• Title/Summary/Keyword: 한국 제4기학회

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Synthesis and Characterization of Polymers with the Moiety of m-Cresol as a Microbicide (항균제로서 m-크레졸의 Moiety를 가지는 고분자의 합성과 특성)

  • 김우식;현석희;이동호;민경은;박이순
    • Polymer(Korea)
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    • v.26 no.3
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    • pp.293-299
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    • 2002
  • By the reaction of m-cresol as a microbicide with acryloyl chloride m-cresyl acrylate (CA) was synthesized, and polymers with the moiety of m-cresol were prepared by the radical terpolymerization of CA -methylmethacrylate -acrylic acid. The contents of CA unit in the polymers were found to be 4.7 mol% and 10.1 mol% from their nuclear magnetic resonance spectra. The number -average molecular weights of the polymers were in the range of 12000 to 15000. Through the hydrolysis of the polymers m-cresol was released. The release rate of the microbicide increased with increasing PH of the release medium. This result can be attributed to enhanced proton dissociation of carboxyl group of the acrylic acid unit in the polymers. These polymers showed microbicidal activities for S. aureus as a positive microbe and E. coli as a negative microbe.

Computational Analysis of an LOx Supply Line System of an Liquid Rocket Engine (액체로켓엔진 산화제 배관 시스템 전산유동해석)

  • Moon, In-Sang;Moon, Il-Yoon;Lee, Soo-Yong
    • Journal of Astronomy and Space Sciences
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    • v.26 no.4
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    • pp.693-702
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    • 2009
  • A computational fluid analysis was performed on an LOx line system of a liquid rocket engine. The model was created with 3D CAD and imbedded to the 3D CFD program. Before the full scale analysis on the system was carried out, each components with simplified models was analyzed to save time and cost. As a result, the inlet pressure of the gas generator should be compensated with a certain device unless the inlet pressure of the line system is sufficiently high. The flow pattern of the exit of the system was dependant upon the location of the orifice as well as the size. As a whole the line system analyzed met the requirements, and will be tested and confirmed after being manufactured.

Reduction of Nitrotoluenes and Simultaneous Removal of Hydrogen Sulfide and Nitrotoluenes by Co3+-centered Hematoporphyrin (포피린의 촉매작용에 의한 니트로톨루엔의 환원 및 니트로톨루엔과 황화수소의 동시 제거)

  • Cho, Jeong-Guk;Kang, An-Soo
    • Applied Chemistry for Engineering
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    • v.5 no.1
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    • pp.37-43
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    • 1994
  • Mononitrotoluenes were reduced to aminotoluenes using porphyrin as a catalyst in the presence of several types of reductants including hydrogen sulfide and 1, 4-dithiothreitol(DTT). Intermediates and final products of porphyrin-catalyzed reduction of mononitrotoluenes were identified and a pathway for the reduction of the nitro group to the corresponding amino group was proposed. The optimum pH for the reduction was determined. The catalytic activity of the porphyrin was confirmed by UV/VIS absorption spectra and basic kinetics of porphyrin-catalyzed reduction were studied. Of several types of reductants tested, DTT sodium hydrosulfite, and hydrogen sulfide were seen to give significant reduction of nitrobodies. When hydrogen sulfide was used as a reductant hydrogen sulfide and nitrotoluenes were removed simultaneously.

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REARING OF THE LARVAL PRAWN, PENAEUS JAPONICUS BATE (보리새우 Penaeus japonicus Bate의 유생사육에 관하여)

  • PYEN Choong-Kyu
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.2 no.1
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    • pp.87-91
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    • 1969
  • Experiments on the rearing of larvae of the prawn, Penaeus japonicus Bate, have been con-ducted by using a large tank A ($3.4\times1.9\times1.0m$) and two small tanks B and C ($1.45\times0.85\times1.0$). 1) Between spawning and the first zoeal stages, no significant elapsed time difference was noticed among the rearing tanks. At about $23^{\circ}C$ of water temperature nearly all of the larvae in the tanks metamorphosed into the first zoeal stage in about 36-48 hours. However the period of time which elapsed between the spawning and post-larval stage showed some differences bet-ween the tanks, i.e., 19-20 days in tank A and 15-17 days in tanks B and C, respectively 2) No difference in body length of the larvae has been observed among the three tanks. 3) The post-larva passed through several molts, one every four or five days, before reaching the young prawn about 36-40 days after spawning. 4) Throughout the zoeal stages the highest mortality was found at the time of molting between the first and second zoeal stages showing about $51.39\%$ in tank A, $50.70\%\;and\;31.91\%$ in tanks B and C, respectively. 5) Total mortality during the duration of the larval stages was around $75\%$ in all the rearing tanks.

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Effect of Surfactant Addition on Se Absorption and Growth of Pak-choi and Leaf Lettuce in Hydroponics (수경 재배 시 계면 활성제 첨가가 상추와 청경채의 생육과 Se 흡수에 미치는 영향)

  • Yuna, Hyung-Kwon;Seo, Tae-Cheol;Zhang, Cheong-Hao;Chun, Chang-Hoo
    • Journal of Bio-Environment Control
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    • v.18 no.2
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    • pp.124-131
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    • 2009
  • Surfactant polyvinyl alcohol (PVA-95) 1, 2, 4mg. $L^{-1}$ and calcium lignosulfonate (CLS) 5, 25, 50, 100mg. $L^{-1}$ were treated to the nutrient solution containing 1.0mg. $L^{-1}$ selenium (Se) to evaluate Se absorption effect using small DFT apparatus. The growth of leaf lettuce and pak-choi did not show unique significance by surfactant kinds and concentration in the tested range and physiological disorder. Vitamin C in leaves of two leafy vegetables was not significantly affected by surfactants also. Among major cations K content in pak-choi was highest in Se I+PVA-95 4mg. $L^{-1}$ treatment, and high in Se I+CLS 5 mg. $L^{-1}$ treatment. Ca content in two leafy vegetables showed increasing pattern by the two kinds of surfactants. Mg content was high in Se I+CLS 25mg. $L^{-1}$ treatment compared to control. Pak-choi absorbed Se about 10 times higher than leafy lettuce. Se content in leaves of two leafy vegetables increased by the treatment of two kinds of surfactants with the exception of CLS 100mg. $L^{-1}$ treatment.

Fundamental Study on the Strength Development of Cement Paste using Hardening Accelerator and High-Early-Strength Cement (경화촉진제와 조강시멘트를 사용한 시멘트 페이스트의 강도발현에 대한 기초적 연구)

  • Min, Tae-Beom;Cho, In-Sung;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.13 no.4
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    • pp.407-415
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    • 2013
  • The purpose of this research is to verify the performance of hardening accelerator in cement paste through mechanical performance evaluation and micro structure analysis on hardening accelerator for development of super high early strength concrete. The research results showed that hardening accelerator produced $Ca(OH)_2$ when hydrated with cement, enhancing the degree of saturation of Ca ion by using differential thermal analysis. Moreover, porosity was reduced rapidly as capillary pores were filled by hydration products of $C_3S$. According to the experiment using hydration measurement testing, when 1% and 3% of accelerator were mixed, hydration rate increased toward the second peak point compared to high early strength cement, before the first peak point disappeared. It turned out that adding accelerator accelerated the hydration rate of cement, especially $C_3S$. The shape of C-S-H is shown depending on the amounts of accelerator added and the production and age of $Ca(OH)_2$ by using SEM to observes hydration products. Therefore, it's evident that hardening accelerator used in this research increases amounts of $Ca(OH)_2$ and accelerates $C_3S$, it is effective for the strength development on early age.

Robust Control of IPMSM Using T-S Fuzzy Disturbance Observer (T-S 퍼지 외란 관측기를 이용한 IPMSM의 강인 제어)

  • Kim, Min-Chan;Li, Xiu-Kun;Park, Seung-Kyu;Kwak, Gun-Pyong;Ahn, Ho-Kyun;Yoon, Tae-Sung
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.19 no.4
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    • pp.973-983
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    • 2015
  • To improve the control performance of the IPMSM, a novel nonlinear disturbance observer is proposed by using the T-S fuzzy model. A T-S fuzzy model is the combination of local linear models considered at each operating point. Usually the inverse model is easy to obtain in linear systems but not in nonlinear systems. To design a nonlinear disturbance observer, a nonlinear inverse model is obtained based on nonlinear inverse model which is the fuzzy combination of the local linear inverse models. The proposed DOB is used with a PDC controller which is one of the T-S fuzzy controller, and its performance improvement is shown from the simulation results.

Design of SIR-based Bandstop Filter with Symmetrical Hairpin Wideband (SIR 기반 대칭 헤어핀 광대역 대역저지 여파기)

  • Kim, Chang-Soon;Lee, Yong-IL
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.18 no.1
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    • pp.43-46
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    • 2018
  • This paper has designed a wideband bandpass filter (WBSF : Wide Band Stop Filter) using a stepped impedance resonator (SIR : Stepped Impedance Resonator) with improved performance and improved hairpin coupling structure. The SIR WBSF is small in size and has the advantage of having excellent bandstop characteristics. The designed BSF has a structure in which a quadrangular shaped hairpin of a / 4 length is arranged symmetrically on the upper and lower sides of the input and output transmission lines. The input and output terminals were terminated at 50 ohms for system applications. The center frequency of the SIR WBSF is 6.3 GHz, which is the second harmonic of 3.15 GHz. The designed filter has a 3dB bandwidth of 2.9 GHz and a transmission coefficient ($S_{21}$) of 33.2 dB. The reflection coefficient ($S_{11}$) at the center frequency is 0.106 dB. The application field is used for fixed microwave relay stations, fixed satellite and earth stations, and fixed satellite communications. The overall size is $20mm{\times}10mm$.

The change of East Asian Monsoon to $CO_2$ increase

  • Kripalani, R.H.;Oh, J.H.;Chaudhari, H.S.
    • The Korean Journal of Quaternary Research
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    • v.20 no.1 s.26
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    • pp.9-27
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    • 2006
  • The East Asian (China, Korea and Japan) summer monsoon precipitation and its variability are examined from the outputs of the 22 coupled climate models performing coordinated experiments leading to the Intergovernmental Panel on Climate Change Fourth Assessment Report (IPCC AR4) following the multi-model ensemble (MME) technique. Results are based on averages of all the available models. The shape of the annual cycle with maximum during the summer monsoon period is simulated by the coupled climate models. However, models fail to simulate the minimum peak in July which is associated with northward shifts of the Meiyu-Changma-Baiu precipitation band. The MME precipitation pattern is able to capture the spatial distribution of rainfall associated with the location of the north Pacific subtropical high and the Meiyu-Changma-Baiu frontal zone. However precipitation over the east coast of China, Korea-Japan peninsular and the adjoining oceanic regions is underestimated. Future projections to the radiative forcing of doubled $CO_2$ scenario are examined. The MME reveals an increase in precipitation varying from 5 to 10 %, with an average of 7.8 % over the East Asian region at the time of $CO_2$ doubling. However the increases are statistically significant only over the Korea-Japan peninsula and the adjoining north China region. The increase in precipitation may be attributed to the projected intensification of the subtropical high, and thus the associated influx of moist air from the Pacific to inland. The projected changes in the amount of precipitation are directly proportional to the changes in the strength of the subtropical high. Further a possible increase in the length of the summer monsoon precipitation period from late spring through early autumn is suggested.

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Synthesis and Anti-corrosion Properties of Succinic Acid Alkyl Half-Ester Derivatives (숙신산 알킬 하프-에스테르 유도체의 합성 및 해수에 대한 방청성능)

  • Baek, Seung-Yeob;Kim, Young-Wun;Chung, Keun-Wo;Yoo, Seung-Hyun
    • Applied Chemistry for Engineering
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    • v.22 no.4
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    • pp.367-375
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    • 2011
  • Succinic acid ester derivatives have been used as additives for the base oil of metal working fluids and pressure working oils. In this paper, a series of succinic acid alkyl half-esters were synthesized with over 97% yields by ring-opening reaction of succinic anhydride and fatty alcohol and were soluble in 100 N base oil within 1 wt% concentration. The structures and purities of ester derivatives were confirmed by $^1H-NMR$ and FT-IR spectrum and GC analysis. Anti-corrosion properties of the esters in sea water were evaluated through ASTM D665 method and weight loss method and compared to that of succinic alkyl esters without carboxylic acid group in the molecule. As the results, anti-corrosion properties of succinic acid alkyl half-esters with carboxylic acid group were better than those of succinic acid alkyl esters without carboxylic acid group. And, Anti-corrosion properties of the esters with a shorter alkyl chain of high concentration showed better performance than those with longer alkyl chain of low concentration. Inhibition efficiency % (IE%) of the esters was over 95% in the concentration of 80 ppm and corrosion rate (CR) was below 0.3 mm/year at the same concentration. Thus, the corrosion properties of succinic acid alkyl half-esters result from the carboxylic acid groups in molecules.