• 제목/요약/키워드: 피혁

검색결과 208건 처리시간 0.025초

유기성 폐기물에 의해 오염된 토양이 지렁이에게 미치는 독성 (Toxicity of Organic Waste-Contaminated Soil on Earthworm (Eisenia fetida))

  • 나영은;방혜선;김명현;이정택;안용준;윤성탁
    • 한국토양비료학회지
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    • 제40권1호
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    • pp.51-56
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    • 2007
  • 유기성폐기물을 농경지에 투여하기 위하여 작물에 미치는 영향, 토양에 축적되는 중금속 농도 분석이 이루어지고 있으나, 토양에 축적된 총 오염물질이 지렁이에게 얼마나 독성을 갖고 있는지가 구명되어 있지 못한 실정이다. 본 연구는 4종류 유기성 슬러지(생활하수슬러지, 공단하수슬러지, 피혁슬러지, 주정슬러지)와 돈분퇴비를 8년 동안 매년 ha당 12,5톤, 25.0톤, 50.0톤으로 처리한 토양에 대한 지렁이의 독성을 측정하였다. 공단하수슬러지를 처리한 토양를 돈분퇴비와 비교해 보면, 축적된 구리는 18.9~26.2배, 크롬은 7.7~34.7배, 니켈은 14.8~18.8배로 나타났고, 피혁슬러지의 크롬은 35.7~268.0배, 니켈은 14.8~18.8배가 축적되었다. 이렇게 오염된 토양에 지렁이를 8주와 16주 동안 각각 노출시켰다. 8주 노출에서 생활하수슬러지와 주정슬러지의 모든 처리토양과 피혁슬러지 25.0톤 처리 토양은 돈분퇴비와 비슷한 낮은 독성을 나타냈으나, 나머지 공단슬러지와 피혁슬러지의 지렁이 치사율은 26.7~96.7%으로 높게 나타났다. 16주 노출에서 주정슬러지 12.5톤, 25.0톤의 토양만 돈분처리 토양과 비슷한 낮은 지렁이 독성을 보였고, 나머지 처리토양들은 모든 53.3~100%의 지렁이 치사율를 나타냈다. 이러한 결과들은 주정슬러지 50.0톤 처리 토양을 제외한 다른 슬러지 처리 토양은 지렁이에게 독성을 가지는 것으로 나타났다.

피혁산업장의 휘발성유기화합물(VOCs) 배출 특성에 관한 연구 (A Study on the VOCs Emission Characteristics in Leather Industries)

  • 김선태;최일환;이규성
    • 한국대기환경학회지
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    • 제23권3호
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    • pp.332-343
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    • 2007
  • The concentrations of major volatile organic compounds (VOCs) were measured using a passive sampler in the leather industries, Shihwa and Banwol industrial complex. The leather industries were classified into four groups in raw materials and main product. The concentrations of total VOCs measured in process for ${\ulcorner}$ manufacture of reconstituted leather and special treated leather${\lrcorner}$was highest. The main VOCs measured in the leather industries was found to be toluene with a average concentration of 1,200 ppb. The major group selected in the leather industries was divided into three groups by the fingerprint analysis and the principal component analysis. The major VOCs in the groups classified by fingerprint analysis were found to be dependent on the characteristics of raw materials and main products.

피혁슬러지 고형화시 시멘트 혼화제의 영향 (The Effect of Cement Admixtures on Solidification of Tannery Sludge based Cement Method)

  • 주소영;박상찬;전태성;손종렬;김태영
    • 환경위생공학
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    • 제18권4호
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    • pp.36-44
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    • 2003
  • The cement-based system among S/S(Solidification/Stabilization) is widely used to treat hazardous wastes. In this study, tannery sludge was solidified to evaluate the stabilization effects of using admixtures in the cement-based S/S. Fly ash as substitute also used to increase the strength of the S/S of hazardous waste. The compressive strength measurement and leaching experiment of chromium metal of solidified mortar were carried out to compare and evaluate the physical and chemical characteristics of solidified hazardous waste sludge. From the result of this study, there was increased of compressive strength by using AEW-3(early-hardening AE water reducing agent), and leaching concentration of chromium became low enough to satisfy the regulatory criteria. The successful solidification for the organic contaminant and heavy metal in hazardous waste should enable to treat by cement-based system using early-hardening AE water reducing admixture and fly ash as substituted cement.

의류용 피혁의 크롬에 관한 연구 (A Study on the Chrome of Clothing Leathers)

  • Cho, Seung-Shick;Sim, Mi-Sook;Kim, Un-Bae
    • 한국염색가공학회지
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    • 제4권1호
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    • pp.16-20
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    • 1992
  • This study was to examine the dry cleaning resistance of chrome bonding in the chrome-tanned garment leathers, and to analyze their chrome content. The results are as follows: 1. The average percentage of the chrome content (as $Cr_2O_3$) in the chrome-tanned garment leathers was 2.7%. 2. By the dry cleaning treatment and its numbers, the values of chrome content were little affected. 3. The resistance against dry cleaning with perchloroethylene $(Cl_2C = CCl_2)$ of samples was confirmed.

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Full-Grain 피혁용 수용성 아크릴 Base coat 수지의 합성 및 물성측정 연구 (A Study of Synthesis and Mechanical property measurement for Waterborne Acrylic Base coat Resin in Full-Grain Leather)

  • 이주엽;김기준
    • 한국응용과학기술학회지
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    • 제28권3호
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    • pp.359-366
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    • 2011
  • In this study we experimented that how polyurethane effect to acrylic-polyurethane resin in Full-Grain leather coatings. First of all, we consummated waterborne acrylic emulsion and waterborne polyurethane resin, Than we prepared F.G leathers which were coated by acrylic resin and acrylic-polyurethane resins. According to measured data for solvent resistance, acrylic resin and acrylic-polyurethane resins had good property. Sample a(WAC) had most low strength($2.10kg_f/mm^2$) and sample d(WAC 93 : WPU 7) had most high strength($3.41kg_f/mm^2$). Also we knew that most good property of abrasion is d(47.4 mg). In elongation case, a(WAC) had most good result(645 %) in this experiment.

허니컴형 광촉매에 대한 암모니아와 트리메틸아민의 흡착 및 열 분해 특성 (Characteristics for Adsorption and Thermal Decomposition of Ammonia and Trimethylamine on Honeycomb Photocatalyst)

  • 김대중;손건석;고성혁;윤승원;송재원;강진아;이귀영;이재의
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2001년도 추계학술대회 논문집
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    • pp.295-296
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    • 2001
  • 동물 축사, 폐수 및 하수처리장, 피혁공장, 생선처리시설 등에서 주로 발생하는 암모니아(NH$_3$) 및 트리메틸아민(($CH_3$)$_3$N)과 같은 악취 물질 제거에 대한 많은 연구가 진행되고 있다. 악취 물질에 대한 처리 기술에는 직접 산화법, 고온 연소법, 효소분해법, 흡착법, 촉매 산화법, 플라즈마 제거법 등과 같은 악취 물질을 분해 제거하는 방법과 단순히 악취를 은폐시키는 마스킹법이 있다. (중략)

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비산회를 첨가한 피혁공장 크롬 슬러지의 고화시 압축강도 및 용출 특성 (The Characteristics of Compressive Strength and Leachability on Solidification of Chromium Tannery Sludge adding to Coal Fly Ash)

  • 주소영;연익준;신필식;전병진;김광렬
    • 환경위생공학
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    • 제16권1호
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    • pp.53-60
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    • 2001
  • In this study, the heavy metals in tannery sludge were solidified by using cement and power plant fly ash. Solidification characteristics were discussed with the compressive strength and chromium leaching characteristics of solids. The compressive strength of cement mortar was increased by the amount of fly ash up to 24.3~33.8%, which was considered the results of pozzolanic reaction. When the content of fly ash was 20%, cement mortar showed the highest value $295kg/\textrm{cm}^2$ for 28 days curing. At early curing days, solidified chromium tannery sludge solids were showed lower compressive strength because of the retard on the hydration of cement, but the compressive strength was recovered to be more than $140kg/\textrm{cm}^2$ for 28 days curing regardless with the amounts of fly ash. Also, the results of leaching tests by KSM and TCLP method were showed that the solidified chromium sludge have leached out 0.3~2.2% and 11~17%, respectively.

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자동차 내장 표피재의 평가 모델링 (Evaluation modeling for car seat covers)

  • 김주용;김안나;이채정;이창환
    • 한국감성과학회:학술대회논문집
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    • 한국감성과학회 2009년도 춘계학술대회
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    • pp.157-160
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    • 2009
  • 자동차는 지난 한 세기의 짧은 역사를 가지고 현재에 이르기까지 급속한 발전을 이루어왔다. 초기의 기능은 단순히 운송수단과 부의 상징이었지만 최근에는 소비자의 감성과 문화적인 흐름을 반영하는 모습이다. 그리하여 소비자의 감성 분석이 자동차 내장의 가장 중요한 부분으로 여기게 되었다. 자동차에 대한 새로운 감성요구를 실현하기 위해서는 인체와 오랜 시간 접촉해 있는 시트 표피재의 분석이 반드시 필요하다. 본 연구에서는 자동차 시트 표피재의 역학적 특성과 감성을 고려한 고급감을 예측하여 고감성 내장 표피재 개발에 기여하고자 한다. 감성용어는 Softness(유연한), Elasticity(탱글탱글한), Volume(풍성한), Stickiness(끈끈한)를 설정하였으며, 이와 대응하는 표피재의 역학적 특성 치를 측정하였다. 감성 평가에서는 현재까지 알려진 가장 확실하고 재현성 있는 측정법인 일대일 비교법을 통해 고급감에 대해 평가하였다. 이를 통하여 역학적 특성 치와 인간의 감성 평가 치와의 회귀 분석을 실시하여 평가 예측을 가능케 하였다. 즉, 자동차 표피재 중 피혁의 4 가지 물리량으로 인간의 감성인 표피재의 고급감을 예측하여 고감성 자동차 시트 표피재의 개발을 위한 평가 모델링을 구축하였다.

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한국에서의 피혁방미에 관한 연구 2 (Studies on the Antifungal Action of Leather in Korea (Part. 2))

  • 김종협;장건형;최춘언
    • 미생물학회지
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    • 제3권1호
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    • pp.18-23
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    • 1965
  • It seems like that the characteristics and drug-resistances of fungi are respectively different in various circumstances. Scores of chemicals were applicated to the leather-fungi in this study. M-dinitrobenzene, 2, 4-dinitrochlorobenzene and phenyl mercuric acetate inhibited the growth of Aspergilli which were isolated from Korean-leather. The minimum fungicidal limits of p-nitrophenol, 8-hydroxyquinoline and sodium-pentachlorophenolate against the Korean-originated strains are different from that of other country. In the mass-screening of fungicides, artificial "Leather-extracts media" have been designed and used, and the media contributed to screening-tests. Fat and oils which are the materials of fat-liquoring in leather manufacture affects the drugresistance of the leather-fungi. It is found that the accelerating-method on malt-agar plate is effective to determinate the fungicidal action of chemicals in short time.hort time.

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2단계 경화형 형상기억 폴리우레탄의 합성 및 분석 (Synthesis and Characteristics of 2 Step-curable Shape Memory Polyurethane)

  • 노건호;이승재;배성국;장성호;이원기
    • 한국환경과학회지
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    • 제27권11호
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    • pp.1023-1028
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    • 2018
  • Shape memory materials are widely used in high-tech industries. Although shape memory polymers have been developed, they have a disadvantage, only unidirectional resilience. Shape memory polymers with bi-directional recovery resilience have been actively studied. In this study, a bidirectional shape memory polyurethane was synthesized using poly(${\varepsilon}$-caprolactone) diol, methylene dicyclohexyl diisocyanate, and hydroxyethyl acrylate. The first physical curing occurred between hard segments and hydrogen bondings when the solution was dried. The second curing in acrylate groups was performed by UV exposure. A degree of curing was analyzed by infrared spectroscopy. The shape memory properties of 2 step-cured polyurethanes were investigated as a function of UV curing time.