• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2009.05a
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• pp.123-124
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• 2009

염화물이 전기아연도금에 미치는 영향을 분석해본 결과 염화물의 양이 부족한 경우에는 도금이 원활하지 않았지만 교반속도를 충분히 주면 도금이 가능하였고, 염화칼륨의 양에 따라서 우선성장하는 면이 달랐으며 가격이 비싼 염화칼륨을 염화나트륨으로 대체 가능성이 확인되었다.

• Journal of the Korean Society of Marine Environment & Safety
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• v.20 no.6
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• pp.730-737
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• 2014

In this study, chloride content of marine concrete bridge at the south coast in 5~34years was calculated based on the measured data and the validity of the proposed value was evaluated. Also, correlation of existence of salt injury prevention coating, chloride content, carbonation depth and the compressive strength of marine concrete bridges were derived and relationship of the four was evaluated. According to the research results, surface chloride content value in the tidal zone proposed form KCI 2009 and value in the splash zone and atmospheric zone proposed form Cheong et al.(2005) was the most valid. Also, salt injury prevention coating of marine concrete bridges had the outstanding effect of preventing chloride content penetration, carbonation depth and reduction in the compressive strength. Compressive strength of concrete was reduced by the increase of carbonation depth and chloride content.

• The Journal of the Korea Contents Association
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• v.16 no.4
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• pp.114-122
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• 2016

Concrete is cost-benefit and high-durable construction material, however durability problem can be caused due to steel corrosion under chloride attack. Recently deicing salt has been widely spread in snowing season, which accelerates micro-cracks and scaling in surface concrete and the melted deicing salt causes corrosion in embedded steel. The previous governing equation of Fick's 2nd Law cannot evaluate the deteriorated surface concrete so that another technique is needed for the surface effect. This paper presents chloride penetration analysis technique for concrete subjected to deicing salt utilizing multi-layer diffusion model and time-dependent diffusion behavior. For the work, field investigation results of concrete pavement exposed deicing salt for 18 years are adopted. Through reverse analysis, deteriorated depth and increased diffusion coefficient in the depth are evaluated, which shows 12.5~15.0mm of deteriorated depth and increased diffusion coefficient by 2.0 times. The proposed technique can be effectively applied to concrete with two different diffusion coefficients considering enhanced or deteriorated surface conditions.

• Journal of the Korea institute for structural maintenance and inspection
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• v.21 no.2
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• pp.46-52
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• 2017

Recently durability design based on deterministic or probabilistic method has been attempted since service life evaluation in RC(Reinforced Concrete) structure exposed to chloride attack is important. The deterministic durability design contains a reasonable method with time effect on surface chloride content and diffusion coefficient, however the probabilistic design procedure has no consideration of time effect on both. In the paper, a technique on PDF(Probability of Durability Failure) evaluation is proposed considering time effect on diffusion and surface chloride content through equivalent surface chloride content which has same induced chloride content within a given period and cover depth. With varying period to built-up from 10 to 30 years and maximum surface chloride content from $5.0kg/m^3$ to $10.0kg/m^3$, the changing PDF and the related service life are derived. The proposed method can be reasonably applied to actual durability design with preventing conservative design parameters and considering the same analysis conditions of the deterministic method.

• Journal of the Korea Concrete Institute
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• v.15 no.6
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• pp.794-801
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• 2003

As it is important to measure the degree of the deterioration and predict service life caused by chloride in concrete structure the methods of measuring chloride in the concrete is raised important problems. This study is to set a new standard for using of the colorimetric method through grasping the character of the colorimetric distinction method, and measuring the chloride content at the place discolored. Also, to predict chloride content around embeded bar and time reaching limit chloride concentration through measuring the chloride content of concrete surface by colorimetric distinction method and this study presents the new concept of concrete degradation and diagnosis of the durability by salt damage. According the results, it is possible to use colorimetric distinction method as simplified measurement to measure the fixed quantity of the chloride concentration. What is more, it would make calculation of concrete surface chloride had a wide fluctuation at the general environment extended. Also, it would be make estimating durability of reinforced concrete structures applied to the basic data.

• Journal of the Korea institute for structural maintenance and inspection
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• v.17 no.1
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• pp.64-75
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• 2013

As both laboratory accelerated experiment and field exposure experiment were performed, at recent, the fifth field test at five year exposures was proceeded according to long period experimental plan. Field experiment, for the adoption of the developed evaluation model, which is consisted of the analysis of chloride penetration profile at gate bridges of sea-dike completed 30 years ago was carried out during upgrading the basic evaluation model with analyzing the annual field test data. The surface concentration of chlorides was replaced to the concentration of chloride of inner concrete near the surface chlorides among his research results at basic model. Maage's suggestion function was accepted too as a diffusion coefficient of chloride after verifying the change of diffusion coefficient by analysis of annual field test data. The comparison of field data with model predictions and the estimation of remaining life time demonstrates that the proposed updated model and maintenance simulation system can be used to predict the chloride penetration profile in the marine tidal zone and appropriate repair period and cost.

• Journal of the Korea Concrete Institute
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• v.18 no.1 s.91
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• pp.65-71
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• 2006

Concrete has a void, which exists as one of defect in concrete. If the porosity of concrete increases, durability of concrete decreases. In this paper, to improve surface void of concrete, surface penetration sealers are applied to specimen. And, it were investigated that the resistances of chloride penetration and freezing and thawing for concrete with surface penetration sealer of two types. According to the results, surface penetration sealer has not show a harmful influence on strength and resistance of freezing and thawing. Surface penetration sealers were effective in the resistance of chloride penetration.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.6
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• pp.18-25
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• 2019

The cracks occurred during service life of concrete structure should be considered in durability design, because of the concrete's material property which is weak in tensile strength. In this study, the fly ash concrete mixtures considering 2 levels of strength is designed and outdoor exposure tests are conducted for those concrete specimens. The exposure environment is set to a splash zone, and in order to evaluate the effect of crack width on the behavior of chloride diffusion, the crack width of up to 1.0 mm is generated at intervals of 0.1 mm at each concrete mixture. After that, apparent chloride diffusion coefficient and surface chloride contents are deducted considering 3 levels of exposure periods(180 days, 365 days, 730 days). The diffusion coefficients of two types of mixture increase with the increase of crack width, and the diffusion coefficients decrease with the increase of exposure periods. In addition, the effect of the crack width on the diffusion coefficient is reduced as the exposure periods increase, which is attributed to the extra hydrate by chloride ion reducing the diffusivity of concrete. The behavior of the surface chloride contents does not significantly change by the increase in crack width, compared to the behavior of apparent chloride diffusion coefficient. Also, In the high strength FA concrete mixture, the surface chloride contents are 78.9 % ~ 90.7 % than the normal FA strength concrete mixture. Thus, Surface chloride contents have correlation with the strength of concrete.

• The Korean Journal of Zoology
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• v.30 no.3
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• pp.239-247
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• 1987

생쥐 신장의 근위세뇨관과 원위세뇨관 세포의 미세구조에 미치는 염화 메틸수은의 독성에 대한 홍삼유출물의 첨독성적 영향을 전자현징경적으로 연구하였다. 염화 메틸수은 처리군의 근위세뇨관 세포에서는 대조군에서 보다 철세 융모가 다소 축소되고 불규칙한 배열을 하였다. Brush border의 인접 부위에서는 작은 경계들이 나타나고 세포질 중앙 부위에서는 치밀체를 함유한 큰 육포들이 관색되었다. Mitochondria는 상당히 팽대되고 기양막은 부분적으로 비후되었으며 다수의 ITsosome이 나타났다. 염화 메틸수은 처리군의 원위세뇨관 세롱에서는 불규칙한 세포 표면, 양사된 세포, 그리고 다수의 ribosome과 소수의 지방사이 나타났으며 mitochondria 는 팽대되고 기고막은 부분적으로 비후되었다. 염화 메틸수은-홍삼추출물 병행 처리군의 근위세뇨관 세포에서는 염화 메틸수은 처리군에서 보다 mitochondria의 팽대 정도가 감소되었으며 육포의 크기와 수도 상당히 감소되었다. 염화 메틸수은-홍모적출물 병행 처리군의 원위세뇨관 세롱에서는 세포 표면이 어느정도 규칙적이고 mitochondria의 정해와 기저막의 비후 정도가 감소되어 정상 세포와 거의 유사하였다.

• Journal of the Korea institute for structural maintenance and inspection
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• v.19 no.5
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• pp.83-91
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• 2015

With varying conditions of concrete surface, induced chloride contents are changed and this is a key parameter for steel corrosion and service life in RC (Reinforced Concrete) structures. Many surface enhancement techniques using impregnation have been developed, however the evaluation techniques for chloride behavior through doubly layered media and time-dependent diffusion are rarely proposed. This paper presents an analysis technique considering double-layer concrete and time-dependent diffusion behavior, and the results are compared with those from the previous test results through reverse analysis. The chloride profiles from the surface-impregnated concrete exposed to atmospheric, tidal, submerged zone for 2 years are adopted. Furthermore surface chloride contents and diffusion coefficients are obtained, and are compared with those from Life365. Through consideration of time effect, the relative error decreases from 0.28 to 0.20 in atmospheric, 0.29 to 0.11 in tidal, and 0.54 to 0.40 in submerged zone, respectively, which shows more reasonable results. Utilizing the diffusion coefficients from Life365, relative errors increases and it needs deeper penetration depth (e) and lower diffusion coefficient ratio ($D_1/D_2$) due to higher diffusion coefficient.