• Journal of the Korean Applied Science and Technology
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• v.37 no.6
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• pp.1619-1626
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• 2020

In this study, the physical properties of water-dispersible polyurethane resins synthesized with polyammonium phosphate and HMDI were studied by coating film samples and full-grain surfaces. Solvent resistance was found to be unchanged in all samples, and in terms of tensile strength, DPU-AP3 (1.887 kgf/㎟) containing the most ammonium polyphosphate showed the lowest physical properties. The elongation rate was measured as 54 8% in the sample containing a large amount of ammonium polyphosphate. Abrasion resistance was measured as 548 mg.loss of a sample containing a lot of ammonium polyphosphate, and it was confirmed that the physical properties of the blended resin of ammonium polyphosphate and water-dispersible polyurethane were changed.

• Composites Research
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• v.33 no.4
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• pp.177-184
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• 2020

Flame retardant(FR) clothes prohibit additional fire diffusion and make the personnel do their tasks without a hitch in a flammable environment. The existing FR clothes, however, are heavy and give high thermal fatigue. Therefore, it is strongly demanded to develop a light, convenient, and eco-friendly clothes. Recently, many works have been reported to make FR fabrics with phosphorus compounds, but their performance could not satisfy the specified criteria in appraisal standards of domestic and American FR clothes or combat uniforms. In this paper, two kinds of phosphorus compounds were applied to cotton fabric. Graphene oxide functionalized with a phosphorus-rich deep eutectic solvent and ammonium polyphosphate were coated on cotton fabric by eco-friendly padding procedure. The coated fabrics were analyzed with thermogravimetric analysis, vertical flame resistance test(ASTM D6413), cone calorimeter test(ISO 5660-1), and method of test for limited flame spread(ISO 15025). It was revealed that the as-made cotton with those two materials simultaneously had better flame resistance than the cottons with each one. Furthermore, an additional coating for hydrophobicity on the FR cotton was tried for better washing fastness.

• Journal of the Korean Applied Science and Technology
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• v.38 no.6
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• pp.1678-1686
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• 2021

In this study, we prepared phosphorous flame-retarding coating solutions by mixing triphosphate (3 phosphonate), phytic acid (6 phosphonate), or ammonium polyphosphate (10 phosphonate) with boric acid as a crosslinking agent and acryl resin binder. Prepared phosphorous flame-retarding coating solutions were coated onto non-woven fabrics, respectively, to obtain high flame-retarding effects. These prepared flame-retardant non-woven fabrics were evaluated using smoke density standard test (ASTM E662), limit oxygen index standard test (ISO E622), and vertical burning standard test (UL 94). Their flame-retarding effects were affected by the number of phosphonate groups. Regardless of natural or synthetic binder resins, their effects showed the following order: ammonium polyphosphate > phytic acid > triphosphate. Natural hydrocarbon compounds were also examined to determine the possible retardancy of binder resins. Results showed that natural hydrocarbon binder resins could be used for preparing fire-retardant nonwoven fabrics.

• Journal of Korean Society of Water and Wastewater
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• v.33 no.4
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• pp.291-297
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• 2019

Phosphorus is a vital resource for sustaining agriculture and nutrition, but a limited non-renewable resource. Thus, the recovery of phosphorus from waste activated sludge(WAS) was attempted by microwave heating and magnesium ammonium phosphorus(MAP) crystallization. Polyphosphate-accumulating organisms(PAOs) in WAS release phosphate from the cell when they are exposed to high temperature environments. Microwave heating caused phosphorus and ammonia to release from WAS. The amount was increased with increasing temperature, showing that 88.5% of polyphosphate present in the cells were released in the form of phosphate at $80^{\circ}C$. A similar result was also observed in the release of ammonia. On the other hand, both phosphorus and ammonia were crystallized with magnesium, and then was harvested as MAP. Phosphorus recovery rate reached almost 97.8%, but the ammonia was about 13.4%. These results cleary indicate that phosphorus could be recovered from WAS using a physiological trait of PAOs. Heavy metal analyses also show that the MAP crystal is useful and safe as a phosphorus fertilizer.

• Fire Science and Engineering
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• v.28 no.5
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• pp.58-63
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• 2014

Fire-resistance paints are supposed to become intumescent and diminish heat transfer along the steel frames in case of a fire. If unsatisfactory fire-resistance paints which do not satisfy their standard specification are used, it may result in a severe disaster. Because satisfactory fire-resistance paints are hardly discriminated from the unsatisfactory ones by a simple visual inspection, more reliable and convenient onsite evaluation methods are necessary. Here we report the preliminary study result on the fire safety testing method for fire-resistance paints using an X-ray analysis method. It was found that the existence and quantity of effective constituents in fire-resistance paints can be detected by the X-ray analysis method. X-ray fluorescence (XRF) analyses showed that P and Cl elements are much more enriched in fire-resistance paints, compared to normal paints. X-ray diffraction (XRD) analyses showed that ammonium polyphosphate is present as the main crystalline material in fire-resistance paints, but absent in normal paints. The X-ray analysis method is expected to be used for the onsite inspection of fire-resistance paints with the upcoming availability of portable XRF and XRD instruments.