Korean Journal of Plant Resources
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    • v.21 no.5
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    • pp.388-394
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    • 2008
  • This study was carried out to develop new cultivars using the $T_5$ generation of transformed rice by PCR analysis with DNA marker in each generation $(from\;T_3\;to\;T_5)$. In the previous study, we successfully developed the transgenic rice plants over-expressing the Arabidopsis $H^+/Ca^{2+}$ antiporter CAX 1 (accession no. U57411) gene. The calcium concentration in brown rice of transgenic plants was higher than that of donor plants, Iipum, and was selected 3 lines out of 25 lines at cultured GMO field. The major agronomic traits such as culm length, panicle length and panicle number of 3 lines at transgenic plants $(T_5)$ were similar to wild type. Also these lines appeared to have disease resistance to rice blast, cold resistance as compared with donor types. The grain shape was similar to donor plant, however, the 1000 grain weight of brown rice was different from transgenic plants. These finding would be used for basic data of new variety registration.

Stabilization of Polyphenolic Antioxidants Using Inclusion Complexation with Cyclodextrin and Their Utilization as the Fresh-food Preservative (폴리페놀계 천연 항산화제의 cyclodextrin inclusion complexation을 통한 안정화와 식품 보존제로의 활용)

  • Kim, Tae-Kwon;Shin, Hyun-Dong;Lee, Yong-Hyun
    • Korean Journal of Food Science and Technology
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    • v.35 no.2
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    • pp.266-271
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    • 2003
  • Insoluble polyphenol antioxidants, quercetin and catechin, were stabilized through the complexation with cyclodextrin to increase heat and pH stabilities. Comparison of inclusion complex formabilities of quercetin and catechin with ${\alpha}-,\;{\beta}-$, and ${\gamma}-CDs$ revealed ${\beta}-CD$ to be the most suitable result. Optimal molar mixing ratio of ${\beta}-CD$ and quercetin or catechin for inclusion complex formation was found to be 1 : 1. Inclusion complexation was confirmed using differential scanning calorimetry. Solubility of ${\beta}-CD-antioxidant$ inclusion complexes increased compared with native antioxidants, Stability against temperature and pH of ${\beta}-CD-antioxidant$ inclusion complex analyzed revealed antioxidant activities of ${\beta}-CD-quercetin$ and catechin inclusion complexes have higher stabilization compare to raw quercetin and catechin. Peroxide value of linoleic acid dissolved in water decreased substantionally after using ${\beta}-CD-quercetin$ inclusion complex. ${\beta}-CD-antioxidant$ inclusion complex can be used effectively as a fresh-food preservative.

Influences of Slag Replacement on the Properties of Shotcrete Using a Slurry-Type Set Accelerator (슬래그 혼입량이 슬러리형 급결제를 활용한 숏크리트 몰탈의 물성에 미치는 영향)

  • Kim, Hyunwook;Moon, Hoon;Kim, Ji-Hyun;Chung, Chul-Woo
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.5
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    • pp.389-396
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    • 2014
  • The set accelerator used for shotcrete at high pH environment often causes the dusting problem in practice. In this research, a slurry-type set accelerator was developed to avoid this problem and its effectiveness was investigated by applying it to shotcrete mortars. Set time, stiffening, compressive strength, and chloride ion penetration resistance were examined with different amounts of slag, used as partial replacement of cement. According to the experimental results, it was found that the earlier responses such as set time, stiffening, and 1-day compressive strength were probably affected by the amount of ettringite, formulated by the hydration between C12A7 and calcium sulfate polymorphs present in blast furnace slag. Whereas, it is believed that the result of compressive strength after 3 days was attributed to the hydration of tricalcium silicates. As for the results of a chloride ion penetration test, the partial replacement of cement with slag significantly reduced the total charge passed through the shotcrete mortar.

Mechanical Properties of Porous Concrete For Pavement Using Recycled Aggregate and Polymer (재생골재와 폴리머를 이용한 포장용 포러스 콘크리트의 역학적 특성)

  • Park Seung-Bum;Yoon Eui-Sik;Seo Dae-Seuk;Lee Jun
    • Journal of the Korea Concrete Institute
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    • v.17 no.4 s.88
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    • pp.595-602
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    • 2005
  • The purpose of this study is to utilize recycled concrete aggregates as permeable pavement materials. This study evaluates mechanical properties and durability of porous concrete depending on mixing rates of recycled aggregates and polyme. As a result, void ratio and permeability coefficient of porous concrete for pavement increased a little as mixing rate of recycled aggregates increased. Void ratio and permeability coefficient increased a lot as mixing rate of polymer increased. As polymer was mixed $20\%$, national regulation of permeable concrete for pavement($8\%$ and 0.01cm/sec) was met. Compressive strength and flexural strength decreased as mixing rate of recycled aggregates increased but they increased a lot as mixing rate of polymer increased. Even when recycled aggregates were mixed $75\%\;with\;10\%$ polymer mixed, national regulation of pavement concrete(18MPa and 4.5MPa) was met. In addition, regarding sliding resistance, BPN increased as mixing rate of recycled aggregates increased. But BPN decreased as polymer was mixed. Compared to crushed stone aggregates, abrasion resistance and freeze-thaw resistance decreased as mixing rate of recycled aggregates Increased. When polymer was mixed, abrasion resistance and freeze-thaw resistance improved remarkably. Compared to non-mixture, $10\%$ mixture of polymer improved abrasion resistance and freeze-thaw resistance about $8.6\%$ and 3.8times respectively.