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PMMA와 TRT전사을 이용한 그래핀의 전기적 특성 비교

  • Min, Jeong-Hong;U, Jeong-Min;Lee, Dong-Seon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.285-286
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    • 2012
  • 육각형 구조를 지닌 2차원의 물질인 그래핀은 우수한 전도도와 투과율로 투명전극의 신소재로 각광 받고 있다. 특히, 그래핀은 현재 투명전극으로 가장 많이 사용되고 있는 Indium Tin Oxide(ITO)로는 구현하기 힘든 Flexible display의 어플리케이션으로 사용하기 위한 목적으로 많은 기술 개발이 이루어지고 있다. 이러한 그래핀의 응용은 가장 먼저 그래핀의 생산이 안정적이고 원활히 이루어질 때 실질적으로 가능할 것이다. 하지만, 탄소로 이루어진 그래핀의 성장은 제한된 기판 위에서만 가능하기 때문에 성장이 이루어진 그래핀을 다른 기판에 전사시켜야하는 문제점이 있다. 그래핀 전사방법에는 직접전사, PMMA 전사, TRT 전사, 금속전사, 망전사, PDMS 전사 등 다양한 방법이 있다. 이 중에서 현재 가장 많이 사용되고 있는 전사방법으로는 직접전사, PMMA 전사, TRT 전사 방법이 있다. 직접전사의 경우 니켈위에 성장된 다층의 그래핀을 전사시킬 때 많이 사용되는 방법으로 니켈 에천트에 전사 시킬 그래핀을 띄워 니켈을 녹인 후 원하는 기판을 이용하여 전사하는 간단한 방법이다. 직접전사는 전사가 이루어진 후 그래핀에 남는 결함이 거의 존재 하지 않는 장점이 있지만 문제점은 단일층의 그래핀의 경우 니켈 에천트위에서 잘 보이지 않을 뿐 아니라 에천트에서 기판으로 전사할 때 너무 얇은 막으로 인해 다 찢어져버린다는 것이다. 이를 해결하기 위해 사용되는 전사 방법으로 TRT를 이용하여 구리위에 성장된 그래핀을 상온 시에는 점성을 가진 테이프를 이용해 부치고 구리에 천트에 구리를 녹인 후 원하는 기판위에 놓고 열을 가해 그래핀을 전사하는 방법이 있다. TRT 전사방법은 얇은 막의 그래핀을 찢어지지 않도록 지지해주어 대면적 기판위에도 전사 할 수 있는 장점이 있지만 전사 후 그래핀에 남아 있는 잔여물들이 많고(그림 1. (b)), 테이프를 이용한다는 점에서 그래핀의 얇은 막이 손상될 수 있는 단점이 있다. 그렇기 때문에 본 연구에서는 직접전사와 TRT전사의 문제점들인 전사 후 잔여물와 그래핀 단일층의 손상을 최소화할 수 있는 방법으로 PMMA전사를 가장 적합한 전사방법이라는 것을 라만 분석, 면 저항측정, 그래핀을 이용한 LED제작을 통해서 살펴 보았다. 먼저 라만 분석을 이용해 TRT전사 후 상당히 많은 빈 공간이 생김을 확인할 수 있었으며, 결과적으로 면 저항이 약 $1.5k{\Omega}$~$3M{\Omega}$까지 PMMA의 약 0.9~1.2 $k{\Omega}$와 비교했을 때 큰 차이가 있음을 확인할 수 있었다. 또한, 이후 각각의 전사방법으로 얻은 그래핀을 LED의 스프레딩 층으로 제작한 결과에서도 TRT전사방법보다 PMMA전사방법의 결과가 좋음을 알 수 있었다(그림 2).

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Ultimate Strength and Design Method of Turn-buckle for Measuring Tensile Force (인장력 측정용 턴버클의 극한강도 및 설계방법)

  • Lee, Swoo Heon;Shin, Kyung Jae;Lee, Hee Du
    • Journal of Korean Society of Steel Construction
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    • v.25 no.1
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    • pp.61-70
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    • 2013
  • A turn-buckle is capable of adjusting the tensile force by left-hand threads and right-hand threads between tension members. There are different types of turn-buckles according to tension member and connection form but the practical and existing turn-buckles are incapable of measuring the tensile force. A turn-buckle for adjusting and measuring tensile force has therefore been developed. This study shows the ultimate strength and reliability for measurement of the new turn-buckles through finite element analysis of the developed ones. From analytic results of the new turn-buckles which have the measurement limit loads of 100kN, 200kN and 300kN, the ultimate strength is approximately five times stronger than the measurement limit capacity. Additionally, a review of the new turn-buckle, which has the measurement limit load of over 300kN, shows that there is a tendency for the size of turn-buckle to become larger. So the connection devices were designed and the loading test was conducted from the concept that the parallel connection of turn-buckle with 300kN capacity can measure the tensile force of 600kN. The results of parallel loading test show the sufficient possibility. Furthermore, the mock-up test was constructed to investigate the release of initial load and corrosion when the new turn-buckle is installed at the outdoor and exposed to rain and atmosphere.

Female Teachers' Mate Selection Preferences in Social, physical, psychological and family role characteristic (미혼 여교사의 배우자 선택에서의 동질혼 추구 경향)

  • Cho, Byung Eun;Lee, Jong Hui;Lee, Hyun Jung;Kwark, Sun Jung
    • Journal of Korean Home Economics Education Association
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    • v.24 no.4
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    • pp.1-18
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    • 2012
  • This study investigated the mate selection preferences of single female teachers by investigating the desired traits in socioeconomic, physical attractions, psychological traits and family roles of their prospected marital partner, in order to explore the current trends in homogamous marriage. A questionnaire was distributed to 295 unmarried female teachers selected by convenience sampling from the various cities. The teachers pursued homogeneity in age, educational attainment, religion, and occupation while they preferred partners with higher income level. In terms of physical assets, the attraction that the teachers felt towards the partner was the most important physical appearances. The respondents preferred partners who are masculine and an androgynous partner. The teachers held high expectations towards their future spouses in that they desired to share the roles of emotional, financial support, child care and kin keeping. A partner who shared modern sex role attitudes was preferred over someone who held traditional one. The pursuit for overall homogeneity reflects that the teachers seek for equality in their relationships with prospected marital partners by exchanging similar characteristic.

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Developing Advanced Total Recycling Method of FRP Boats (FRP선박의 일괄 재처리 방법의 개선)

  • Lee, Seung Hee;Yoon, Koo Young
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.16 no.1
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    • pp.53-59
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    • 2013
  • Since 1990s, the major recycling methods for mechanical recycling of FRP(Fiber Reinforced Plastics)boats has involved shredding and grinding of the scrap FRP in a new recycled product. But still it leads to secondary problem such as air pollution, unacceptable shredding noise level and few limited applications. This study is to propose a newly advanced method which is more efficient and environment friendly waste FRP regenerating system. As extracting FRP layer and making the recycled fiber for recycled-fiber reinforced concrete(RFRC) from waste FRP, the recycling process has some merits in a sense of the recycling energy and the environmental effects. In this study, for those tasks, spectro-chemical differentiation method and coloring water-soluble dye treatment makes the roving layer more distinguishable photophysically. Also that has remarkably reduced safety hazards and energy. Using the mechanical properties of polymers and composite, FRP with the orthotropic and laminated plastic structure has been easily separated in the new extracting system. Also the new method has introduced five kind of separating manuals for the some different compositions of FRP boats. The roving fiber of laminated glass-fiber layer is as good as the polyvinyl fiber which is cost-high commercial fiber to increasing strength of concrete products. The early study has shown the effectiveness of laminated glass-fiber layer which also is chemical-resistant due to the resin coating. These results imply that more efficient and environment friendly recycled glass fiber can be better applied to the fiber reinforced concrete(FRC) substitute and this study also has shown wide concrete applications with RFRC from the waste FRP boat.

Intraspecific variation and geographic study of Lonicera insularis (Caprifoliaceae) based on chloroplast DNA sequences (엽록체 DNA를 이용한 섬괴불나무(Lonicera insularis Nakai)의 종내변이 및 지리학적 연구)

  • Jeong, Keum Seon;Kim, Mi Sun;Lee, Woong;Pak, Jae-Hong
    • Korean Journal of Plant Taxonomy
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    • v.44 no.3
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    • pp.202-207
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    • 2014
  • Lonicera insularis Nakai (Caprifoliaceae) is Korean endemic plant that lives along the shore of Ulleungdo and Dokdo. The aim of this study is to construct a phylogenetic relationship within six species (L.maackii, L.chrysantha, L.subsessilis, L. harai, L. morrowii) of genus Lonicera L. and Wigela subsessilis as outgroup and intraspecific variation of L. insularis using chloroplast DNA five regions sequences. Sequence analysis revealed that both L. insularis and L. morrowii showed complete homologies in the intergenic regions of trnL-trnF, trnS-trnG, psbM-trnD and matK coding region. However, sequence in the petN-psbM intergenic region showed a single nucleotide difference between both species, thus we designated them as CP01 and CP02. The plants having CP01 are prevalent in the Ulleungdo and Dokdo, while L. insularis and L. morrowii from Ulleungdo and of Dokdo, and Japan have CP02. This confirmed the existence of two cp DNA lineages with different geographical distributions. We can infer the allopatric speciation by geographical barrier. The result will provide the important basal data to study speciation and specie evolution of ocean islands such as Ulleungdo and Dokdo.

The Development and Validation of Instrument for Measuring High School Students' STEM Career Motivation (고등학생들을 위한 이공계 진로동기 검사도구 개발 및 타당화)

  • Shin, Sein;Ha, Minsu;Lee, Jun-Ki
    • Journal of The Korean Association For Science Education
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    • v.36 no.1
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    • pp.75-86
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    • 2016
  • The purpose of the present study is to develop and validate an instrument to assess STEM career motivation. We developed 32 items for 7 constructs (i.e. education experience, career value, academic self-efficacy, career self-efficacy, career interest, parents' support, and career motivation) on STEM career motivation based on Social Cognitive Career Theory (SCCT; Lent et al.,1994). 767 first year high school students participated in this study. The items were validated by Messick's framework (1995). In this study, we examined the validity of items in four aspects (i.e. content, substantive, structural and generalizability of validity). Methodologically, we used Rasch analysis, Exploratory factor analysis, confirmative factor analysis based on structural equation modelling. We confirmed that our instrument with 32 items as valid and reliable for measuring the STEM career motivation. In addition, we tested the STEM career motivation model based on SCCT. Our model explained the data well, suggesting that external factors (education experience and parents' support) and cognitive factors (perception of value, self-efficacy and interest) were significantly related to STEM career motivation.

A Study on the Impact of the App-Book Purchasing Behavior of Smart phone Users in Korea (국내 스마트폰 사용자들의 앱북 구매행위에 미치는 영향요인 연구)

  • Lee, Jong-Ok;Kim, Yong-Moon
    • The Journal of Society for e-Business Studies
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    • v.18 no.3
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    • pp.45-67
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    • 2013
  • In order to research the factors influencing on the intentions for smart phone users to purchase "App-Book" in Korea, the study examines the levels of influences using on an additional variable, "cost", as well as the four key variables(performance expectancy, effort expectancy, social influence, and facilitating conditions) proposed by Unified Theory of Acceptance and Use of Technology(UTAUT; Venkatesh et al., 2003) validation. The result of the research confirms that the hypotheses of UTAUT model variable are generally supported by the information technology and many related previous researches. There is one exception, however, that facilitating conditions do not influence on the App-Book purchasing behavior by smart phone. It is revealed that the "age" and "experience" of the independent variables, as the proposed control variables, are most visible effect of control on the purchase intention and purchase behavior. This study has an academic significance of presenting a new integrated model to perform the research of the similar next App-Book services and purchase behavior related to the acceptance of new media. It also clarifies to the related companies that the usefulness of App-Book, the easiness of use, the cost and the social influence of purchasing App-Book by Outsider's intent. These aspects have practical implications as being presented.

Strength Characteristics of the Soil Mixed with a Natural Stabilizer (친환경 토양안정재를 혼합한 지반의 강도특성)

  • Kwon, Youngcheul;Oh, Sewook
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.1
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    • pp.45-51
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    • 2012
  • This article aims to find method to mix a harmless hardening agent and soil generated during construction to make paving materials. The main purpose of this research is to get rid of the harmfulness(Chromium (VI), etc.) of cement which has been generally and frequently used as a hardening agent and strengthen it so that it can be used for the general foundation solidification and stabilization of civil engineering/construction structures such as dredging soil treatment, marine structure foundation treatment, surface soil stabilization, and river bank erosion prevention. NSS(Natural Stabilizer Soil) used for this study takes as its chief ingredient the mixture of lime and staple fibers extracted from natural fibers. It increases the shearing strength of soil that it improves the support and durability of the foundation and prevents flooding and frost as well. The pH measured to know its eco-friendliness was 6.67~7.15, and according to the migration testing, only Pb and CN were lower than the standards, so it can be said that NSS has almost no harmful components in it. According to the result of uniaxial strength testing, when the mixture ratio of weathered soil to NSS was 6%, about 1,850kpa strength was expressed. And according to the result of CBR. testing to figure out its appropriateness as a paving material, the CBR of the foundation was 4%~6%. But when the mixture ratio of NSS is over 6%, the water immersion CBR. is over 100%; thus, it is expected that it will show great utility as a paving material.

Pullout Characteristics of Pressure Reinjection-Grouted Reinforcements in Decomposed Granite Soil (화강풍화토 지반에 설치된 압력재주입 그라우팅 보강재의 인발특성)

  • Shim, Yong-Jin;Lee, Jong-Kyu;Lee, Bong-Jik
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.11
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    • pp.61-68
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    • 2012
  • Most widely methods for reinforcement of soil utilized in Korea are anchor method, soil nail method and micro pile method. These methods are classified by the intended use of the structure to be constructed, but the reinforcement of the ground is accomplished contains in common the process of grouting work after inserting the reinforcements. Domestically, gravity grouting has been used mostly so far, but there has always been the risk of insufficient restoration of the loose ground area from the drill holes because the grouting is conducted only by gravity. On the other hand, pressure reinjection grouting may enhance the grouting quality by solving the problem of the existing grouting method considerably since it additionally reinjects grouting through pre-installed tube a certain time after the first grouting. Accordingly, this study evaluated the pullout characteristics by the grouting methods by performing model test on decomposed granite soil, and investigated the support increasing characteristics of reinforcements depending on the curing time, reinjection pressure, and uplift force variation of the pressure reinjection grouting. The result of this research shows that the pressure reinjection grouting demonstrated 1.1~1.3 times of performance of the gravity grouting, and suggests some analysis on optimal water content, reinjection pressure and curing time of the pressure reinjection grouting.

An analysis of creative trend of election Ads and PR strategy which appears in recent political campaign - Focused on 2010. 6.2 local election, 2011. 10.26 by-election, 2012. 4.11 general election, 2012. 12.19 presidential election (한국 최근 정치캠페인에서 나타난 크리에이티브한 선거광고홍보전략 트렌드 분석 -2010. 6.2지방선거, 2011. 10.26 보궐선거 2012. 4.11 총선, 2012. 12.19 대선을 중심으로)

  • Kim, Man-Ki
    • Journal of Digital Convergence
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    • v.11 no.8
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    • pp.65-73
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    • 2013
  • Outcome of election depends on which candidate of politics uses more original and creative idea for Ads and PR of election in election campaign strategy of political campaign. Especially, since political Ads and PR are the ways of capturing voters' sensitivities with one line of copy(slogan) and one image, Ads and PR are very important. This research analyzes unique and creative trend of political campaigns which are used in each unit election which is held four times(2010. 6 2 local election, 2011. 10 26 by-election, 2012. 4 11 general election, 2012. 12 19 presidential election) during 2010~2012. For analysis, search analysis of text and image used in video, internet, booklet type of Ads and PR material for election, and election campaign. Video is used in election campaign during election period. Unique and creative political campaign is customized micro-marketing election strategy trend which tries to fit for tendency of backing including gender, age group, social atmosphere, etc. This research excludes the degree of success of this election strategy from subject of analysis.