• Elastomers and Composites
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• v.40 no.4
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• pp.249-257
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• 2005

Polyurethane(PU) prepolymers were prepared from polyol and diisocyanate. Unionized PU prepolymers were synthesized from poly(propylene glycol)(PPG, MW: 1000), 2,2-bis (hydroxymethyl) propionic acid(DMPA), and isophorone diisocyanate(IPDI) by prepolymer syhthesizing process. After PU prepolymers were dispersed into water, the physical properties were investigated by changing the molar ratio of polyol and diisocyanate. The results showed a stable state with the best physical properties when the prepolymer was composed of PPG/DMPA with hard segment=40%, NCO%=3.43%, [NCO]: [OH]=1.5: 1.0 in molar ratio, and was dispersed into water with 30% solid content. PU prepolymers also were synthesized with various molar ratio of PPG and DMPA. Upon higher molar ratio of DMPA, particle size of polyurethane dispersion(PUD) gradually decreased. PU-prepolymers prepared from the various blocking agents represented characteristic initial deblocking temperatures that depended on the blocking agents, and the beginning of deblocking occured within 30 mins on all the blocking agents used.

• Applied Chemistry for Engineering
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• v.9 no.4
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• pp.491-496
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• 1998

The composition of isocyanates and polyols influence prepolymeric properties of adhesive and calking sealant based on polyurethanes (PU). One component moisture curing prepolymers, which reacted with surface humidity of substrate, were synthesized in several kinds of composition. Reactivity, structural change and properties of the prepolymers were studied as a preliminary step to manufacture PU based adhesive and sealant. To study the effects of mole ratio ([NCO]/[OH]), we used toluene diisocyanate (TDI), 4, 4'-diphenylmethane diisocyanate (MDI), and ether-polyols such as PTMG and PPG which have good resistance to hydrolysis and excellent low-temperature properties. The each prepolymers could be prepared in different molecular weight without any significant structural change. The mole ratio 1.78 of [NCO] to [OH] showed the fastest reactivity. It was confirmed that effect of polyols was larger than that of isocyanates on the prepolymer in reactivity. Several kinds of compounds were manufactured with each prepolymer, and tensile and properties were tested. And the optimum quantity of curing accelerator for the PU was 0.05~0.1%. In the tensile test, TDI based PU was superior to MDI based PU, and also PTMG based PU was superior PPG based PU.

• Journal of the Korean Society of Clothing and Textiles
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• v.26 no.5
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• pp.684-690
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• 2002

The microcapsules containing fragrant material as functional compound were produced by in-situ polymerization. The prepolymer was made from urea-formaldehyde(UF) and melamine-formaldehyde(MF) as wall materials of microcapsules. The effects of wall material, dispersing agent and ratio of wall material to core material on the mean diameter variation were investigated. Thermal efficiency and release behavior of microcapsules were measured. The resultant UF and MF microcapsules are capable of preserving fragrant oil for long self-life.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2003.04a
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• pp.93-96
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• 2003

일반적으로 폴리우레탄계 마이크로캡슐은 양말단에 과량의 NCO기를 가지는 폴리우레탄 프리폴리머의 중합에 의한 것으로서, 이어서 수용액상에서 쇄연장제의 첨가에 의해 계면에서 완전한 폴리우레탄막을 중합하는 방법을 취하고 있다. 그러나 이러한 프리폴리머법에 의한 마이크로캡슐의 형성은 여러 가지 제조상의 문제점을 지니고 있다. Vanzo 등이 10$\mu\textrm{m}$이하의 작은 입자를 얻기 위해서는 비교적 고농도의 분산제와 높은 교반속도를 사용할 필요가 있었으며, 또한 그 입자크기분포의 제어가 어려웠다. (중략)

• Elastomers and Composites
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• v.44 no.1
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• pp.76-83
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• 2009

The purpose of this study was to investigate the effects of combined use of several types of silicone polymers on the physical properties of the dental polyvinylsiloxane impression materials (PVS). Four types of silicone prepolymers having different molecular weight and vinyl group position, and two types of cross-linkers having differently located silyl hydride functional groups were used in various combinations for the formulation. The samples containing bimodal or trimodal prepolymers showed higher tensile strength, elongation at break, and elastic deformation than those containing only one type of prepolymer. The samples using CR210 cross-linker which has side- and terminal-silyl hydride groups showed higher elastic deformation and elongation at break than those using CR101 cross-liker which has side-only silyl hydride group. High vinyl content prepolymer having side vinyl group delayed setting even though it enhanced tensile strength. Further studies are needed to clarify the specific role of this component on setting time and to find appropriate controlling methods for making improved PVS with optimum workability.

• Applied Chemistry for Engineering
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• v.16 no.1
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• pp.86-92
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• 2005

Poly(urethaneethyl acrylate) hybrid emulsions were synthesized to improve their thermomechanical and solvent resistance properties. In the synthesis, dimethylol propionic acid was used to impart hydrophilicity to the hybrid polymers, and ethyl acrylate monomer was added to the polyurethane prepolymer after neutralization with triethylamine. After dispersion of the neutralized prepolymer, chain extension was carried out with ethylene diamine. Consequently, poly(urethaneethyl acrylate) hybrid emulsion was prepared via soap free emulsion polymerization of ethyl acrylate with reduction-oxidation initiator couple of t-butyl hydroperoxide/sodium bisulfite at $50^{\circ}C$. Tehsile strength, 100% modulus, elongation, and solvent-resistance properties of the hybrid emulsion were measured and compared with those of polyurethane homopolymer, poly(ethyl acrylate) homopolymer, and simple blended samples.

• Journal of the Korea institute for structural maintenance and inspection
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• v.9 no.4
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• pp.235-242
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• 2005

This study is on the evaluation of performance of polymer cement mortar which is used for pre-wetting spray method. Pre-wetting spray method is an epoch-making method to repair concrete structures damaged, which is added a small quantity water preciously to dry mortar to reduce dust and rebound and spray mortar mixed with fixed quantity water at nozzle before spray. The result showed that physical performance such like compressive, flexural and adhesive strength of polymer cement mortar, TS 100 used for pre-wetting spray method was superior to other repair mortar. Also durable performance such as resistance on permeability of chloride ion, carbonation, chemical and freezing-thawing was excellent.

• 한국정보통신설비학회:학술대회논문집
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• 2007.08a
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• pp.315-319
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• 2007

지하에 설 치된 맨홀의 구조물이 노후되거나, 내부에 수 용된 시설물로 작업 공간이 협소하여 맨홀 구조물을 대개체 할 펼요가 있을 경우, 지금까지는 대부분 현장 콘크리트 타설에 의한 방법을 사용하였다. 이러한 방법은 거푸집 시공, 콘크리트 타설, 콘크리트 양생, 거푸집 철거 등의 공정이 소요되어 공사 기간이 장기화 되고, 도심지에 위치한 맨홀인 경우에는 차량과 보행자의 통행 불편을 초래하기도 하였다. 또한, 통상적으로 사용되고 있는 프리캐스트 맨홀에 비해 시공 품질이 낮아 향후 맨홀의 운용 및 유지관리에 많은 어려움을 겪는 원인이 되기도 하였다. 본 논문에서는 이러한 문제점들을 해결하기 위해, 폴리머 콘크리트를 이용하여 하부, 벽체, 상부로 구성된 다수의 세그먼트를 생산한 후, 현장에서 이들 세그먼트를 조립하여 맨홀을 설치하는 방법을 연구하였다. 가변형 거푸집을 이용한 세그먼트 제작과 조립식 블록에 의한 관구를 사용하여 현장 적용성을 높임은 물론, 프리캐스트로 생산되는 폴리머 콘크리트 맨홀 수준의 시공 품질을 확보할 수 있도록 하였다.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 1996.11a
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• pp.193-198
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• 1996

고연소속도 HTPB/AP 추진제를 얻기 위하여 현재 각광받고 있는 3종의 철화합물 연소촉매를 선정하여 연소속도 증진효과와 기계적 특성, 공정성 및 노화특성에 미치는 영향을 검토하였다. 사용한 철 화합물은 HTPB 프리폴리머에 silicone-ferrocene이 그라프트된 $BUTACENE^$\circledR$$ 과 결합제 역할을 하는 acylaziridinyl ferrocene(AAF), 그리고 입자크기가 30nm인 $NANOCAT^$\circledR$$ superfine iron oxide(SFIO)이었다. 이들 철 화합물을 추진제에 적용한 결과 공정성의 경우 $BUTACENE^$\circledR$$ 은 혼합점도가 높았으나 pot life의 감소는 없었으며 AAF와 SFIO는 혼합점도는 비교적 낮은 반면 pot life가 현저히 감소하는 경향을 보였다. 추진제의 노화거동은 연소촉매를 사용하지 않았을 때보다 저하되었으나 metal deactivating 산화방지제인 $PRO-TECH^$\circledR$$ 과 함께 사용할 경우 공정성 및 노화특성 모두 바람직한 수준으로 향상되었다. 기계적 특성은 SFIO를 제외하고는 저하되었으며 $BUTACENE^$\circledR$$ 은 프리폴리머로서, AAF는 결합제로서의 기능이 다소 미흡하였다. 한편 연소촉매의 함량에 따른 촉매효과는 AAF>SFIO>$BUTACENE^$\circledR$$ 순이었고 철 함량 측면에서는 AAF>$BUTACENE^$\circledR$$ >SFIO 순이었다.

• Journal of the Korea Concrete Institute
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• v.24 no.2
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• pp.103-109
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• 2012

Micro-cracks with a width less than 0.1 mm in precast concrete panels do not cause structural problem, but they can cause problems in long term durability and concrete surfaces aesthetic, requiring additional repair costs. In this paper, polymer cement concrete is used to increase flexural tensile strength and to prevent micro-cracks due to construction loads on LB-DECK panels. Using 5% polymer-cement ratio, the panel crack moment is increased by improving flexural tensile strength and controlling visible micro-cracks during construction stage of LB-DECK.