• Title/Summary/Keyword: 합성변수

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A Experimental Study on the Compressive Capacity of Circular Section Wood using Synthetic Resins (합성수지를 이용한 원형단면 목재의 압축보강 성능에 관한 실험적 연구)

  • Park, Sung-Moo;Park, Kwang-Seob;Kang, Pyeong-Doo;Ha, Jong-Han
    • Journal of Korean Association for Spatial Structures
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    • v.9 no.3
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    • pp.93-100
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    • 2009
  • As interest in latest cultural heritance is increased, an importance about conservation of dilapidated cultural building asset is risen. Most of cultural building asset used wood by main material and conservation repair about corrosion and damage by deterioration of these cultural building asset considers cultural value of member and the basis principle is the archetype maintenance. Accordingly, conservation processing method that use synthetic is embossed. This paper experimented with reinforcement sectional area ratio, direction of section, length, strength of synthetic resins as variable and manufactures total 14 specimens as experimental study about compression reinforcement performance of circular section wood that strengthen by synthetic resins. The result of this paper has shown that adequate strengthen is more efficient than new member and the most important authenticity in strengthen and repair of cultural heritance can be ensured.

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Synthesis of Al-Doped ZnO by Microwave Assisted Hydrothermal Method and its Optical Property (마이크로파 수열합성법을 이용한 알루미늄이 도핑된 산화아연 합성 및 그 광학적 특성)

  • Hyun, Mi-Ho;Kang, Kuk-Hyoun;Lee, Dong-Kyu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.2
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    • pp.1555-1562
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    • 2015
  • Metal oxide semiconductors have been applied in several areas, such as solar cells, sensor, optical elements and displays, due to the high surface area, unique electrical and optical characteristics. Zinc oxide among the metal oxide has excellent physicochemical properties. Zinc oxide is a n-type semiconductor with a wide direct transition band gap of 3.37 eV at room temperature and large exciton binding energy of 60 meV. Cation-doped zinc oxide studies were conducted to complement the electrical and optical characteristics. In this paper, Al-doped ZnO was synthesized by hydrothermal synthesis using microwaves. ZnO was synthesized by adjusting the precursor ratio and using different dopants. The optimal ZnO synthesis conditions for crystal shape and optical properties were determined. The optical properties of aluminum doped zinc oxide were then examined by SEM, XRD, PL, UV-vis absorbance spectrum, and EDS.

Dynamic Behavior of 2D 8-Story Unbraced Steel Frame with Partially Restrained Composite Connection (합성반강접 접합부를 갖는 2차원 8층 비가새 철골골조의 동적거동)

  • Kang, Suk Bong;Lee, Kyung Taek
    • Journal of Korean Society of Steel Construction
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    • v.19 no.5
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    • pp.503-513
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    • 2007
  • The seismic responses of a building are affected by the connection characteristics that have effects on structural stiffness. In this study, push-over analysis and time history analysis were performed to estimate structural behavior of 2D eight-story unbraced steel structures with partially restrained composite connections using a nonlinear dynamic analysis program. Nonlinear $M-{\theta}$characteristics of connection and material inelastic characteristics of composite beam and steel column were considered. The idealization of composite semi-rigid connection as fully rigid connection yielded an increase in initial stiffness and ultimate strength in the push-over analysis. In time history analysis, the stiffness and hysteretic behavior of connections have effects on base-shear force, maximum story-drift and maximum moment in beams and columns. For seismic waves with PGA of 0.4 g, the structure with the semi-rigid composite connections shows the maximum story-drift with less than the life safety criteria by FEMA 273 and no inelastic behavior of beam and column, whereas in the structure with rigid connections, beams and columns have experienced inelastic behaviors.

Behavior of Composite Structure by Nonlinearity of Steel - concrete Interface (I) -Parametric Study for Nonlinear Model of Interface- (강·콘크리트 경계면의 비선형성에 따른 합성구조체 거동(I) -비선형 경계면 모델에 따른 매개변수 연구-)

  • Jeong, Youn Ju;Jung, Kwang Hoe;Kim, Byung Suk
    • Journal of Korean Society of Steel Construction
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    • v.15 no.5 s.66
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    • pp.499-507
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    • 2003
  • As the load is increased on the steel-concrete composite structure, its interface begins to show nonlinear behavior due to the reduction of interaction, micro-crack, slip and separation, and it causes slip-softening, Therefore, it is essential to consider the partial-interaction analysis technique. Until now, however, full-interaction or, in some instances, the linear-elastic model, which are insufficient to simulate accurate behavior, are assumed in the analysis of composite structure since the analysis method and nonlinear model for interface are very difficult and complicated. Therefore, the design of composite structure is followed by the experimental method which is inefficient-because a number of tests have to be carried out according to the design environments. In this study, we carried out the nonlinear analysis according to various interface nonlinear models by interaction magnitude, and analyzed more accurate structural behavior and performance by maximum tangential traction and slip-softening at the interface. As a result of this study. we were able to prove that the nonlinear model of interface more exactly represents behavior after yielding, such as ultimate load: that initial tangential stiffness of interface has a significant effect on the yielding load of structural members or part: and that the maximum tangential traction and slip-softening mainly effects structural yielding and ultimate load. Therefore, the structural performance of composite structure is highly dependent on the steel-concrete interface or interaction, which may result in initial tangential stiffness, maximum tangential traction and slip-softening in nonlinear model.

Analysis of Reinforcement Effect of Steel-Concrete Composite Piles by Numerical Analysis (II) - Bearing Capacity - (수치해석을 이용한 강관합성말뚝의 보강효과 분석 (II) - 지반 지지력 -)

  • Kim, Sung-Ryul;Lee, Si-Hoon;Chung, Moonkyung;Lee, Juhyung
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.6C
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    • pp.267-275
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    • 2009
  • The steel pipe of steel-concrete composite piles increases the pile strength and induces the ductile failure by constraining the deformation of the inner concrete. In this research, the load-movement relations and the reinforcement effect by the outer steel pipe in the steel-concrete composite pile were analyzed by performing three-dimensional numerical analyses, which can simulate the yielding behavior of the pile material and the elasto-plastic behavior of soils. The parameters analyzed in the study include three pile materials of steel, concrete and composite, pile diameter and loading direction. As the results, the axial capacity of the composite pile was 1.9 times larger than that of the steel pipe pile and similar with that of the concrete pile. At the allowable movement criteria, the horizontal capacity of the composite pile was 1.46 times larger than that of the steel pile and 1.25 times larger than that of the concrete pile. In addition, the horizontal movement at the pile head of the composite pile was about 78% of that of the steel pile and about 53% of that of the concrete pile, which showed that the movement reduction effect of the composite pile was significant and enables the economical design of drilled shafts.

Optimization of Enzymatic Synthesis Condition of Structured Lipids by Response Surface Methodology (반응표면분석에 의한 기능성 유지의 효소적 합성 조건 최적화)

  • Cho, Eun-Jin;Lee, Jong-Ho;Lee, Ki-Teak
    • Korean Journal of Food Science and Technology
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    • v.36 no.4
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    • pp.531-536
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    • 2004
  • Synthesis conditions were optimized using response surface methodology for producing structured lipids (SL) by interesterification of DHA-enriched algae oil derived from microalgae, Schizochytrium sp. and corn oil. Reaction was performed fer 24 hr at $55^{\circ}C$ catalyzed by immobilized lipase from Rhizomucor miehei (RM IM) in shaking water bath. Major fatty acids of SL were palmitic (21.70 mol%), oleic (20.20 mol%), and linoleic (27.34 mol%) acids, and DHA (15.06 mol%). To separate newly synthesized SL-triglycerides (TG) species, HPLC with evaporative light scatting detector (ELSD) was used. Production conditions were optimized using central composite design with reaction temperature $(35-75^{\circ}C,\;X_1)$, reaction time $(2-42\;hr,\;X_2)$, and enzyme concentration $(2-14%,\;X_3)$ as variables. When variables were $70.28^{\circ}C\;(X_1),\;28.74\;hr\;(X_2),\;and\;11.30%\;(X_3)$, maximum content of selected three peaks of synthesized SL-TG species was predicted as 6.97 area%.

The Economic Impact of the May 18 Democratic Uprising on the Regional Economy: A Synthetic Control Method (SCM) approach (5·18민주화운동이 지역경제에 미친 경제적 영향 분석: 통제집단합성법(SCM)을 이용한 접근)

  • Ryu, Deockhyun;Seo, Dongkyu
    • Analyses & Alternatives
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    • v.6 no.2
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    • pp.155-183
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    • 2022
  • The purpose of this study is to econometrically analyze the negative impact of the May 18 Democratic Uprising on the Gwangju/Jeonnam regionional economy using the Synthetic Control Method (SCM). The SCM SCM is a methodology similar to the difference-in-difference(DID) method of microeconometrics. It is applied to macroeconomic variables such as country, region, etc. to estimate the causal relationship between specific events and the dependent variable. In this study, as of 1980, local tax revenue data of metropolitan local governments were used as a proxy variable for the economy of the region, and the impact of the May 18 Democratic Uprising on the economy of Gwangju/Jeonnam region was analyzed through various socio-economic indicators. In this study, data were used to analyze from 1971 to 2000, and as a result of empirical analysis, local tax revenues in Gwangju/Jeonnam area were less collected than normal routes up to 17%. In addition, the significance of this analysis was confirmed through in-time placebo effect analysis and in-space placebo effect analysis, which are methods of analyzing the robustness of the control group synthesis method.

Effect of Nano-sized Calcium-silicate-hydrate (C-S-H) Crystals on Cement Hydration (나노 크기 칼슘-실리케이트-하이드레이트(C-S-H) 결정이 시멘트 수화에 미치는 영향 분석)

  • Gyeong-Tae Kim;Su-Ji Woo;Sung-Won Yoo;Young-Cheol Choi
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.2
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    • pp.153-160
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    • 2023
  • In this study, nano-sized C-S-H crystals were synthesized using the liquid phase reaction method and their properties were investigated. The synthesized C-S-H crystals were added to the cement composite in suspension form to determine their effect on the hydration properties of the cement. The amount of chemical admixture was varied to obtain nano-sized C-S-H crystals with optimal agglomerated morphology, and SEM photographs were analyzed. A cleaning process was added to remove harmful substances other than the synthesiz ed C-S-H crystals. It was found that the concentration of harmful substances was reduced in the case of C-S-H crystals subjected to the cleaning process. The synthesized C-S-H suspensions were prepared with and without the cleaning process, and cement composites were prepared with the cement weight content as the main variable. The effect of C-S-H crystals on the initial hydration properties of the cement was confirmed by microhydration heat analysis. In addition, mortar specimens were prepared to measure the compressive strength over time. The test results showed that the nano-sized C-S-H crystals act as nucleation sites in the cement paste to promote the early hydration of the cement and increase the early compressive strength.

Experimental and Numerical Study of Fire Resistance of Composite Beams (무피복 합성보의 내화성능에 대한 실험 및 해석적 연구)

  • Ahn, Jae Kwon;Lee, Cheol Ho
    • Journal of Korean Society of Steel Construction
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    • v.27 no.2
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    • pp.143-153
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    • 2015
  • In this paper, the standard fire resistance test under load and associated numerical study were carried out to evaluate the fire resistance of unprotected partially encased beams and slimfloor beams. The temperature evolution and the deflection increase of the composite beam specimens were investigated and the effects of the key behavioral parameters including the load ratio, the reinforcement, and the fire exposure were analyzed. The test results showed that the temperature rise of the partially encased beams and slimfloor beams is considerably slow compared to the conventional H-shape composite beams. Up to at least 90 minutes, the reinforcements in the partially encased composite beams maintained below the temperature at which the cold steel strength is sustained. Unprotected partially encased beams and slimfloor beams in the experimental program achieved the fire resistance more than 2 hours according to the limiting deflection criteria. This implies that unprotected partially encased beams and slimfloor beams can be very promising alternatives to enhancing the fire resistance of steel beams. This study also conducted the fully coupled thermal-stress analysis by using the commercial code ABAQUS to the thermal and structural behaviour of composite beams in fire. The numerical predictions provide acceptable correlations with the experimental results.

Analyzing Operational Efficiency of GTL Reforming Process by using Aspen Plus (Aspen Plus를 이용한 GTL Reforming 공정별 운전효율 비교)

  • Bae, Jihan;Kim, Yongheon;Kim, Jaeho
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.143-143
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    • 2010
  • GTL(Gas-to-Liquids)공정 중 합성가스 제조공정(Reforming Process)인 ATR(Auto-Thermal Reforming), SCR(Steam Carbon Reforming), POx(Partial Oxidation)의 시뮬레이션 연구를 수행하였다. Reforming 공정에서 생산된 합성가스는 GTL 합성유 제조공정인 FT(Fischer-Thropsch) 반응기로 주입되며, 합성유 생산에 최적의 효율을 보이는 H2/CO 비(합성가스에 포함된 반응물비)는 2.0으로 알려져 있다. FT공정은 합성가스를 원료로 고온 및 고압 반응을 거쳐 GTL 공정의 최종 생산품인 FT합성유를 제조하는 공정이다. 본 연구에서는 FT공정 효율 극대화를 위해 reforming 공정에서 생성되는 합성가스 내 H2/CO의 비를 2로 수렴토록 모사조건을 설정하였으며, 상기 조건을 만족하는 reforming 공정들의 운전 온도 및 feed 조성을 분석하고 비교하고자 한다. 현재 GTL 플랜트관련 산업계에 적용 혹은 주 연구대상인 reforming 공정으로는 ATR, SCR, POx 공정이 있다. ATR 공정은 $850{\sim}1100^{\circ}C$에서 메탄, 스팀 및 산소를 원료로 활용하여 H2 및 CO를 생산하는 공정으로 발열/흡열 반응이 상존하여 에너지 비용이 낮지만 공정구조 상 열회수설비 및 ASU(Air Separation Unit)이 필요하기에 CAPEX(초기설비 설치비용)가 높은 편이다. SCR공정은 CH4, Steam 및 CO2를 연료로 하기에 이산화탄소가 일정부분 포함된 가스전에도 적용이 가능하나 공정 운전 중 지속적으로 외부에서 열을 공급해야 하기에 에너지 투입비용이 높은편이며, 탄소침적의 문제가 있어 대용량 플랜트에는 적합하지 않다. POx공정은 약 $1,500^{\circ}C$의 고온에서 CH4가 O2에 의해 부분 산화되는 방식으로 촉매가 필요없어 설비비가 타 공정에 비해 저렴하나 생산가스의 H2/CO비가 다소 낮아 전체적인 GTL 공정효율이 저하되는 단점이 있다. 상기 세 공정은 GTL 산업계에서 실증 및 효율증대를 위해 주로 연구되는 공정이기에 본 연구의 분석대상으로 설정하였다. 본 연구에서는 상용공정모사기인 Aspen Plus를 활용하여 reforming 공정별로 FT합성공정의 최적 조건(H2/CO=2)을 만족하는 합성가스 생산조건 분석 및 비교를 수행할 예정이다. 운전조건인 공정 운전온도 및 feed 가스조성 등을 모사하기 위해 합성가스 reforming 공정을 모델링하고 공급유량 및 압력 등의 운전변수는 GTL국책과제 1단계 연구수행 결과를 토대로 선정하고자 한다. GTL공정의 경우, 설비의 운전조건이나 연료가스의 구성 및 유량에 따라 적합한 reforming 공정이 다르기에 본 시뮬레이션 결과를 향후 GTL 플랜트 공정모델 설계시 reforming 공정선정에 참고자료로 활용하고자 한다.

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