• Title/Summary/Keyword: 하전물질

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GC/MS and its applications for the analysis of cosmetic produtcts (GC/MS와 화장품 분석의 응용)

  • 노경원
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.19 no.1
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    • pp.1-19
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    • 1993
  • Gas chromatography serves to separate the mixtures into its components, and mass spectrometer is used to analyzing of unknown compounds. But there are many problems the identification of horn compounds using by GC only. As this reason GC/MS a very powerful analyzing technique. Mass spectrometer consists of 1) inlet stem 2) ion source 3) Bass filter 4) detectors and 5) data system. There are two analyzing modes in the GC/MS, those are scan and SIM(selected ion mom toping) modes. Scan mode is used when analyzing unknown compounds and SIM mode al lows the mass spectrometer to detect specific compound with very high sensitivity. As GC/MS applications for the analysis of cosmetic products, volatile compounds in lotion, earn foundation and hair color, and carbon distribution of fatty acids in soap were performed. Also as a new sample pre-treatment technique, head space sampler/GC/MS introduced in order to analyze the volatile compounds in a toothpaste.

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Characteristics of Heavy Metal Removal from Aqueous Solutions using Leather Industry by-products (피혁산업 부산물에 의한 용존 중금속 제거 특성)

  • Kim, Keun-Han;Lee, Nam-Hee;Paik, In-Kyu;Park, Jae-Hyung;Yang, Jae-Kyu
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.5
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    • pp.417-426
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    • 2010
  • In this study, ten different bio-adsorbents were prepared by immobilization of vegetable tannins such as mimosa(Catechol Tannin) and chestnut(Pyrogallol Tannin) on the collagen matrix which was derived from during leather manufacturing processing. Removal efficiency of Cu(II), Cd(II), Zn(II), Pb(II), Cr(III) by each bio-adsorbent in synthetic wastewater was evaluated by a laboratory-scale batch reactor at different reaction conditions. When mimosa was used as a vegetable tannin, the penetration efficiency of mimosa into the inner bundle of fiber depended on the dose of the naphthalene condensated penetrant; 3% ${\geq}$ 1.5% > 0%. For all bio-adsorbents, removal of heavy metal ions was not observed below pH 3.0 but was rapidly increased between pH 3.0 and 6.0, showing near complete removal of all heavy metal ions except Zn(II) above pH 6.0. Removal of Cr(III) was quite similar for all bio-adsorbents while removal of Cu(II), Zn(II) and Pb(II) was higher by bio-adsorbents immobilized with chestnut than that by mimosa. Adsorption of Pb(II) and Cu(II) by S10 bio-adsorbent was little affected by the presence of monovalent and divalent electrolytes as well as variation of 1000 times ionic concentration with $NaNO_3$.

Fractional efficiency of Nanomaterials for the High efficiency respiratory filters (고효율 호흡보호구의 나노물질 입경별 제거 효율)

  • Lee, Gwang-Jae;Ji, Jun-Ho;Kim, Won-Geun;Yook, Se-Jin;Kim, Jong-Kyo;Kim, Jung-Ho
    • Particle and aerosol research
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    • v.12 no.3
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    • pp.95-102
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    • 2016
  • Controlling exposures to occupational hazards is important for protecting workers. Certified facepiece respirators are recommended when engineering controls do not adequately prevent exposures to airborne nanomaterials. The objective of this study is to carry out the experimental performance test to investigate the fractional efficiencies of the filter media for two grades of facepiece respirators. Experimental performance evaluations were carried out for the test NaCl particles and silver nanoparticles. For media of respirator filter, the penetration of NaCl particles was less than 5% and the most penetrating particle size occurred at about 40 nm. For silver nanoparticles, the most penetrating particle size was about 20nm with higher efficiency than those of NaCl particles. Charge characteristics of airborne nanoparticles is important because the media of respirator filter is made by the electret filter media.

Variation of Flow and Filtration Mechanisms in an Infiltration Trench Treating Highway Stormwater Runoff (고속도로 강우유출수 처리를 위한 침투도랑에서 흐름조건에 따른 여과기작 및 효율분석)

  • Guerra, Heidi B.;Yu, Jianghua;Kim, Youngchul
    • Journal of Wetlands Research
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    • v.20 no.1
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    • pp.63-71
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    • 2018
  • The particle filtration mechanisms in an infiltration trench should be varying due to the different hydraulic conditions during stormwater runoff. The understanding of these variations associated with different filtration mechanisms and their effect on the particle removal efficiency is of vital importance. Therefore, a LID (Low Impact Development) system comprising of an infiltration trench packed with gravel and woodchip was investigated during the monitoring of several independent rainfall events. A typical rainfall event was divided into separate regimes and their corresponding flow conditions as well as filtration mechanisms in the trench were analyzed. According to hydraulic conditions, it was found out that filtration changes between vertical and horizontal flows as well as between unsaturated, saturated, and partially-saturated flows. Particle separation efficiency was high (55-76%) and was mainly governed by physical straining during the unsaturated period. It was then enhanced by diffusion during the saturated period (75-95%). When the trench became partially saturated at the end of the rainfall event, the efficiency decreased which was believed to be due to the existence of a negatively charged air-water interface which limited the removal to positively charged particles.

Transfer of Genetic Substance Through the Cell Wall of Geranium (Pelargonium zonale hybrids, 'Pinto Scarlet') Callus (제라니움 세포벽을 통한 유전물질의 전이)

  • 유장걸;소인섭;홍경애
    • Korean Journal of Plant Tissue Culture
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    • v.21 no.1
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    • pp.29-34
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    • 1994
  • The possibility that DNA could move out of the single cells isolated from geranium (Pelargonium zonale hybrids, 'PintoScarlet') callus was determined by the elechophoretic DNA analysis after treatment of low pH, various concentrations of KNO$_3$, 2,4-D, and GA$_3$ followed by the centrifugal force, all of which are hewn to and the physico-chemical properties of the cell wall. The centrifugal force of l,800 xg was need for DNA migration after the above treatment, but 7k300 xg was required without the treatments. In this experiment the optimum concentration (300 mg/L) of sodium dodecyl sulfate (SDS) used as an anion detergent to collect the negatively charged DNA was very critical not to damage the cell wall It can be concluded that the centrifugal force played a key role for the DNA migration through the cell wall, and the treatments of low pH (4.0), 0.5% KNO$_3$, 1.5 mg/L GA$_3$and 1mg/L 2,4-D further increased the DNA migration.

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Adsorption Features of Lead Ion on Waste Undaria pinnatifida (폐기된 해조류를 이용한 납 이온의 흡착 특성)

  • Seo Myung-Soon;Kim Dong-Su
    • Resources Recycling
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    • v.13 no.4
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    • pp.23-31
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    • 2004
  • Basic studies have been conducted regarding the attempt of the utilization of waste Undaria pinnatifida as an adsorbent for the adsorption treatment of lead-containing wastewater. Undaria pinnatifida was found to be chiefly composed of hyo-carbonaceous compounds and have a fairly high specific surface area, which suggesting the possibility of its application as a Potential adsorbent. The electrokinetic Potential of Undaria pinnatifida particles was observed to be negatively highest at around pH 8 and the fact that its electrokinetic potentials are negative at the whole pH range supported it might be an efficient adsorbent especially for cationic adsorbates. Under the experimental conditions, $Pb^{2+}$ was found to mostly adsorb onto Undaria pinnatifida within a few minutes and reach the equilibrium in adsorption within ca. 30 minutes. The adsorption of $Pb^{2+}$ was exothermic and explained well by e Freundlich model. Acidic pretreatment of Undaria pinnatifida enhanced its adsorption capacity for $Pb^{2+}$ , however, the reverse was observed for alkaline pretreatment. The formation of organometallic complex between $Pb^{2+}$ and some functional groups on the surface of Undaria pinnatifida was considered to be one of the main drives for adsorption. Finally the adsorbability of$ Pb^{2+}$ was examined to be rather affected by several solution features such as the coexistence of other adsorbate, the variation of ionic strength, and the concentration of complexing agent.