• Title/Summary/Keyword: 표면물성

Search Result 1,470, Processing Time 0.027 seconds

Physical Properties of the Silica-Reinforced Tire Tread Compounds by the Increased Amount of Vulcanization Agents (가교제 증량이 트레드용 실리카 컴파운드의 물성에 미치는 영향)

  • Seo, Byeongho;Kim, Ki-Hyun;Kim, Wonho
    • Elastomers and Composites
    • /
    • v.48 no.3
    • /
    • pp.201-208
    • /
    • 2013
  • In this study, effect of different amounts of sulfur and vulcanization accelerators in the acrylonitrile styrene-butadiene rubber (AN-SBR)/silica compounds on the properties of tire tread compound were studied. As a result, cure rate and degree of cross-linking of the compounds were increased due to enhanced cross-linking reactivity by the increased amounts of sulfur and vulcanization accelerators. Also, abrasion resistance and the mechanical properties such as hardness and modulus of the compounds were improved by enhanced degree of cross-linking of the compounds. For the dynamic properties, tan ${\delta}$ value at $0^{\circ}C$ was increased due to the increase of glass transition temperature ($T_g$) by enhanced degree of cross-linking of the compound, and tan ${\delta}$ value at $60^{\circ}C$ was decreased. Initial cure time ($t_1$) showed the linear relationship with tan ${\delta}$ value at $60^{\circ}C$. This result is attributed that reduced initial cure time ($t_1$) of compounds by applying increased amount of curatives can form cross-linking in early stage of vulcanization that may suppress development of filler network. This result is verified by observation on the surface of annealed compounds using AFM (atomic force microscopy). Consequently, decreased initial cure time is considered a very important parameter to reduce tan ${\delta}$ at $60^{\circ}C$ through reduced re-agglomeration of silica particles.

가스치환포장 및 감마선을 병용처리한 최소가공 절임배추의 품질특성

  • 안현주;김재현;김재경;조철훈;김장호;육홍선;변명우
    • Proceedings of the Korean Society of Postharvest Science and Technology of Agricultural Products Conference
    • /
    • 2003.10a
    • /
    • pp.185.2-186
    • /
    • 2003
  • 세계적으로 최소가공식품(minimally processed foods)의 시장이 확대되면서, 최소가공된 과채류의 미생물학적 안전성 확보가 중요한 사안으로 대두되고 있다. 이에 본 연구는 김치제조용 원료배추를 모델로 하여 감마선 및 가스치환 포장법을 병용한 절임배추의 미생물학적, 이화학적 특성을 평가하였다. Fresh-cut상태의 절임배추(염농도 3%)를 각각 air, 100% $CO_2$, 25% $CO_2$/75% $N_2$가스를 주입하여 포장한 후 0, 0.5, 1, 2 kGy의 선량으로 감마선 조사하여 3주 동안 저장하면서 분석에 사용하였다. Total aerobic bacteria, coliforms, Salmonella, lactic acid bacteria의 분포를 살펴본 결과, $CO_2$혹은 $CO_2$/$N_2$포장과 감마선을 병용처리한 경우 저장기간 동안 total aerobic bacteria, coliforms 및 Salmonella 모두 1kGy의 선량에서 90% 이상 감소시킬 수 있는 것으로 나타나, 일반 함기포장보다 효과적인 것으로 나타났다. 색도 및 물성은 포장방법에 따른 차이를 보이지 않았으며, pH의 경우도 감마선 조사 및 가스치환 포장시 더욱 효과적으로 유지할 수 있었다. FRAP(ferric reducing antioxidant power) value 및 DPPH radical 소거능과 같은 생리활성 능력을 측정한 결과 포장방법 및 감마선 조사에 의한 차이를 보이지 않았다. 따라서 가스치환 포장 및 감마선 조사를 병용시 함기포장구 보다 낮은 감마선 조사선 량에서 병원성 미생물을 제어할 수 있었으며, 이화학적 품질이 우수하고 저장성이 향상된 절임배추를 제조할 수 있었다.7로 4$0^{\circ}C$ 진공건조와 -7$0^{\circ}C$ 동결건조의 L값 변화보다 큰 변화를 보였고, 또한‘a’값과 ‘b’값의 경우도 마찬가지로 5$0^{\circ}C$ 열풍건조의 경우가 양파의 내부와 외부면의 적색도 및 황색도 변화가 크게 일어나는 경향을 나타내었다. 건조과정 중 vitamin C의 함량변화는 건조에 의한 수분함량의 감소로 vitamin C의 함량은 상대적으로 증가하였고, -7$0^{\circ}C$ 동결건조의 경우가 가장 높은 vitamin C의 증가량을 나타내었고, 그와 반대로 5$0^{\circ}C$ 열풍건조의 경우는 열에 의한 vitamin C의 변화로 인한 상대적 증가량은 감소하는 경향을 나타내었다.아현미가 더욱 조밀하였다. 10시간 탈삽처리에서 상품성이 우수하였다. 그러나 25'E 28시간 탈삽처리는 탈삽의 균일도가 다른 처리에 비해 떨어지는 경향이었다. 경우, 사과표피의 색도 변화를 현저히 지연시킴을 확인하였다. 또한 control과 비교하여 성공적으로 사과에 코팅하였으며, 상온에서 보관하여을 때 사과의 품질을 30일 이상 연장하는 효과를 관찰하였다. 이들 결과로부터 대두단백질 필름이 과일 등의 포장제로서 이용할 가능성을 확인하였다.로 [-wh] 겹의문사는 복수 의미를 지닐 수 없 다. 그러면 단수 의미는 어떻게 생성되는가\ulcorner 본 논문에서는 표면적 형태에도 불구하고 [-wh]의미의 겹의문사는 병렬적 관계의 합성어가 아니라 내부구조를 지니지 않은 단순한 단어(minimal $X^{0}$ elements)로 가정한다. 즉, [+wh] 의미의 겹의문사는 동일한 구성요 소를 지닌 병렬적 합성어([$[W1]_{XO-}$ $[W

  • PDF

Quality of Jeju Island's Indigenous Pork Fed with Dried Citrus Byproducts (건조 감귤부산물을 급여한 제주도 재래돼지의 품질)

  • Jung, In-Chul;Moon, Yoon-Hee;Yang, Seung-Joo
    • Journal of the Korean Society of Food Science and Nutrition
    • /
    • v.36 no.2
    • /
    • pp.228-232
    • /
    • 2007
  • The purpose of the study was to investigate the quality characteristics of Jeju island's indigenous pork fed with citrus byproducts. Samples were the Jeju island's indigenous pork loin without citrus byproduct (JNP-0) and the Jeju island's indigenous pork loin fed with 8% and 15% citrus byproducts during growing and fattening periods (JNP-1). The pH, VBN content, bacterial counts, L* value, frozen loss, thawing loss, water boiling loss, hardness, springiness, cohesiveness, chewiness, and shear force value were not significantly different between JNP-0 and JNP-1 (p<0.05). The TBARS, a* value, b* value, water holding capacity, and pan boiling loss of JNP-0 were significantly higher than those of JNP-1 (p<0.05), but the gumminess of JNP-1 was significantly higher than that of JNP-0 (p<0.05). For sensory characteristics, taste, flavor, juiciness, and palatability were not significantly different between JNP-0 and JNP-1, but tenderness of JNP-1 was sig-nificantly higher than that of JNP-0 (p<0.05).

Interfacial Properties and Stress-Cure Sensing of Single-Shape Memory Alloy (SMA) Fiber/Epoxy Composites using Electro-Micromechanical Techniques (미세역학적 시험법을 이용한 단-섬유 형태 형상기억합금/에폭시 복합재료의 계면특성 및 응력-경화 감지능)

  • Jang, Jung-Hoon;Kim, Pyung-Gee;Wang, Zuo-Jia;Lee, Sang-Il;Park, Joung-Man
    • Journal of Adhesion and Interface
    • /
    • v.9 no.3
    • /
    • pp.20-26
    • /
    • 2008
  • It is well know that the structure of shape memory alloy (SMA) can change from martensite austenite by either temperature or stress. Due to their inherent shape recovery properties, SMA fiber can be used such as for stress or cure-monitoring sensor or actuator, during applied stress or temperature. Incomplete superelasticity was observed as the stress hysteresis at stress-strain curve under cyclic loading test and temperature change. Superelasticity behavior was observed for the single-SMA fiber/epoxy composites under cyclic mechanical loading at stress-strain curve. SMA fiber or epoxy embedded SMA fiber composite exhibited the decreased interfacial properties due to the cyclic loading and thus reduced shape memory performance. Rigid epoxy and the changed interfacial adhesion between SMA fiber and epoxy by the surface treatment on SMA fiber exhibited similar incomplete superelastic trend. Epoxy embedded single SMA fiber exhibited the incomplete recovery during cure process by remaining residual heat and thus occurring residual stress in single SMA fiber/epoxy composite.

  • PDF

Evaluation of Fiber Arrangement Condition of CF/PP Composites Using Electrical Resistance Measurement and Wettability (전기저항 평가법 및 접촉각을 이용한 CF/PP 복합재료 사출성형품 섬유 배열성 평가)

  • Kwon, Dong-Jun;Shin, Pyeong-Su;Kim, Jong-Hyun;Park, Joung-Man
    • Journal of Adhesion and Interface
    • /
    • v.17 no.1
    • /
    • pp.15-20
    • /
    • 2016
  • Fiber arrangement was important for fiber reinforced thermoplastic composites using injection fabrication. In this work, fiber arrangement in CF/PP was investigated to use electrical resistance (ER) method during injection times. There were 3 types of injection products of CF/PP with different ER change ratio by fiber arrangement. High ER change ratio case of injection CF/PP products had better increased tensile strength. This reason was due to the fiber arrangement of CF/PP by injection. Fractured surface and contact angle of CF/PP products were used to evaluate for injection product quality. Uniform fiber arrangement of CF/PP by injection type exhibited the uniform heat condition of melted CF/PP. Steady thermal transfer effect occurred from melted CF/PP to steel injection mold. Steady thermal transfer effect of CF/PP was transmitted to high ER change ratio of mold. Ultimately, good condition CF/PP product by injection molding method could be predicted by using ER method.

Thermal and Mechanical Properties of Epoxy Composites Using Silica Powder (실리카 파우더를 이용한 에폭시 복합소재의 열적/기계적 특성)

  • Lee, Hye Ryeon;Song, JeeHye;Kim, Daeyeon;Lim, Choong-Sun;Seo, BongKuk
    • Journal of Adhesion and Interface
    • /
    • v.17 no.1
    • /
    • pp.7-14
    • /
    • 2016
  • Epoxy composites with concentrations of 5-70 wt% of silica particles were prepared in order to improve mechanical property and poor thermal stability. The mechanical and thermal properties were investigated and compared to the corresponding properties of neat epoxy composite. Furthermore, the effects of silane compound treatment on silica particles were observed by the experimental results of the tensile strength, glass transition temperature, and thermal stability of epoxy composite. Tensile strength of epoxy composites was measured by universal testing machine (UTM) and after that, the structure and morphology analysis of epoxy nanocomposites were analyzed by field emission scanning electron microscope (FE-SEM) and energy dispersive spectroscopy (EDS). The increased solid content of CA0030 particle improved the tensile strength of epoxy/ modified composites to give 30-50 MPa. The thermal expansion coefficients (CTE) of neat epoxy resin and epoxy/silica composites measured with a thermomechanical analyzer (TMA) showed that the incorporation of silica particles was helpful to reduce the CTE of neat epoxy resin.

Evaluation on Rear Fracture Reduction and Crack Properties of Cement Composites with High-Velocity Projectile Impact by Fiber Types (섬유 종류에 따른 시멘트복합체의 고속 비상체 충격에 대한 배면파괴저감 및 균열특성 평가)

  • Han, Sang-Hyu;Kim, Gyu-Yong;Kim, Hong-Seop;Kim, Jung-Hyun;Nam, Jeong-Soo
    • Journal of the Korea Concrete Institute
    • /
    • v.27 no.2
    • /
    • pp.157-167
    • /
    • 2015
  • Cement composites subjected to high-velocity projectile shows local failure and it can be suppressed by improvement of flexural toughness with reinforcement of fiber. Therefore, researches on impact resistance performance of cement composites are in progress and a number of types of fiber reinforcement are being developed. Since bonding properties of fiber with matrix, specific surface area and numbers of fiber are different by fiber reinforcement type, mechanical properties of fiber reinforced cement composites and improvement of impact resistance performance need to be considered. In this study, improvement of flexural toughness and failure reduction effect by impact of high-velocity projectile have been evaluated according to fiber type by mixing steel fiber, polyamide, nylon and polyethylene which are have different shape and mechanical properties. As results, flexural toughness was improved by redistribution of stress and crack prevention with bridge effect of reinforced fibers, and scabbing by high-velocity impact was suppressed. Since it is possible to decrease scabbing limit thickness from impact energy, thickness can be thinner when it is applied to protection. Scabbing of steel fiber reinforced cement composites was occurred and it was observed that desquamation of partial fragment was suppressed by adhesion between fiber and matrix. Scabbing by high-velocity impact of synthetic fiber reinforced cement composites was decreased by microcrack, impact wave neutralization and energy dispersion with a large number of fibers.

Quality Characteristics of Yanggeng Sweetened with Trehalose and Textural Changes During Storage (트레할로스 첨가량과 저장시간에 따른 양갱의 품질 특성)

  • Jung, HyoSun;Lee, JongSuck;Yoon, HyeHyun
    • Culinary science and hospitality research
    • /
    • v.20 no.3
    • /
    • pp.113-124
    • /
    • 2014
  • This study investigated the quality characteristics of Yanggeng sweetened with various amounts of trehalose (0, 40, 60, 80, 100 % of trehalose) and their changes during storage times. The moisture content, color value, $^{\circ}Brix$, pH, texture profile, QDA and acceptance for samples were tested. As a result of the mechanical tests, moisture content and pH were increased while hardness were decreased with increased trehalose content. Also, moistness, gloss and after taste were increased with increased trehalose in the sensory attribute difference test. Acceptance test showed Yanggeng with 60% trehalose and 40% sucrose obtained the highest scores on flavor, taste and overall acceptability. During storage in refrigerator, Yanggeng sweetened with higher % of trehalose showed significantly higher moisture content, and lower syneresis and hardness than the control sweetened with only sucrose. The results of the sensory test showed that 60% trehalose Yanggeng was the highest in flavor, after taste, and overall acceptability.

Estimation of Critical Chloride Content for Corrosion of Reinforcing Steel in Concrete by Field Exposure Experiment (현장 폭로실험에 의한 콘크리트 중 철근의 부식 임계 염화물량 평가)

  • Yu, Kyung-Geun;Bae, Su-Ho;Park, Jae-Im;Lee, Kwang-Myong;Kim, Jee-Sang
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2008.04a
    • /
    • pp.585-588
    • /
    • 2008
  • To predict the service life of reinforced concrete structures exposed to chloride environment, quantitative measures of material properties such as the critical chloride content for corrosion in concrete and the diffusion coefficient of chloride ions of concrete and the surface chloride content of the concrete are essential. However, it should be noted that they are influenced by several factors such as concrete mix proportions, cement type, and environmental conditions, etc. Thus, the purpose of this research is to estimate more actually the critical chloride content for corrosion of the reinforcing steel in concrete by field exposure experiment. For this purpose, the prism concrete test specimens were made for water-cement(W/C) ratios of 31%, 42%, 50%, and 70%, and then the field exposure experiment for them were conducted at Youngduk of the east coast for about 3 years. During the test, corrosion monitoring by half cell potential method was carried out to detect the time to initiation of corrosion for test specimens and its chloride content was evaluated by breaking the concrete test specimens when corrosion of the reinforcing steel in concrete was perceived. It was observed from the test results that the critical chloride content for corrosion of reinforcing steel in concrete would be dependent on W/C ratio and almost irrespective of concrete cover.

  • PDF

A study on the Characteristic of Waste Ground Rubber Tire Powders with Pre-treatment Process for Recycling (전처리 공정에 따른 폐타이어 재생 고무분말의 특성연구)

  • Park, Jongmoon;An, Ju-Young;Park, Jin-Eui;Bang, DaeSuk;Kim, Bong-Suk;Oh, Myung-Hoon
    • Resources Recycling
    • /
    • v.24 no.2
    • /
    • pp.55-61
    • /
    • 2015
  • In this study, mechanical properties of waste ground rubber tire powder were investigated to evaluate the influence of pre-treatment process for recycling. The tensile test, fracture test and morphology observation were carried out using various kinds of waste ground tire powders, which were produced by grinding and devulcanization process, respectively. As a results, it was found that the produced rubber powder through grinding process increased its tensile strength and elongation with decreasing particle size because of decreasing surface area. Devulcanized rubber powder also increased its tensile strength and elongation by de-crosslink with sulfur. It could be also suggested that devulcanization treatment after grinding process was more efficient recycling process for both increasing tensile property and fracture elongation of waste ground rubber tire powders.