• Korean Journal of Environmental Agriculture
• /
• v.30 no.2
• /
• pp.169-178
• /
• 2011

BACKGROUND: This study aimed to estimate the measurement uncertainty associated with determination of cadmium and lead from tomato paste by ICP/MS. The sources of measurement uncertainty (i.e. sample weight, final volume, standard weight, purity, molecular weight, working standard solution, calibration curve, recovery and repeatability) in associated with the analysis of cadmium and lead were evaluated. METHODS AND RESULTS: The guide to the expression of uncertainty was used for the GUM (Guide to the expression of Uncertainty in Measurement) and Draft EURACHEM/CITAC (EURACHEM: A network of organization for analytical chemistry in Europe/Co-Operation on International Traceability in Analytical Chemistry) Guide with mathematical calculation and statistical analysis. The uncertainty components were evaluated by either Type A or Type B methods and the combined standard uncertainty were calculated by statistical analysis using several factors. Expected uncertainty of cadmium and lead was $0.106{\pm}0.015$ mg/kg (k=2.09) and $0.302{\pm}0.029$ mg/kg (k=2.16), on basis of 95% confidence of Certified Reference Material (CRM) which was within certification range of $0.112{\pm}0.007$ mg/kg for cadmium (k=2.03) and $0.316{\pm}0.021$ mg/kg for lead (k=2.01), respectively. CONCLUSION(s): The most influential components in the uncertainty of heavy metals analysis were confirmed as recovery, standard calibration curve and standard solution were identified as the most influential components causing uncertainty of heavy metal analysis. Therefore, more careful consideration is required in these steps to reduce uncertainty of heavy metals analysis in tomato paste.

• Journal of the Korean Vacuum Society
• /
• v.14 no.2
• /
• pp.59-68
• /
• 2005

We developed a national medium vacuum standard by static expansion method. A 133 Pa capacitance diaphragm gauge was calibrated and analysed according to the document of 'Guide to the Expression of Uncertainty in Measurement' of ISO. The results showed that the expanded uncertainty of $2.628\times10^{-3}$ Pa at $95\%$ confidence level and coverage factor of k=2.

• Journal of the Korean Society of Visualization
• /
• v.3 no.2
• /
• pp.71-78
• /
• 2005

Uncertainty introduced by a cross-correlation algorithm based on FFT has been investigated using PIV standard images. The standard images were generated by the Monte Carlo simulation method. Both bias and random errors from the velocity vector have been analyzed with regard to the particle diameter, displacement, and the number of particles. The uncertainty of velocity is evaluated based upon the IS0/IEC standard. As a result, a total error of $0.26\%$ is included in the PIV cross-correlation algorithm. In addition, the uncertainty budget is presented, where the effect of the above three variables is examined. According to the budget, the variation of the number of particles within the interrogation window mainly contributes to the combined standard uncertainty of the real measured velocity field when excluding the effect of errors by the experiments itself. Finally, the expanded uncertainty is found to be about $12\%$ at the $95\%$ confidence level.

• Journal of the korean academy of Pediatric Dentistry
• /
• v.47 no.4
• /
• pp.416-426
• /
• 2020

The purpose of this study was to calculate uncertainty of orthodontic measurement in skeletal class III malocclusion children using lateral cephalometry analysis software which obtained traceability in previous study. Using this data, standard reference of measurement value for skeletal class III malocclusion was obtained. Lateral cephalometric data was collected from 144 children who visited Pediatric Dentistry from 2017 to 2020 for orthodontic treatment. Orthodontic measurement was analyzed with software which obtained traceability. Type A evaluation of uncertainty and type B evaluation of uncertainty was calculated to obtain combined standard uncertainty and expanded uncertainty. Standard reference of skeletal class III children was compared to standard reference of skeletal class I children. Distribution range for skeletal class III malocclusion children aged 6 to 10 with 95% confidence interval was provided using calculated uncertainty of orthodontic measurement value.

• Proceedings of the Korea Electromagnetic Engineering Society Conference
• /
• 2001.11a
• /
• pp.310-314
• /
• 2001

측정의 소급성과 신뢰성을 확보한다는 전제하에 오차의 개념을 버리고 측정시의 측정불확도를 분석하는 것이 측정과학에 있어서 세계적인 추세이다. 본 논문에서는 전달표준인 열전압변환기를 사용하여 고주파전압계의 정밀 교정에서 불확도를 산출하기 위하여 수학적 모델을 설정하고 측정에 관계되는 모든 불확도 요인을 분석하였다. 케이블의 영향과 열전대감지기와 직류전압계의 상관관계, 직류소스, RF소스, 감쇠기, 반사계수와 DUT 등 측정에 있어서 관계되는 모든 불확도요인을 분석하여 확장불확도를 산출하였다.

• Proceedings of the Optical Society of Korea Conference
• /
• 2003.07a
• /
• pp.280-281
• /
• 2003

광도 측정의 기본단위인 칸델라 눈금을 확립하는 방법에는 흑체에서 방출되는 분광복사휘도를 기준으로 사용하는 광원 기반 방법과 극저온 절대 복사계(absolute cryogenic radiometer； ACR)로 부터 출발하여 실현하는 검출기 기반의 두 가지 방법이 사용된다. ACR를 사용하면서 검출기 기반 칸델라 눈금의 불확도가 흑체의 온도 측정 불확도로부터 전파되는 불확도 보다 휠씬 작기 때문에 각국의 국가 측정 표준 대표기관에서 검출기 기반 칸텔라 눈금을 실현하고, 교정이나 측정 서비스를 제공하고 있다. (중략)

• Korean Journal of Optics and Photonics
• /
• v.15 no.3
• /
• pp.258-262
• /
• 2004

The uncertainty of the detector-based candela scale is limited by the area measurement uncertainty of radiometric apertures. The apertures were fabricated with a diamond-turning machine which trimmed the edge of the apertures as sharply as a knife edge. The positions of the apertures were controlled by a digital feedback algorithm to scan the laser spot with the beam waist less than 5 ${\mu}{\textrm}{m}$. The knife edge scan yielded a set of coordinates on the edges of the aperture. The areas of the apertures were obtained by fitting the coordinates to the ellipses. The relative standard uncertainty of the measurement was estimated to be 8${\times}$10$^{-5}$.

• Analytical Science and Technology
• /
• v.23 no.4
• /
• pp.363-370
• /
• 2010

This study was performed to validate reference materials (RMs) for proficiency testing (PT) in waste inter-laboratories. Dioxin RMs were prepared from fly ash in industrial incinerators. The relative standard deviations (RSDs) of analytical results were 2.6~15.7% for the dioxin RMs in 10 replicates (between and withinbottles). Data were collected and statistical analysis was performed by the One-way ANOVA test. The combined uncertainties of target isomers in dioxin analysis were 0.114~7.091.

• The Journal of the Acoustical Society of Korea
• /
• v.42 no.2
• /
• pp.143-151
• /
• 2023

In this paper, a method for evaluating the measurement uncertainty is proposed when measuring of floor impact sound insulation of buildings using standard heavy impact source. In addition to the effect of repeated measurements, several other factors such as measurement location, impact location, equipment used for sound pressure measurement, and heavy impact source, were considered. A mathematical model for the average maximum impact sound level and the uncertainty evaluation method for each factor were proposed. The present proposed method was applied to measurement results to evaluate the average maximum impact sound pressure level and the measurement uncertainty.

• Korean Journal of Ecology and Environment
• /
• v.40 no.2
• /
• pp.193-200
• /
• 2007

The objective of this study was to estimate uncertainty of online TOC analyzer in water quality monitoring system. A procedure for the estimation of measurement uncertainty of total organic compounds (TOC) based on the ISO approach is presented. It is based on a mathematical model that involves 4 input parameters (standardization, sensitivity, solute effect and representativeness). In this study, a major problem in estimating the uncertainty of online TOC analyzer was the solute effect. It was strongly depends on organic materials. So homogeneity of the sample is the most important consideration. Modified concentration and combined standard uncertainty was $4.71{\pm}0.36$ mg $L^{-1}$ by model modified in this study.