• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 1998년도 가을 학술발표회논문집
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• pp.45-48
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• 1998

카이토산(chitosan)은 항미생물성, 무독성, 인체적합성 및 양이온성 등의 특성을 지니며 항균, 방취, 보습, 생체적합성 및 생분해성 등의 다양한 기능을 나타내고 있는데, 이를 바탕으로 카이토산을 단독 또는 다른 천연섬유재료와 복합화시키는 연구가 행해지고 있다. 본 연구에서 선택한 카이토산과 복합체를 형성할 수 있는 성분인 견 피브로인(silk fibroin)은 17 종의 아미노산으로 이루어진 단백질로서 의류용 및 의료용 재료로서 이용되고 있는 고급섬유재료이다. (중략)

• 한국의류학회지
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• 제35권1호
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• pp.115-124
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• 2011

This study provides an eco-friendly dyeing processing for chitosan fiber using Oenothera odorata jacquin as a dye. The effects of chemical mordants (Al, Cu, Fe) and natural mordant (Chestnut shell) on the color change for dyed chitosan fibers were measured by K/S values, L, $a^*$, $b^*$, H, V, C values, color fastness, and antimicrobial activity. The results are as follows. Dyeing conditions of Oenothera odorata jacquin on chitosan fibers were optimized to $70^{\circ}C$, 30 minutes and 200% on weight of fabric (o.w.f.). The pre-mordant concentration of aluminium (Al), copper (Cu) and iron (Fe) of chitosan fibers was optimized to 3% (o.w.f.) and 1% (o.w.f.), respectively. The post-mordant concentration of chemicals, such as Al, Cu and Fe, on chitosan was determined to 1% (o.w.f.). The hue of chitosan fibers by chemical mordants was measured to be reddish & yellow. The pre-mordant concentration of Chestnut shell of chitosan was optimized to 70% (o.w.f.). The post-mordant concentration of Chestnut shell on chitosan was determined to be 50% (o.w.f.). The hue of chitosan fibers by Chestnut shell mordant was measured to be reddish & yellow. The wet cleaning fastness of chitosan fibers was improved by a pre-mordant that used chemical mordants. In the case of the Chestnut shell mordant, the wet cleaning fastness was improved by a post-mordant. The dry cleaning fastness of chitosan fibers was excellent regardless of mordants and mordant methods. The antimicrobial activity of the chitosan fiber was shown at 99.9% and its excellent qualities remained after the dyeing and mordant processing.

• 한국의류산업학회지
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• 제14권2호
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• pp.311-319
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• 2012

The purpose of this study is to investigate the dyeing property of gromwell on modified cotton fabric by chitosan. Modified cotton fabrics were manufactured by crosslinking agent epichlorohydrin in the presence of chitosan. Gromwell colorants were extracted with methanol. Modified cotton fabrics dyed using gromwell were post-mordanted using Al, Fe and Cu. The dyeability (K/S) and color factors (L, a, b, ${\Delta}E$ and h) of modified cotton fabrics were measured by computer color matching. Additionally the fastness to washing and light were also investigated. The dye-uptake of modified cotton fabrics increased with the dyeing time. The saturated dyeing time was about 10minutes at $50^{\circ}C$. The dyeability (K/S) was remarkably increased with increasing content of chitosan because of having a amine group of chitosan. Modified cotton fabrics were dyed yellowish red by non and Fe mordanting, blueish red by Al and Cu mordanting, respectively. The washing fastness of non, Al, Fe and Cu mordant in the presence and absence of chitosan were increased $1{\rightarrow}2$, $3{\rightarrow}4$, $4{\rightarrow}4-5$ and $4{\rightarrow}4-5$ respectively. And light fastness of non, Al, Fe and Cu mordant in the presence and absence of chitosan were increased $1{\rightarrow}1-2$, $1{\rightarrow}1-2$, $1.2{\rightarrow}2.3$ and $1-2{\rightarrow}2$ respectively.

• 한국의류학회지
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• 제34권5호
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• pp.775-783
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• 2010

This study examines the dyeability, light fastness, washing fastness, and the antibacterial activity of chitosan and nano silver composite non-woven fabrics dyed with an extracted solution from Chrysanthemum Indicum Linn. The results show that an increase in the chitosan and nano silver percentage resulted in an increase in the $a^*$ values and $b^*$ values; however, the $L^*$ values decreased in the undyed condition. ${\Delta}E$ values of chitosan and nano silver composite non-woven fabrics were higher than cotton 100% non-woven fabrics in the dyed condition with an extracted solution from Chrysanthemum Indicum Linn, and mordant treatments influenced the chrominance change. In the dyed condition with an extracted solution from Chrysanthemum Indicum Linn, an increase in the percentage of chitosan and nano silver resulted in an increase of the K/S values. The dyeability of chitosan and nano silver composite non-woven fabrics increased by mordant treatments. The light fastness and washing fastness of the mordanted non-woven fabrics were better than the non-mordanted. For the antibacterial activity, the bacterial reduction rate of chitosan and nano silver composite non-woven fabrics was 99.9% to Staphylococcus aureus and Klebsiella pneumoniae.

• 패션비즈니스
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• 제7권2호
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• pp.97-106
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• 2003

The purpose of this study was to investigate Chinese men's perception and satisfaction on Korean apparel products. The 1000 Questionnaires were distributed to Chinese men, and returned 863 questionnaires were analyzed by mean and percentage with SPSS 10.0. The results of this study were as follows: Chinese men had more perception on their own brand and Italy brand than UK, Korean, and Japan brand. Over age fifties of Chinese men preferred Korean brand to the other ages. Chinese men perceived positively Korean fashion products as more trendy, very creative, high-class, qualitative, expensive and creditable, otherwise, there were little famous brands among Koran apparel products. Chinese men satisfied on Korean apparel products positively, specially, age forties and fifties, resident from Harbin, income 2 and 3 level, and young casual mild group showed higher satisfaction on Korean apparel products than the others.

• 한국의류산업학회지
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• 제12권6호
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• pp.837-842
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• 2010

This study examines the dyeability, light fastness, washing fastness, and antibacterial activity of chitosan and nano silver composite knit fabrics dyed with extracted solution from Chrysanthemum Indicum Linn. The results show that ${\Delta}E$ values of chitosan and nano silver composite knit fabrics were higher than cotton 100% knit fabrics in dyed condition with extracted solution from Chrysanthemum Indicum Linn, and mordant treatments influenced the chrominance change. Chrysanthemum indicum Linn confirmed that this could be a polygenetic colors. ${\Delta}E$ values of post-mordant treatments knit fabrics were higher than pre-mordant treatments knit fabrics in dyed condition with extracted solution from Chrysanthemum Indicum Linn., and mordant treatments method influenced the chrominance change. The dyeability of chitosan and nano silver composite knit fabrics was increased by mordant treatment. The fastness of the chitosan and nano silver composite knit fabrics was better than cotton 100% knit fabrics. In the result of antibacterial activity, the bacterial reduction rate of chitosan and nano silver composite knit fabrics was 99.9% to Staphylococcus aureus and Klebsiella pneumoniae.

• 한국의류산업학회지
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• 제8권4호
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• pp.458-464
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• 2006

The adsorption ability of heavy metal ions from the aqueous solution by chitosan, which it is well known natural biopolymer, has been investigated. The fundamental study in this research is focusing on the physicochemical adsorption utilizing the chitosan as a organic chelating adsorbent, adsorb especially heavy metal ions from the waste liquid solution. The adsorption ability of the chitosan between metal ions, having different characteristics with Mw of 188,600, 297,200, and 504,200 g/mol and degree of deacetylation (DD) of 86.92% and 100% were investigated targeting on the $Ni^{2+}$, $Co^{2+}$, $Zn^{2+}$, and $Pb^{2+}$ ions, respectively. The uptake of heavy metal ions with chitosan was performed by atomic absorption flame emission spectrophotometer (AAS) as conducted residual metal ions. It was found that chitosan has an strong adsorption capacity for some metals under certain conditions. Chitosan, which have 100% degree of deacetylation showed high adsorption recovery ratio and have an affinity for all kinds of heavy metals. In contrast, the molecular weight of chitosan was not completely affected on metal ion adsorption.

• 한국의류산업학회지
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• 제5권5호
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• pp.529-538
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• 2003

Chitosan should be satisfied a certain Mw range for the final application, Low molecular weight chitosan(LMWC) can be acquired by depolymerizing high molecular weight starting chitosan. Using $H_2O_2$ in depolymerizing chitosan is very effective and reproducible in controlling Mw of resulting LMWC. However, $H_2O_2$ can break glycoside linkage of chitosan and oxidize some $-NH_2$ groups in chitosan. It has been reported that decrease in DA(degree of deacetylation) of LMWC prepared by $H_2O_2$. However, any quantitative data of decrease in DA has not been reported yet. In this study, DA of initial chitosan and DA of $H_2O_2$ treated chitosan were measured and the change in DA of chitosan upon $H_2O_2$ treatment were investigated. Change in DA was very different upon $H_2O_2$ treatment condition. LMWC also showed DA change upon time passage. Pre-swelling treatment of initial chitosan and low ratio of $H_2O_2$/chitosan prevented a decrease in DA significantly. Yellowing of LMWC was detected upon time passage, however, decrease in DA was minimal (around 1%).

• 한국의류산업학회지
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• 제5권5호
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• pp.520-528
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• 2003

Chitosan was depolymerized by oxidizing agent, hydrogen peroxide ($H_2O_2$) and general properties of resulting low molecular weight chitosan(LMWC) were studied. Effect of amount of $H_2O_2$, ratio of $H_2O_2$/chitosan, and reaction temperature were investigated in preparing LMWC. In addition, the reduction of molecular weight of prepared LMWC were measured after a certain time passage. Pre-swelling treatment of starting chitosan affected uniform and mild reaction of depolymerization and increased the solubility of resulting LMWC. Prepared LMWC (Mw 100,000) showed a decrease in Mw by 25-35%. Prepared LMWC(Mw 60,000-70,000) showed a decrease in Mw by 10-15% after 7 months. Therefore, this depolymerizing process can be concluded desirable in terms of stability. In addition, yellowing of pre-swelling treated chitosan upon time passage was insignificant compared with that of untreated chitosan. Therefore, pre-swelling treatment of chitosan before depolymerization would be beneficial in terms of stability of physical state.

• 한국의류산업학회지
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• 제5권1호
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• pp.64-70
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• 2003

Water-insoluble chitosan with molecular weight of 2,000,000, 580,000, 80,000, and 40,000 and more than 90% of degree of deacetylation were prepared to test antibacterial activity of chitosan against a pathogenic bacteria, methicillin resistant Staphylococcus aureus (MRSA). As experimental method, the Shake Flask Method (SFM) and Modified Shake Flask Method (MSFM) were applicated. The anti-microbial activity of chitosan/acetic acid aqueous solution is consistent irrespective of Mw of chitosan. MIC value of SFM measurement was 0.2 ppm, and MIC value of modified SFM measurement was 25 ppm. But MIC value of chitosan/acetic add solution and chitosan treated cotton filter paper was equally 5 ppm. The antibacterial activities of chitosan were different in different test measurements employed. The antibacterial activities of chitosan/acetic acid solution and chitosan treated cotton filter paper were also different. Therefore, it needs to be pointed out that the test measurements of anti-microbial activity have some problems.