• Title/Summary/Keyword: 표면물성

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Synthesis of Ceramide Nanoemulsion by High-Pressure Homogenizer and Evaluation of Its Stability (고압 균질기를 이용한 세라마이드가 함유된 나노에멀젼 제조 및 안정성 평가)

  • Hidajat, Marcel Jonathan;Noh, Jongho;Park, Jongbeom;Hong, Jaehwa;Kim, Hyeonhyo;Jo, Wantaek
    • Korean Chemical Engineering Research
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    • v.58 no.4
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    • pp.530-535
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    • 2020
  • A ceramide-containing nanoemulsion was synthesized by using a High-Pressure Homogenizer (HPH) to observe its changes in properties and long-term stability. The droplet size, droplet distribution and zeta potential of nanoemulsion were examined by varying the pressure and the number of passes of the HPH. The increase in HPH pressure and number of passes decreased the average droplet size and made the nanoemulsion more uniform. However, beyond certain operating condition, the recombination between the droplets was confirmed due to droplet surface energy and emulsifier. This study also shows that the decrease in droplet size increased the nanoemulsion viscosity although only minimal changes occurred in the zeta potential. The formed nanoemulsion was then tested for its stability by storing it at 25 and 45 ℃ for 28 days. During the first week, the average droplet size increased due to recombination and then subsequently remained constant. We confirmed that ceramide nanoemulsion for industrial application could be synthesized by using HPH.

The Phenomenon of the Slag Foaming and the Result of using Various Slag Deforming Agents in the Steelmaking Converter (제강(製鋼) 전로(轉爐) 정연시(精鍊時) 슬래그 폼(Slag Foam)발생(發生) 현상(現像) 및 진정제(鎭靜劑) 종류(種類)에 따른 사용효과(使用效果))

  • Chun, Sang-Ho;Song, Choong-Ok;Ban, Bong-Chan
    • Resources Recycling
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    • v.15 no.2 s.70
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    • pp.18-23
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    • 2006
  • Foaming of slag is a thermodynamically unstable phenomenon and has significant effects in iron and steelmaking processes. For better recycling method of pulp sludge, the application as an defoaming agent during steelmaking process was adopted and tested. The forming machine has been modified in order to produce the briquettes, which are made of pulp sludge and slag with different weight ratio. Influencing factors on the foaming phenomena have been studied and tested for better understanding of foaming phenomena. Experiments were carried out with $CaO-FeO-SiO_2$ based slags with Ar gas injection and addition of coke particles. The slag basicity and (%FeO) contents adapted as major factors to treasure foaming tendency of the slag system. It was found that foam index (${\Sigma}$) gradually decreased as both the basicity and the (FeO) content increase. Four kinds of antifoaming agent such as aluminium dross, cokes, rice bran and pulp sludge with steelmaking slag have been tested in actual process. Aluminium dross was the most effective, and pulp sludge with steelmaking slag also showed the desired results.

Effect of Dispersant Contents on the Dispersity of Conductive Carbon-black and Properties of Screen-printed Source-drain Electrodes for OTFTs (분산제 함량에 따른 전도성 카본블랙의 분산 특성 및 스크린 인쇄된 OTFTs용 소스-드레인 전극 물성)

  • Lee, Mi-Young;Bae, Kyung-Eun;Kim, Seong-Hyun;Lim, Sang-Chul;Nam, Su-Yong
    • Polymer(Korea)
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    • v.33 no.5
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    • pp.397-406
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    • 2009
  • We have fabricated source-drain electrodes for OTFTs using a screen-printing technique with carbon-black pastes as conductive paste. And effects of dispersants contents (SOP 10-40%) on the dispersity of carbon-black pastes and characteristics of screen-printed source-drain electrodes for OTFTs using two types of dispersants (DB-2150, DB-9077) were investigated. As contents of both dispersants were increased the dispersity of carbon-black mill-bases was improved, whereas the carbon-black pastes exhibited different dispersion characteristics. For the case of DB-2150, the dispersity of the pastes was improved with increasing dispersant content and the storage modulus G' in their rheology characteristics were reduced. But, for the DB-9077, the storage modulus G' of pastes were increased with dispersant content due to the flocculated network structure formed by interactions among carbon-black powders and dispersants. But, since this flocculated network structure of the pastes using DB-9077 resulted in the conduction path of carbon-black structures, the conductivities of screen-printed electrodes and mobilities of the OTFTs with them were better than those using pastes with DB-2150.

A Study on the Basic Properties of Wood Impregnated with Inorganic Compounds (무기물처리 목재의 기초물성에 관한 연구)

  • Kim, Geon Hyoung;Oh, Tae Kyung;Lee, Weon Hee
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.4
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    • pp.15-21
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    • 2006
  • Composite materials were prepared by impregnating water glass into the wood, followed by soaking in solutions of boric acid or phosphoric acid. The effects of these treatments on the physical and mechanical properties of the specimens and especially on its heat resistance were investigated. 1) Weight Percent Gain (WPG)s increased with increase of concentrations of water glass. However, there was little relationship between treatment temperatures and WPG. Generally, WPGs of double treated specimens were higher than single treated ones. 2) Percent shrinkages in each directions of the specimens treated with water glass had higher value than other specimens. Percent shrinkages of the specimens treated with boric acid or phosphoric acid were decreased as compared with untreated specimen. However, the specimens treated with water glass or phosphoric acid showed very high hygroscopicity. 3) The bending strengths of all specimens treated inorganic substances were slightly decreased. However, the values of compressive strength and hardness of most specimens treated with inorganic substances increased or similar to that of untreated specimen except for a phosphoric acid treated specimens. 4) The specimens had good heat resistance. Weight losses of all specimens treated inorganic substances were about 50~70%. In particular, the specimens treated at $300^{\circ}C$ and $400^{\circ}C$ almost kept their shapes.

최소가공 과일의 갈변저해를 위한 저해제의 탐색

  • 박연주;최소영;김영언;문광덕
    • Proceedings of the Korean Society of Postharvest Science and Technology of Agricultural Products Conference
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    • 2003.04a
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    • pp.119.1-119
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    • 2003
  • 단체 급식의 증가와 더불어 편의식품을 선호하는 소비 경향에 맞추어 최소가공한 과일의 갈변저해를 위한 저해제를 탐색하였다. 실험에 사용한 과일은 배와 감으로 각각 박피하여 속심을 제거한 후 배는 8조각으로 절단하고 감은 1~2cm 두께로 slice 하였다. 저해제는 1% ascorbic acid, citric acid, NaCl, MgCl$_2$, CaCl$_2$, oxalic acid, EDTA, raffinose, salicylic acit, sporix를 사용하였다. 또한 열수 추출한 오약, 계피, 황기, 당기, 건칡, 진피, 천궁, 감초 등도 저해제로 사용하였다. 최소가공한 과일은 저해제에 3분간 침지한 후 물기를 제거하고 tray에 포장하여 실온에서 저장하면서 colorimeter를 이용하여 갈변도의 변화를 측정하였다. 갈변 정도를 나타내는 $\Delta$E 는 시간의 경과에 따라 점차 감소하는 경향을 보였으나 배의 경우 변화 정도가 크지 않았다. NaCl, MgCl$_2$, CaCl$_2$를 처리한 배의 갈변 정도가 가장 적었다. cysteine을 처리한 구에서는 황화합물 냄새가 났다. 또한 oxalic acid를 처리한 구에서는 연화가 빠르게 일어났으며 저장 시간이 경과함에 따라 수분이 용출되었다. 한약재는 자체 색으로 인해 배의 색변화를 증가시켰으며 이취가 발생했다. 또한 저장 시간이 경과함에 따라 건조가 빠르게 일어나 관능적으로도 좋지 않은 결과를 나타냈다. 감에서는 CaCl$_2$, MgCl$_2$를 처리한 구에서 색의 변화가 가장 적었으며 cysteine은 색변화는 적었으나 배의 경우과 같이 이취가 발생하였다. 한약제는 계피와 진피를 처리한 감에서 색의 변화를 저해하는 효과를 보였다.를 처리하였을 경우 당귀, 천문동을 처리한 구에서 효과를 보였다. oxalic acid는 갈변저해에는 효과적이었으나 시간이 경과함에 따라 수분의 용출이 증가하였으며 물성의 변화도 컸다. 또한 ZnCl$_2$를 처리한 구에서는 이취 발생과 수분 용출이 컸으며 색의 변화도 컸다.내었다. 고온 단시간 처리구의 경우 저온 장시간 처리구와는 달리 저장 1일 후부터 그 농도가 다소 상승되었다가 다시 감소는 경향을 보였다. 한편 열처리하여 냉각시킨 직후 및 저장1주 후 사과의 pH, 산도, 당도, 경도, 과육의 갈변도 등을 조사하였던 바 대조구 및 처리구간에 일부 항목에 있어서는 약간의 차이를 나타내었다. 대치할 수 있을 것이라고 사료된다. 수분함량은 기계적 검사보다 관능검사와 더욱 높은 상관관계를 나타냈다.내었다. 항균활성이 우수한 생약재를 농도별로 활성을 조사한 결과, 물 추출물과 10% Ethanol 추출물 모두 낮은 농도에서도 우수한 항균활성을 나타내었다.취와 함께 점질성 갈변물질이 생성되었다. 이와 같은 결과로 볼 때, BAAG의 처리는 BAAC의 경우보다 가격은 저렴하면서도 항균력은 우수한 천연 항균복합제재로써 농산물 식품원료에 적용하여 선도유지 기간을 연장할 수 있는 효과를 기대할 수 있었다. 과일 등의 포장제로서 이용할 가능성을 확인하였다.로 [-wh] 겹의문사는 복수 의미를 지닐 수 없 다. 그러면 단수 의미는 어떻게 생성되는가\ulcorner 본 논문에서는 표면적 형태에도 불구하고 [-wh]의미의 겹의문사는 병렬적 관계의 합성어가 아니라 내부구조를 지니지 않은 단순한 단어(minimal $X^{0}$ elements)로 가정한다. 즉, [+wh] 의미의 겹의문사는 동일한 구성요 소를 지닌 병렬적 합성어([$[W1]_{XO-}$ $[W1]_{XO}$ ]

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Accuracy of Digital Impression Made from Different Elastomeric Impression Materials: Three-Dimensional Superimpositional Analysis (치과용 탄성 인상재를 기반으로 채득된 디지털 모형의 정확성 연구: 3차원 중첩 분석)

  • Kim, Ki-Baek;Jung, Jae-Kwan;Kim, Jae-Hong
    • Journal of dental hygiene science
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    • v.14 no.2
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    • pp.94-100
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    • 2014
  • The purpose of this study was to evaluate the accuracy of digitized elastomeric impression materials of crown abutment, using non-contact white light scanner and virtual three-dimensional superimpositional analysis. The stone models and impressions were digitized white light scanner to create three-dimensional surface models. Stone models were used as CAD reference model (CRM). The resulting point clouds (ASC file) from digitization of impressions using converting software. Discrepancies between the points in the point clouds and CRM were measured by superimpositional software. Mean and standard deviation of values of discrepancies were analyzed by one-way ANOVA and multiple comparison (${\alpha}=0.05$). The mean discrepancy between the impressions for the extra-light body (XLB), light body (LB), and heavy body (HB) group were $5.10{\pm}1.45{\mu}m$, $6.30{\pm}1.87{\mu}m$, $9.80{\pm}1.52{\mu}m$, respectively. The different impression materials affected the digitization of impressions significantly (p<0.05). As a result, digitization of elastomeric impression materials on dental scanner was influenced by material sort.

Effect of Preparation Conditions of PAN-based Carbon Fibers on Electrochemical Characteristics of Rechargeable Lithium ion Battery Anode (PAN계 탄소섬유 제조조건에 따른 리튬이온 이차전지 음극의 전기화학적 특성)

  • An K. W.;Lee J. K.;Lee S. W.;Kim Y. D.;Cho W. I.;Ju J. B.;Cho B. W.;Park D. G.;Yun K. S.
    • Journal of the Korean Electrochemical Society
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    • v.2 no.2
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    • pp.81-87
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    • 1999
  • Poly-acrylonitrile (PAN) based carbon fibers were stabilized under various tensions in the presence of air at about $200^{\circ}C$ and sequentially carbonized under some different gas environments in the range of 700 to $1500^{\circ}C$. The prepared carbon fibers were used for rechargeable lithium ion battery anode to investigate preparation parameters effects on electrochemical characteristics. It was found that the tension during stabilization, carbonization temperature and gas atmospheres affect the carbon fiber properties such as conductivity, mechanical strength, surface morphology and diffusion coefficient of lithium ion, which are closely related to the on electrolchemical properties as well as the charge/discharge characteristics.

Manufacturing and Mechanical Properties of Epoxy Fibers Spinning using Anhydride and Amine Hardeners (산 무수물계 및 아민계 경화제를 이용한 열경화성 에폭시 섬유 제조 및 물성)

  • Shin, Pyeong-Su;Kim, Jong-Hyun;Park, Ha-Seung;Baek, Yeong-Min;Kwon, Dong-Jun;Park, Joung-Man
    • Composites Research
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    • v.29 no.6
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    • pp.408-413
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    • 2016
  • Commonly-used polymers are manufactured as versatile forms. Furthermore, continuous polymer fibers are recently manufactured using nylon or aramid fiber. One of common epoxy was also used to make polymer fibers. Bisphenol-A type was used as base epoxy whereas amine and anhydride were used as hardeners. Epoxy fibers was cured by stepping up the temperature to maintain the shape of epoxy fiber. Surface energy was measured to confirm the degree of interfacial adhesion by modified static contact angle method. After mechanical properties were measured via fiber tensile test, the evaluation of fiber fracture was proceeded. Tensile strength of epoxy fiber using amine type hardener was higher as 138 MPa than anhydride case as 70 MPa. Fractured surface exhibited different failure patterns at the cross-section.

Preparation and Cleaning Properties of Environmental Friendly Semi-Solvent Cleaning Agents (친환경 준용매계 세정제의 제조와 그 세정 특성)

  • Kang, Doo Whan;Ha, Soonhyo;Han, Jongpil;Lee, Byoung Chul;Yeo, Hak Gue;Bae, Jang Soon;Yeum, Kou-Sul
    • Applied Chemistry for Engineering
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    • v.18 no.2
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    • pp.188-193
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    • 2007
  • Semi-solvent type cleaning agents were prepared by mixing naphthenes, natural terpene oil, surfactant and water, and measured their physical properties. And also, cleaning efficiency for flux and grease was measured by gravimetric method. By measuring the physical properties, pH for cleaning agents were 6.0~6.7, surface tension, 27.4~28.4 dyne/cm, and wetting index, 8.65~12.46 (with water), 11.99~17.43 (without water). The cleaning agent composed of naphthene, 30 wt%, natural terpene oil, 45 wt%, surfactant, 13 wt%, co-surfactant, 12 wt%, and water, 0 wt% had the largest wetting index, and shown the most effective cleaning properties for flux (98.66%) and grease (93.44%). The conductivity with $0.5{\sim}0.9{\mu}s/cm$ to the cleaning agent containing small amount of water was found to form W/O type microemulsion.

Effect of Amine Oxide Zwitterionic Surfactant on Characteristics of Liposome (아민 옥사이드 양쪽성 계면활성제 첨가가 리포좀 특성에 미치는 영향에 관한 연구)

  • Mo, DaHee;Lee, SuMin;Lee, JuYeon;Han, DongSung;Lim, JongChoo
    • Applied Chemistry for Engineering
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    • v.27 no.3
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    • pp.291-298
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    • 2016
  • In this study, zwitterionic surfactants were added to liposome systems at different pH conditions to understand the effect of surfactants on liposome characteristics. For this purpose, amine oxide surfactants having different hydrocarbon chain lengths were synthesized and the structure of the resulting product was elucidated by using $^1H$ NMR, $^{13}C$ NMR, and FT-IR. In addition, the physical properties of newly synthesized surfactants such as critical micelle concentration (CMC), surface tension and isoelectric point were measured. The stability characteristics of liposome systems including average particle sizes and zeta potentials were measured by varying pH and hydrocarbon chain lengths of an amine oxide surfactant. Effects of the pH and hydrocarbon chain length of an amine oxide surfactant on fluidity of a liposome membrane were also examined by measuring the deformability and the binding degree between the surfactant and liposome.