• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.3
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• pp.335-342
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• 2022

In this study, self-healing hybrid capsules were prepared by mixing self-healing solid capsules and self-healing microcapsules using inorganic materials as core materials. Self-healing hybrid capsules were mixed with 3 % according to the composition ratio of 3:7, 5:5, and 7:3 based on the mass of the cement to prepare a self-healing cement composite material. The healing properties of crack self-healing hybrid capsules were evaluated through hydrostatic water permeability test and surface crack monitoring. It was found that the self-healing hybrid capsules prepared by mixing the composition ratio of the self-healing solid capsules and the self-healing microcapsules at 7:3 has a great effect on improving the crack self-healing performance.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.4
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• pp.531-538
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• 2022

In this study, the self-healing hybrid capsules were prepared, were mixed with 3 %, 5 %, and 7 % based on cement mass. The healing performance were evaluated according to mixing ratio self-healing hybrid capsule. As a result of the experiment, it was found that the crack healing performance improved as the mixing rate of the self-healing hybrid capsule increased, but the quality performance tended to decrease. Therefore, it is judged that using the mixing ratio of the hybrid capsule within 5 % reduces the quality performance to within about 10 % and secures about 90 % or more of the healing performance.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.4
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• pp.568-575
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• 2023

This paper aims to evaluate the quality characteristics and healing performance of precast concrete incorporating self-healing technology as a key technique for the construction of smart cities. The study found that precast concrete mixed with hybrid capsules exhibited a tendency of reduced slump and air content, impacting the quality characteristics. Specifically, the slump decreased by up to 14 %, and the air content by up to 9 %. Moreover, the inclusion of hybrid capsules in the concrete resulted in a maximum decrease of 16 % in compressive strength and 18 % in flexural strength. However, the introduction of hybrid capsules significantly enhanced the crack healing performance. The assessment through water permeability tests showed that the healing rate of 0.3 mm crack width after a 28-day healing period improved as the mixing ratio increased, with the healing rates at 1 %, 3 %, and 5 % hybrid capsule mixtures observed to increase by approximately 16 %, 25 %, and 32 %, respectively.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.38 no.8
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• pp.701-707
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• 2014

The ecofriendly yellow ocher is used in the manufacturing of cosmetics, construction, and food packaging. The polyethylene terephthalate (PET) used for manufacturing food containers has a microporous structure that causes aeration. Hydrophilic yellow ocher may be applied to hydrophobic PET by surface modification to overcome this issue. The aim of this study is to fabricate a yellow ocher polystyrene hybrid structure in the form of nanoparticles using an optimizing molar ratio of styrene, divinylbenzene, and potassium peroxodisulfate for use in emulsion polymerization. The polymerization was conducted in a yellow ocher suspension that was prepared by dispersing mechanically ground yellow ocher in DI water. The prepared hybrid structure was measured using scanning electron microscopy, energy dispersive X-ray spectroscopy, and X-ray diffraction. The measurement revealed the spherical morphology and Si component that resulted from the yellow ocher in the polystyrene particles. We expect that this hybrid structure would be used as platform material to minimize aeration in PET.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2011.03a
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• pp.99-99
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• 2011

최근 건강에 대한 관심이 높아지면서 천연 기능물질을 이용한 고기능 및 고부가가치 상품개발이 여러 산업분야에서 일반화되는 추세이다. 대표적으로 마이크로캡슐은 원하는 기능을 발휘할 수 있는 기능성 물질을 다양한 방법으로 다양한 제품에 부여함으로써, 기능성 물질을 오랜 기간 동안 외부로 방출하거나 외부의 환경으로부터 보호하는 수단으로 각광받고 있다. 이러한 마이크로캡슐은 의약분야 제초제, 멸충제, 곰팡이 방지제, 살균제로 적용되는 농약분야, 식품 분야, 화장품 분야 등의 전반에 걸쳐 응용 및 연구가 활발히 이루어지고 있다. 이에 본 연구에서는 다양한 나노 합성기술과 유/무기 하이브리드를 이용해 서방화 관련 기술을 개발하여 보습성, 항균, 노화방지, 외부 유해물질로부터의 피부보호 특성을 가진 인체 친화형 복합기능성 섬유 가공조제를 개발하여 다양한 섬유소재에 적용하고자 하며, 궁극적으로 기존 선진국 제품의 기능을 뛰어넘는 원천기술, 즉 새로운 가공제 합성과 응용성, 그 성능평가와 동시에 최적의 처리기술을 개발함으로써 섬유제품의 부가가치를 높이는 계기를 마련하고자 한다. 본 연구에서는 나노미터 직경을 갖는 침상형의 주형(hydroxyapatite)을 이용하여 중공 나노구조체를 제조 한 후 이에 천연고분자를 혼합하여 초음파처리 후 유/무기 하이브리드 기술을 이용한 서방성 가공제를 합성하였다. 중공의 나노구조체 확인은 투과전자현미경(TEM)을 이용하였으며, 주형의 나노구조체는 주사전자현미경(FE-SEM)으로 확인하였다. 이상의 결과를 통해 본 연구에서 제안한 방법이 나노구조체의 새로운 합성방법으로써 가능성을 확인할 수 있었다.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.4
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• pp.569-576
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• 2022

In this study, the healing performance of hybrid self-healing concrete was investigated by mixing bacterial pellets(BP) and solid phase capsules(SC), respectively, based on organic-inorganic self-healing material(MC). Constant water head permeability test was applied as a method of evaluating the healing performance, and the healing rate and the healed crack width calculated by the equivalent crack width were used as evaluation indicies. As a result of the water permeability test, when the initial crack width was 0.3 mm, the healing rates of MC-BP and MC-SC were 2.1~3.0 %pt higher than that of MC, and the healed crack width of hybrid concrete increased by 0.017~0.018 mm. In conclusion, it was found that the self-healing performance was not significantly improved even if the two types of healing materials are used together.

• Korean Chemical Engineering Research
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• v.46 no.4
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• pp.669-675
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• 2008

Carbon black has been widely used in composites, tonor resin, and ink materials. Since carbon black readily agglomerates, it is important to disperse carbon black in real applications. Aiming to improve dispersion stability, carbon black was chemically oxidized to possess hydroxyl groups using a phase transfer catalyst at room temperature. The modified carbon black (CB-OH) was grafted by a silane coupling agent, p-methylacryloxypropyltrimethoxysilane, to carry teminal vinyl groups. The modified carbon black was subsequently used in miniemulsion polymerization to achieve encapsulted core-shell structure. Finally, well-encapsulated carbon black by polymer was obtained in the size range of 100-500 nm. Throughout the polymerization, the effects of surface modification, types of monomers, initiators, and emulsifiers were investigated.