• Journal of the Korean Applied Science and Technology
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• v.30 no.2
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• pp.233-243
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• 2013

The inorganic pearlescent pigment have high physical and chemical stability, thus it is used in a variety field, which has better light stability, solvent resistance and thermostability. In this paper, we were synthesized the pearlescent pigment for cosmetics which was coated cobalt chloride for base of blue color metal oxide on mica titania substrate using hydrothermal synthesis method. To complement the color of the pigment by cobalt, pearl pigment were coated by different metal salt and cobalt ratio, to implement a variety of color value, depending on the kind of metal salts were synthesized. Synthesized pearlescent pigments appear various color as kind of added metal salt precursor and molar ration of cobalt and other metals. We controlled coating and color by composition of metal salt and type of metal salts, and that confirm the pigment characteristics of color changes through the analysis of color difference meter. Synthesized pigment was characterized by SPM, SEM, XRD, and EDS.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2011.03a
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• pp.65-65
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• 2011

천연염색에 대한 관심이 높아지고 있지만 색상의 재현성, 견뢰도의 취약성, 디자인의 제한성의 문제로 실용화의 한계에 부딪히고 있다. 이를 극복하기 위하여 본 연구는 침염 위주의 천연 염색에서 벗어나 키토산을 바인더로 이용하는 날염의 유효성을 검토하고자 한다. 본 연구에서는 키토산을 바인더로 이용한 방법을 제시하고자 키토산과 광물성, 동 식물성 안료를 혼합하여 날염호를 조제하여 날염하였다. 키토산의 점도와 농도, 키토산을 이용한 바인더와 안료의 비율 등을 변화시키고 날염직물의 색상과 염착량, 세탁 일광 마찰 견뢰도를 측정하여 적정조건을 도출하였다. 기존의 합성바인더와 구아검을 사용한 경우의 색상, 염착량, 견뢰도와 비교하여 키토산 날염 바인더로서의 유효성을 검토하였다. 키토산을 바인더로 이용한 날염방법에서 적정 점도는 저 중점도, 농도는 1.7%정도가 적절한 것으로 판단하였다. 날염호 제조시 안료의 비율을 증가시켜 진한 색상을 얻을 수 있었으며, 그 비율은 광물성 안료의 경우 1:4, 동 식물성 안료의 경우 1:10까지 변화시켜 명도의 차이를 나타낼 수 있다. 실험결과를 바탕으로 적정조건에서 날염한 직물의 견뢰도를 평가한 결과, 광물성 안료의 경우 4등급 이상, 동 식물성 안료의 경우 3등급 이상으로 우수하게 평가되었다. 안료의 비율이 높아지면 마찰 견뢰도는 감소하였다. 키토산, 구아검, 합성바인더의 색상과 견뢰도를 비교해 본 결과 색상은 동일한 계열로 나타났으며, 키토산을 바인더로 이용한 경우 세탁, 일광, 마찰 견뢰도는 구아검보다 우수하게 평가되었다. 합성바인더의 경우 세탁, 마찰 견뢰도는 비슷하게 나타났으며, 일광견뢰도의 경우 키토산이 더 우수하게 평가되었다.

• 한국문화재보존과학회:학술대회논문집
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• 2002.02a
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• pp.12-20
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• 2002

The analysis of danchung pigments at the Geunjeongjeon Hall in the Gyeongbokgung Palace were carried out by EXRF and MXRD. The analytical results showed that mineral pigments were employed for the inside of the Geunjeongjeon Hall. The main ingredients of green pigments were chalcanthite and celadonite. Red pigment was cinnnabar. It was also revealed that synthetic pigments were applied for the outside of the Hall. Yellow pigment was chrome yellow. The main ingredients of red pigments were red lead and hematite. Green pigments were emeral green and chrome green. Lazurite was employed for blue pigment and titanium dioxide for white one.

• Polymer(Korea)
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• v.36 no.1
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• pp.104-110
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• 2012

The dispersion of pigment particles is important because it is capable of increasing the color strength, contrast, and transmittance of color-LCD products. Pigment dispersion properties are very important factors for the quality of LCD color filters. The chemical structure of polymeric dispersants for pigment is important to improve dispersion stability and prevent aggregation or flocculation of pigment in organic or aqueous systems. Polymeric dispersants should contain both anchoring group that interacts with pigment surface and stabilizing group that provides steric stabilization. Moreover, the molecular weight and composition of block copolymer have the an effect on pigment dispersion. In this study, adequate dispersants, block copolymers containing (2-dimethylamino)ethyl methacrylate as anchoring group and oligo(ethylene oxide)methyl ether methacrylate as a stabilizing group were designed and synthesized by atom transfer radical polymerization in order to prepare well-defined structure, molecular weight and composition.

• Journal of Conservation Science
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• v.36 no.5
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• pp.351-367
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• 2020

The pigments of three old and new celestial charts folding screens(『Celestial Chart(Folding Screen)』 and 『Old and New Celestial Charts, Eight-Panel Folding Screen』 of National Folk Museum of Korea and 『Koudou-Nanboku-Ryousouseizu』 of National Diet Library of Japan) were analyzed to estimate their dating. It was estimated that the 『Celestial Charts(Folding Screen)』 was painted using traditional pigments from the Joseon dynasty such as azurite, indigo lake, malachite, atacamite, vermilion, iron oxide, cochineal, gamboge, orpiment, lead white, talc and soot. The green and blue colors of the 『Old and New Celestial Charts, Eight-Panel Folding Screen』 and 『Koudou-Nanboku-Ryousouseizu』 were painted using artificial inorganic pigments such as emerald green and ultramarine blue. These pigments were imported from Europe post the mid-19th century. In the 『Old and New Celestial Chart, Eight-Panel Folding Screen』, only artificial inorganic pigments were used for green and blue colors. However in the 『Koudou-Nanboku-Ryousouseizu』, emerald green and atacamite in green color, and ultramarine blue and indigo lake in blue color were used together. Based on both the results of pigment analysis and the study of star charts and inscriptions, the 『Celestial Charts(Folding Screen)』 was painted post mid-18th century. The 『Koudou-Nanboku-Ryousouseizu』 and 『Old and New Celestial Charts, Eight-Panel Folding Screen』 were painted after green and blue artificial pigments were imported in the mid-19th century. The 『Koudou-Nanboku-Ryousouseizu』 in which both traditional and western artificial pigments were used, can be dated earlier than the 『Old and New Celestial Chart, Eight-Panel Folding Screen』.

• Polymer(Korea)
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• v.33 no.5
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• pp.463-468
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• 2009

Syntheses of monodisperse and micron-sized hollow plastic pigment (HPP) were carried out through the core-shell reaction. The effects of the reaction parameters, such as the particle size, molecular weight, the swelling time, agitation rate, and the solid contect were investigated. This micron-sized HPP could be made by using the alkali soluble core with at least bigger than 200 nm size. To obtain a higher opacity ratio, the swelling time and molecular weight of the core should be controlled. The agitation rate affected the particle's morphology. To prevent the shell destruction, the agitation rate must be sufficiently low in case of the syntheses of micron-sized HPP. In this study, micron-sized HPP exhibiting the high hiding power and narrow particle distribution could be obtained.

• Journal of the Korean Applied Science and Technology
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• v.29 no.3
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• pp.393-401
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• 2012

Inorganic pigment is excellent at stability to human body and compatibility with different materials and has been used in a variety of field such as cosmetics, printing inks, paints, and construction materials for improving the aesthetic features. In this paper, hydrothermal synthesis method was used to prepare the manganese and iron dopped with titania pigment. As process parameters, the amount of manganese precursor and iron precursor, and calcined temperature was changed. Optimum amounts of manganese and iron dopped with titania precursor to give excellent color index was manganese 1.0wt% and iron 1.5wt% for dopped titania, and Optimum calcination temperature was $550^{\circ}C$. The synthesized pigments were analyzed by XRD, SEM, EDS, Spectrophotometer and UV-Vis Spectrometer.

• Proceedings of the KAIS Fall Conference
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• 2012.05a
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• pp.340-343
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• 2012

본 연구는 적외선 반사율 특성을 갖는 세라믹 블랙안료의 개발이며, 기능성안료를 건축내외장재에 적용하여 도심열섬현상 방지 및 에너지 효율을 높이는데 목적을 두고 있다. 세라믹안료의 색상은 Black을 합성하였으며, 각각 적외선 반사율과 내산성, 내열성 시험을 하여 색상변화를 측정하였다. 태양에너지의 측정파장영역 190~2000nm에서 TSR은 35.27%로 나타났으며, 내산성 시험 및 내열성 시험의 결과 거의 변색되지 않은 것을 알 수 있었다.

• Clean Technology
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• v.19 no.3
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• pp.257-263
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• 2013

The zinc phosphate-coated mica (ZP/mica) pigments were prepared using phosphoric acid, zinc nitrate and mica as starting materials, and used as anticorrosive pigments. The scanning electron microscopy (SEM) and x-ray diffraction (XRD) techniques were used to observe the morphology and crystal structure of prepared pigments. The prepared pigments were incorporated into an epoxy binder to prepare coating and the corrosion inhibition performance of the pigments was evaluated using electrochemical impedance spectroscopy (EIS). It was found that the anticorrosive performance of the ZP/mica pigment prepared at $70^{\circ}C$ was the better than that prepared at $20^{\circ}C$. The formation of ZnO, in addition to $Zn_3(PO_4)_2{\cdot}2H_2O$, was observed on ZP/mica pigment prepared at $70^{\circ}C$. The excellent anticorrosive performance of ZP/mica pigment could be ascribed to the synergistic effect with electrochemical anticorrosive mechanism from zinc compounds on mica and barrier anticorrosive mechanism from lamellar mica.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2010.06a
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• pp.274-274
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• 2010

안료의 색상은 출발원료의 조성, 입자크기 및 소결온도에 의한 결정구조 등에 의존한다. 본 연구에서는 Rutile구조를 갖는 세라믹안료인 $TiO_2-WO_3$-NiO의 합성에서 소결온도를 결정하기 위해 소결전 출발원료를 습식법에 의하여 Jar Mill에서 0.7-0.9um로 혼합분쇄한 후 $100^{\circ}C$에서 24시간 건조하였다. 건조후 $1100-1280^{\circ}C$에서 5구간을 선정하여 소결한 시료를 Jar Mill에서 0.8-1um로 분쇄한 후, 다시 $100^{\circ}C$에서 24시간 건조하였다. 이렇게 얻어진 시료를 XRD로 상합성 정도를 조사하고, 색상 및 착색력을 spectrophotometer를 분석하였다. 색상은 1150와 $1250^{\circ}C$에서 가장 좋은 Yellow 색상이 관찰되었으며, XRD에 의한 결정성의 분석결과와 비교적 일치하고 있다. Rutile구조를 갖는 세라믹안료의 색상은 소결시의 결정화도에 따라 민감하게 변화되고 있음을 알 수 있다.