• Title/Summary/Keyword: 함유된 철의 양

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Investigation of useful components in soybean seeds: Purification and characterization of soybean ferritin (콩 유용성분 탐색에 관한 연구: 콩 Ferritin의 정제 및 특성)

  • Seo, Kyung-Won;Oh, Suk-Heung
    • Applied Biological Chemistry
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    • v.41 no.7
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    • pp.522-526
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    • 1998
  • Ferritin from germinated soybean seeds was purified by ammonium sulfate precipitation (0.55 saturation), ion-exchange chromatography on DEAE-cellulose, gel filtration chromatography on Sephacryl S-300, and HPLC with Bio-Scale Q2 column. SDS-PAGE analysis showed that the purified ferritin is composed of subunit with an apparent M, 21,000. The molecular mass of the native soybean ferritin estimated by gel filtration on Sephacryl S-300 and non-denaturing polyacrylamide gel electrophoresis appeared to be $510{\sim}560\;kDa$. Soybean ferritin contained 833 mol Fe/mol protein, which is 31-fold more iron than pumpkin ferritin and stained positive for iron on non-denaturing gel. Soybean ferritin cross-reacted with anti-soybean rabbit ferritin antiserum.

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Development of a new engobe for raku ceramics (적색 RAKU 도자기의 화장토 개발에 관한 연구)

  • Kwon, Young Joo;Hwang, Dong Ha;Lee, Byung Ha
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.1
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    • pp.21-26
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    • 2014
  • Red clay has been used for making rakuyaki for the past 400 years. Because the resources for red clay in Japan are being depleted, many potters in Japan began to develop new materials which can replace red clay. In this study, It is analyzed that the chemical and physical properties of red clay from Shigaraki (Shiga, Japan), and developed a novel engobe which can be used for making Rakuyaki instead of Shigaraki red clay. Results from Raman spectroscopic examination showed that ferric oxide content in Shigaraki red clay is 9.4 % (Goethite 5 %, Wustite 4.4 %), and that the mechanism of red color development by the firing at $900^{\circ}C$ for 10 min is the chemical transformation of Goethite into Hematite, and the subsequent formation of solid solution with Alumina and Silica. To make similar ferric oxide content to that of Shigaraki red clay, we added 5 g of Goethite and 9 g of Wustite to 100 g of White kaolin from Hadong area (Gyeongsangnam-do, Korea). The $L^*a^*b^*$ color scale of the mixture was 56.83, 27.22, and 23.28, respectively, and stable red color was successfully developed under the same firing condition used for Shigaraki red clay.

Seasonal variations of nutrients in Korean fruits and vegetables : Examining water, protein, lipid, ascorbic acid, and ${\beta}-carotene$ contents (한국인 상용 과일과 채소의 계절별 영양성분 변화 : 수분, 단백질, 지방, 아스코르브산, 베타-캐로틴 함량)

  • Kim, Mee-Jeong;Kim, Ju-Hyeon;Oh, Hyun-Kyung;Chang, Moon-Jeong;Kim, Sun-Hee
    • Korean journal of food and cookery science
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    • v.23 no.4 s.100
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    • pp.423-432
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    • 2007
  • The purpose of this study was to investigate the seasonal variations in water, protein, lipid, ascorbic acid, and ${\beta}-carotene$ contents of 17 vegetables and 4 fruits that are available all the year round and frequently consumed by Koreans. The water contents of the fruits ranged from 83-89%, and the vegetables contained more water than the fruits. The apples and pears had more water in the spring and summer than in the fall and winter. The tangerines showed a high water content in the winter, whereas the strawberries contained more water in the fall. The vegetables also showed seasonal variations in water content. The protein contents of the fruits were lower than 1%; the cucumbers contained 0.1% protein, which was the lowest level, but spinach, lettuce, bean sprouts, sesame leaves, and mushrooms had more than 1% protein. The ascorbic acid and ${\beta}-carotene$ contents of the apples, pears, and tangerines were higher in the fall and winter than in the spring and summer. The vegetables, in general, contained more ascorbic acid than the fruits. The cabbage and radishes showed higher ascorbic acid contents in the fall and winter than in the spring and summer, indicating that vegetables as well as fruits are more nutritious during their harvest season. The zucchini, spinaches, and green peppers had higher ${\beta}-carotene$ contents in the winter than in the other seasons. The above results show that there were seasonal differences in the ascorbic acid and ${\beta}-carotene$ contents of the fruits and vegetables. In addition, the fruits and vegetables had a tendency to contain more ascorbic acid and ${\beta}-carotene$ in the season they were harvested. Therefore, we recommend the consumption of those fruits and vegetables during their harvest season.

Development and Performance Evaluation of X-Ray Shields using Fe2O3 and Al2O3 (산화철, 알루미나를 이용한 X선 차폐체 개발 및 성능 평가)

  • Hui-Su, Yang;Ji-Hwan, Kim;Min-Cheol, Jeon
    • Journal of Advanced Technology Convergence
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    • v.1 no.2
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    • pp.19-25
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    • 2022
  • It is intended to evaluate the performance of the shield after manufacturing a shield with cheap and eco-friendly iron oxide and alumina instead of lead, which is a radiation shielding material. After manufacturing the shield by mixing iron oxide and alumina with gypsum, the performance is evaluated by comparing it with gypsum board and lead apron using an X-ray tube. As a result of the experiment, the shielding performance of alumina was lower than that of the gypsum board, and when 50% of alumina was contained, the shielding performance was similar to that of the gypsum board. Iron oxide became similar to the shielding performance of lead apron when it contained about 75%. A shielding material using alumina shows shielding performance similar to that of gypsum, so it is not suitable as a substitute for lead. However, since iron oxide exhibits similar shielding performance to lead, it can be used as an X-ray shielding material to replace lead in the future, so further research is needed.

A study to reduce the intestinal transport of endosulfan by indole (인돌을 이용한 잔류성 농약 endosulfan의 소장 흡수 억제 연구)

  • Gong, Daecheol;Kim, Juyeon;Choi, Hansol;Noh, Sang Kyu
    • Food Science and Preservation
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    • v.21 no.1
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    • pp.91-96
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    • 2014
  • Evidence suggests that dietary indole, particularly rich in cruciferous vegetables, may reduce the risk of cardiovascular diseases. Endosulfan is a residual organochlorine pesticide, which is detected in fruits, vegetables, and crops. In this study, we investigated the effect of luminal indole on endosulfan transport in the small intestine in mesenteric lymph duct-cannulated rats. The duodenum was also cannulated and a fasting phosphate buffered saline-glucose solution was infused overnight at 3 mL/hr. After recovery, a lipid emulsion containing [2,3-$^{14}C$] endosulfan ($^{14}C$-endosulfan) was infused into the duodenum for 8 hours. The tested rats were infused with the same lipid emulsion, but with indole. Samples from the lymph-fistula were collected hourly, and the luminal contents and mucosa were collected at the end of the infusion. The lymph flow in the mesenteric lymph did not differ between the two groups. However, the intestinal absorption of both endosulfan and cholesterol were significantly decreased by indole. The amount of radioactive endosulfan, which remained in the mucosa, was greater in the indole-infused rats due to the decreased transport of endosulfan into the lymph. This study indicates that the indole decreases the intestinal transport of endosulfan into the mesenteric lymph.

Preparation of Iron-Coated Sand and Arsenic Adsorption (철코팅 모래흡착제 제조 및 비소흡착)

  • Chang, Yoon-Young;Kim, Kwang-Sub;Jung, Jae-Hyun;Lee, Seung-Mok;Yang, Jae-Kyu;Park, Joon-Kyu
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.7
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    • pp.697-703
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    • 2005
  • Iron-coated sand(ICS) was prepared with variation of particle size of Joomoonjin sand, primary and secondary coating temperature, coating time, and dosage of initial Fe(III). An optimum condition of the preparation ICS was selected from the coating efficiency, stability of coated Fe(III), and removal efficiency of As(V). Coated amount of Fe(III) increased as primary coating temperature increased with smaller particle size of sand. Coating efficiency was quite similar over the investigated secondary coating temperature and time, while adsorption efficiency of As(V) onto ICS was severely reduced with ICS prepared at higher secondary coating temperature. By considering these results, an optimum secondary coating temperature and time for the preparation of ICS was selected as $150^{\circ}C$ and 1-hr, respectively. Coating efficiency increased us the dosage of initial Fe(III) up to 0.8 Fe(III) mol/kg sand and then no distinct increase was noted. Maximum As(V) adsorption was observed at 0.8 Fe(III) mol/kg sand. Secondary coating temperature and time were important parameters affecting stability of ICS, showing decreased dissolution of Fe(III) from ICS prepared at higher coating temperature and at longer coating time. From anionic type adsorption of As(V) onto ICS, it is possible to suggest the application of ICS for the removal of As(V) contaminated in acidic water system.

Efficient bio-gas desulfurization purification technology development Using ion-exchange fibers (이온교환섬유를 이용한 바이오가스 고효율 탈황정제기술 개발)

  • Tak, Bong-Yeol;Tak, Bong-Sik;Min, Gil-Ho;Lee, Sang-Min;Lee, Won-Gu;Lee, So-A
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.116-116
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    • 2011
  • 바이오 가스 플랜트의 혐기소화 공정에서 발생하는 바이오 가스는 중 유해가스인 황하수소($H_2S$)는 부식성 가스로 수천 PPM농도를 함유하여, 발전기나 가스보일러로 이용하는 경우에는 $H_2S$를 제거하는 탈황공정이 반드시 필요하다. 탈황방식에는 산화철 탈황(건식 탈황)과 생물 탈황이 현재 많이 사용되고 있어나 산화철 탈황은 산화철 pellet이 유화철에 변화하면 탈황능력이 저하되어 pellet을 교환해야 하며 많은 비용이 발생한다. 생물 탈황 방식은 유황산화세균의 서식활동조건(온도, 반응시간, 산소량)확보가 반드시 필요하여 높은 운전기술을 필요로 한다. 본 연구에서는 바이오가스 전처리 기술 중 활성탄 또는 약액을 이용한 기존의 탈황정제방식보다 흡착성능이 뛰어난 이온교환섬유를 이용하여, 황화수소($H_2S$)를 95% 이상 제거할 수 있는 고효율 섬유상 이온촉매 악취제거 시스템 개발을 수행하였다. 이온교환섬유는 방사선 조사를 이용하여 부직포에 라디칼을 인위적으로 형성시켜(그라프트 중합) 양이온 또는 양이온을 교환할 수 있도록 제조된 섬유상의 흡착제로, 이온교환 섬유의 화학적 이온교환과 물리적 흡착 및 탈착반응이 동시에 발생되고, 활성탄/실리카켈 보다 흡착능력이 2~4배 높다. 또한 이온섬유의 재생기능을 이용하여 장기적 다양한 악취($H_2S$, $NH_3$, 아민계, 메르갑탄류, 알데히드 등) 및 유해가스(VOCs, NOx, SOx) 등을 95% 이상 제거할 수 있다.

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Preparation and Effect of Eudragit E100 Microcapsules Containing Grapefruit Seed Extract on Kimchi (자몽씨 추출물을 함유한 Eudragit E100 미세캡슐의 제조 및 김치에 대한 영향)

  • 김한수;정성기;조성환;구재관;이승철
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.32 no.8
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    • pp.1239-1244
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    • 2003
  • Microcapsules were prepared by coacervation method using acetone/liquid paraffin system to control the ripening of kimchi. Eudragit E100, which was soluble at below pH 5.0 in aqueous solution, was used to make microcapsules to be sensitive to acidity of kimchi. The microcapsules with Eudragit E100 containing grapefruit seed extract (GFSE) showed the highest yield of 92.13%, the size of microcapsules was decreasing as increasing the amount of aluminium stearate, a dispersing agent. Morphology of the microcapsules determined by scanning electron microscopy showed spherical forms. GFSE, encapsulated antimicrobial agents, was quickly released at acidic buffer (pH 4,5,6) within 1 storage day. However, 70% of encapsulated GFSE in Eudragit E100 microcapsules was continuously released at pH 7 till 3 days, and it was sustained till 9 days. Characteristics of kimchi containing microcapsules of GFSE were analysed with ripening period. Decease of pH in kimchi was retarded with the added GFSE microcapsules till 2 days of fermentation, but GFSE did not affect pH in kimchi after 3 days. Total numbers of microorganisms and lactic acid microorganisms in kimchi were decreased with increasing the amount of the added GFSE microcapsules, however, the effect of controlled released GFSE from pH sensitive Eudragit E100 microcapsules was hard to detect. These results suggest the possibility of pH sensitive microcapsules for high qualify of kimchi.

Mössbauer and Infrared Absorption Spectroscopy of Tourmaline Minerals (전기석 광물의 뫼스바우어 및 적외선 흡수 분광학)

  • Kim, Hee Jong;Kim, Soo Jin
    • Journal of the Mineralogical Society of Korea
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    • v.6 no.2
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    • pp.105-115
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    • 1993
  • $M{\ddot{o}}ssbauer$ and Infrared absorption spectra of the iron-bearing tourmaline minerals show that the ferrous and ferric ions occupy the Y and Z octahedral sites. The Fe ions are almost ferrous, predominantly partitioning into Y site and partly take in Z site. The $Fe^{2+}$ content of the Z sites in brownish black tourmaline minerals are higher than that in blue/green tourmaline minerals. Therefore, 720 nm peak of brownish black samples is broader than that of blue/green samples in optical spectra. All of the blue/green tourmaline minerals used in experiment have only $Fe^{2+}$ ion. The IR spectra of tourmaline depend on the cation environments around OH groups, as also evidenced by their chemical analyses. There appear no difference in IR spectrum between O(1)H and O(3)H binding characters in the heat-treated samples. But the characteristic $3565cm^{-1}$ peak appears in the ferrous hydroxyl bearing silicates, where dehydroxylation temperature for OH coordinated to $Fe^{2+}$ is $700{\sim}800^{\circ}C$.

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Mineralogical and Geochemical Characteristics of Soils of Barton Peninsula, King George Island, South Shetland Islands, West Antarctica (서남극 사우스셰틀랜드 킹조지섬 바톤반도 육상 토양의 광물학적, 지화학적 특성)

  • Jung, Jaewoo;Koo, Taehee;Yang, Kiho;Kim, Jinwook
    • Journal of the Mineralogical Society of Korea
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    • v.30 no.1
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    • pp.21-29
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    • 2017
  • Surface soils on Barton Peninsula, King George Island, West Antarctica were investigated to acquire the mineralogical and geochemical data of soil in Antarctica. Multiline of techniques for example, X-ray diffraction (XRD), transmission electron microscopy (TEM)-electron energy loss spectroscopy (EELS), and wet chemistry analysis were performed to measure the composition of clay minerals, Fe-oxidation states, cation exchange capacity, and total cation concentration. Various minerals in sediments such as smectite, illite, chlorite, kaolinite, quartz and plagioclase were identified by XRD. Fe-oxidation states of bulk soils showed 20-40% of Fe(II) which would be ascribed to the reduction of Fe in clays as well as Fe-bearing minerals. Moreover, redox states of Fe in smectite structure was a ~57% of Fe(III) consistent to the values for the bulk soils. The cation exchange capacity of bulk soils ranged from 100 to 300 meq/kg and differences were not significantly measured for the sampling locations. Total cations (Mg, K, Na, Al, Fe) of bulk soils varies, contrast to the heavy metals (Co, Ni, Cu, Zn, Mn). These results suggested that composition of bed rocks influenced the distribution of elements in soil environments and soils containing clay compositions may went through the bio/geochemical alteration.